Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex 11- United Kingdom (UK)

SAFETY DATA SHEET

HUNTSMAN

HARDENER HW 2934

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1 Product identifier
Product name
Product code
Product description

HARDENER HW 2934
00048074
Not available.

1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use

: Hardener for adhesive systems

1.3 Details of the supplier of the safety data sheet

Supplier
Huntsman Advanced Materials (Europe)BVBA
Everslaan 45
3078 Everberg I Belgium
Tel. : +41 61 299 20 41
Fax: +41 61 299 20 40
e-mail address of person
responsible for this SDS

Global_Product_EHS_AdMat@huntsman.com

1.4 Emergency telephone number

Supplier
Telephone number

EUROPE: +32 35 75 1234

France ORFILA: +33(0)145425959
ASIA: +65 6336-6011
China: +86 20 39377888
Australia: 1800 786 152
New Zealand: 0800 767 437
USA: +1/800/424.9300

ISECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition

: Mixture

Classification according to Directive 1999/45/EC [DPDJ

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
R43
Classification
R52/53
Human health hazards
May cause sensitisation by skin contact.
Environmental hazards

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard symbol or symbols

Indication of danger

Date of issue I Date of revision

Irritant

: 8 September 2011

1113

Conforms to Regu lation (EC) No. 1907/2006 (REACH), Annex II United Kingdom (UK)

HARDENER HW 2934
Date of printing

: 8 September 2011

MSDS no.

00048074

Date of issue

: 8 September 2011

Version

1.02

SECTION 2: Hazards ident ification

Risk phrases

R43- May cause sensitisation by skin contact.

R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

Safety phrases

S2- Keep out of the reach of children .

S24- Avoid contact with skin .
S37- Wear suitable gloves.
S46- If swallowed, seek medical advice immediately and show this container or label.

Hazardous ingredients

N(3-dimethylaminopropyl)-1,3-propylenediamine

Supplemental label
elements

Not applicable.

Special packaging reguirements

Containers to be fitted
with child-resistant
fastenings
Tactile warning of danger

: Not applicable.

Not applicabte.

2.3 Other hazards

Other hazards which do
not result in classification

: Not available.

ISECTION 3: Composition/informatio n on ingredients

: Mixture

Substance/mixture

Classification
Identifiers

CAS: 14970-87-7
triethylene glycol
dimercaptan N, R51/53

1-3

Xn; R20/22
N; R51/53

N(3dimethylaminopropyl)1,3-propylenediamine

CAS: 10563-29-8

1- 3

Xn; R21 /22

C; R34
R43

2,4,6-

CAS: 90-72-2

1- 3

Xn;R22
Xi; R36/38

4-dimethylaminoethyl1-methyl-4-piperazine

CAS: 104-19-8

1 3

T; R24
Xn ; R22
C; R34

n-butyl acetate

CAS: 123-86-4
Index: 607-025-00-1

1-3

R10
R66,R67

Product/ingredient
name

tris(dimethy1aminomethy1)phenol

67/548/EEC

See section 16 for

the full text of the Rphrases declared
above

Regulation (EC) No.

1272/2008 [CLP]
Acute Tox. 4, H302
Acute Tox. 4, H332
Aquatic Chronic 2,
H411
Acute Tox. 4, H302
Acute Tox. 4, H312
Skin Corr. 18, H314
Eye Dam. 1, H318
Skin Sens. 1, H31 7
Acute Tox. 4, H302
Skin lrrit. 2, H315
Eye lrrit. 2, H319
Acute Tox. 4, H302
Acute Tox. 3, H3 11
Skin Corr. 16, H314
Eye Dam. 1, H318
Flam. Liq . 3, H226
STOT SE 3, H336

Type
[1]

[1]

[1)

[1]

(1] (2]

See Section 11 for the

full text of the H
statements declared
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this
section.
~

I Date of Issue I Date of revision

8 September 20 11

2113]

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II- United Kingdom (UK)
H.IJ.RDENER HW 2934
]

Date of printing
Date of issue

3/13

8 September 2011
8 September 2011

MSDS no.

00048074

Version

1.02

SECTION 3: Composition/information on ingredients

[1]
[2]
[3]
[4]

Substance classified with a health or environmental hazard

Substance with a workplace exposure limit
Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex X III

Occupational exposure limits, if available, are listed in Section 8.

ISECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention if irritation occurs .
Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie , belt or waistband. In case of inhalation of decomposition
products in a fire, symptoms may be delayed. The exposed person may need to be
kept under medical surveillance for 48 hours.

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or
wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the
event of any complaints or symptoms, avoid further exposure. W ash clothing before
reuse. Clean shoes thoroughly before reuse.

Ingestion

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing . If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact

No known significant effects or critical hazards.

Inhalation

Exposure to decomposition products may cause a health hazard. Serious effects

may be delayed following exposure.

Skin contact

May cause sensitisation by skin contact.

Ingestion

No known significant effects or critical hazards.

Over-exposure signs/symptoms
Eye contact

No specific data.

Inhalation

No specific data.

Skin contact

Adverse symptoms may include the following:

irritation
redness

Ingestion

No specific data.

Date of issue I Date of revision

: 8 September 2011

3113