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1.
Cl
-1
Cl-
Group 7
Cl2
+1
ClO-
+3
ClO2-
+4
ClO2
+5
ClO3-
+7
ClO4-
for ions like ClO4- the charge on the ion is equal to the sum of the oxidation numbers
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Extraction of Aluminium (continued) - Electrolysis Cell.
The steel container is coated with carbon (graphite) and this is used as the negative
electrode (cathode).
Aluminium oxide (Al2O3) is an ionic compound.
When it is melted the Al3+ and O2- ions are free to move and conduct electricity.
Electrolysis of the alumina/cryolite solution gives aluminium at
the cathode and oxygen at the anode.
4Al3+ + 12e6O2- - 12e-
aluminium + oxygen.
4Al(l) +
3O2(g)
there are more protons in each nucleus so the nuclear charge in each element
increases ...
therefore the force of attraction between the nucleus and outer electron is
increased, and ...
there is a negligible increase in shielding because each successive electron enters the
between the energy of the ionizing radiation and the energy of the
ejected electron equals the energy required for ionization. Ionization
energies are typically reported either in kJ/mol or in eV (1 eV = 96.485
kJ/mol).
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6. hydrolysis reactions of an organic compound like eter require a
catalyst - an acid (H+ ions) or alkali (OH- ions) as reaction with
water is very slow. The dilute acid provides both the acid catalyst
and the water.
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7. If the pressure is higher, the chances of collision are greater.
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9.As molecules get larger, then dispersion forces will increase,
and you may get other intermolecular forces such as dipole-dipole
attractions as well. Gases made of molecules such as these will be
much less ideal.
Like helium, a hydrogen molecule also has two
electrons, and so the intermolecular forces are going to
be small - but not as small as helium. In the hydrogen
molecule, you have two atoms that you can distribute
the charges over.
A helium molecule consists of a single small atom, and
the van der Waals dispersion forces are as low as it is
possible for them to be.
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The ideal gas equation is:
pV = nRT
Pressure, p: Pressure is measured in pascals, Pa - sometimes
expressed as newtons per square metre, N m-2. These mean
exactly the same thing.
Therefore Mr =
mRT
---------------pV
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because iodine is less reactive than bromine so it's 1- ions do not
displace the bromine ions in sodium bromide. (It is lower down in
the group).
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Astatide ion, At-, is a reducing agent. So when it's oxidised, the
product is astatine:
2At- ------> At2+ 2eHAt is not a redox product, and the others are reduction or
neutralisation products of the H2SO4.
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17.It can be either Nacl or NaBr uptill the colorless solution but
what is happeneing on the addition of excess HNO3.??
HNO3 simply removes the NH3 ligands by protonating them,
regenerating the silver halide ppt.
The key is the "excess NH3(aq)" used, instead of "excess
concentrated NH3(aq)" that is required to dissolve AgBr(s). Hence
it can be deduced that the ppt is AgCl(s), rather than AgBr(s).
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18.Equilibrium constants aren't changed if you change the
concentrations of things present in the equilibrium. The only
thing that changes an equilibrium constant is a change of
temperature.
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19.Ammonium compunds ALWAYS react with alkalis to form
salt,water and AMMONIA gas.So the answer would be C since
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22.
Electrophile
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23. trace back the reaction
sodium propionate is the sodium salt of propionic acid which has the chemical formula
Na(C2H5COO).
C2H5COO
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Na
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24.
A.
C.
1,3-dichloro-3- 2,3methylbutane dichloropent
ane
no chiral carbon
No Chiral Carbons
A.1,3-dichloro2,2dimethylpropa
ne
D.2,4-dichloropentane
dichloropentane
2 chiral
carbons
A. 1,3
2 chiral carbons
1 chiral
carbon
o chiral carbon
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============================ 26.CH 3CH 2 OH
+2[ O ]----------- CH 3 COOH +H 2O ) The molar mass of ethanol
is trivial to compute:
(M( CH3 CH2OH )=6M( H )+2M( C )+M( O )=46.08 g/mol )
hence we have (2.30
ethanol.
g /46.08
g/mol approx0.05
mol ) of
In the case of methanal, HCHO, the oxidation goes further. The methanoic acid or methanoate
ions formed are easily oxidised to carbon dioxide and water.
aldehyde
ketone
aldehyd
e
aldehyde
2,4-dinitrophenylhydrazine:
Add either a few drops of the aldehyde or ketone, or possibly a
solution of the aldehyde or ketone in methanol, to the Brady's
reagent. A bright orange or yellow precipitate shows the presence
of the carbon-oxygen double bond in an aldehyde or ketone.
--------------------------------------------------------------------------------------------------28-D
Generally
Alcohols tend to have higher boiling points than the hydrocarbons because of the strong hydrogen bond between hydrogen and oxygen atoms.
29-B
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optically active= Chiral compounds
If the hydrogen atoms are on the opposite side of the double bonds of the carbon
chain, then it is said to be in "trans" configuration.
THEREFORE B is the answer.
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Statement:1
wrong =>
wrong =>
answer is C
for
Statement:2
answer is D
Now if Statement:1 is correct, instead of checking for
statement:2 , check for statement 3 first.
If youre sure its that Statement:3
answer will be A.
And if youre sure Statement:3 its wrong, then check statement
2.
Statement:2 is correct
your answer is B
and if Statement:2 is wrong
your answer is D.
if
B : 1 and 2 correct
C : 2 and 3 correct
D : 1 correct
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Diradical : an atom or molecule having two unpaired electrons
Molecular oxygen (O2) is a rare example of a stable biradical (two unpaired electrons having the
same spin), with an even number of electrons.
39.
Hydrolysis using dilute alkali
This is the usual way of hydrolysing esters. The ester is heated
under reflux with a dilute alkali like sodium hydroxide solution.
There are two big advantages of doing this rather than using a
dilute acid. The reactions are one-way rather than reversible, and
the products are easier to separate.
Taking the same esters as above, but using sodium hydroxide
solution rather than a dilute acid:
First, hydrolysing ethyl ethanoate using sodium hydroxide
solution:
i.e salt and alcohol
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40.
Ester has general structure
.
EG.When sodium hydroxide is added to an ester, say for example
to ethyl ethanoate, a salt sodium ethanoate is formed along with
ethyl alcohol. The reaction is shown below.
Also the enclosed part will act with OH- forming alcohol
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