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2.1 Introduction
In Chapter 1 it already was mentioned that concrete is a porous material which is not entirely liquid
tight. The challenge in this respect is to discover the structural possibilities of reinforced and prestressed
concrete. A liquid of gas can penetrate the concrete by capillary suction or under influence of hydrostatic pressure, respectively pressure differences. Other driving forces behind the transport mechanisms
are concentration differences, temperature differences and the draining of pores by chemical shrinkage.
By the effect of pressure differences a medium shall be able to flow through the porous concrete. As a
result of concentration differences across a reservoir wall, diffusion will take place. When cracks, joints
and seams are present, the transport driven by pressure will generally be much larger than the transport
driven by diffusion. However, for an uncracked casing, molecular diffusion will be an important cause
of - a relatively small - transport of fluid.
ce
+ wcr C + V1 =
320
+ 0.6 320 + 10 = 102 + 192 + 10 = 304 l
3.15
192 + 10
100% = 66%
304
2-1
Suppose that after some time a hydration degree is reached of h = 0.7 , in 1 m3 of concrete an amount
of capillary water Vw,cap is left of :
Vw,cap = Vw,o h ( 0.4 C ) = 192 0.7 ( 0.4 320 ) = 102 l
For the determination of the porosity of the hardened cement paste, this capillary volume Vw,cap has to
be increased by the initial air entrapment V1 = 10 l and the extra capillary pore volume generated by the
chemical shrinkage. This last volume is indicated by Vch , shr and is equal to 25% of the chemically bound
water:
paste
Vcap
126
Pc =
100% = 1000 100% = 12.6%
V
c
In most cases, the capillary porosity of concrete varies between 10% and 15%. The volume of gel pores
is normally not included in the capillary pore volume.
2.2.2 Permeability
Permeability of a material is the property that defines the ease of fluid transport through that material.
The material concrete, with a porosity of 10% to 15%, does not necessarily need to be permeable for
liquids. This depends on the manner how the porosity manifests itself. Several possibilities are shown in
Fig. 2.1.
high porosity
low permeability
porous
permeable
porous
not permeable
low porosity
high permeability
2-2
100
80
h ,max
60
40
20
0
0
0.1
0.2
wcr
0.3
0.4
0.5
0.6
0.7
0.8
Fig. 2.2: Maximum achievable degree of hydration and required degree of hydration
for the realisation of a closed capillary pore system.
(2.1)
where:
product
ammonia
n-butane
carbon dioxide
ethylene
hydrogen
methane
nitrogen
oxygen
propane
water
oil
sodium chloride
liquid
0.009
0.008
0.014
0.010
0.008
0.010
0.017
0.019
0.008
0.174
0.241
0.138
0.125
0.012
0.142
0.141
0.166
0.216
1.0
3.2
1.0
Contrary to the permeability k , the intrinsic permeability would be a real material parameter. However, one should be aware that in practice some dependence on the penetrating fluid will be present [2].
2-3
The permeability of concrete is depending on the permeability of the aggregates, the cement paste and
the boundary layer between the cement paste matrix and aggregates. Although the aggregates constitute
about 70|% of the concrete and their permeability demonstrates considerable variations (Table 2.2), still
the permeability of concrete will mainly be determined by the cement paste and the mentioned boundary layer between cement paste and aggregates.
type of aggregate
permeability k [m/s]
10-6 10-10
10-8 10-15
10-10 10-15
10-10 10-13
10-13 10-15
sandstone
limestone, dolomite
granite
diorite-porphyry
quartz
wcr ;
degree of hydration;
micro-crack formation;
fabrication of the concrete (in relation to its purpose);
curing of the concrete.
Because of the many factors that influence the permeability, the values for are very different for the
several classes of concrete. The intrinsic permeability for concrete varies between 10-14 and 10-19 m2.
For hardened normal gravel concrete with a wcr from 0.4 to 0.5, often a permeability k is chosen of
10-11 up to 10-12 m/s. Application of blast furnace cement (CEM III) in combination with a low wcr
may lead to permeabilities that are a factor 100 less. Addition of fly ash to the cement delivers a lower
permeability as well. Very tight concrete is obtained by the suppletion of silica fume. This material is a
required additive for the production of high-strength concrete. The permeability of concrete produced
with light, slightly water absorbing aggregates, does not need to be larger than that of normal gravel
concrete, in some cases it even may be a factor 1000 lower. This is caused by the very dense boundary
layer between the aggregates and matrix.
As a result of the relatively porous boundary layer between the dense aggregates and the cement paste
matrix, the permeability of concrete generally will be larger that that of the hardened cement paste. A
rough estimate for the difference is a factor 10. However, slightly absorbing aggregates may produce a
very dense boundary layer leading to a permeability that does not need to be larger than that of the cement paste itself.
2-4
100
90
80
70
60
50
40
30
20
10
100
0.7
wcr
0.6
80
0.4
0.3
0.5
60
0.2
40
10
20
amount of capillary pores [vol. %]
30
40
Fig. 2.3: Permeability k [m/s] for water of hardened cement paste [Powers].
r t
2
(2.2)
where:
x
r
= penetration depth
= pore diameter
= surface tension
= time
= dynamic viscosity
[m]
[m]
[N/m]
[s]
[Pa.s]
The penetration depth x of a gas or a liquid driven by a (hydrostatic) pressure can be computed with
the formula ([5], also see Fig. 2.4):
x=
r 2 g ht
Pcap
(2.3)
where:
[kg/m3]
[m/s2]
2-5
pi
h
Qc
pe
Fig. 2.4: Penetration depth (left) and flow (right) through uncracked concrete.
h = pressure head (m water column) [m]
Pcap = capillary porosity
[m3/m3]
From a number of liquids and gases that are stored in tanks, the dynamic viscosity is listed in Table 2.1.
For several other liquids, in Germany classified as reference liquids used for classification of environmentally damaging liquids, the dynamic viscosity is given in Table 2.3.
The practical use the formulae (2.2) and (2.3) is limited, because the determination of the representative
pore diameter r is quite a challenge. Capillary pores vary in diameter between 10-9 and 10-4 m. To
avoid this problem, with the formula of Valenta ([6], [7]) a reasonable approximation can be obtained:
2k ht
Pcap
x=
(2.4)
where:
= permeability
no.
main
chemical group
[m/s]
possible
hazardous
action
reference
liquid
dynamic
viscosity
[Pa.s]
surface
tension
[N/m2]
density
[kg/m3]
aliphatic
hydrocarbons
loss of
strength
n-heptane
0.041
20.3
686.8
aromatic
hydrocarbons
loss of
strength
toluene
0.582
28.5
866.9
alcohols
dissolving
attack
n-butane
alcohol
2.928
33.5
809.4
esters
dissolving
attack
ethyl acetate
0.450
23.9
925
aldehydes,
ketones
dissolving
attack
methyl ethyl
ketone
0.4
24.6
803
aliphatic
amines
n-butyl amine
0.5
23.0
740
halogenated aliphatic
hydrocarbons
production of
chlorides
methyl
chloride
0.440
26.5
1325.5
organic
acids
dissolving
attack
acetic acid
(20% solution)
1.10
47.7
1026.1
halogenated aromatic
hydrocarbons
production of
chlorine
chloro
benzene
0.810
33.5
1106.4
2-6
Above formulae for the calculation of the penetration depth are based on the assumption that during the
penetration process the permeability remains unchanged. However, when the penetrating fluids are able
to react with the cement paste, the assumption of a constant permeability is no longer correct. In the
pore system reaction products may be deposited, leading to a reduction in permeability (also see Section
2.3.3). When the reaction products are soluble, a process of leaching out may occur, which even can increase the permeability. Further, the extrapolation of short-term permeability tests to the long-term behaviour of structures is a challenging but difficult task.
Example 2
Question
Give an indication of the penetration depth of lightly aggressive waste water under a pressure head of 1 m in hardened concrete after 3 and 28 days, followed by 1 and 5 years.
Data
Cement type: blast-furnace cement (coarse) CEM III 42.5;
A wcr of 0.45 and 0.55, respectively;
The concrete with wcr = 0.55 appeared to be poorly compacted and poorly cured;
The waste water can be considered to be water with the following properties:
Dynamic viscosity: = 103 Pa.s
Density: = 1000 kg/m3
Maximum pressure head: h = 1 m
Intrinsic permeability
It is assumed that the concrete reaches a degree of hydration of 60% and 70% for a wcr of 0.45 and 0.55, respectively. With the aid of Fig. 2.3, the permeability k and the capillary porosity Pcap of the hardened cement paste
can be found, the obtained values are listed in the table below under the headings mixture A and mixture B.
Because of the relatively poor curing of mixture B, a permeability factor for the concrete is selected, which is a
factor 10 higher that that of the hardened cement paste.
Penetration depth x
The penetration depth is determined with the formula of Valenta (2.4). The table below shows the results.
time
exposure time
days or years
3 days
28 days
1year
5 years
exposure time
seconds
260 103
2.4 106
31 106
157 106
mixture A
wcf = 0.45
k = 17 1013 m/s
kcon = k = 17 1013 m/s
Pcap 0.30
0.002
0.005
0.019
0.042
kcon
mixture B
wcf = 0.55
k = 45 1013 m/s
= 10k = 45 1012 m/s
Pcap 0.35
0.008
0.025
0.089
0.201
Discussion
The calculated values clearly show the effect of the wcr on the penetration depth. For a wcr of 0.45, after 5
years of penetration, the waste water will just have reached the reinforcement (assume a concrete cover of 30
mm). Notice that transport of ions by diffusion is not taken into account and may lead to an extra contribution
to the flow.
Penetration by capillary suction into the outer centimetres of concrete is often much larger than the penetration
driven by fluid pressure.
Next to the wcr , the way and carefulness of the fabrication and curing of the concrete are determining factors
for the actual permeability. In many cases, these factors are even more important than the choice of the wcr
However, it should be clear that in the opposite case of a concrete with a superb fabrication and curing but
with a high value for the wcr , it is not possible to produce a concrete with a high tightness.
2-7
connection tube
400 mm
glass funnel
liquid
100 mm
In [8] a comparison has been made between the results of the ISI/DIS 7031 test and the capillary absorption test. In this research the penetration depth has been studied of water as well as diesel and petrol. No unambiguous relation could be established between the penetration depth according to the
ISO/DIS 7031 test and the capillary absorption test. For an extensive elaboration it is referred to [8, 9].
plastic cap
75 mm
50 80 mm
dehydrating
agent
dehydrating zone
5-70 mm
inside, dry
capillary zone
seal of
epoxy resin
100 mm
Fig. 2.6: Schematic of test setup for the determination of moisture transport through concrete.
12
10
8
water emission
moisture from
specimen only
2
capillary water absorption
0
change moisture
content of concrete
-2
-4
100
200
300
400
height of specimen [mm]
500
600
700
800
Fig. 2.7: Absorption and emission of water after 290 days as function of the specimen height [12].
2-9
at which a concrete specimen sucks up water from a shallow basin and releases moisture at the top in a
confined space with a constant humidity of 3% (Fig. 2.6). Because of the constant difference in relative
humidity one would expect that a steady-state situation would develop, in which a constant flow of water would be absorbed at the bottom and released again at the top of the specimen. However it was observed that for the larger specimen the absorption of water stagnated. No water was sucked up anymore
and (nearly) no moisture released at the top. This phenomenon is caused by a reaction between the cement paste and the water. Lime crystals in the pore system dissolve and generate a concentration gradient, which creates a diffusion process that prohibits further capillary intrusion of the water [10]. It
should be remarked that chemical interactions between the penetrating fluid and the cement paste
may occur that influence the penetration rate as well (for example the dynamic viscosity may be reduced).
Qc =
A p
(2.5)
Where:
= intrinsic permeability
Qc = flow through the concrete
[m2]
[m3/s]
A = cross-sectional area of wall
[m2]
p = pressure difference over the wall or slab thickness [Pa]
= dynamic viscosity of the fluid
[Pa.s]
d = wall thickness
[m]
A worked out example can be found below.
Example 3
Question
Determine the flow of water through an uncracked concrete panel.
Data
Concrete on bases of CEM I
Wall thickness: d = 0.25 m
Pressure difference across the wall: p = 4 104 Pa
Wall area considered: A = 1 m 2
Intrinsic permeability: = 18 10 20 m 2
Dynamic viscosity: = 103 Pa.s
Solution
With Darcys formula it directly follows:
A p
1 4 104
Qc =
18 1020 = 28.8 1012 m3 /s = 0.0025 l/day
= 3
d
10 0.25
A. Structural level
At structural level attention is paid to the existing crack pattern. The following characteristic aspects
can be distinguished:
2-10
1) Crack width;
2) Number of cracks;
3) Type of cracks;
a) Separation cracks;
b) Flexural cracks;
4) Crack characteristics;
a) Stability (for example not stable due to settlement and continuous shrinkage);
b) Cyclic crack width (cyclic loading).
On the one side the crack pattern is determined by the relevant loading scenarios and on the other side
by the design and dimensioning of the structure.
B. Crack level
For the calculation of the transport of a fluid through a crack, the following parameters are important:
1) Crack width;
2) Crack length, i.e. the thickness of the concrete element;
3) Morphology of the crack face;
Both the crack patterns and the transport of a fluid through a single crack are governed by factors that
display a large amount of scatter. These conditions invite to address transport problems of fluids
through cracks with probabilistic considerations respectively probabilistic computations.
However in the next section, a deterministic approach will be followed for the analysis of the transport
problem.
w3 p
l
d
[m3/s]
(2.6)
where:
w = crack width
p = pressure difference
l
= crack length
= dynamic viscosity
d = thickness of concrete element
= coefficient, depending on roughness of the crack face
[m]
[Pa]
[m]
[Pa.s]
[m]
[-]
The factor depends on the morphology of the crack surface, the type of aggregates and the wcr . For
smooth surfaces it holds = 1/12 (Poiseuille). Because of the roughness of the crack surface the value
of reduces with a factor 2 up to 10. The magnitude of the factor increases with increasing crack
width. For many practical applications a value of = 0.01 can be selected. Separation cracks with a
crack width w < 0.06 mm can be regarded as liquid tight for a period of at least 72 hours [14]. In Germany, these 72 hours is used as the reference period for the definition of the suitability of concrete for
environmental protective structures. By the way, for very small crack widths, w < 0.1 mm , the reliability of equation (2.6) is quite limited.
2-11
When determining the factor it normally is assumed that the crack width remains constant. Alterations in the crack width during the fluid transport due to clogging up of the crack, due to autogenous
healing or due to freezing up (cryogen applications) are not explicitly taken into consideration. Cracks
may also become larger by cyclic loading.
For separation cracks with a varying crack width in flow direction, the crack width w in formula (2.6)
has to be replaced by the effective crack width weff given by (Fig. 2.8):
wA
h
wB
(2.7)
Example 4
Question
Calculate the flow of water through a crack of 1 m length in a 0.25 m thick wall. Vary the crack width from 0.1 to
0.2 mm.
Data
Wall thickness: d = 0.25 m
Crack width: w = 0.1, 0.15 and 0.2 mm
Crack length: l = 1 m
Pressure drop over wall: p = 4 104 Pa (4 m water head)
Dynamic viscosity: = 103 Pa.s
Morphology factor: = 0.01
Solution
With the formula of Poiseuille (2.6) the following relation is found:
w3 p
w3 4 104
Qcrack =
l = 0.01 3
1 = 1.6 106 w3 m3 /s
d
10 0.25
The results for the given crack widths are shown in the table below. For reasons of comparison the results of example 2 (flow through uncracked concrete) are indicated as well.
Crack width w
[m]
0.00010
0.00015
0.00020
Qcrack
3
m /s
-6
1.610
5.410-6
12.810-6
l/day
Qc (example 2)
Qcrack Q c
138
467
1106
0.0025 l/day
0.0025 l/day
0.0025 l/day
55103
187103
442103
conclusion
The results of the calculations clearly show that the fluid transport through cracks can easily exceed the flow
through uncracked concrete by a factor 105. Therefore, it confidently can be concluded that generally the transport
of fluids through cracks will be several orders of magnitude larger than the transport through the concrete itself.
2-12
Flexural cracks
In the case of the presence of flexural cracks, the flow rate will predominantly be determined by the size
of the concrete compressive zone (Fig. 2.9). Relation (2.5) can be used for the determination of the flow
rate, in which case the wall thickness d of the element has to be replaced by the depth of the concrete
compressive zone hx . This leads to a conservative estimation of the permeability, because the flexural
cracks that still have a significant flow resistance are not included in the analysis.
h
hx
w2 w1
htm
w1
measurement length
3000 mm
temperature
P1
pressure
strain gauges
cracks
displacement transducers
P0
pressure
P2 pressure
flow meters 1 2
pressue reducer
filter
Fig. 2.11: Setup for measurement of air and water transport through cracks in a concrete beam [12].
As1
= 0.60%
reinforcement
20
As 2
= 0.57%
16
As 3
As 4
As 5
As 6
= 1.15%
16
s = 125 mm
concrete
IBAP
EDF
R1
R2
R3
E3
R4
E4
R5
E5
E6
1250
1000
750
E4
500
E6
250
0
E5
0.05
0.10
0.15
imposed strain []
0.20
0.25
0.30
Fig. 2.13: Liquid transport through cracked concrete as function of the imposed strain
with reinforcement configurations according to Fig. 2.12 [12].
2-14
continuous hydration;
sedimentation of solid particles that are present in the penetrating liquid;
closure of the crack by cement particles from the crack face;
swelling of the cement paste.
Schiessl
wcrit 0.20
[mm]
Hl
Meischner
0.15
0.10
Lohmeyer
0.05
10
15
20
25
30
35
H l hw [-]
Fig. 2.14: Relation between critical crack width and ratio of liquid head and wall thickness
(Lohmeyer [25], Meischner [26] and Schiessl et.al. [27]).
Meischner [26] is a bit more optimistic, however it should be remarked that his curve is based on results
of experiments conducted under laboratory circumstances.
Recent laboratory research of Scheissl et. al. [27] even provides wider margins for the occurrence of
autogenous healing.
However the values of Lohmeyer, that are based on practical observations, still have preference for
practical applications.
(2.8)
Smaller values of hx are acceptable, provided that certain crack-width conditions are satisfied. These
conditions depend on the presence or absence of self healing:
w95% < 0.1 mm (without self healing)
w95% < 0.2 mm (with self healing)
(2.9)
2-16
hx ,max 2 Dmax
(2.10)
In the case of separation cracks, Lohmeyer gives a guideline for the critical crack width for which autogenous healing is still possible. This guideline is given in Table 2.4. An important parameter in this table is the ratio of the pressure head H l and the wall thickness hw or hb of the element. For a crack in
the floor slab the pressure head should be measured from the bottom side of the slab.
ground
water
level
ground
water
level
liquid
head
Hl
hw
liquid
head
Hl
position
of largest
crack
Cat.
1
2
3
Hl
hw
or
2.5
5
> 5 1)
Hl
hb
calculated
wcrit
[mm]
0.20
0.15
0.10
Remark
Cyclic loading is permissible as long as
its effect is explicitly taken into account.
This delivers such a stringent condition
that preferably cyclic loading should be
prevented, for example by thermal isolation of the structure.
Table 2.4: Permissible crack widths for separation cracks for which still water tightness
can be guaranteed (after [28]); Classification of tightness criteria [2].
2-17
800
water
hd / h = 7
temp. 20 0C
= PVA fibres (0.8 vol. %)
= steel fibres (1.0 vol. %)
= PAN fibres (1.7 vol. %)
= no fibres
flow [ml/min.m]
600
400
200
0
0
0.1
crack width [mm]
0.2
0.3
0.4
Fig. 2.15: Permeability for water of ordinary concrete and fibre concrete [18].
2.9 References
[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15] Bomhard H. (1992): Concrete and Environment - An Introduction, FIP symposium, Budapest,
Vol. 1, pp. 51-59.
[16] Edvardsen C. (1996): Water penetration and autogenous healing of separation cracks in concrete, Betonwerk+Fertigteiltechnik, Vol. 11, pp. 77-85.
[17] Nordheuss H.W. (1991): Berechnungsgrundlagen und Vorschlge fr die Konstruktion und
Ausbildung von Fugen in Bodenplatten aus Beton, die chemischen Angriffen ausgesetzt sind,
Darmstadt.
[18] Tsukamoto M. et al: Permeability of cracked fibre reinforced concrete, Darmstadt Concrete,
Vol. 6, pp. 123-136.
[19] Betoniek (1998): Voeistofdicht beton III, no. 9, October 1998.
[20] Bomhard H. (1983): Wasserbehlter aus beton Anforderungs-, Entwurfs, Planungs- und Bemessungskriterien, Mnchen, 46 p.
[21] BS 5337 (1976), Code of Practice for the Structural Use of Concrete for Retaining Aqueous
Liquids, British Standards Institution, London.
[22] BS 5337 (amendment 1982: see [23]) (1976), Code of Practice for the Structural Use of Concrete for Retaining Aqueous Liquids, British Standards Institution, London.
[23] ACI-committee 350/AWWA (1993), Testing Reinforced Concrete Structures for water tightness, ACI-Structural Journal, Vol. 90, No. 3, pp 324-328.
[24] Schntgen B., Durchlssigkeituntersuchungen an gerissenen Betonbauteilen (mit Wasser und
wssriger Lsung), Deutscher Ausschluss fr Stahlbeton, 25, Forschungkoll., pp. 79-86.
[25] Lohmeyer G., Wasserdurchlssige Betonbauwerke Gegenmassnahmen bei Durchfeugtungen,
Beton 2/84, pp 57-60.
[26] Meischner H., Ueber die Selbstheilung von Trennrissen in Beton, Beton- und Stahlbetonbau,
Vol. 87 No. 4, pp95-99.
[27] Schiessl P. et. al. (1993), Massgebende Einflussgrssen auf die Wasserdurchlssigkeit van gerissenen Stahlbetonbauteilen, DBV Arbeitstagung, Wiesbaden, pp. 25-32.
[28] Lohmeyer G. (1994), Weisse Wannen Einfach und Sicher, Beton-Verlag, Dsseldorf, p. 255.
2-19