Professional Documents
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Submitted By
Md. Mohsin Alam
ABSTRACT
Natural dyes may be defined as the dyes which are extracted from the flower petals, leaves, bark,
steam to ensure environmental friendly dyeing of the sample and end uses of the dyed sample with
the application of mordanting agents to retain better fastness properties. Natural dyes are very
popular for their different hues and environmental friendly nature but most of the natural dyes are
non-substantive and must be applied on textiles with the help of mordants, usually a metallic salt,
having an affinity for both the coloring matter and the fibre. In this study, natural dyes were
extracted from marigold flower petals and applied on 100% cotton knitted fabric in exhaust method
using six different metallic salts (K2Cr2O7, FeSO4, NiSO4, CuSO4.5H2O, potash alum) as mordant.
Various fastness properties of the dyed sample were measured to evaluate the effect of different
mordanting agents on fastness properties of dyed samples. The effluent was characterized through
COD measurement to find the pollution load of different mordants. From the observation of the
overall result it is found that sample dyed with marigold flower extract having mordanted with
potash alum shows excellent color fastness and less environmental hazardous properties.
2. NATURAL DYEING:
Natural dyeing may be defined as a process of dyeing the textile materials with the extracts from the
natural sources like plants, animal and minerals by the help of mordants, usually a metallic salt,
having an affinity for both the coloring matter and the fiber.
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3. NATURAL DYES:
Natural dyes are the dyes and pigments obtained from renewable resources of nature, such as plant
and animal and minerals. Natural dyes are applied chiefly for coloration of food, drugs,
cosmetics,textile, paper, leather, shoe-polish, candle, wood etc. Natural dyes are mostly nonsubstantive and must be applied with mordants on textiles [1]. Natural dyes cover a wide range of
chemical classes including indigoid, anthraquinone, alpha-naphthoquinone, flavones, flavonols dihydropyrans, anthocyanidins and carotenoids [2].
Thus, for proper fixation of natural dyes on any textile fibre, mordanting is essential in most of the
cases.
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8. MORDANTING AGENT:
Mordants are substances which are used to fix a dye to the fibres. They also improve the take-up
quality of the fabric and help to improve color and light-fastness. Now-a-days most natural dyers use
chemical mordants such as alum, copper sulphate, iron or chrome. The most commonly used
mordant is alum.
The following materials have been used at different process in this research work:
Material
General description
100% cotton knitted fabric of 160 GSM.
Fabric
Dye
Salt
Washing agent
Artificial perspiration
IR Dyer
(v)
Crock meter
(ii)
Electronic Balance
(vi)
(iii)
(vii)
(iv)
Rota Wash
11. METHODOLOGY:
Flower Water-
100gm
5 litres.
Temperature- 60oC
11.2. MORDANTING:
Mordanting is the method used to fix a dye to the fibres by using mordanting agents. This method
improves the take-up quality of the fabric and help to improve color and light-fastness. The sample
of cotton is mordanted before dyeing. For mordanting different eco-friendly mordanting agents like
Potassium Dichromate (K2Cr2O7), Ferrous Sulphate (FeSO4), Nickel (II) Sulphate (NiSO4), Copper
Sulphate (CuSO4.5H2O), Stannous Chloride (SnCl2), Potash Alum [K2Al2(SO4)3.24H2O] etc. have
been used. The cloth is then mordanted by dipping it in a solution of above mentioned mordants
separately and water. The cloth is thus ready for subsequent dyeing. A common principle has been
followed during mordanting with different mordanting agents
Recipe:
Mordanting agent 5 g/l
Temp
Time
M: L
60 min
Procedure:
a. Weight sample fabric of 5 gm.
b. Take 100cc water into a pot and add 5gm mordanting agent at room temperature.
c. Now put the sample into the solution and load the pot in the machine.
d. Raise the temperature to 100oC and keep it for 60 min.
e. Cool to 40oC and kept overnight for conditioning.
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1000C
1: 20
Process Curve:
20 g/l
Time
60 min
Salt
5g/l
Temp
600C
Leveling agent
1g/l
M: L
1:20
Procedure:
a. Take 20g/l (10% stock solution) of dye solution into a pot and then 5gm salt is added.
b. Before put the mordanted sample it was soaked in cold water
c. Now Put the mordanted sample into the pot and load the pot in the machine.
d. Raise the temperature to 60oC and keep it for 60 min.
e. Cool to 40oC.
f. Cold rinse for 5 min.
Process Curve:
Temp (0c)
60
400C
Time (min)
11.4. WASHING:
At the end of the dyeing process the samples are washed by following
Recipe:
Soaping agent -
M: L-
1:20
Temperature-
40oC
Time-
10 min
Then the samples are cold washed by hand and dried by Hot Air Dryer.
Process Curve:
Temp (0c)
Add sample & soaping agent
40
Drain & Rinsing
R .T
0
10
Time (min)
SL NO
FASTNESS
METHOD
01
02
03
04
05
Fastness
SnCl2
Wash fastness
3-4
3-4
4-5
3-4
Alkaline Perspiration
4-5
Acidic Perspiration
4-5
4-5
Saliva
4-5
4-5
Water
4-5
4-5
4-5
Dry Rubbing
4-5
4.5
Wet Rubbing
4-5
4-5
4-5
Light fastness
4-5
COD (mg/l)
1247
855
1351
760
811
1635
15. CONCLUSION:
This project work indicates that samples dyed with marigold flower extract dye have an influencial
effect on the fastness properties due to the use of different mordants. Different mordants impart
better fastness properties differently like samples mordanted with potash alum shows excellent color
fastness to wash and samples mordanted with ferrous sulphate and potash alum are more resistant to
perspiration. Mordents like copper sulphate and potash alum makes the sample more resistance to
saliva and gives the sample higher fastness to light. Briefly it can be said that potash alum mordant
gives better fastness properties in all aspects to the sample dyed with marigold extract dyes.
16. SUGGESTION FOR FUTURE WORK:
In future non-aqueous and other solvent assisted system for extraction of color may be used.
In future it may extend to other natural flower and using more types of mordanting agents.
The mordanting and dyeing at 1000C and 600C respectively in this research work may be
changed to new experiment in future.
In future natural mordanting agents like aloevera during mordanting may be used instead of
chemical mordanting agents for natural dyeing and printing.
It may be research on effect of shade & analysis of anti-microbial finishing on different types of
fabric by dyeing with marigold extracted dyes.
REFERENCES
[1] http://www.wikipedia.org /Natural Dye
[2] Dyeing of Textiles with Natural Dyes by Ashis Kumar Samanta and Adwaita Konar, Department
of Jute and Fibre Technology, University of Calcutta, India
[3] Pruthi, Neelam;Agarwal,Radhika;Singh,S,Jeet,Saroj Effect of mordants on printting with
merigold flowers dyeNatural Product Radiance,Volume-6;Issue-4;Page:306-309 (2007)
[4] Nilani, Duraisamy, P., Dhamodaran, Kasthuribai, Alok Semwol and Suresh The Effect of
Marigold Flower Dye with Natural Mordant on Selected Fibers; Journal of Pharmacy Research,
Volume-1; Issue-2; page: 176-181 (Oct- December 2008)
[5] M., HarikrishnanExtraction of natural dyes (Xanthophyll) from marigold flower Journal of
Advanced Scientific Research, Volume-4; Issue-2; Page: 48-50 (2013)
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