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NICKEL SULPHAMATE
Nickel Sulphamate is offered as a purified concentrate; which has been treated to remove both organic and
inorganic impurities. It contains no addition agents; therefore it may be used as a base for a new nickel
sulphamate bath, or merely to replenish the nickel content of an existing nickel sulphamate solution.
Nickel Sulphamate offers several advantages over the nickel plating baths.
1.
It is capable of producing stress free deposits than other nickel plating baths.
2.
3.
4.
It is a concentrated liquid.
5.
6.
7.
APPLICATIONS
1.
2.
Electroforming.
Electrotypes and stereotypes.
3.
4.
Electronic components.
5.
Roller coating.
6.
7.
550 g/l
100 g/l
PHYSICAL PROPERTIES
Specific gravity
..
1.30 - 1.34
Density
..
33 - 35 OBe
Colour
..
Green
NICKEL SULPHAMATE
..
75.0 litres
Nickel Chloride
..
1.5 kgs.
Boric Acid
..
3 kgs.
Water
..
..
0.01 to 2 g/l
Cathode movement
..
2-10 gms
Range
g/l
75
75-100
Nickel Chloride
Boric Acid
g/l
g/l
15
30
15-30
26-35
OPERATING CONDITIONS
Density
...
29-31 OBe
Temperature
pH
...
...
40-50 OC
3.5 to 4.5
Current density
...
Anodes
...
...
1:1
Voltage
...
2 to 8
...
103,000 PSI
Internal stress
...
Hardness
...
NICKEL SULPHAMATE
Filtration Agitation :
For best results the bath should be subjected to constant filtration of about 3-4 changes/hr. This will serve
a two fold purpose of cleaning the bath and affording the solution the agitation it requires to assure uniform
deposits.
NICKEL SULPHAMATE
Difficulty in maintainig pH :
Check Boric Acid. Good procedure is to leave an anode bag full of boric acid in the dummying section
of the tank until the boric acid concentration is around 30-35 g/l.
Non-Uniform plate :
Inorganic impurities. Bath should be dummied.
Low rate deposition :
pH low
Current density low
Inorganic impurities
Brittle deposits :
Organic contamination, Carbon treat
pH high.
Equipment :
Tanks
Heaters or heat exchangers
Filters
Control of Bath :
Density and pH provide most of the answers for daily control. An analytical procedure for nickel, chloride
and boric acid is as follows :ANALYSIS OF THE NICKEL SULPHAMATE BATH
Nickel :
1.
2.
3.
4.
Calculations :
ml EDTA X 2.934 =
gms/lit. of Nickel
Boric Acid :
1.
2.
3.
4.
Calculations :
ml of Sodium Hydroxide X 6.184
Chloride determination :
1.
2.
3.
4.
5.
Calculations :
ml of Silver nitrate X 2.378 = gms/lt of Nickel chloride
NICKEL SULPHAMATE
Amps/sq.ft.
.0001
.0003
.0005
.0007
.001
.002
10
12
36
60
84
120
240
20
30
6
4
18
12
30
20
42
28
60
40
120
80
40
15
21
30
60
50
2.4
7.2
12.2
16.7
24
47.7
100
1.2
3.6
6.1
8.4
12
24
Issued on : 9.8.04
Supersedes all earlier
NICKEL SULPHAMATE