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Rabicycle
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Agreatvarietyofphysicalprocessesbelongingtotheareasofquantumcomputing,condensedmatter,atomicandmolecularphysics,andnuclearandparticlephysics
canbeconvenientlystudiedintermsoftwolevelquantummechanicalsystems.Inthiscase,oneoftheeffectsisrepresentedbytheoscillationsbetweenthetwoenergy
levels,asforexample,electronneutrinoemuonneutrinoflavourneutrinooscillations.Inphysics,theRabicycleisthecyclicbehaviourofatwostatequantum
systeminthepresenceofanoscillatorydrivingfield.Atwostatesystemhastwopossiblestates,andiftheyarenotdegenerate(i.e.equalenergy),thesystemcan
become"excited"whenitabsorbsaquantumofenergy.
Theeffectisimportantinquantumoptics,nuclearmagneticresonanceandquantumcomputing.ThetermisnamedinhonourofIsidorIsaacRabi.
Whenanatom(orsomeothertwolevelsystem)isilluminatedbyacoherentbeamofphotons,itwillcyclicallyabsorbphotonsandreemitthembystimulated
emission.OnesuchcycleiscalledaRabicycleandtheinverseofitsdurationtheRabifrequencyofthephotonbeam.
Thismechanismisfundamentaltoquantumoptics.ItcanbemodeledusingtheJaynesCummingsmodelandtheBlochvectorformalism.
Forexample,foratwostateatom(anatominwhichanelectroncaneitherbeintheexcitedorgroundstate)inanelectromagneticfieldwithfrequencytunedtothe
excitationenergy,theprobabilityoffindingtheatomintheexcitedstateisfoundfromtheBlochequationstobe:
,
where istheRabifrequency.
Moregenerally,onecanconsiderasystemwherethetwolevelsunderconsiderationarenotenergyeigenstates.Thereforeifthesystemisinitializedinoneofthese
levels,timeevolutionwillmakethepopulationofeachofthelevelsoscillatewithsomecharacteristicfrequency,whoseangularfrequency[1]isalsoknownastheRabi
frequency.ThestateofatwostatequantumsystemcanberepresentedasvectorsofatwodimensionalcomplexHilbertspace,whichmeanseverystatevector is
representedbytwocomplexcoordinates.
where and arethecoordinates.[2]
.Thebasisvectorswillberepresentedas
and
Allobservablephysicalquantitiesassociatedwiththissystemsare2 2Hermitianmatrices,whichmeanstheHamiltonianofthesystemisalsoasimilarmatrix.
Contents
1Howtoprepareanoscillationexperimentinaquantumsystem
2DerivationofRabiFormulainanNonperturbativeProcedurebymeansofthePaulimatrices
3RabioscillationinQuantumcomputing
4RabioscillationinAmmoniamaser
5Seealso
6References
7Externallinks
Howtoprepareanoscillationexperimentinaquantumsystem
Onecanconstructanoscillationexperimentconsistingoffollowingsteps:[3]
(1)Preparethesysteminafixedstatesay
(2)Letthestateevolvefreely,underaHamiltonianHfortimet
(3)FindtheprobabilityP(t),thatthestateisin
If wasaneigenstateofH,P(t)=1andtherearenooscillations.Alsoiftwostatesaredegenerate,everystateincluding isaneigenstateofH.Asaresultthereare
nooscillations.SoifHhasnodegenerateeigenstates,neitherofwhichis ,thentherewillbeoscillations.TheseprobabilitiesofoscillationsaregivenbyRabi
Formula.OscillationsbetweentwolevelsarecalledRabioscillation.ThemostgeneralformoftheHamiltonianofatwostatesystemisgiven
here,
and
arerealnumbers.Thismatrixcanbedecomposedas,
and
arethePaulimatrices.Thisdecompositionsimplifiestheanalysisofthesystem
areconstants.Considerthecaseofaspin1/2particleinamagneticfield
.The
.Where
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isinstate
thatiseigenstateof
.Thatis
.HereHamiltonianistimeindependent.
SobysolvingtimeindependentSchrdingerequation,wegetstateaftertimetisgivenby
aftertimetisgivenby
,whereEisthetotalenergyofsystem.Sothestate
.Nowsupposespinismeasuredinthexdirectionattimet,theprobabilityoffindingspinupis
givenby
where isacharacteristicangularfrequencygivenby
.[4]SointhiscaseprobabilityoffindingspinupstateinXdirectionisoscillatoryintimetwhen
whereithasbeenassumedthat
,thatiswhenthe
Hamiltonianisdegeneratethereisnooscillation.SowecanconcludethatiftheeigenstateofanabovegivenHamiltonianrepresentsthestateofasystem,then
probabilityofthesystembeingthatstateisnotoscillatory,butifwefindprobabilityoffindingthesysteminotherstate,itisoscillatory.Thisistrueforeventime
dependentHamiltonian.Forexample
,theprobabilitythatameasurementofsysteminYdirectionattimetresultsin
is
.[5]
,whereinitialstateisin
ExampleofRabiOscillationbetweentwostatesinionizedhydrogenmolecule.
Ionizedhydrogenmoleculeiscomposedoftwoproton and andoneelectron.Thetwo
protonsbecauseoftheirlargemassescanbeconsideredtobefixed.LetuscallRbethe
distancebetweenthemand and thestateswheretheelectronislocalisedaround or
.Assume,atacertaintime,theelectronislocalisedaboutproton .Accordingtothe
resultsofprevioussectionweknowitwilloscillatebetweenthetwoprotonswithafrequency
equaltotheBohrfrequencyassociatedwithtwostationarystate
and
ofmolecule.
Thisoscillationoftheelectronbetweenthetwostatescorrespondstoanoscillationofthemean
valueoftheelectricdipolemomentofthemolecule.Thuswhenthemoleculeisnotina
stationarystate,anoscillatingelectricdipolemomentcanappear.Suchanoscillating
dipolemomentcanexchangeenergywithanelectromagneticwaveofsamefrequency.
Consequently,thisfrequencymustappearintheabsorptionandemissionspectrumofIonized
hydrogenmolecule.
DerivationofRabiFormulainanNonperturbativeProcedurebymeansofthePaulimatrices
LetusconsideraHamiltonianintheform
Theeigenvaluesofthismatrixaregivenby
and
.Where
and
.sowecantake
.
Noweigenvectorfor
canbefoundfromequation:
So
Usingnormalisationconditionofeigenvector,
.So
Let
and
Soweget
.so
.Thatis
.Takingarbitraryphaseangle ,wecanwrite
.Similarly
.
Soeigenvectorfor
eigenvalueisgivenby
Asoverallphaseisimmaterialsowecanwrite
Similarlywecanfindeigenvectorfor
Fromthesetwoequations,wecanwrite
http://en.wikipedia.org/wiki/Rabi_cycle
valueandweget
.
and
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Letattimet=0,systembein
ThatIs
Stateofsystemaftertimetisgivenby
Nowasystemisinoneoftheeigenstates
.
or
,itwillremainthesamestate,howeverinageneralstateasshownabovethetimeevolutionisnontrivial.
Theprobabilityamplitudeoffindingthesystemattimetinthestate
Nowtheprobabilitythatasysteminthestate
isgivenby
willbefoundtobeinthearbitrarystate
isgivenby
Bysimplifying
.........(1).
Thisshowsthatthereisafiniteprobabilityoffindingthesysteminstate
frequency
whenthesystemisoriginallyinthestate
.Theprobabilityisoscillatorywithangular
,whichissimplyuniqueBohrfrequencyofthesystemandalsocalledRabifrequency.Theformula(1)isknownas
Rabiformula.Nowaftertimettheprobabilitythatthesysteminstate
isgivenby
,whichisalso
oscillatory.ThistypeofoscillationsbetweentwolevelsarecalledRabioscillationandseeninmanyproblemssuchasNeutrinooscillation,ionizedHydrogen
molecule,Quantumcomputing,Ammoniamaseretc.
RabioscillationinQuantumcomputing
Anytwostatesystemiscalledqubit.LetaSpinhalfsystembeplacedinaclassicalmagneticfieldwithperiodiccomponentsuchas
.TheHamiltonianofsystem(proton)ofmagneticmoment infield isgiven
,where
andb
isgyromagneticratioofproton.Onecanfind
eigenvalueandeigenvectoroftheHamiltonianbyabovementionedprocedure.Letattimet=0thequbitisinthestate
ofbeingfoundinstate
betweenthelevels
givenby
and
where
hasmaximumamplitudefor
adjustthetimetduringwhichtherotatingfieldactssuchas
obtainasuperpositionof
and
.Inparticular
.ThisisthephenomenonofRabioscillation.Theoscilltion
thatisatresonance.So
or
,wehavea pulse:
,attimetitwillhaveaprobability
.Togofromstate
tostate
.Thisiscalleda pulse.Ifatimeintermediatebetween0and
itissufficientto
ischosen,we
.Thisoperationhascrucialimportanceinquantumcomputing.
Theequationsareessentiallyidenticalinthecaseofatwolevelatominthefieldofalaserwhenthegenerallywellsatisfiedrotatingwaveapproximationismade.Then
istheenergydifferencebetweenthetwoatomiclevels, isthefrequencyoflaserwaveandRabifrequency isproportionaltotheproductofthetransition
electricdipolemomentofatom andelectricfield ofthelaserwavethatis
.Insummary,Rabioscillationsarethebasicprocessusedtomanipulate
qubits.Theseoscillationsareobtainedbyexposingqubitstoperiodicelectricormagneticfieldsduringsuitablyadjustedtimeintervals.[6]
RabioscillationinAmmoniamaser
Inmolecularphysics,awellknownexampleofatwostatesystemisanitrogenatominthedoublewellpotentialofanammoniamolecule.Thetunnelsplittingofthe
ammoniaNH3moleculefindsapplicationintheammoniaMASER,anacronymforMicrowaveAmplificationofStimulatedEmissionofRadiation,similarlyas
LASERisanacronymforLightAmplification.WhilemagneticinteractionsoftheNH3moleculesarenegligible,themoleculesdipolemomentsareverysensitiveto
externalelectricfields.Aprominentcauseforthesplittingofenergylevelsisthetunneleffect.AsanexampleweregardtheammoniamoleculeNH3.Ifwesqueeze
thenitrogenatomalongthezaxisthroughtheequilateraltriangleformedbythehydrogenatoms,thentheNatomseesadoublewellpotentialV(z).TheNatomcan
beoneithersideoftheplaneoftheHatoms.HencetheNH3moleculeformsatwostatesystemwithtwobasisstatesorspatialeigenstates and
withthe
nitrogenatomononesideortheotheroftheplaneofhydrogenatoms,anditsenergygroundandfirstexcitedstates and arethesymmetricandantisymmetric
quantumsuperpositionsofthespatialeigenstates(ignoringrotationalandvibrationalstates).ThesystemcanchangefromLtoRandbackbecausethereisacertain
probabilityamplitudeAthatthenitrogenatomtunnelsthroughthecentralpotentialbarriertotheotherwell.Theammoniamaserisbaseduponthetransitionbetween
theenergyeigenstates,whichmayalsobedescribedastheRabioscillationbetweenthespatialeigenstates.However,theinversiontransitionisseenonlyatlowgas
pressure.Asthegaspressureisincreased,thetransitionbroadens,shiftstolowerfrequencyandthenquenches(thefrequencygoestozero).Theammoniamolecule
appearstoundergospatiallocalisationasaresultofinteractionwiththeenvironment.Thiswouldbeofimmensetheoreticalinterest.Inchemistryandintheclassical
worldgenerally,enantiomorphicmoleculeswithdistinguishablespatialeigenstates and
arealwaysfoundintheirspatialeigenstates(classicalbehaviour)rather
thantheirenergygroundstates(quantumbehaviour).Whilstammoniaisnotenantiomorphic,itdoesappeartoshowbothbehaviours,quantumatlowpressureand
classicalathighpressure,ifthequenchingisconsideredtobeadirectobservationoflocalisationorcollapseofthewavefunctionintoaspatialeigenstate.Withinthe
contextofthedecoherenceprogramme,ithasbeentreatedquantitativelyinthatway.Thebroadening,shiftandquenchingoftheRabioscillationaresimply
consequencesofimpactsandmaybedescribedwithintheframeworkofanoscillatorsubjecttowhitenoisefromtheenvironment.Thereisnoevidenceforlocalisation
ontospatialeigenstates.[7]
Seealso
Atomiccoherence
Blochsphere
Laserpumping
Opticalpumping
Rabiproblem
VacuumRabioscillation
Neutralparticleoscillation
References
http://en.wikipedia.org/wiki/Rabi_cycle
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1.
2.
3.
4.
5.
6.
7.
RabicycleWikipedia,thefreeencyclopedia
EncyclopediaofLaserPhysicsandTechnologyRabioscillations,Rabifrequency,stimulatedemission(http://www.rpphotonics.com/rabi_oscillations.html)
Griffiths,David(2005).IntroductiontoQuantumMechanics(2nded.).p.353.
SourenduGupta(27August2013)."Thephysicsof2statesystems"(http://theory.tifr.res.in/~sgupta/courses/qm2013/hand5.pdf)(PDF).TataInstituteofFundamentalResearch.
Griffiths,David(2012).IntroductiontoQuantumMechanics(2nded.)p.191.
Griffiths,David(2012).IntroductiontoQuantumMechanics(2nded.)p.196ISBN9788177582307
AShortIntroductiontoQuantumInformationandQuantumComputationbyMichelLeBellac,ISBN9780521860567
"au:Herbauts_Iin:quantphSciRateSearch"(https://scirate.com/search?q=au:Herbauts_I+in:quantph).SciRate.
QuantumMechanicsVolume1byC.CohenTannoudji,BernardDiu,FrankLaloe,ISBN9780471164333
AShortIntroductiontoQuantumInformationandQuantumComputationbyMichelLeBellac,ISBN9780521860567
TheFeynmanLecturesonPhysicsVol3byRichardP.Feynman&R.B.Leighton,ISBN9788185015842
ModernApproachToQuantumMechanicsbyJohnSTownsend,ISBN9788130913148
Externallinks
AJavaappletthatvisualizesRabiCyclesoftwostatesystems(laserdriven)(http://www.itp.tu
berlin.de/menue/lehre/owl/quantenmechanik/zweiniveau/parameter/en/)
extendedversionoftheapplet.Includeselectronphononinteraction(http://www.itp.tuberlin.de/menue/lehre/owl/quantenmechanik/elektronphonon
wechselwirkung/parameter/en/)
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Categories: Quantumoptics Atomicphysics
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