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Article history:
Received 7 January 2013
Accepted 24 July 2013
Available online 3 August 2013
The effective thermal conductivity of porous materials is a function of the intrinsic characteristic of the
solid and the uid phases that occupy the pores, of the volume fraction of the pores, and of their
dimensional distribution. This last aspect is less known and studied than the others because the porous
microstructure is difcult to dene in conventional geometric terms. In this work, an Intermingled
Fractal Units model (denominated IFU) is presented, developed by varying some constructive aspects of
the Sierpinski carpet. Simple fractals can be used effectively to describe pore size distributions which
present a regular growth toward the larger diameters and therefore are not suited to describe very
common structures which present one or more peaks in their distribution. But the use of more fractal
units means that the IFU is able to effectively simulate the pore size distribution, the volume fractions of
the voids as well as the geometry of the microstructure of non-fractal porous materials.
By turning IFU model into electrical fractal pattern, it is possible to calculate effective thermal conductivity of the materials. In this approach the value of effective thermal conductivity coefcient derived
from the nth stage was used as a default value for the solid phase in the nth 1 step.
This full fractal procedure has been veried with deterministic or random fractal models as well as
with some porosityeconductivity experimental data, namely, those obtained from advanced ceramics
(Yitria stabilized zirconia) already available in the scientic literature and the results are comparable and
very close.
2013 Elsevier Ltd. All rights reserved.
Keywords:
Fractal geometry
Microstructure-nal
Model
Porosity
Thermal conductivity
Yitria stabilized zirconia
1. Introduction
Over the last few decades, a geometry that refers to gures with
fractional dimension, known as fractals has been developed. The
* Corresponding author. Tel.: 39 706755063; fax: 39 706755067.
E-mail address: ulrico.sanna@dimcm.unica.it (U. Sanna).
1359-4311/$ e see front matter 2013 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.applthermaleng.2013.07.031
Nomenclature
A
a
AA
AAp
AB
ABp
B
c
Df
k
keff
kf
kM
ks
L
l
nB
nth
unit type A
cross-sectional area of the specimen
total area of unit A
pore area of unit A
total area of units B
pore area of units B
unit type B
conductance
fractal dimension
conductivity
effective thermal conductivity
uid thermal conductivity
thermal conductivity for material M
solid thermal conductivity
thickness of the body
length of the piece of material
number of units B
iteration
[3] and Y. Shi et al. [4] developed a fractal model for porous media
based on the fractal characteristics of pores in the media. Xu et al.
[5] derived an analytical expression for mass transport in homogeneous porous media without empirical constant.
As far as porosity is concerned, Fractal Geometry, displays a well
known series of sponges, that regardless of their being originally
very simple they call to mind the pore size distribution or the
morphology of their outlines (as for example the Sierpinski carpet
or its corresponding tridimensional model known as the Menger
sponge) [1,2].
The development in the space of the scaling procedures (selfsimilarity, applied on no less than two/three orders of magnitude)
allows processing, in fractal terms, the porosimetric data obtained
with the well-known techniques of mercury intrusion porosimetry
[6], gas adsorption or image analysis [7]. Its applications can be
found in the scientic literature in large numbers and include
traditional and advanced ceramic materials, sandstones, soils but
also cement materials. Winslow [8] described an X-ray scattering
technique for measuring the dimension of a fractal surface to
demonstrate that the surface of hydrated cement paste is fractal in
character, and has a large fractal dimension. Livingston [9] presented a model to describe nucleation and growth for the hydration
of tricalcium silicate. Lange [10] explored several image analysis
techniques that provide insight into the nature of pore structure as
observed in backscattered electron images of polished sections.
In Arandigoyen et al. [11], microstructure of blended mortars
is studied taking into account porosity, pore size distribution
and surface fractal dimension, meanwhile Diamond et al. [12]
Q
R
R1
R2
R3
Rs
Rf
Reff
Rf
Rs
S
T1
T2
V
187
heat ow
resistance
resistance for rst line of pattern
resistance for second line of pattern
resistance for third line of pattern
resistance of solid phase
resistance of uid phase
total resistivity
uid resistivity
solid resistivity
area involved in heat transfer
temperature in extremity 1
temperature in extremity 2
pore volume
Greek symbols
188
keff Q
L
jT2 T1 j$S
(1)
where Q and S represent the ow and the area involved in the heat
transfer and jT2 T1 j is the temperature difference across the L
thickness of the body. Alternatively, this study demonstrates (for
the same model used in Ref. [19]) how the keff value can be calculated by exploiting in a complete and direct manner the fractal
character of the models adopted to represent the microstructure. By
using IFU it is possible to simulate every pore size microstructure
(fractal or non-fractal), furthermore this model can be converted
into electrical fractal patterns. An advantage of the IFU model is that
it uses the same equation for each nth stage. In fact the keff calculated in the nth step is then used in the nth 1 stage as the ks.
Heat transference along one direction has been considered. This
procedure can be started from any scale and it is very important
because for many materials it is difcult to nd ks experimentally,
while porosimetric data is much more easily available. This full
fractal procedure has been veried with deterministic or random
fractal models (the same used by Huai et al. [19]) as well as with some
porosityeconductivity experimental data, namely, those obtained
from advanced ceramics (Yitria stabilized zirconia) already available
in the scientic literature, microstructure of which is non fractal [26].
Fig. 2. Example of IFU model based on two Sierpinski carpets: A (Df 1.89, i 4, n 1)
and B (Df 1.63, i 4, n 12).
nB
AAp $AA
$AB ABp
(2)
with AA, AB, AAp and ABp, respectively the total area and the area of
the pores belonging to units A and B which make up the IFU (Fig. 2);
b) denition of the circuit diagram of the units, assuming that at
each subsequent iteration of the scaling keff is the calculation result of
the previous stage (Fig. 3); c) in case several materials have a distinct
pore size distribution and are mixed together: estimating a value of
keff nal representative of the real microstructure through a new
circuit diagram which allows to evaluate possible different solid
phases or uid which will give rise to combinations and thus different
values of keff (depending of the articulation of the circuit diagram)
which will be processed through a calculation of an average.
By dening the smaller cell (Fig. 3) corresponding to the size of
the smallest pores, keff f (circuit diagram corresponding to the
microstructure) is provided.
Being c and R respectively conductance and average electrical
resistance:
i 1.
189
Fig. 4. Comparison of the keff obtained using our procedure and those obtained using Huai method for SC1 [19] (kf being equal).
1
R
(3)
1
1
1
2
1
3
R
R
R
1
1
1
c
2
1
3Rs 2Rs Rf
Being; R Reff
l
a
(4)
(5)
(6)
Fig. 6. Comparison of the keff obtained using our procedure and those obtained using
Huai method for RSC1 [19].
(7)
1
where Reff, Rs, RA, l and a are respectively the total resistivity, the
solid resistivity and the uid resistivity, the length of the piece of
material and the cross-sectional area of the specimen.
1
2 1
1
Reff $l=a
3 Rs l=a 2Rs l=a Rf l=a
(8)
1
21
1
Reff
3 Rs 2Rs Rf
(9)
Being conductivity
keff
1
;
Reff
becomes:
(10)
1
keff
21
31
keff
ks
2
ks
1
;
k1
(11)
2
1
ks 2k k ;
s
f
3
(12)
kf $ks
Fig. 5. Fractal models of the porous microstructure RSC2 [19] (random) and electrical equivalent circuits; s is solid, f is uid/pore and s is dummy solid.
190
Fig. 7. Logelog plot of the experimental porosimetric MIP data from Ref. [26].
Table 1
IFU model data for experimental ceramics.
Ceramic 72%
Units
Pore
lA-max (mm)
Df
nth
Ceramic 51%
Unit type A
Unit type B
Unit type A
Unit type B
1
3
0.6
1.63
4
6212
2
0.01
1.77
3
1
3
0.6
1.63
4
870
1
0.02
1.89
2
A number of possible and different congurations of connections in series and parallel for the same system will be then processed in order to get an average thus eventually obtaining a keff
that can be compared with the data acquired experimentally.
3. A fractal model designed on Huai et al. to predict thermal
conductivity
As we mentioned in Ref. [19], thermal conductivity values were
derived from the application of the Law of Fourier-Laplace and the
nite volume method.
In this part the application of a full fractal model and approach
with the aim to extremely simplify the calculation of thermal
conductivity, has been reported.
Fig. 1 shows the fractal model named SC1 in Ref. [19], a Sierpinski
carpet with Df 1.893 and Fig. 3 shows, for the same model, the
corresponding equivalent electrical circuit, in terms of resistance
proposed in this work. Dening the elementary cell with sides three
times the size of the smallest pores, we can write for the rst step:
keff
kf $ks
2
ks
3
2kf ks
(13)
This rst cell is taken as part of the solid from the stage succeeding the fractal scaling with a ks equal to the value keff previously calculated.
Fig. 8. Pore size distributions; experimental (points) and derived from the IFU model (curves) for the ceramics [26].
191
192
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