Professional Documents
Culture Documents
Project
Name: Jaya Lakshmi
Passport number: k0586741
Lecturer name: Mr. An Chu
Table of content
Nu.
Subject
Page
1.
Introduction
2.
3.
15
References
20
Introduction
The
aftermaths of atomic bomb , Fat Man and Little Boy on Nagasaki and
Hiroshima, Japan are devastating. Two largest cities were destroyed in the
blink of eyes. Bodies without complete parts, organs, and unidentified
corpses were scattered on the Ground Zero on August 6 and 9, 1945. The
massive killing as the closure to the Pacific War of Allies and the Empire of
Japan that had entered fourth year during the time. This project which
consumes merely six year from October 1939 to August 1945 is a triumph
due to the consent given by the 32nd President of United States, Franklin
Delano Roosevelt or known as FDR for a research on Uranium to be
conducted. Despite of the consequences, the Manhattan Project is the gate
to the modern warfare and the victory of developing nuclear physics. The
gathering of Germany scientist who fled from their country and influence of
Albert Einstein makes the process smoother and successful. This paper will
enlighten on the Manhattan Project itself, the scientific researches carried
out as well as the positive impacts of this researches on nuclear physics.
Briefly, nuclear physics is the study of constituents and interaction of atomic
nuclei. In nuclear physics, a nuclear reaction is a process in which two nuclei or
nuclear particles collide, to produce different products than the initial particles. The
Manhattan Project is the winner of the battlefield and provides U.S a short lived
atomic monopoly.
Despite Bush's assertion that a bomb could probably be produced by 1945, he and
the other principals associated with the project recognized the magnitude of the
task before them. For any large organization to take laboratory research into design,
construction, operation, and product delivery in two-and-a-half years (from early
1943 to Hiroshima) would be a major industrial achievement. Whether the
Manhattan Project would be able to produce bombs in time to affect the current
conflict was an open question as 1943 began. (Obvious though it seems in
retrospect, it must be remembered that no one at the time knew that the war would
end in 1945 or who the remaining contestants would be if and when the atomic
bomb was ready for use).
10
Rutherford, Einstein, and Bohr proved to be wrong in this instance, and the proof
was not long in coming. Beginning in 1934, the Italian physicist Enrico Fermi began
bombarding elements with neutrons instead of protons, theorizing that Chadwick's
uncharged particles could pass into the nucleus without resistance. Like other
scientists at the time, Fermi paid little attention to the possibility that matter might
disappear during bombardment and result in the release of huge amounts of energy
in accordance with Einstein's formula, E= mc2, which stated that mass and energy
were equivalent. Fermi and his colleagues bombarded sixty-three stable elements
and produced 37 new radioactive ones. They also found that carbon and hydrogen
proved useful as moderators in slowing the bombarding neutrons and that slow
neutrons produced the best results since neutrons moving more slowly remained in
the vicinity of the nucleus longer and were therefore more likely to be captured.
One element Fermi bombarded with slow neutrons was uranium, the heaviest of the
known elements. Scientists disagreed over what Fermi had produced in this
transmutation. Some thought that the resulting substances were new "transuranic"
elements, while others noted that the chemical properties of the substances
resembled those of lighter elements. Fermi was himself uncertain. For the next
several years, attempts to identify these substances dominated the research
agenda in the international scientific community, with the answer coming out of
Nazi Germany just before Christmas 1938.
11
The radiochemists Otto Hahn and Fritz Strassmann were bombarding elements with
neutrons in their Berlin laboratory when they made an unexpected discovery. They
found that while the nuclei of most elements changed somewhat during neutron
bombardment, uranium nuclei changed greatly and broke into two roughly equal
pieces. They split and became not the new transuranic elements that some thought
Fermi had discovered but radioactive barium isotopes (barium has the atomic
number 56) and fragments of the uranium itself. The substances Fermi had created
in his experiments, that is, did more than resemble lighter elements; they were
lighter elements. Paramountly, the products of the Hahn-Strassmann experiment
weighed less than that of the original uranium nucleus, and herein lay the primary
significance of their findings. For it followed from Einstein's equation that the loss of
mass resulting from the splitting process must have been converted into energy in
the form of kinetic energy that could in turn be converted into heat. Calculations
made by Hahn's former colleague, Lise Meitner, a refugee from Nazism then staying
in Sweden, and her nephew, Otto Frisch, led to the conclusion that so much energy
had been released that a previously undiscovered kind of process was at work.
Frisch, borrowing the term for cell division in biology-binary fission-named the
process fission.For his part, Fermi had produced fission in 1934 but had not
recognized it.
Chain Reaction
12
14
with higher energy. The crucial question was whether uranium-235 could fission with
fast neutrons in a chain-reacting manner, but without enriched samples of uranium235, scientists could not perform the necessary experiments.
The Uranium Committee
President Roosevelt responded to the call for government support of uranium
research quickly but cautiously. He appointed Lyman J. Briggs, director of the
National Bureau of Standards, head of the Advisory Committee on Uranium, which
met for the first time on October 21, 1939. The committee, including both civilian
and military representation, was to coordinate its activities with Sachs and look into
the current state of research on uranium to recommend an appropriate role for the
federal government. In early 1940 the Uranium Committee recommended that the
government fund limited research on isotope separation as well as Fermi's and
Szilard's work on chain reactions at Columbia.
Isotope Separation
Scientists had concluded that enriched samples of uranium-235 were necessary for
further research and that the isotope might serve as a fuel source for an explosive
device; thus, finding the most effective method of isotope separation was a high
priority. Since uranium-235 and uranium-238 were chemically identical, they could
not be separated by chemical means. And with their masses differing by less than
one percent, separation by physical means would be extremely difficult and
expensive. Nonetheless, scientists pressed forward on several complicated
techniques of physical separation, all based on the small difference in atomic weight
between the uranium isotopes.
The Electromagnetic Method
The electromagnetic method, pioneered by Alfred O. Nier of the University of
Minnesota, used a mass spectrometer, or spectrograph, to send a stream of charged
particles through a magnetic field. Atoms of the lighter isotope would be deflected
more by the magnetic field than those of the heavier isotope, resulting in two
streams that could then be collected in different receivers. The electromagnetic
15
method as it existed in 1940, however, would have taken far too long to separate
quantities sufficient to be useful in the current war. In fact, twenty-seven thousand
years would have been required for a single spectrometer to separate one gram of
uranium-235.
Gaseous Diffusion
Gaseous diffusion appeared more promising. Based on the well-known principle that
molecules of a lighter isotope would pass through a porous barrier more readily than
molecules of a heavier one, this approach proposed to produce by myriad
repetitions a gas increasingly rich in uranium-235 as the heavier uranium-238 was
separated out in a system of cascades. Theoretically, this process could achieve
high concentrations of uranium-235 but, like the electromagnetic method, would be
extremely costly. British researchers led the way on gaseous diffusion, with John R.
Dunning and his colleagues at Columbia University joining the effort in late 1940.
Centrifuge
Many scientists initially thought the best hope for isotope separation was the highspeed centrifuge, a device based on the same principle as the cream separator.
Centrifugal force in a cylinder spinning rapidly on its vertical axis would separate a
gaseous mixture of two isotopes since the lighter isotope would be less affected by
the action and could be drawn off at the center and top of the cylinder. A cascade
system composed of hundreds, perhaps thousands, of centrifuges could produce a
rich mixture. This method, being pursued primarily by Jesse W. Beams at the
University of Virginia, received much of the early isotope separation funding.
Liquid Thermal Diffusion
The Uranium Committee briefly demonstrated an interest in a fourth enrichment
process during 1940, only to conclude that it would not be worth pursuing. This
process, liquid thermal diffusion, was being investigated by Philip Abelson at the
Carnegie Institution. Into the space between two concentric vertical pipes Abelson
placed pressurized liquid uranium hexafluoride. With the outer wall cooled by a
circulating water jacket and the inner heated by high-pressure steam, the lighter
16
isotope tended to concentrate near the hot wall and the heavier near the cold.
Convection would in time carry the lighter isotope to the top of the column. Taller
columns would produce more separation. Like other enrichment methods, liquid
thermal diffusion was at an early stage of development.
17
Fission begins with the high-energy collision of neutrons with the nucleus of another
atom. Protons cannot partake in nuclear bombardment because of the electrostatic
repulsion between positively-charged protons and nuclei. For fission to proceed, a
neutron fired at the atom must fuse with the nucleus, producing a less-stable
isotope. The heavy atom, chemically volatile, will split into two stable atoms,
discharge neutrons, and generate energy (in the form of Gamma radiation). The
neutrons released are free to collide and fuse with nuclei of other nearby atoms a
chain reaction ensues, progressing exponentially throughout the sample of atoms,
releasing more and more heat radiation. It is this constant amplification of energy
that constitutes the devastating power of an atomic weapon.
If every atom were fissionable, there would be no stability to matter and the world
would be an uninhabitable chaos of energy transformations. Thus, only certain
isotopes of few atoms will undergo a fissile chain reaction. Nobel physicist Neils
Bohr discovered that Uranium, the ninety-second element, is an example of a
fissionable atom. The predominant form of uranium has a mass number of 238 and
is relatively stable; U-235, a rare isotope, easily undergoes nuclear fission and can
sustain a chain reaction. If a neutron traveling at adequate velocity and the
appropriate angle collides with a uranium-235 nucleus, the unstable nucleus
absorbs the neutron, consequently increasing to an exceedingly unstable state.
Instantly the U-236 splits into two atoms of different elements, emitting 2 neutrons
that carry on the chain reaction, and liberating large quantities of gamma radiation.
Subsequent to John Dunning and Eugene Booths successful separation of uranium
235 from uranium 238 in 1941 , uranium became the leading example for fission
research. As scientists probed further into the capabilities of fission, they began to
visualize, as Fermi did, the awesome destructive potential of only a minute mass of
uranium 235. Thus, the dream of a weapon with unmitigated atomic power was
spawned.
With this basic knowledge of atomic chemistry and the motivation of a world crisis,
the Manhattan project began in 1942. Two prominent challenges delayed the
successful unleashing of nuclear energy: processing of sufficient fissionable
material, and the actual design of a nuclear bomb that would maintain and
18
maximize a fissile chain reaction. Dunning and Booth managed to separate the two
isotopes of uranium before the institution of the Manhattan project, proving that it
was indeed possible. But the level at which their research was performed was purely
scientific; a project tasked with ending a world war required much more intensive
and efficient processing. Additionally, no one had any experience constructing a
dimensionally-feasible nuclear reactor in deployable size.
As the Manhattan team quickly learned, the relative abundance of uranium 235 was
not only extremely small, but when found, uranium ore was nearly impossible to
purify into U-235. Natural uranium ore is comprised of a mixture of isotopes 235 and
238. Typically, one percent of the mass of uranium ore being considered is
composed of the unstable isotope, while the rest is relatively useless U238.Therefore, to develop the prophesied weapon, engineering innovations were
essential. Ernest O. Lawrence of the University of California, Berkeley developed the
first technique to isolate a practical amount of uranium 235, using a modified mass
spectrometer.Lawrences method dealt with the electromagnetic properties of
atoms, an integration of chemistry and physics.
Uranium 235 is a lighter isotope than Uranium 238. Thus, when equal physical
forces act on atoms of U-235 and U-238, the isotopes will behave simply as two
different masses. Therefore, as Newtons laws describe, the force acting on the
lighter mass will show greater affect on the motion of the mass than the force
acting on the heavier mass. In Lawrences apparatus, the magnetic force exerted by
an electromagnetic arch attracted the electrically charged portions of atoms, and
thus, uranium atoms traveled along the raised arc. Uranium 235 atoms, naturally
lighter than the stable isotope, would pass closer to the magnetic tract than the
heavier U-238 atoms, and could thus be collected. To mobilize the uranium atoms
into gaseous particles, fluorine gas was circulated over solid uranium ore, creating
uranium tetrachloride gas. The gaseous particles were then passed across the arc
multiple times, each trial gaining a more purified sample of uranium 235
tetrachloride.
To Lawrences chagrin, his method of uranium purification proved largely inefficient.
Due to high maintenance costs and the time-consuming nature of the process, only
19
one gram of uranium 235 was harvested after millions of dollars spent in production
and repairs. Lawrences design was quickly abandoned.
General Leslie Groves, director of the Manhattan Project, purchased land in Oak
Ridge, Tennessee to pursue another proposed method of uranium separation.
Centered on the theory of gaseous diffusion of uranium hexafluoride, principles of
chemistry and physics were again assimilated in an attempt to accomplish a feat of
engineering. Similarly, the technique Groves pursued dealt with the motions of
particles of different masses. When contained in a porous vessel, gaseous particles
will randomly collide and bounce until passing through a pore in the container a
process known as effusion. At constant temperature, all gaseous particles have
equal kinetic energies, and therefore, through the properties of thermodynamics,
less-massive particles move with higher velocity than heavier particles. When
applied to effusion, lighter gases travel across a porous membrane faster than
heavier gases. Uranium 235 hexafluoride, the lighter of the two isotopic gases,
diffuses faster than U-238 hexafluoride. Over intervals of time, Groves concluded,
this process could be used to separate uranium isotopes.
The foremost problem with this technique was the quality of materials used in
construction. The masses of the two isotopes of uranium are so similar that the
diffusion must be run in completely airtight conditions. Grease could not be used to
seal the miles of tubing, however, because uranium hexafluoride reacts so quickly
with organic compounds. Thus, materials engineering was incorporated to fabricate
new plastics to assemble the contraption. The engineering efforts resulted in an
effective material known as Teflon. Higher quality porous membranes were essential
to the process as well. The final product was a $100,000,000 facility consisting of
thousands of consecutive membranes and diffusion tanks across miles of Teflon
tubing an engineering masterpiece. Due to restrictions of the budget, however,
construction on the Oak Ridge plant was only carried far enough to produce a
mixture of the two isotopes, half stable, half unstable. This end product was
subsequently fed into other series of separation techniques, becoming the main
source of U-235.
20
References
1. Rhodes, R, The Making of the Atomic Bomb, 1986, pp. 461
2. Rhodes, R, The Making of the Atomic Bomb, 1986, pp. 275
3. 60 Years Ago, Bulletin of the Atomic Scientists, Vol. 58, No. 6, May/June
2003,
pp. 54
4. Bracchini, M. A., The History and Ethics Behind the Manhattan Project, April
30, 1997, http://www.me.utexas.edu/~uer/manhattan/project.html
5. Rhodes, R, The Making of the Atomic Bomb, 1986, pp. 492-494
6. Rhodes, R, The Making of the Atomic Bomb, 1986, pp. 495
21
22