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[NTRODUCTIoN
includingsilica sinter-depositing
hot springsand
steam-heated
acid-sulfatealteration.
A consequenceof the increasedexplorationfor
The main objective of this review is to
gold depositsduring the Iate 1970s and early summarize the characteristicsof HS minerali1980s was tlre revision of the classificationof
zation formed primarily within the epithermal
epithermaldeposits in order to account for the
environment,tlroughrecognizingthe potentialfor
variationsobservedin stylesof mineralizationand
HS conditionsto occur at greaterdepths.Earlier
inferred genetic environments. Among the
studies have argued for a magmatic fluid
numerousclassificationsthat followed, one group
componentin HS deposits(e.g., Sillitoe 1983,
of deposits clearly showed a common set of
1989, 1991a;Hayba et al. 1985; Henley t99t
features,this deposittype is characterized
by the
White 1991;Rye 1993;Hedenquistet al. 1994a),
presence of minerals diagnostic of highand the identificationand characterization
of HS
sulfidationstates(e.g.,enargiteand luzonite)and
depositshas contributedto a re-evaluationof the
acidic hydrothermal conditions (e.g., alunite, role of magmatic fluids in other types of
kaolinite, pyrophyllite). The terms enargite-gold hydrothermalsystems(Hedenquist& Lowenstern
(Ashley 1982),Goldfield-type(Bethke 1984,after
1994; Simmons this volume; de Ronde this
(Bonham
Ransome 1909), high-sulfur
1984, volume). In this context, particular aftention is
1986), quartz-aluniteAu (Berger 1986), acid- given to the characteristicsthat are helpful in
sulfate (Heald et crl. 1987), and alunite-kaolinite determiningthe nature of the magmatic contri(Berger & Henley 1989) were applied to this
bution to the hydrothermalsystem through time
group in referenceto someof its mineralogicalor
and space.This review considersfeaturesof many
inferred geoclremicalattributes.The term highof the depositslisted in Table l, with locations
sulfidation(HS) (Hedenquist1987)is now widely
shown in Figure 1, but is basedon a selectionof
used;the term was proposedoriginally to refer to
fourteendepositsfor which the resultsof detailed
a fundamental genetic aspect, the relatively geologicaland geochemicalstudiesare available
oxidized state of sulfur contained in the
(Tables 2, and 3). For simplification,bibliohydrothermalsystem(i.e., initially SO2-rich).This
graphic referencesare not given in the text for
aspectis significantbecauseit links HS deposits generaldeposit features;these referencesmay be
with one of the two main types of terrestrial found in Table 1. For regional studies of HS
magma-relatedhydrothermalsystems(Henley &
deposits,particularlywith respectto othertypesof
Ellis 1983), those associatedwith andesitic magmatic-hydrothermal
base-and precious-metal
volcanoeswhose surface manifestationincludes deposits,the reader is referred to reviews by
high-temperaturefumaroles and acid sulfate- Heald et ul. (1987), Bonham (1989), Sillitoe
chloridehot springsand crater lakes.By contrast, (1989, l99la), Berger& Bonham(1990),Camus
Iow-sulfidation deposits form from neutral-pH, (1990),White & Hedenquisr(1990),Mitchell &
reduced(H2S-rich)hydrothermalfluids similar to
Leach (1991), Mitchell (1992), and White et al.
thoseencounteredin geothermalsystems(Henley ( I 99s).
& Ellis 1983), with surface manifestation
7-
A. Arribas../r.
Table l. Principal high-sulfidation deposits or documcnted prospects ordered geographically
N'in
t;ig. I
I
2
3
1
5
6
1
d
9
l0
ll
t2
l-)
l4
l-5
l6
t1
l8
la
20
2l
22
L-)
24
26
21
28
29
30
3l
.1.')
34
3-5
36
38
39
40
4l
42
43
44
A<
46
41
48
49
50
420
Deposit
References
q9.:Balkans
\
,--<+s-+s
421
A. Arribas, Jr.
Age
{Ma)
1.9
Metals.
( t o n n e s I)
Local volcanic
setting
C u .A u . A g
Central-vcnt
6 0 , 0 0 0 t C u . 4 t volcanir
Au. t80r Ag (c)
S u n r n r i nl l l c .
Color:rdo
22..5
Time
betwecn host
rock & deposit
Hbx . vcins.dis in
VS
None observed
N/A
Hbx. vcinlcts
Diatreme
complex
Ands/dac vol.
Mioccnc + older
volx + metavol
Qtz{iorite
porphyry
<analyl.error
( 1 0 . 1m . y . )
Dac volc
Mioccnc sed
Dacite domes
md llows
Vcrtical brcccilrs,
vcins. slralab0urd
replacenrnls
"letl{cs
Vcins or
.
hhx,dis and stk
sunounding veins
Jurassicgranite.
Cretaceous dac
porpyhry +pyr
Not reported
7 . 0r n . y .l ()
(PoorlYrJatul)
Horblende :rrds
(Middlc Volcs)
<0.5 nry
Qtz-latite porphyry
Qtz-monzonite
porphyry
<analyl.error
(10.-5 m.y.)
Dis in stratatrountl
VS/MS bodies.
v c i n s .h b x
''hdgcs"
with
v c i n s .h b x + d i s
in VS
Au (Ag. Cu)
Domes along
l -10t Au. t 4.1 Ag. preexisting ring
-17.000 Cu (p)
fracrue
Miocene andesitc
Andesitc
<analyl. crror
(t0.,1 m.y.)
<analyt. crror
(+1.0n).y.)
Snrall volcanos
l t l r A u ( p ) + l 8 r in a c:rldrra'i
Au reserves
Au, Cu.Ag
Dome along
1 7t A u
preexrstlnS
c:ildera margin
Goldlicld.
Ncvadir
2l
Dcposit li)rm
< 1 . 0n r . y .
1 . . 1 - 1 . 0 A u . C u .A g
Dome complex
9 2 t A u . 1 8 3r A g
120.000r Cu (p)
-94
Cu. Au
Domc akrng
>t0 r Au (c)
caldcra m:trgin'l
5-J.-s
Genetically
rclated rtxks
Pliocene Au
l5 t Au(c)
I . 5 -I . 2
C u .A u .A g
900.(100
r Cu.
1 2 0r A u ( c )
Nansatsu,
Japiur
Principal host
roc Ks
"[.cdges"
with
v e i n s .h h x + d i s
in MS
ParatliscPcak.
Nevai:r
lg-lti
Au, Ag. Hg
47 t Au, 12-55Ag
457 r Hg (p)
Within or close
to a central-vcnt
volcano
And/dac vol
P u eb l o V i e j o .
D o n r i n i c a nR c p .
-l-l(.)
Au. Ag
>600 I Au (p;
Sillitoe. 199.1)
Mzurdiatreme
complex
CA bimodal
N/A
(Rhy + basalr)
volcanic suite
Mushrtxrnrshapcd
bodics with stk +
dls
Julcani,
Peru
g.lt
Dome complcx
around a cenual
dlareme
Dac to rhyodacitic
domes and tuft.s
Dac/rhyulacitic
porphyry
<analyr.crror
(+0. I m.y.)
Vcins
El Indio,
Chile
ll-tt
Au. Ag. Cu
-140 t Au.
-1.100r Ag (c)
CA vol
N/A
Veins + stk
Cu. Au, Ag
>lll5
t Au (c)
Dome complex( l)
Paleozoic seds +
granitcs. Pliocene
illtrusivc dacite
Dac/rhyrxlactic
porphyry
stocks
<1.2 nr.y.
Veins;alsohbx at
N. dcl Famtina
RrxJ:rJtluilu.
Spain
Au
10 t Au (p)
Caldera margin
Ands flows
+ dykes
<analyt. error
(+0.7 m.y.)
Vcins.hbx. dis in
VS
I l-10
Stratabourrrl
btxlics
commonly with
hbx
Abbrcviations used: CA : calc-alkaline, MS - massive silica, VS : vuggy silica, ands : andesitic, bre : breccias, dac - dacitic, dis =
disseminations,hbx = hydrothermalvein breccia or brecciapipes, pyr - pyroclastics,qtz = quartz,rhy : rhyolitic, sed: sedimentaryrock, stk
- stockwork, vol : volcanic rock (unspecifled),volx : volcaniclastics
2
I
Approximate number, quoted from paper or estimatedfiom ligures: 150 nr lbr Paradisc
1p; : produced, (c) : estimaled total contained
P e a ki s f b r i n d i v i d u a lo r e b o d i e s
422
Table 2 (continued)
Dcposit/district
locatlon
Control on mineralization
Relation to
porphyry systen)
Relerences
Motomhoto.
lndurcsia
250
Porphyry Cu-Au
prospectsnearby. age
within 1.0 m.y.
Pcrcll6 ( I 994)
Nalcshitan.
Phi lippi nes
150
hoposcd,
none lo)owr)
Lcpanto.
Phi li ppi ncs
500
Above + adjaccnt
samc age porynyry
Cu-Au dcposit
Garcia ( l99l ),
Anihas et a/. ( I 995b)
C h i n l u a s hi h ,
Taiw;rrr
800
Nonc k-nown
H u a n g( 1 9 5 5 ) ,
Tan et al. (1993)
Ziiinshan.
China
60()(')
None known
Nansatsu.
Japiut
<150
None known
Sunrmrtville.
Colorado
250
Inrusion-ccncred
scricitic, low grade
stk mineralization
S t e v e n& R a t t i ( 1 9 6 0 ) .M e n h c r l
et al. (19'73). Stoffregen ( I 987 ).
Rye (199,j)Gray& Coolbaugh
( 1994)
Goldlrcld.
Nevalir
Modcratcly + shallow
dipping faults & fissures
400
Nonc lnown
R a n s o m c( 1 9 0 9 ) ,A s h l e y ( 1 9 7 4 ) .
A s h l c y & S i l b e r m a n( 1 9 7 6 ) .
V i k c ( 1 9 8 9 .w r i t t e nc o n r m u n .
I 995)
ParadiscPcak.
Nev:da
< 150
Sericitic. stk Au
minerahzation (East
Zone)
J o h n ? / a / . ( 1 9 9 1) .
Sillitoe& Lorson (1994)
P u c h l oV i e . j o .
D o n ) i n i c a nR c p .
4UXt)
Ntne l*rown
R u s s e l l& K e s l e r ( 1 9 9 1) .
Muntean et a1.( I990)
Julcani.
Pcru
Steep liactures
600
None klown
El lndio.
Chile
Porphyry Cu-Mo
mineralization
nearby
LOcal I aults
Losurda-Calder(xr
& McPhail
( I 994). Losada-Caldcr6nel a/.
{ I 994)
Rrxllrit1uiIar.
Spaitr
Nrne Lrown
>l(x)
<150
zunyite,which are typical of hypogene(T : 200350 "C) acidic conditions (advanced argillic
Meyer & Hemley 1961).This type of
assemblage;
of HS deposits,but it may
aluniteis characteristic
also appearin areasof advancedargillic alteration
void of ore mineralization(e.g., Iwao 1962; Flall
1978). Alunite in steam-heatedenvironments
forms with kaolinite and interlayered illitesmectiteat about 100 to 160 'C where fumarolic
vapor condensesabove the boiling zone of
neutral-pH,H2S-richfluid, typical of geothermal
s y s t e m st h a t f o r m l o w - s u l f i d a t i o nd e p o s i t s .
423
A. Arribcts,,Ir.
Propylitic
Leached
silicic
Quartz alunite
, I
rock
rock
rock
Kaolinitic
rock
Mineralizedvuggy
quartz rocl(
'100
m
Becauseof the relatively shallow and dynamic Proterozoic EnAsenAu deposit located in the
environment of mineralization, overprinting Baltic shield of central Sweden; Fig. I ). The
(<1.6 Ma) and
among the three types of acid-sulfatealteration youngestdepositsare Pleistocene
is possible;however,the
occur in the central western Pacific (Kelly,
(including sLrpergene)
Lepanto,and Chinkuashih).The concentrationof
spatial relation of each type of alunite to ore is
different, and correct identificationis important depositsin young volcanic areas is mainly a
reflectionof the fact that older HS depositsare
for exploration (Rye et al. 1992:. White &.
more likely to be eroded.
H e d e n q u i s1t9 9 5 ) .
Gold. copper,and variablearnountsof silver
AGE ANDECONOI\{IC
are the main productsof HS deposits(Table 2).
DISTRIBUTION,
Rodalquilar),
occasionally
with
Gold (Nalesbitan,
StcNInrcaNcB
silica by-product(Nansatsu),is the only economic
other magmatic- metal in the smaller deposits.No copper is
In
common with
lrydrothermal deposits (e.g., porphyry copper produced at Paradise Peak and Pueblo Viejo.
Mercury is producedat ParadisePeak, and the
deposits),HS depositscoincideworldwide with
plutonic-volcanicarcs. This associationis best Julcanidistrict has beena sourceof a remarkable
consistirrg
of Ag, Cu, Pb,
observedin the Cenozoicdepositsof the Circurn- polymetallicassemblage
Europe Au, W, Bi, and Zn (Table 2). The six largest
Pacificand the Balkanbelt of southeastern
deposits or districts (Chinkuashih,El Indio,
(F-ig I ). These deposits occur in two main
settings:in islandarcs and at continentalmargins. Goldfield, La Coipa, Lepanto,arrd Pueblo Viejo)
eachcontainsmore than about 100tonnesof gold.
The tectonic regime during formation of the
deposits seems to be dominantly extensional The economic potential of this type of
(Sillitoe 1993). Some deposits(e.g., Goldfield, mineralizationis clear in regions such as the
C h i l e a nA n d e s( S i l l i t o e1 9 9 1 a ) .
Rodalquilar, Summitville) formed in intracontinentalregionsduring periodsof extensiotl
VoLCANIcSITTTnCANDASSOCIATED
that followed regional compression and subROCKS
IGNEOUS
m.y.
ductiorrby several
Tertiary HS depositspredominate,and only a
The high-sulfidationdeposits consideredin
few deposits are Mesozoic (e.g., Pueblo Viejo,
Table 2 occur within intennediate-composition
Zijinshan),Paleozoic(e.g., Temora and othersin
volcanic rock sequenceshaving ages broadly
Australia),or PreCambrian(the early
southeastern
A Arribas, Jr.
Dcposit
Lateralalterationzoning
(outwardfrom nrinemlizcd txxlies)
Vertical altcration
zonin-9
(shallow t() dccp)
Pnncialore nrinerals
( )re
mineralization
rn:
Ag/Au
Motonlboto
VS ,qr-alu |qt7-kao )
k a o - s m cr i l l - c h l
Silicacorc
35--15
Nalcsbitan
SilicificdHbx )qL.-kx>
alu rill-sme-cbl-cal
Silicacorc
Vcry
Io* As
Lcpanto
VS/MS , tz-alu-kaor
kao-qtz-illrchl-ill
Silic:r corc
Chinkuashih
VS,MS rtltz-alu-kaor
ill-chl-kao
Silica corc
Zijrnshar
Silicacorc
N/A
N:ursaLsu
VSA4S ralu-dic-pyo'
ill-kao-smct
PRO
V S ( M S ) t q t z - a i u -t
qu-kao 'kao-ill I
snrc-chl
M S ( V S ) r q r z - : r l u - k aro
ill-smc I
PRO
Vertical(dueto deF)sit
s t y l c )M
: S ( V S )|
q?-alu-kaorsme-chl
VS/h4Sralu 'dic-serp Y ) s e r - c h lt P R o
e n a - l u z .p 1 ' .c l c . n a t . A u . a r g .
plr. cpy. bor. sph. gal. cas. stir
n)()1. can
S i l i c uc o r e
<2
vs(MS) ,qrz_kao_
x l u r q t z - k a or S E R
Silicaeorc
2-10
Siliclrcore
<|
M S ( V S )) q l z - a l u - k ( )
(SERin laulted.deeper('l)
EastZonedeposit)
Early:Kao-py-qu r
du-py<ltz
L a r e :M S r p y o _ d i a
S i l i c uc u r e
Sunrnritville
Goltllicld
Pu'irdiscPeak
P u e h l oV r e j o
Conrplex+ overprinted
Julcuri
pre<rrc:VS/MS)qtz_alukart rqtz-kao:Syn<rre:
qtz-pyo-pyrqu- kao-py+
q?-siir-py lq(Z-kao-smc
Vcins
El Indrr
Vcins
S i l i c uc o r e
Silicacore
La Mcjicaua.
Nevrdrx drl
Fiunatina
Rulalquilar
VS,MS rqtz-aiu-kaor
qtz-kao-ill r ill-sme-chl
InAA+
MS zoncs
10-30
.170
10-10
<I
A b b r e v i a t i o n su s c d :A A : a d v a n c e da r g i l l i c ,H b x - h y d r o t h e r m abl r c c c i a ,M S : m a s s i v es i l i c a , P R O - P r o p y l i t i c .S I J I { :
s e r i c i t i c ,V S - v u g g y s i l i c a , V S ( M S ) = v u g g y s i l i c a d o m i n a n t ,a l u - a l u n i t e , a r s : a r s e n o y r i t eb, a r - b a r i t c . b i s :
b i s m u t h i n i t eb
, o r = b o r n i t e ,b o u - b o u r n o n i t ec, a l : c a l c i t e .c c o = c h a l c o c i t ec, h a l . q t z: c h a l c e d o n yo r c h a l c e d o n i cq u a r t z ,
c h l : c h l o r i t e ,c i n = c i n n a b a r ,c a n : c a n f i e l d i t ec, a s : c a s s i t e r i t ec,o l - c o l u s i t e ,c o v : c o v e l l i t e ,c p y - c h a l c o p y r i t ed, i c :
d i c k i t e ,d i g : d i g e n i t e ,e l e : e l e c t r u m ,e m p : e m p l e c t i t e f, a m - f a m a t i n i t e( s t i b i o l u z o n i t e )g,a l : g a l c n a ,g c o - g e o c r o n i t r ,
, o l : m o l y b d c n i t c ,n a t . A u:
gol : goldfielditeh
, u e - h i i b n e r i t ,e i l l : i l l i t e , k a o : k a o l i n i t e ,l u z : l u z o n i t e ,m a r : m a r c a s i t cm
n a t i v e g o l d , n a t . S: n a t i v e s u l f u r ,n a t . T e: n a t i v et e l l u r i u m ,o r o = o r p i m e n t ,p y - p y r i t e .p y o : p y r o p h y l l i t c ,q t z : q u a r t z ,
rea=realgar,sele:selenides,ser=sericite,sid-siderite,sme:smectite,sph:sphalerite,sta=stannite.stb:stibnitc,
, u : t o u r m a l i n ew
, ol : wolfiamite
s u l f - s u l f i d e so r s u l f b s a l t st,e l l : t e l l u r i d e st,e n : t e n n a n t i t et,e t : t e t r a h e d r i t et o
I
B a s e do n f l u i d - i n c l u s i o n( f l i n c ) o r g e o l o g i c a (l g e o l )e v i d e n c e b; l a n k r v h e r en o t s p e c i f l e d .
'Boiling
( H b x ) - b o i l i n g d u e t o a b r u p tp r e s s u r cr e d u c t i o na - s s o c i a t ewdi t h h y d r o t h e r m abl r e c c i a t i o n
A. Arribus,Jr.
The depositis 3 km long and consistsof a tnain
is difficult, but useful for discussion of the
zone of breccia and replacementmineralization
of
design
differences among deposits and
alongthe LepantoFault(Fig. 4A). Multiple veins
exploration strategies.In this context, White
associatedwith smaller diagonal faults branch
three end-memberstylesof
(1991) distinguished
from the rnain zone and extend into both the
the
Circumof
deposits
HS deposits,namedafter
Pacific:Temora,El Indio, and Nansatsu.Irregular hanging wall and foot'ivall (Garcia l99l). The
cross-sectionof
characteristicmushroom-shaped
silicifiedoresdominatein
bodiesof disseminated,
many of the orebodiesat Lepantois relatedto the
the Temora-style. Cavity-filling veins with
intersectionof the steeplydipping Lepanto fault
of
sericiticand clay-rich haloesare characteristic
and branch veins with the unconfonnity at the
El Indio-style ALr deposits. A large group of
depositsfalls into White's(1991)Nansatsu-style, base of Imbanguiladacite (Fig. aB). Lithologic
which is characterizedby wallrock-alteratiort variations in the host rocks also played an
importantrole in the fonnation of the deposit.as
zoning similar to that shown in Figure2, and by
shown by lenses of stratiform enargite-luzotrite
ores within a
the occurrenceof enargite-bearing
which resultedfrom replacernentof detrital
ore
silica
massive
silica core consistingof vuggy or
ntary
layers within volcaniclastic and sedirne
rock (Table 3). Mineralization in this style of
units(Garcial99l ).
deposit forms irregular strataboundbodies (e.g., basement
vein-like
Nansatsu, Lepanto) or subvertical
"ledges"(e.g.,Chinkuashih,
AITEN.ITIONMINERALOGYANDZONING
Goldfield,
massesor
Lepanto, Rodalquilar, Summitville). These
As mentioned above, the lateral alteration
depositscontainbrecciabodies,veins,stockworks
oresthat replace zoning that is characteristicof HS deposits
of small veins.and disseminated
reflects the reaction and neutralizationof highor irnpregnate intensely altered country rock'
temperature acidic fluids with wallrock. The
two
Ericksen& Cunningham(1993)distinguished
innermost zone of vuggy or tnassive silica
Agstylesof HS depositsin the Andeanprovince:
alterationcommonly has sharpboundarieswith a
and Au-rich polymetallic base-metalveins' and
low-gradevuggy silica and breccias;the two types zone that may contaitrquartz, alurrite,kaolinite,
dickite,pyrophyllite,diaspore,and zunvite'.l'his
are broadly comparable with El Indio- and
gradesinto a second
advancedargillic assemblage
resPectivelY.
Nansatsu-styles,
envelope of argillic alteration, composed of
l,ocal subverticalfaults and fracturesare the
mineralssuch as quartz,kaolinite,illite, sericite,
dominant control on HS mineralizationand they
and smectite,and an outermosthalo of propylitic
are present in rnost deposits (Table 2). Other
examplesof structuralcontrolsobservedin some alteration,with chlorite. illite, smectite. and
districts arnong the foufteen selected include: carbonate(Fig. 2, Table 3). The width o1' eacl.t
rnoderatelyto shallow-dippingfaults (Goldfield)' zonevarieswidely; for example,vuggy silicaand
advancedargillically altered rock fonn narrow
caldera ring and radial faults (Rodalquilar),the
dilationaljog of a strike-slipfault (Nalesbitan), (<70 cm) vein selvagesat Julcatri(Deen 1990)'
but form wide (>50 m) rock bodiesat Sumrnitville
diatremering-faults(Lepanto,Pueblo Viejo), the
or Lepanto (Figs. 2 and 4). Late-stage',cavitycontactbetweena dome or volcanic conduit and
country rock (Motomboto, the Missionary filling planarveins at Julcaniand E,l Indio may
ln the
orebody at Summitville), and a lithologic extendoutsidethe zoneof alunite-kaolinite'
ore
of
the
most
however,
deposits,
majority of HS
unconfbrmity(PuebloViejo, Lepanto).In threeof
is containedwithin the silica core, inside the
the fburteen deposits, the principal control is
argillicenvelope('Iable3).
advanced
at PuebloViejo, and
lithological(maarsediments
interbeddedpyroclastic layers at ParadisePeak
and Nansatsu;Table 2).
A unique cornbinationof the structuraland
lithologicalcontrolscharacteristicof HS deposits
is exhibitedby the LepantoCu-Au-Ag deposit.
lln
Russian and eastern IJuropcan tcrrninology lhcse rtlcks are
'metasomatic quartzites" with nrorc specilic
conrmonly termcd
names such as porous quartzites, diasporc quartzitcs' alunite
q u a r t z i t e sa, n d d i c k i t eq u a r t z i t e s( e . g . .V c l i n o v e t u l . 1 9 9 0 ) r '
@
NW
A. Arribas, .Jr.
IKM
I
ffi
l ^ ^ a
f-'-^l
tl
m
@
Vuggysilica
Advancedargillic
Argillic
Sricitic
Propylitic
Inlensesupergeneacij-sulfateovsrprint
Au-(Cu-Te-Sn) htghsulfidation deposits
-100
Elsvation(m)
500m
High-suffidationEpithermalDeposits
I
I
1ee5).
A. Arribas, Jr.
Deposit
Mrxoniboto, Indoncsia
N a l c s b i t a n ,P h i l i p p i n e s
L c p a n t o ,P h i l i p p i n e s
C h i n k u a s h i h ,T a i w a n
Z i . l i n s h a n .C h i n a
Host-mineral
studicd
Barite
Quartz
Enargitc
Quartz, baritc.
alunite
Qu:rtz (no dctails
rcfx)rtcd)
N a n s a t s uJ, a p a n
Quartz
Akaiwa, Japan
Mitsumori-Nukeishi, Japan
DiasJnre
Quartz. ba-ritc,
quanz pnen(x
Quartz phcnoc
S u n i m i t v i l l e ,C o l o r a d o
Baritc
Coldlielcl,Nevada
Quartz-phenoc
Quartz, baritc
Quartz, barite
Quartz
Julclni, Peru
Ccarhuaraso, Peru
Colqui.jirca,Peru
Can-Can (La Coipa),
Chilc
El Indio, Chile
Quartz phenrr
Quartz phenoc
Wol, ena, quartz
Sidcritc
Quartz phenoc
Qufiz phcnoc
Sphalcritc. quartz
hiibnerite
Quartz phenoc
N/A
Tcmpcrature
("C)t
Asstriatcd
Salinity
(cquivwt.%NaCl) altcration
150-180
22(J-260
t](\-290
<l
0.24.5
I8{).330
o.2-t2
Atusil
AA/sil
AA/sil
a 1 a
I 6(f-3(X)
220 380
l 0(I- 160
(300-+20)
13(l250
-210
25F310
I 9(I-240
2I(I 330
3 ,t 9
0-5
(3-2(
))
<l
up to 30
Scr
sir
AA/sil
AA/sil
Scr
AAisil
0.5-1.1
l8(}_280
2-18
(300-390)
(upto 9)
230-480+
2I (),280
(37(H10)
r80-2I0
300,380
(upto 4-50)
I 60-280
36045t)
230-330
220,250
330-380
23(f,260
l7(I 350
5 1 8
0.2-8
AAisil
AAisil
<3
AA/sil
Ser
920
6-9
7 18
.+-ll
< l-40
I 90-280
i4(}-l80
(>3(n)
2(XI'+60
l6(i-340
230-480
0 .l 4
0.t-2.1
(upto 27)
t 3 l
0 . 3 , 12
341
- t(x)
3[r35
\ ) 4
38,46
AA/sil
AAisil
AA/sil
AA-/sil
AA/sil
donrinant
AA"/Ser
AA + scr
Scr
Rrxlalquilar,Spain
Quartz, quartz
phcnm
17F300
22(}.450
230
245
AA/sil
Ser
Furtei-Serrenti,ltaly
Quartz,barite,
quartzphentr
I 9(),320
9(I 140
(390-5m)
0.4-23
0.4-I .6
(32 45)
AA/sil
432
Table 4. (continued)
Dcposit
Commcnls
Rcl'crcnccs
Percll6( I 99:l)
Sillitm el rr1.(1990)
(1995),
Mancano
& Campbell
Garcia(1991)
Rcconnaisanccsrudy in latc-stagcbarite
Reconnaissancc
studyi liquid CO2 observcd
Samplcd intcrval 3 knl long by 0.5 kn hieh t ctnling tluitls
awav fionr subjaccntporphyry Cu-Au degrsit, whcrc
Th >.150'C & salinity up to 5.1eq wt.rl NaCl
P r x r r l y - d o c u m e n t esda m p l e sa l o n g a ' 1 5 ( l n r v e r t i c a li n t c r v a l :
the highcr Ths in sanples lt -7,50 m dcpth: CO2 ohserved
Asstrciatcdwith main stagc Cu
Dorrpaltcration zonc (>6(X) nr depth)
Associatcd with late. shallow silica-Au
Assrriated with carly silica and quartz-dickite
Late, vug-lilling quirtz
Qtz in brcccia. salrneliquid and krw-salimty vapor cmxist
Vein quartz -4(X) m helow Kasuga deposit
Coarsc-grainedclilsgrre
Not (known) Au or Cu mincralization, but high salinity
lluids
L i c l u i t l - r i c h :s a l i n i t y > 6 e q w l . 7 N a C l o n l y i n v u g g y s i l i c a
associatedwith Cu mineralization: CO2 obscrvcd
Lrquid- and vapor-rich inclusions: also polyphaseinclusions
Latc barite-Au assemblagc
Truc T5 is interpretedto be 25(1290"C
Hydrostatic and ncar-lithostaticprcssuressuggested
PiiraclisePcrk, Ncvatla
J o h ne t a 1 (. 1 9 9 1 )
Sillitoe& Lorson(l99tl)
J u l c a n i ,P c r u
Quaru-alunitetpyrite
Pro-oretourmalinc brcccia dykes, lithostatic pressureslikely.
Main-stagc orc fluicls, also inner veins, liquid-rich inclusions
Latc-stageore fluids, also in outcr vcinsl P correction applied
Quartz-alunitctpyrite
Quartz-al u ni tetpyrite
Two generationsidcntillcdl both may be very salinc. Evidcncc
firr P abovc hydrostatic and higher salinities at dcplh
Coppcr and gold stages
Late stage
Interprctcd as carly, with vapor-rich inclusions,CO2 observetl
LM & NF. includes liquid-, vapxrr-richand potyphasc inclusions
NF: complctc transiLionliom porphyry-type fluids in Ksilicatc stage (30(),6(X)+"C, up to 67 eq wtq, NaCl)
through sercitic to epithcrmal f'luids in HS (AA) stage;
vapor-rich inclusions typically less saline
Vcrtical temperature and salinity gradient: high-lcmperature
brines coexist with low -;Llinity vapor inclusions:
hydrostatic and near-lithostatic pressuressuggested
Includes hi-eh+ low-salinity fluids (22-23, <6 eq wt% NaCl)
Latc stagc
Bruha&Noble(198.1)
Shclnutt& Noble(1985)
Dccn ( 1990)
Deen( 1990)
Bruha&Noble(l9ti3)
Bruha& Nohlc(198.1)
Townley( 1991)
M ( ) t o r n b o t o I, n d o n c s i a
n * a l c s b i l a nP. h i l i p p i n c s
L c p a n t o ,P h i l i p p r n c s
C h i n k u a s h i h .T a i w a n
Z i . j i n s h a nC
, hina
N a n s a t s uJ, l p a n
A k a i w a ,J a p a n
M i t s u m o r i- N u k e : i s h iJ, a p a n
S ur n m i t v il l c . C o l o r a t i o
ColtlliekI, Ncvatla
Ccrrhuaraso, Pcru
C o l c l u i l i r c aP
, cru
C a n - C a n( L a C o i p a ) .
Chile
El Indiu, Chilc
La Mc.jicana(LM) and
Ncvacirs Famatina(NF),
Argcntina
Rrxlalquilu, Spain
Furtci-Scrrcnti, Italy
Folinsbee
et trl.(.1912).Ycn
( 1976),Tanet uL.(.1991)
Zhanger al. (1991)
Hcdcnquist
et ul. (1991.t)
Akamatsu
& Yui (1992)
(199-5)
Aoki & Watanabc
Sdnger-von
Oepenat a/. ( I 989),
Arribis et al. (1995a)
Ruggieri( I 993b)
433
A. Arribas,Jr.
Temperature("C)
and Julcani (Deen 1990) are broadly similar, but
their salinitiesare distinctly different (0.2-4.5
200
400
300
equiv.wt.% NaCl versus8-18 equiv.wt.% NaCl,
H2O+5wf/.NaCl
respectively),providing constraintson the role of
a saline magmatic liquid (versus Iow-salinity
vapor) in the generationof HS deposits.
Group 3. Lower temperature(e.g., 90-180
"C), dilute (typically <5 equiv. wt.yo NaCl)
o
liquids; these have been documentedin a few
0)
deposits associatedwith late-stage(e.9., Audno 6
barite)mineralization.The late-stageore fluids at
oC;
Deen 1990) and
Julcani are hotter (220-250
o
(s
slightlymore saline(6-9 equiv.wt.% NaCl), than
3
theseaverages,but no correlationamong the late
stagesin differentdepositsis attemptedhere.
A
;
- -n' n o
"Sericitic" fluids. As mentioned
Group ./.
a,
E
above,sericitic(quartz-sericite-pyrite)
is the most
q)
common alteration assemblageobserved below
o
the ore zone in some HS deposits.Although
detailed documentation is lacking for many
deposits,higher temperaturesand higher salinity
fluid-inclusionsseemto characterizethe sericitic
zone with respect to the shallower zones of
alteration(Table 4). For example,at Rodalquilar
Figure 6. Elevation versus temperature diagram
(Arribas et al. 1995a), documentation of temshowing the range (horizontal line) and average
perature and salinity along a >600-m vertical
(vertical line) of fluid-inclusion homogenization
interval(extending500 m below the ore zone;Fig.
temperatures
measuredin the RodalquilarAu deposit,
6) shows a gradient which correlateswith the
Spain.Also shown are the temperatures
calculated,on
change in dominant alteration,from silicic and
the basis of 63aSsurfide-surrare
for four coexisting aluniteadvancedargillicQ : 170-300oC,salinity:2-15
pyrite samples(large filled circles),referenceboilingequiv. wt.% NaCl at the elevationof the orebody) point curves,and vertical spansof the alterationzones
mentioned in the text. Estimated salinities of fluid
to sericitic(T: 220-450oC,salinity:2-45 equiv.
inclusionsin the shallowadvancedargillic/siliciczone
wt.% NaCl) assemblages.
and
deep sericiticzone range between2 to 30 equiv.
The transition from advancedargillic alteration,
wt.%
NaCl and 2 to 45 equiv.wt.% NaCl, respectively
through quartz-sericite-pyrite, to K-silicate
(modified from Arribas et al. 1995a).
alteration and typical porphyry-type hightemperature(600+ "C) and high-salinity(up to 67
equiv. wt.% NaCl) fluids of magmaticorigin is
rich hypersalineinclusions(i.e., with Groups 1
displayed,among the examplesreviewed,at the
del
and 4, above).Thesefluids may be the result of
Lepanto-FSE and La Mejicana-Nevados
liquid, or they may
Famatina epithermal-porphyrycopper systems. boiling of a high-temperature
reflect immiscible vapor and hypersalineliquid
The cooler and less saline inclusion fluids
derived directly from shallow-emplacedmagma
documentedin the ore zoneof the HS depositsare
(Rye 1993; Hedenquist & Lowenstern 1994
interpretedto reflect mixing of magmatic and
this volume).
Shinohara1994;Hedenquist
meteoricfluids in an environmentshallowerthan
that of porphyry mineralization.Furthermore,in
Sulfur-is otope Ev iden ce
common with porphyry-type deposits, highThe abundanceof coexisting hydrothermal
temperature, vapor-rich. low-salinity fluid
liquidsulfidesand sulfates,in additionto the possibility
inclusionscoexist with high-temperature,
q)
-'
(g
q)
434
rt
-Sultides -
t
It
F
I
Lepanto
--F
Sulfates^
V& V= 634515
p0 - 420
Chinkuashih
- t vI
Summitville
--.--*
Goldfield
PuebloViejo
Julcani
200- 390
I
@
I
I
180- 260
ry
200- 350
Y
-
200 - 240
l r f f i
t
! v
2-6
20 -270
'1-
Nansatsu
aSSHzs-sor
Temp.("C)' H2S/SO4
210- 270
i
:.
a
El Indio
Rodalquilar
-;
r
t - ' l
t
@"f"
l
I
I
220- 330
'(minerat
pairs)
10
20
6345(%",CDT)
!-igure 7. Range of 63o5(per mil) values for sulfidesand sulfatesfrom nine highsulfidationdeposits.Also shown are the valuescalculatedfor 5'oS for total sulfur in the
hydrothermal system (triangles), H2S/SO4.and the range of temperaturesdetermined
from sulfide-sulfate mineral pairs. Solid triangles indicatedepositsin which 6toS* was
calculated on the basis of isotopic analysesof samples of unaltered whole rock
genetically related to mineralization. See Appendix for referencesand information on
dataplotted.
'oS/"S
in host rock and genetically
of measuring
(Sasaki
et al. 1919),allows
related igneousrock
sulfur-isotopestudiesto provide information on
the composition,temperature,and sulfur sources
of the hydrothermalfluids. The resultsof detailed
studies in nine HS districts show a remarkable
consistency (Fig. 7). In agreement with the
observations in active volcanic-hydrothermal
systems(e.g.,Kiyosu & Kurahashi1983),sulfide
and sulfate minerals are mainly in isotopic
'oS/1'S
equilibrium, and, therefore,their overall
depends.onthe temperatureof mineralizationand
'"S/"S
of total sulfur in the hydrothermal
the
system. Only the data for alunite from the
Campanavein in El Indio (Fig. 7) are different.If
the measuredEl Indio alunites are not steamheatedor supergene(unlikely as they containfinegrainedpyrite; Jannaset al. 1990),the most likely
"magmatic-steam"(Rye et al.
explanation is a
1992)origin, in which the 63aSof aluniteis close
to the compositionof total sulfur in the system
(e.g.,Alunite Ridge in Marysvale;Cunninghamel
al. 1984: Rve el al. 1992\ . Combined with the
43s
./r.
.4..4rrihns.
lack of post-depositional
effectsthat disturbthe
and (4) the availability
stable-isotope
systematics.
of detailed information on the isotopic
compositionof fluids in active geothermaland
systems. which allows
volcanic-hvdrothermal
fluids estimatedin HS depositsto be compared
with thosein theiractiveequivalents.
'fhese
rnay be
Some limitationsstill exist.
rndependent
of obviousfactorssuch as sampling
procedures(fundamental
or mineral-preparation
for achievingrepresentativc
and reliableresults).
analyticalimprecision.and naturalvariations,as
observedin activesystems(c.g.,Aoki 1991,1992,
Rowe 1994).Importantlimitationsthat rnust be
taken into accourrtfor optimum use of the stableisotope data are related to ( l ) the choice of
temperatureof mineral formatiott fbr calculation
of the lluid isotopiccomposition.(2) thc lack of
mineral-water lractionation factors for some
minerals (e.g, pyrophyllite), and (3) the
disagreement among fractionation constants
proposedlbr evencommonmineralssuchas illite
(see Dilles er a/. 1992, for a discussion)and
kaolinite. For examole.at 200 oC there is a
difference of -20" lno between tlte D/lI fiactionationconstantsfor kaolinite - water as given
by Marumo et al. (1980) on the basisof samples
Oxygen- and Hydrogen-isotope Evidence
In terms of oxygett and hydrogen isotopic of mineralsand rvaterfrom activesystems,and by
t,iu & Epstein(1984)on the basisof experimental
composition,the fluids that form HS depositsare
results. For these reasons.discussionof the
arguably some of the better documentedand
understoodin ore-depositstudies.This situation sourcesof water during acidic alteratiorrin the
depositsconsideredhere is basedon the average
contrastssharply witli that of a decadeago, at
which time no data were availableto corroborate of the data collected for alunite, for which
the affinity suggestedbetween fluids in active fractionationfactors are well-known (Stoffregen
alunite
volcanic-hydrothermalsystemsand HS deposits et al. 1994).The magmatic-hydrothermal
(e.g.,Healdet al. 1987;Hedenquist1987).Stable- typical of HS depositsgives good resultsbecause
(post-mineralD-H
isotope studies of HS deposits are particularly it is relatively coarse-grained
problem;
Stoffregen
et al. 1994)
is
not
a
exchange
illuminatingbecauseof: (l) the abundanceand
with
associated
ore, thus
minerals and commonlyis closely
variety of oxygen-and hydrogen-bearing
(e.g.,alunite,illite, kaolinite),(2) the development recordingequilibriurnconditionsof a f-luidcloser
of analytical procedures for complete stable- in compositionto the ascendingmirreralizing
solution than the kaolinite or illite from outer
isotopeanalysisof alunite,including6l8orooand
alterationzones.
6'tOu' that help to distinguishthe varioustypes
Oxygen and hydrogen isotopic compositions
of alunite and associatedacid-sulfatealteration
water
in HS depositsare clearlyconsistentwith
of
(Rye et al. 1992; Wassermanet ctl. 1992), (3)
mixing between a high-temperaturemagmatic
fewer limitations on the interpretationof the
ond
f
l u i d o f 6 1 8 0 : 9 + 1 o / naon d6 D : - 3 0 + 2 0 " / o a
isotopic data becauseof the relativelyyoung age
part
(Fig.
because
of
groundwaters
8). In
of mineralizationof most HS depositsand general meteoric
bv a sulfate-rich
alteration.which is characterized
(3)
lsotopic
equilibassemblage
alunite-pyrite
rium between sulfide and sr-rlfate in the
hydrothermal
solutionsresults,in a nrajorityof the
calculated
on the
deposits.in reliabletemperatures
(Fig 7). Pyrite-alunite
basis on A3aSrr:s-so+
rnineral pairs were used most commonly, and
rvheresamplingrvith depth is available,thev shorv
oC over200-m
a thermalgradient:e.g.,220to 330
clevationat Rodalquilar(Arribas et al. 1995a).
200 to 390 "C over .--900m at S'.tmmitville(R1'e
1993)1220 to 420 'C over 500 m at l-epanto
(Hedenquistand Carcia 1990: J \\r. Hedenquist.
unpr-rb.data). Other mineral prirs used with
consistent results include p1'rite-barite(Vikre
(Venncmann
1989: Deen 1990),sphalerite-barite
(Vikre
1989).The
plrite-g1'psurn
et al. 1993),and
is consistentlvith
rangeof isotopictemperalures
and
temperaturesestimatedfrom fluid inerlusions
(e.g.,
et
ul.
1980;
Flemley'
alterationmineralogy
Reyes 1990;Rey'eset ul. 1993).l-he rangeis also
consistent with formation of altrnite at
belorv-400 "C, rvhenSO2gas starts
temperatures
to dispropottionatein the h1'drothermalsolution
(Sakai& Matsubaya1911;,
Bethke1984).
F
H igh-su(idation Epithermal Depos its
Alunite
alteration
stg.
mineralization
Ore
stg.
Q
Alteration/
O
.
^?y,
n
Subduction-related
volcanrcvapor
-40
3
>
a
-ou
t9 -eo
o
ta
-100
-tzv
-140
6180(%",sMow)
compositionof hydrothermal
Figure 8. Summary diagram showing variation in oxygen- and hydrogen-isotope
fluids in high-sulfidationdeposits.The averageisotopic compositionfor the main stagesof acidic alteration
(circles)fluids are shown. Where possible,only alunite data were used for the
(squares)and ore-mineralization
alterationstage(6D and 6r8O5eo);
6'tOo, is not usedbecausehydroxyl oxygenrequilibrateswith the hydrothermal
fluid during cooling (Rye et al. 1992),Tie-lines befweendata points connectsamplesfrom the same deposit.Inset
shows the isotopic composition of fields defined by waters from active geothermalsystemsand high-temperature
in subduction-related
andesiticvolcanoes(from Giggenbach1992b).Go: Goldfield, Ju:
fumarolecondensates
Julcani,Le- Lepanto,Nansatsudistrict: Ka - Kasuga,Iw : Iwato, NF : Nevadosdel Famatina,PV : Pueblo
Veijo, Ro : Rodalquilar,RM : Red Mountain, Lake City, Colorado, Su : Summitville. The approximate
compositionsof groundwaterssuggestedfor severaldepositsare indicatedby the intials parallel to the meteoric
water line. SeeAppendix for referencesand information on dataplotted.
the very light isotopic composition of local
meteoric water, this meteoric-magmatic watermixing trend is displayed particularly well by the
three stages of alterationlmineralization at Julcani
(Deen 1990; Rye 1993): from a magmatic-waterdominated early stage of (alunite) acid-sulfate
alteration (Ju, Fig. 8), through main ore-stage
fluid-inclusion waters (Ju1 and Ju2), to meteoricwater-dominated late ore-stage fluid-inclusion
437
A. Arribas, Jr.
ALTERATION
Mixing with
shallow
meteoric water
Absorptionof
high P vapor
uagmatic-'j
brine
Heated
oroundwater
cell
\ Ionvective
Metal-bearing
hypersaline /
liquid
l-
Heated
groundwatet
ll
Figure 9. Model showing the two main stagesof evolutionof HS deposits.A: Early stageof advancedargillic
alterationdominatedby magmatic vapor. B, and Bt: Two genetic hypothesesproposedfor the stage of ore
vapor by entrainmentin meteoricwater cell at depth to explain lowformation.B, - absorptionof high-pressure
salinity, mixed magmatic-meteoricore fluid (Hedenquistthis volume). B, - ascendingmetal-bearingmagmatic
brine with shallow cooler meteoricwatersto explain high-salinity,mixed magmatic-meteoricore fluid (White
I 99 I ; Rye I 993; Hedenquistet al. 1994a).
440
r
$
i
constituting
a relativelvsmall part of the rnixturc-l'he
(gcnerally <113, ltig. 8).
fluid-inclusiorr
evidence,by contrast.is inconclusivebecauseof
Nevertheless,
the lack of ternporal infonr-ration.
high-salinity inclusion fluids
high-temperature,
have been interpretedto form early in most I{S
deposits(e.g., Bruha & Noble 1983: Ruggieri
l993bl Arribaset ul. 1995a).TheseflLridsrnal'be
restrictedto greater depths. as demonstratedat
Rodalquilarand in other depositswlrere highrviththe deep
fluid is associated
salinityinclr-rsion
(Table
4).
This
latter obsersericiticalteration
vationsuggests
an episodicasccntof high-salinity
magmaticliquid fiom the greaterdepthsof the
system,rvherethe hypersaline
liquid
hydrothermal
of its high density(Fig. 9A).
tendsto staybecause
These nragmaticbrines rnay be rnore closely
relatedto the K-silicatealteration(and,in places.
porphyry m ineralization) that envelopes the
( F i g .9 A ; S i l l i t o c1 9 8 9 ) .
intrusion
The conditionsduring the rnain stageof ore
fbrmationare not yet as lvell-understood,and this
reflects the much rrore variable geochemical
environmentin cornparisonwith that associated
with acidic alteration.During the ore stage,the
hydrothennalliquid may bc lessdominatedby a
"sulfurmagnraticvapor phasearrd its associated
'fhe
presenceolgas bufibr" (Giggenbach1987).
this SO2-H2Sbufltr is the reasorrthat the early
stageof alterationis so oxidized,as reflectedby
the alunite-pyriteassernblage(Whitney 1988;
Giggenbach1992a).Instead,conditionsduringthe
ore stage f'luctuate within a range of redox
potential that is reflectcd by enargite-pyrite+
assoaluniteand enargite-tennantite-chalcopyrite
ciations,which are relativclyhigh to intermediate
sulfidation-stateassemblages,respectively (see
this volurne).tn the Lepanto
Fig. 3 in Hedenquist,
(Claveria & l'ledenquist1994) and El Indio
(Jannas et al. 1990) deposits, these two
are relatedto CLr-richand Au-rich
assemblages
with the latterbeing
respectively,
mineralization,
of later stage in both cases.The more reduced
of increased
corrditionsare a likely consequeltce
water-rock interaction, and, to some extent,
fluid
dilution of the oxidizedrnagrnatic
increased
by meteoricwater; this trcnd is also consistent
with the isotopic compositionof waters in tlre
main ore stageof variousdeposits(Fig. 8). No
441
A. Arrihas,Jr.
442
tectonicand hydrodynamicenvironment.None of
the threernodelssatisfiesthe overall evidence.For
example,if metalswere suppliedonly by a dense,
high-salinityliquid, a relationwould be expected
among estimated salinities, metal associations,
and ore gradeor metal abundances
of the various
deposits.Suchseemsrrotto be the case.Similarly,
if alterationand mineralizationwere solely the
result of interaction between groundwater and
low- and high-pressurevapor, respectively.high
salinitiesshouldnot be as comtnonas they
unlessthey areexplainedby localboilingof dilute
to moderately saline meteoric or seawaterdominatedfluids.
SYNTHESIS
Gold, Cu, and Ag (and in a few exceptional
casesalso Hg, W, Bi, Pb, and Zn) are produced
from HS deposits.As a sourceof Au, and because
their mode of occurrenceand the potential to
overlie porphyry-typernineralizationhave been
widely recognizedonly within the past 10 to l5
years, HS deposits represent a valuable
exploration target that has been overlooked in
someregions.Most known HS depositsare young
in age, Tertiary and even Quaternary. Highsulfldation deposits fbrm dominantly in
subduction-related plutonic-volcanic
arcs,
'fhe
commonlyduring crustalextension.
deposits
form at a depth intermediatebetweenthe surface
and shallow (few kilometersdepth) intermediatecomposition
intrusions.
The intimaterelationship
amongHS deposits,
volcanic host rocks, and oxidized magrnaticfluid
derivedfrom a degassing
intrusionis supported
by
(l) the volcanicrocks
the followingobservations:
hosting HS deposits were erupted immediately
prior to mineralization, (2) the ore-fbrming
hydrothermalsystemcommonly follows the same
plumbing as that of the magmaticsystem(i.e.,
rnineralizationspatiallyassociatedwith domesor
volcanicconduits),(3) the isotopiccompositionof
hypogenesulfides(e.g., enargiteand pyrite) and
sulfates(e.g.,alunitegnd.barite)
commonlycan be
'oS/"S
modelledfrom the
of sull'ur in rgneous
rocks thought to be genetically related, by
equilibriumfractionationbetweenH2Sand SOain
solutionat T -200-400 oC, and (4) on the basisof
High-sulfidationEpithermalDeposits
ACKNOWLEDGMENTS
Valuableinsight on variousaspectsrelatedto
this excitingore-formingenvironmentwas gained
and field work with M. Aoki,
throughdiscussions
J. Hedenquist.
A. ArribasSr.,C. G. Cunningham,
W.C. Kelly, R. O. Rye, J. J. Rytuba,andT. A.
Steven. Earlier versions of this manuscript
benefited from constructive reviews by Phil
Bethke,Andrew Campbell,Anne Thompson,John
Thompson, Peter Vikre, Noel White, and Jeff
Hedenquist, who also provided abundant
on HS depositsworldwide.
documentation
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APPENDIXI
Summary of data and references used to compile
Figures 3, 7, and 8.
Figure 3
K2O versusSiO2variationdiagram.The name
of lithologic units analyzed,number of sarnples
(n), and data sources are given: Chinkuashih,
daciten : 18 (Chen & Huh 1982);Choquelimpie,
Choquelimpie
volcaniccomplex(5 units).n - 20
(Gropper et al. 1991: chemical data fbr the
feldspar porphyries genetically related to
mineralization are not available); Goldfield.
rhyodaciten : 6 (Ransome1909;Ashley, unpub.
analysesin Sillitoe 1993);El Indio, Cerro de las
TortolasFormation,n: 15 (Maksaevet al. 1984
in Sillitoe 1993);Julcani,daciteand rhyodacite,
n
: 10 (Petersenet al. 1917); Laurani, Laurani
vofcanicand intrusiverocks, n : 10 (Jimenezet
al. 1993); Lepanto, Imbanguila dacite and least
alteredquartzdiorite porphyry,n : 4 (A. Arribas.
unpub. data); Motomboto, porphyritic intnrsions,
n: 10 (Perell61994, and written comm. 1995):
Nansatsu, Upper Formation and hornblende
andesitein Middle Volcanicrock, n :2 (E lzawa,
written comm. 1995); ParadisePeak, averageof
Younger andesites,
n : 3l (John et al. l99l);
Rodalquilar,hornblendeandesite,dacitetuff, and
rhyolite domes, n : 7 (Arribas et al. 1995a);
Summitville,Fisher quartzlatite,n: 7 (Steven&
Rattd i 960).
Figure 7
values.Giverr below are
Rangeof 63aS1o/oo)
for sulfides (nrirs),
the number of measurements
sulfates (nso+), sulfide-sulfate mineral pairs
(rA'oS), and references:Lepanto,flr2s: 52, n.no
:38 (Hedenquist
&
& Garcia1990;J. Hedenquist
M. Aoki, unpub. data); Chinkuashih,nvzs : 4,
^
3
4
trsoo : 2, ,L"S : 2 (Folinsbee et al. 1972);
Nansatsu,nszs: 6, n soq: 9 (Hedenquistet al.
1994a);Summitville,flLts : >11, n ssa : 17,
, A t o s : 7 ( R y ee t a l . l e e b ; :c o t a n e l d .n l 1 r s : 1 6 ,
n so+:16, n63ag: 7 (Jensenet al. 1911;Vikre
1989);PuebloViejo, ngzs: 19,n s174:7,ny3aS:
4 (Vennemannet al. 1993); Julcani,n11rs: 183,
453
A. Arribas,Jr.