Professional Documents
Culture Documents
CHAPTER 6
CHAPTER 6
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m
Vx
[kg / m 3 ]
(1.1)
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- Bulk density (g) - due to the bulk volume (Vg) which represents the
volume occupied in a given volume of a granular material.
- Stack density (s) corresponding to the stacks volume (Vs) (form by
elements witch have regular geometrical shape), including the voids
between the elements.
Density is one of the most important physical characteristics of
building materials, allowing global assessment of other technical
features. In the design, bulk density and measuring the pile self-weight of
construction elements.
1.3. Structural characteristics
Material structure, in terms of solid matter distribution and pores, is
expressed as: compactness, porosity and voids volume.
Compactness (C) is the proportion of the volume (Va) is occupied
by the volume of material constituents (Vr ).
V
V
(1.2)
C r a ; C% r 100
Va
Va
Compactness is directly related to strength, which should be even
higher with greater compactness of the same material.
Porosity (P) is the proportion of pore volume occupies the volume
of a solid body and may be apparent or open it consists of open pores
(that communicates with the outside) and is composed of pores closed
when not communicate with the outside.
C + C P = 1% + P% = loo%
(1.3)
The porosity and apparent porosity in particular, are in inverse
relationship with the durability of a material, the apparent porosity is as
large as lower mechanical resistance and resistance to environmental
factors but the lower closed porosity is much greater capacity better
thermal insulation.
The voids volume (Vvoid) is the proportion that the volume of grains
participating in the gaps in the bunch formation volume of granular
material.
The value of goals is important when making materials resulting
from the agglomeration of granules - concrete and mortar.
Granularity expresses the relative content of different size granules
of a granular material.
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80
70
60
50
40
30
20
10
0
0
Di-1
material
material
material
material
Di
Dmax
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10
F
A
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Stress will oppose the removal or proximity of the two parts of the
section, while efforts will be opposed lunecrii mutual tangential
sections.
The mechanical testing involves subjecting the mechanical
action of external forces of a sample representative of a material
to its partial or total rupture.
Internal force per unit area () that arises in a body, its
structure in response to the action of external forces is called the
unitary effort (stress) or internal stress.
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deformation of the specimen and thus will deform state efforts. This test is
called the friction test.
Compressive strength is determined by the relationship:
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13
Fmax
A0
(1.4)
where:
F = maximum force recorded during the test, N;
Ao = initial area of the specimen perpendicular to the direction of
force in mm2.
Static compression test bodies may take the form: cubic. prismatic
and cylindrical.
Size of the test results of friction will depend on:
Geometry of specimen (specimen form) as follows:
- The ratio between height and the cross section determines the
outcome of the large pieces and smaller cubic prismatic specimens;
- Determines the shape of the specimen cross-sectional results of
increasingly larger as the number of sides is greater.
It follows therefore that for the same material, samples of sections
equivalent resistances obtained on prismatic specimens (RPR) will be
lower than those obtained on cylindrical specimens (Rcil) that are smaller
than those from the cubic specimens.
Specimens volume, as the specimen volume is higher, lower
compressive strength results. This influence is explained by increasing
probability of existence of structural defects with increasing specimen
volume.
For cubic specimens, the most commonly used, the results
obtained on the sample side 10 cm will be 10% higher than those
obtained on the sample side 20 cm.
1.6.2. Static tensile test
Tensile strength of most building materials is lower than
compressive strength, is significantly influenced by initial state
microfisurare material structure, whereas areas not involved in the
response structure microcracks in tensile forces.
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15
series of errors that, in some cases make the results obtained are
considered only.
CHAPTER 2
2. SUBSTANCES STRUCTURE
Building materials are generally well-defined, from chemical and
physical point of view, mixtures of substances.
Substances properties of are determined by the atoms types
present in the structure, the bonds type established between them or
between the constituents and physical state.
Substances have different characteristics as a result of chemical
composition, structure and mode of presentation, but all are simple or
complex compounds of atoms.
2.1. Chemical elements
The atom (from the Greek athomos - that can not be
separated) is the smallest part of a chemical element that can
exist either alone or in combination with similar particles of the
same element.
Atoms have the following characteristics:
Presents a complex structure
Has small dimensions (<10-9 m)
Can exists as independent
Are electrically neutral
Chemical element is the substance that can not be
decompounded into simpler substances by usual chemical or
physical procedures and which can form, by chemical
combination, the compounded substances.
109 chemical elements are known of which 91 (natural) can be
found in nature and the remaining 18 were put out in the laboratory
(artificial).
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In 1913, Nils Bohr, believes that the electrons are rotating around
the nucleus by circular trajectory, and Arnold Sommerfeld in 1916 shows
that the trajectory is in the form of an ellipse with the nucleus located in
one of the ellipses focal.
Orbital is the region of space where the probability of occurrence
of a given electron having a well defined energy is maximum.
Electrons are particles having the mass of 9.1108 x 10-31kg
(1/1837 from the of protons mass) and negative electrical
charge and in an atom, equal with the number of protons.
Electronic shell of atoms is composed of a fixed number of
electronic layers. Each electronic layer is characterized by the principal
quantum number "n" that defines the layers energy and is conventional
noted, from the nucleus outward, with the symbols K, L, M, N, O, P, Q or
Arabic numerals from 1 to 7. In one layer can coexist maxim 2 x n2 (2, 8,
18,...) electrons. Because in energy level can only a maximum number of
electrons can be found than, electrons in addition are placed in the next
energy level outwards. The structure of atoms - energy layers and
particles in the nucleus are schematically presents in fig.2.1.
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calculations
and
working
with
mole
gram
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acid (Si (OH) 4), countries (H3PO4, H2SO4) and very strong (HCl) for
elements of groups V, VI, VII respectively.
As shown in Table 2.2 combinations alkali earth oxides, Group II of
the periodic system with various other acidic or amphoteric oxides can
position their properties as binders in the group is primary or secondary,
on the basis of this rule may provide behavior of combinations not
studied yet.
Table 2.2.
Period oxide elements
Group II oxides acids
SiO2 Al2O3 Fe2O3 Cr2O3 Mn2O3 SnO2
BCO II
III MgO
IV CaO
IV ZnO
V Sro
V CdO
VI BeO
without binder properties studied, the binder properties studied
2.3. Spread in crust elements
Earth's crust (16 ... 20 km depth) is a major source of construction
materials and raw materials for the construction industry.
The knowledge gained while on the earth's crust allowed to
calculate the percentages involved in the chemical composition of its
various elements. American Geochimitii Clark and Washington made
the first calculations of these percentages and they have called MF,
later called clark-uri.
Clarkurile of medium frequencies is the percentage by weight of
the items involved in crust formation. Items with the highest clarkuri are:
oxygen (47.2%), silicon (27.6%), aluminum (8.8%), iron (5.1%), calcium
(3.6%), sodium ( 2.6%), potassium (2.6%), magnesium (2.1%).
It notes that of the 92 naturally occurring elements in the
intervening eight crust structure with 99.64%, other 84 items are in a very
small percentage, dispersed into other elements or less in the form of
local clusters (veins).
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and . Only radiation emitted (photons), the nuclei can return to the
fundamental energy.
The phenomenon of radioactivity is governed only by a law called the
law of disintegration, which is stated as follows: the probability of decay
of a radionuclide per unit time is constant and is independent of external
conditions. Mathematical expression of this law in differential form is:
and the full form is:
N = N0. e- . t
Where:
N = no. radioactive nuclei at the initial time, t = 0;
T = decay time lasts;
= decay constant, or probability of decay, radionucleu own
species.
Radioactive decay is a reaction that follows after a first-order
kinetics and half-life which is a basic feature, t0, 5 (t1 / 2) species-specific
radionuclide. The half-t0, 5 can range from microseconds to billions of
years.
e) spontaneous fission is rare, only nuclei with atomic weight about
232. From this nucleus with mass number smaller nuclei (at least two light
nuclei) without interfering with the external energy.
Interaction of nuclear radiation environment
When nuclear radiation (particles , ,
and neutrons) crosses
the environment, they deplete their energy or by a mechanism monoact
or in a large number of impact processes. Energy given environment
produces a number of effects, among which the most important are the
ionization and excitation.
and
radiation (charged) produce the environment due to
strong ionization process that occurs predominantly by plucking
electrons from atoms and molecules collide with, while losing energy.
Electrons can also plucked their other ionized atoms or molecules.
Ionization process intensity is expressed quantitatively by the number of
ion pairs formed on a tape of the incident trajectory, called specific
ionization or ionization power. This task depends on mass and energy
incident radiation, and on the nature of passage. Ionization power of
particles (A is 4 amu) is considerably higher than that of a particle (A
is 0.00055 amu) at the same energy, for example, produces air particle
50000-100000 ion pairs / cm, and particle, the same energy, only 30300 pairs of ions / cm.
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15
radiation (no load) directly collide with the electrons orbit the
atom, transferring energy and throughout, as a result, the electron can
be pulled out and ejected from the atom with a kinetic energy equal to
the difference between the photon energy h
incident and energy
connecting the electron to atom (Ec = h - El). Electron beam produces
an electron plucked secondary.
ionization of atoms under the
influence of radiation is much lower than that produced by radiation
and .
If the energy lost by radiation from the collision energy is less about
the electron, then it can not be torn from the atom or molecule to which
it belongs, has held only that the atom excitation and electron energy
taken the form of heat is dissipated .
Neutrons are particles without electric charge and zero rest mass
interacts with the environment differently from other types of radiation.
They do not interact with orbital electrons of atoms, atomic nuclei but
only in three types of physical processes: elastic or inelastic scattering,
diffusion in the environment and slowing down and capture by nuclei. As
a result, there occurs a direct ionization of the environment, but only
through a secondary recoil atoms displaced by elastic collisions with light
nuclei or particles emitted in the capture reactions.
The maximum distance that a radiation crosses a certain energy in
a given environment is called penetration or distance traveled and
expressed in meters. Example: radiation in air has a pathway 0.0380
m and radiation of several meters.
Be emphasized that while
radiation have a relatively short
distance, depending on the nature, radiation is higher by 1-2 orders of
magnitude, and
radiation and especially neutrons, which run across
any environment, their course has much higher values. Table 1 presents
some characteristics of nuclear radiation.
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CHAPTER 2
Table 2.4. Convert Curie - Becquerel
Ci Ci
Bq Bq
kCI (103C) TBq TBq (1012 Bq) Ci
GBq Ci GBq (109 Bq) mCi
mCi (10-3) MBq MBq (106 Bq)
Ci
Ci (10 / 6 Ci) kBq kBq (103 Bq) nCi
nCi (10-9Ci)
PCI Bq Bq
PCI (10-12Ci) MBq MBq (10-3) FCI
Absorbed dose
Various nuclear radiation ( ,
,
) interacts differently with
different materials they pass through. To avoid these biological effects of
radiation, use size D - dose absorbed, which expresses the amount of
energy transferred to unit mass of absorbent material. As a unit, the
system S.I. Gray is used (symbol Gy) after the name of English scholar.
One gray corresponds to a joule per kilogram. Frequently used
Submultiples of gray, such as micrograyul ( Gy)
1 gray (Gy) = 1 J / kg:
Old unit absorbed dose is Radul
1 rad = 100 erg / g
The relationship between these units is as follows:
1 Gy = 100 rad and 1 rad = 10 2Gy (centigray)
Absorbed dose rate can be expressed in: Gy / s, rad / minute, or
rad / day, as it is more convenient.
Equivalent dose
Biological effects of nuclear radiation is different, even at the
same absorbed dose. For example: a gray radiation in human tissue is
more dangerous than a gray radiation
is slower because the
particle electric charge and more than - more energy dissipates along
the journey . To restore all ionizing radiation on an equal basis in relation
to the possibility of negative effects, he introduced a quantity called
equivalent dose, the unit of measure (SI) site is sievert (symbol S ),
named after the scientist Swedish.
Dose equivalent is equal to the absorbed dose multiplied by a
factor of radiation quality, a factor which takes account of how
radiation distributes its energy in the tissue. For example, radiation , -,
and X factor was taken as equal to unity.
Sievert's (S ) is defined as the equivalent dose for tissue exposed to
radiation with quality factor equal to unity when the tissue that absorbed
dose is 1 Gy, so the gray and sievert units are numerically equal.
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18
= 1 S = 1 Gy 1j/kg
Typically used sievert's multiples such as M S
Rem is used as the unit's old (Roentogen Equivalent Man) The
relationship between these units is:
S 1 = 100 rem or 1 rem = 1 C S
For example, when a radionuclide is deposited in the human
body, it is possible to calculate the radiation dose absorbed by the
body, if known radionuclide activity.
Knowing the level of radiation in dwellings is important for
determining exposure of the population since most people spend a
great deal of time in confinement (average occupation factor of 0.8 is
statistically determined).
Radiation source is constituted by the main primordial
radionuclides present ubicular the earth's crust, ie 40K. 87Rb and two
series of radioactive elements from 238U and 232Th.
Other natural radionuclides, such as those present in the 238U
series, radionuclides cosmogenici (8H, 7Be, 14C, 22Na, etc..) Sio those
from 238U spontaneous fission (eg 90Sr) can be neglected because their
contribution to the total dose of radiation is small .
Radioactive elements of interest in the building materials are the heavy
metals., 220Rn and 222Rn except that belong to the noble gases.
Gaseous radionuclides, released by construction elements, generates
short-lived progeny, which are incorporated by inhalation and is the
etiologic agent of lung cancer radioindus.
Radiobiological risks resulting from the presence of radioactive
substances in building materials are composed of external radiation
emitting radionuclides produced by drop the items and materials from
internal irradiation from inhalation of radon and its daughter products
accumulate in living quarters.
Absorbed dose rate inside the building depends only on the type
of construction material used and its origin. Construction elements acting
both as a source of irradiation and as suppressors of cosmic and
terrestrial irradiation, intense outdoors.
Evaluation of radiation dose on the whole body of the radioactive
content of building materials.
Indoor absorbed dose rate depends mainly on the activity
concentration of natural radionuclides in building materials. Linking the
radioactive content of the radiation dose is difficult.
The main contributors to the dose of radiation are absorbed from 40K
(35%) 232Th (40%) and 238U offspring (25%). As such, determining the
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After the value of the degree of hardness, the waters are classified as
(tab.2.4).
Tab.2.4
Characteristic of water hardness
<50 Very Soft
Soft 50 ... 100
100 ... 200 Middle
Tough 200 ... 300
> 300 Very Hard
Hard water can not be used in boilers, the operation of pipelines
(salts deposit on pipe walls, and difficult to reduce the flow section) in
heat exchangers (deposited salts reduce thermal conductivity) in some
processes (preparation of concrete and mortars).
Water hardness which does not allow use in certain areas should
be subject to a complex: preparation processes - to reduce impurities treatment processes based on one of the following:
By mechanical removal of impurities is accomplished by
decanting (separation) in large tanks (settlers) by the separation of
suspended impurities is achieved under the action of its own weight.
Water, partially purified (clarified) is then filtered by passing through
layers of gravel and sand.
Coagulation is achieved by introducing colloidal impurities in
water of chemicals called coagulants, which carries agglomeration and
sedimentation of very fine dirt bands such large formats (see Chapter 3),
after which water is filtered through sand filters. Coagulanii most often
used are: aluminum sulphate, ferric sulphate, ferric chloride, etc..
Degassing seeks removal of gases, mainly aggressive (O2, CO2)
dissolved in water and heat is conducted in facilities called degassed.
Chemical softening seeks removal of ions that cause water
hardness (Ca 2 + and Mg 2 +) using the following methods:
Softening with lime and soda, the lime [Ca (OH) 2] and soda
(Na2CO3) lead to the formation of sparingly soluble carbonates which
precipitated
Ca (HCO3) 2 + Ca (OH) 2 + 2H2O
2CaCO3
MgCl2 + Na2CO3 +
2NaCl MgCO3
Softening trisodium phosphate is used when water is to achieve a
degree of hardness as a (d0 10), removal of impurities is achieved by
precipitation of calcium phosphate and magnesium.
3Ca (HCO3) 2 + 2Na2PO4 CA3 (PO4) 2 + 6Na) (HCO3)
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CHAPTER 2
glass vessels, silver, of which the air out). One thing worth mentioning is
that substances placed in liquid air changes its properties:
flowers, meats, fruits become brittle;
rubber loses its elasticity and is also brittle;
mercury solidifies and becomes malleable;
produce lead to striking, metallic sound (specific).
Liquid air is used to obtain very low temperatures and also to study
the behavior of substances or materials at such temperatures. Of liquid
air by fractional distillation, separated oxygen, nitrogen, rare gases.
2.11.3. Chemical
In terms of chemical properties have air gas components. Due to
the presence of oxygen, air support combustion. But burning is less
intense than in oxygen because nitrogen reduces oxygen action. Air is
essential for life. man can live weeks without food, several days without
water, but can not survive without air or 6 minutes. Man eating,
breathing, 12 kg of air in 24 hours.
In addition to the maintenance of life and as a source of CO2 for
plants, the air is of particular importance in the industry. In ferrous and
nonferrous metallurgy, all oxidation processes ore roasting and occur
only in the presence of air. The research laboratories are used to obtain
very low temperatures. Mixed with coal dust, in certain circumstances,
be used as explosives in underground works.
The sheath air of our planet depends on:
preserving the earth's heat;
the role perfectly natural filter for certain solar radiation;
protection from the meteor shower;
achieve optimum water flow;
the possibility of transmitting sound, Radio etc..;
conducting flight operations;
providing the conditions essential to life.
2.12. Macrostructure materials
Materials may have a unitary structure in a volume sufficient to
achieve a majority element of construction but have a composite
macrostructure, made from fixing a matrix of components that are
present in different forms (fig.2.17).
Fig. 2.18. Macrostructure materials
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41
CHAPTER 3
3. STATES OF MATTER
Matter can be presented in 4 states: plasma (99.98% of the
matter in the universe), gas, liquid and solid. For the study of
construction materials it is in our interest only the states in which matter
is found on earths conditions temperature and pressure meaning
the states: gas, liquid and solid.
In a material found in well determined physical conditions
(temperature and pressure) there are 2 tendencies that act in opposite
directions and lead to the realization of its own state:
The first tendency is due to the forces of interparticular
bondage (Van der Walls forces, hydrogen bonds etc.) under the
action of which the particles tend to dispose themselves orderly,
realizing a state of equilibrium poor in energy;
The second tendency is due to the thermal agitation of
particles which never disappears, its size depending on temperature
and leads to the destruction of the orderly structure.
Depending on the share of these tendencies, in a material one
of the 3 aggregation states can be realized
The solid state in which the tendency to order
predominates, the thermal agitation of particles manifesting
under the form of small amplitude oscillations around a position
of equilibrium (considered fixed in space) and for this reason
solids have own volume and shape.
The liquid state in which the constituent particles, under
the influence of the thermal agitation, execute a movement of
oscillation and one of translation, without producing major
modifications on the distance between particles (which are
found at a medium distance.
The gas state defined by
attraction forces, under the action
constituent particles have a chaotic
from this one result the status with
volume.
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CHAPTER 3
triclinic (parallelepiped)
simple
centered
simple
simple
bodycentered
orthorhombic (cuboid)
tetragonal (square
cuboid)
rhombohedral
(trigonal trapezohedron)
hexagonal (centered
regular hexagon)
cubic
simple
body-centered face-centered
CHAPTER 3
(isometric; cube)
CHAPTER 3
CHAPTER 3
a.
c.
b.
d.
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OC
1713
573
tridimit
870
cristob
alit
sticla de c
uart
1470
topitura
cristobalit
tridimit
cuart
cuart
timp
racire-incalzire lenta
racire rapida
CHAPTER 3
temperatura (C)
lichid
1538
1390
906
768
ferita
ferita
timp
cub cu fete
-10
nemagnetica dizolva max.1,7%C
centrate 3,66 m.10
2,90 m.10 -10 paramagnetica
cub centrat 2,88 m.10 -10 feromagnetica dizolva max.0,03%C
Forma de
cristalizare
Parametri
de retea
Principalele
caracteristici
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10
11
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12
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dv
dx
(3.1)
where:
= tangential stress that appears to move by a force of a
portion of a liquid than other portion;
dv
dx
13
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a.
b.
c.
Fig.3.8. Voltage dependence tagenial - speed gradient liquid
and plastic flow cvasiplastic
Liquids with a threshold voltage (fig.3.8) cvasiplastice plastic
and which is characterized in that the stream must exceed a threshold
voltage (. In this category are oil paints, clay pasta, fresh concrete,
etc..
Fluids characterized by fig.3.8.a curve (plastic flow), are called
Bingham fluids, thus assumed that the fluids flow at rest have a certain
rigidity following a three-dimensional structures, able to withstand the
efforts of unit lower than threshold voltage. Once destroyed this
structure, fluid flow, behaving like a Newtonian fluid (as it explains that
dyes remain on the support webs).
14
CHAPTER 3
0 ea
0 ebp
where:
= Viscosity of liquid at normal atmospheric temperature and
pressure
= temperature;
p = pressure
a and b = experimental constant
Variation of viscosity with temperature explains why, for
optimum lubrication of machine parts are used, as seasons, lubricants
with different viscosities.
In practice, the viscosity can be expressed in the form of
kinematic viscosity, defined as the ratio of dynamic viscosity and
density of the liquid for a given temperature:
N.s.m / kg
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15
16
CHAPTER 3
p
ps
sau U
p
100%
ps
(3.3)
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17
18
CHAPTER 3
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19
freeze).
Fig.3.10. Changes in the freezing water volume
Experimentally, it was revealed that: substances which increase
the volume of melting, melting temperature increases with increasing
pressure, the substance which reduces the volume of melting, melting
temperature decreases with increasing pressure.
3.9. The mechanism of crystallization from melts
It was shown that the method of solidification and cooling rate
depends on the chemical nature of the melt - a rapid cooling
20
CHAPTER 3
phenomenon.
Fig.3.11. Crystallization from solutions
scattered throughout the melt mass. When the temperature of
solidification, the particles are disposed around the crystallites, not
randomly, but in future crystal axes, making the tree formations called
dentrite (fig.3.11). Melt the metal cools, the crystallization tendency is
so pronounced that at the melt surface, dentritele is observed with the
naked eye. Over time, the solidification temperature of the particles
from the melt takes place between the branches dentritelor - ordered
filling gaps - and thus take the form of solid crystal in all directions.
Following the process of melt crystallization throughout the
mass, the first phase crystallites are spread across the table and they
melt and are formed around dentritelor dentritele be isolated crystals
grow continuously until they meet. Since the meeting between the
crystal is made at random crystal growth stops after random buttons, so
that the crystalline solid formed from the melt, crystals are not regular in
shape - ideal - but the crystal grain of irregular shape. Ordered
structure but each grain is characteristic of crystalline state. In this way,
explains the characteristics of crystalline structures of isotropic grain
(rock, metal, etc.).
3.10 The liquid transformations to gas and the gas
transformations to liquid
The liquid transformations to gas and the gas transformations to
liquid produces to the variation of all parameters of state(temperature,
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23
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CHAPTER 4
4. SUBSTANCES SYSTEMS
In nature, so in the construction materials, substances (with the
same structure and chemical composition) can not be found singular,
only very rarely, usually in a system form and in contact with other
substances.
In the separation limit of two substances, their homogeneity
changes, peripheral layers of particles (molecules, atoms, ions) are
subject to different actions than those the inner particles are subjected
and consequently the structure of substances with greater cohesion
forces molecular pressure occurs and in the same time will attract
particles of substances having smaller cohesion forces and thus in the
contact area, the concentration of the substance becomes bigger than
the rest of its volume.
These disturbances lead to the interface phenomenon (contact
area of two substances).
4.1. Interface phenomenons
Interface phenomenons depend on the internal cohesion forces
and their intensity will depend on:
the chemical structure of substances with they are coming into
contact, because it determines the size of the internal cohesion forces;
the substances states of matter, because for the same
substance the cohesion forces size depends on the state of matter
(decrease from solid state to the gaseous state)
temperature and pressure, because the energetic state and the
internal cohesion are modified.
particles concentration, as internal cohesion depends on the
number of constituents.
4.1.1. Adsorption, absorption, sorption and desorption
Adsorption is the phenomenon witch leads to form of a layer
particles (molecules, atoms, ions) from a substance with less internal
cohesion forces (liquid or gas) on the surface of a substance with greater
cohesion forces (in liquid or solid).
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Sorption is the sum between adsorption and absorption.
sl
lg
sl
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manifest the superficial tensions corresponding to the interfaces: solidgas, solid-liquid and respectively liquid-gas.
lg
sg
lg
sg
sl
sl
(4.1)
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b
Fig.4.3. Capillary movement
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d2
.g.h
4
4
h .
g .d
(4.2)
where:
d = diameter of the capillary tube
= liquids density
g = gravity acceleration
Note that the capillary height for the same liquid and solid will be
grater as the diameter is smaller. In a capilar, the capillary height will be
lower than in a capillary vessel due to the diameters variationan
nonlinear path, so in a sandy soil capillary height will be higher than in
gravel. To prevent ground water to rise in constructions walls, building
elements which cut capillaries are provided (fig.4.4).
Zidarie
Sistem de intrerupere
a capilaritatii
Teren
umed
CHAPTER 4
The liquids that can not form homogeneous mixtures are called
immiscible.
4.1.6. Influence of absorption on the substances characteristics
At the gas - liquid separation surface and immiscible liquids by
adsorption the surface tension is modified. In the adsorbed layer the
surface tension has a intermediary value between the surface tension of
the two substances that come in contact, closer to the lower surface
tension.
Liquids surface tension, with application in practice can be
modified using the surface-active substances.
Surface-active substances, generally organic substances having a
polar structure, accumulate on the liquids surface of orienting
themselves according to the surfaces (hydrophilic or hydrophobic)
nature forming "molecular brushes".
The formed monomolecular layer modifies the attraction force
between liquids molecules that leads to surface tensions modification
to the characters (hydrophobic or hydrophilic) modification.
Adsorption on solid surface modifies a number of their properties.
Practically all the solid materials in the air can be considered that they
have on their surface an adsorbed film from the gases and water vapor
in the atmosphere, it producing the following changes:
Gradual increase in volume, beginning from the contact
surface, which can cause cracks in the solid;
Decrease of the tensile strength, due to open microcracks from
the solids surface, where the adsorbed molecules protrude, widening
and deepening them with a wedge effect (fig.4.5); it was established
that the tensile strength of glass bar heated (in vacuum at 3500C when
the gas desorption is produced from the glasses surface) is two times
higher than a similar sample, but kept in the air; this explains why the
thinner wires strength is greater than those with higher cross section.
Desorbtie
Adsorbtie
CHAPTER 4
P
F
oil
oil
water
a.
b.
Fig.4.7. Liophobisation and liophilisation processes
CHAPTER 4
Cubs side
1cm
1mm
Nr. of
cubs
1
103
Table 4.1.
Specific surface
cm2/cm3
6
6
60
6x10
10
CHAPTER 4
100
10
1
100m
10m
1m
106
109
1012
1015
1018
1021
600
6000
60000
600000
6000000
60000000
6x102
6x103
6x104
6x105
6x106
6x107
If the particles shape is spherical (the sphere has the lowest surface
volume ratio from al the geometrical bodies) the specific surface is
reduced to 80%.
The specific surface size can be accomplished by several methods
such as:
Materials milling (in tubular ball mills) when the particles can
reach the size in order of microns (for cement) and if one takes into
account the surfaces rough of the particle the specific surface increases
significantly.
Increasing of the surface roughness, especially by the moderate
action of corrosive agents. Due to the solids surfaces unhomogeneity,
the corrosion occurs ununiform, the surface turning into a field filled with
microscopic grooves.
Precipitation methods. The products resulted from chemical
reactions, precipitate on inert solid support from chemically point of
view.
4.2. Disperse systems
It was shown that the materials consist of mixtures of substances
which can be distinguished between them by the chemical structure or
state of mater. The substances mixtures are forming the substances
systems which are characterized by:
The components of the system, defined by the individual
substances chemically differentiated.
Systems phases are consisting of homogeneous and distinct parts,
physically separated from each other through well-defined surfaces.
11
CHAPTER 4
Systems type
Systems
name
< 10-7
homogeneous
Solutions
heterogeneous
Colloids
Observations
The dispersoid has small
molecules of the atoms or
ions, can not be observed
by optical microscope
The dispersoid can be
observed by high definition
optical microscope but not
by free eye
12
CHAPTER 4
> 10-5
name
gas
gas
G-G
Gas
mixtures
liquid
gas
liquid
solid
G-L
L-L
S-L
liquid
solutions
solid
gas
G-S
alloys
solid
solution
G-G and G-L solutions are achieved due to the gas ability to
diffuse gas through the solvents constituents;
13
CHAPTER 4
The L-L and S-L solutions dizolvation occurs in two stages: in the
first stage the solutes bonds are destroyed realizing solvent solute
bonds witch are diffusing in the solvent in the next stage.
G-S and S-S solutions are realized in liquid state of the solvent
and, if necessary, of the solute, according to L-L mechanism.
S-S solutions basic constituent for metals and isomorphic crystalline
substances, are achieved by replacing the solvent from the crystalline
lattice with solute particles substitutional solutions or by positioning of
the solute particles in the interstices of the solvents crystalline lattice interstitial solutions (fig.4.8).
a.
b.
c.
14
CHAPTER 4
solvent
solvent
+ hidratare +- - + +
+
+
+ -+
a
+ -+
z
i
l
hidro
- +
- - +- +
+ polarizare - +
+
- +
+
- +
disociere electrolitic +
+- + - +- +
a) solut cu reea ionic
b) solut cu reea molecular
a.
b.
Fig. 3.7. Schema dizolvrii solidelor n lichidecu moleculepolare
+
+ e
r
a
t
a
r
- + hid
+ -+
++
-+
+ +- +
za i
l
o
r
d
i
h
+
-++
-
solut
solut
lattice are van der Waals type or hydrogen bonds and the solvent
solute connection forces are van der Waals type.
For the study of building materials is particularly interested in the
mechanism of dissolving of solids in liquid solvents, especially water.
Dissolving will depend on the soliss (the solute) and waters
(solvent) bonds nature and occurs in two stages (fig.4.9).
15
CHAPTER 4
%Cm
s
S
100
(4.3)
Where:
s - mass of solute (g)
S - solvent mass (grams)
Concentration percentage of volume - is the ratio of solute mass
and 100ml of solution.
%Cv
s
V
100
(4.4)
Where:
s - mass of solute (g)
V - volume of solution (ml)
Mass of solution in grams contained in one milliliter of solution is
called titre and is denoted T.
Volume percentage concentration represents the ratio between
the solute and 100 units of volume of solution.
%Cv
v
V
100
(4.5)
Where:
v - solute mass (ml)
V - volume of solution (ml)
Molar concentration (molarity) - is expressed by the number of
moles of solution dissolved in one liter of solution.
16
CHAPTER 4
%Cm
m
V
1000
(4. 6)
Where:
m - the number of moles of solution
V - volume of solution (ml)
Molal concentration (molality) - is expressed by the number of
moles of solution dissolved in 1000 g of solvent.
%m
m
Vs
1000
(4. 7)
Where:
m - number of moles of solution
Vs - volume of solvent (ml)
Normal concentration (normality) - is expressed by the number of
gram equivalents (val) solution dissolved in one liter of solution.
%m
m
Vs
1000
(4.8)
Where:
V1-number of validated solution
S solutions volume (ml)
In practice there are cases in which substances can form
homogeneous mixtures, mix in any proportion between them, but more
often mixing can be achieved within certain limits, that can have a
maximum concentration - the saturation limit.
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17
CHAPTER 4
18
F.M.'s Law Raoult (1867) states that the relative decline of the
vapor pressure of a dilute solution is directly proportional to the mole
fraction of solute in solution is independent of temperature and nature of
the solute.
According to Raoult's law vapor pressure of a solution will always
be lower than that of pure solvent - the solvent molar fraction are several
solution to pure solvent solution where the fraction is 0.
The consequences of reducing the vapor pressure are boiling
temperature raising and lowering the solidification temperature
(freezing) with liquid solutions of pure solvent.
Lowering the freezing temperature of water solutions have
application in the implementation of building construction in cold
weather (pouring concrete and mortar processing) or de-icing roads.
Osmosis is the process of passing through a semi-permeable
membrane has a solvent in the same solvent solution or a diluted solution
more concentrated one.
Semi-permeable membrane is a film with very small pores that
allow passage of solvent molecules retaining the solute molecules.
Osmosis phenomenon occurs because of a solution to reduce the
concentration diffusion.
If in an enclosed space (such as a glass bell) is located two bowls:
one with a solvent and a solution of the same solvent (Fig. 4.10) the
following process occurs: the two vessels in the area will be closed vapor
was the two liquids (solvents and solution) with different vapor pressure in
this space and how there can be only one vapor pressure means that
the two vapor pressures must be equal. How p0 solvent vapor pressure
must be constant change of the solution vapor pressure p1. This process
is possible only if the solution is diluted, which is a condensation of the
vapor evaporating the solvent and therefore its continuous. The process
ends when all the solvent evaporated. Trend follows the dilution of the
solution.
19
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20
CHAPTER 4
liquid
solid
gaz
G-L
liquid
L-L
solid
gaz
liquid
solid
S-L
G-S
L-S
S-S
Name
aerosols
Fine
foams
Coloidall
emulsions
sols
xerogels
gels
alloys
CHAPTER 4
21
22
CHAPTER 4
micele
Faz lichid dispersat
23
CHAPTER 4
gel
sol
Fig.4.13. Gelling
CHAPTER 4
24
dispersion, substances used for this purpose are called gum inhibitors,
and the process is called peptizare.
Tyxotropy gels are owned (tyxotropic) the applicant passes the
energy intake.
While kept in dry gels lose by evaporation or chemical processes
much of the liquid phase is replaced by a gaseous phase realizing the
drying process.
Gels in which the liquid phase was replaced by a gaseous phase
are called xerogels.
Drying gels is accompanied by:
large volume contraction due to rearrangement strucuturii, if
contraction is hindered (for accession on aggregate cement stone in
concrete) structure may crack;
Reduced elasticity, the increase of stiffness due to the
completion of additional physical connections and sometimes the
chemical bond.
Stiffening process irreversible in time, gelurior, as a result of
structural changes is called physical and chemical aging gels.
In contact with the liquid phase (if water wetting) gels absorb the
liquid and increase its volume, a process called dipping. Drying gels after
soaking leads to a further reduction in the volume of lower intensity than
before realizing mbibrii. Variations in volume during drying - are all
soaking strongest gels are more elastic and fresh.
Explains the phenomena of colloidal systems strengthening
hydraulic binders, bitumen processing processes, structure and use of
sealants, the behavior of clays etc.
4.2.4. Heterogeneous systems
Macroeterogen dispersed heterogeneous systems are systems, less
stable, the size of aerosols is larger than 10-5cm.
CHAPTER 4
25
CHAPTER 5
CHAPTER 5
CHAPTER 5
The process means the shift from an initial state of the system in a
final.
Thermodynamic processes can be classified by many criteria, but
in terms of chemical interest:
- After the processs sense, are: reversible processes, the system
can be restored to its original state from the final state on the same sense
that the direct process occurs and irreversible processes, the system can
not be restored to its initial state on the direct processs sense;
- After the occurring conditions: isochoric processes (v = const., dv
= 0), isobar (p = const., dp = 0), isothermal (T = const, dT = 0), adiabatic
when there is no heat exchange, Q = 0).
When in the Ist principle of thermodynamics the pressure and the
temperature are chosen as independent variables, frequently
encountered conditions in practice, the heats variation at constant
pressure is called enthalpy or caloric content in transformations case.
If the system fails heat, enthalpys variation will be negative and
the process will be called exothermic.
If the system receives heat, enthalpys variation is positive and the
process is called endothermic.
In a chemical reaction we encounter:
- Reaction enthalpy (reaction heat) - the amount of absorbed or
released heat during a chemical reaction
- Formation enthalpy of (heat of formation)
- Enthalpy of reaction for the formation of a substances mole
- Enthalpy of combustion (combustion heat) - the amount of
released heat in complete combustion of a substances mole
If the amount of released heat (Q) by unit mass (kg) or volume
3
(m ) of substance is estimated, the calorific power (q) is defined.
Q = q. m (J / kg) Q = q respectively. V (J/m3)
Thermochemical laws are:
Lavoisier - Laplace law - the amount of necessary heat for a
substances decomposition into its components is equal to the amount
of consumed heat in forming the substance from the same elements.
Hess's Law - the amount of absorbed or released heat in a
chemical change is the same regardless of how transformation occurs
directly or in stages.
Equilibrium normal states in nature tend to minimum internal
energy with temperature decrease during the transformations. This
tendency of the system to move toward the minimum energy state is
CHAPTER 5
CHAPTER 5
energy
Er
energy
energy Ea
Ea
Er
Ep
time
a) exothermal reaction
Ea
Ep
Er
Ep
time
b) ) exothermal reaction
time
c) endothermal reaction
dc
dt
(5.1.)
CHAPTER 5
dCA dCM
(5.2)
where:
k = speed constant (depending on temperature, pressure, presence of
catalysts, etc.).
CA, CB, CC ... and A, B, C...represents the molar concentration of
reactants, A, B, C...
a, b, c ... coefficients
Temperature affects the reaction speed as the kinetic energy of
the reactants increases with temperature; is experimentally
demonstrated that increasing the reactants temperature with 100C the
resulted in a doubling or tripling the reactions speed. This is used in
practice to reduce the construction materials forming time.
The pressure at which chemical reaction occurs is also a mitigating
factor of great importance to the reaction rate, whereas the
compactness of the system and thus influence the probability of collision
of particles and is determined when the reactants are gaseous
reactants.
The presence of catalysts (substances that occur in a chemical
process without going into the reaction products composition)
accelerates the chemical reaction. The mechanism of these chemical
reactions can be explained by the formation of intermediates products
(catalysts and reactants) and that are quickly passing in reaction
products and catalyst regeneration, following the formula:
A + B + K AK + B AB + K
(5.3)
5.2.2. Order of reaction
Order of reaction is expressed by the sum of the reactants
concentration exponents involved in the reaction speed reflecting
the number of particles witch by simultaneous interaction,
determines a chemical reaction.
CHAPTER 5
v1= k1 . CaCO3
- Second order reactions are the most common and consist of the
forming from two reactants of reaction products:
A + B reaction products
v2 = k2.CA. CB = k2 A1 B1
H 2 +Cl 2 2 HCl
v 2 = k 2 . H2 1 .Cl2 1
v3 = k 3 . C A. CB . CC =
= k 3 . A1.B1 . C1
2H 2 + O 2 H 2 O
v 3 = k 3 . H 2 2 .O2 1
CHAPTER 5
k1 . Aa .Bb = k2 . Cc .Dd
k
Cc .D
k 1 a b
k2 A .B
(5.4)
CHAPTER 5
10
CHAPTER 5
a)
b)
c)
A
C
produi de reacie
CHAPTER 5
11
CHAPTER 5
12
13
CHAPTER 5
a)
b)
c)
reaction products
reactants
C2S
CHAPTER 5
14
CHAPTER 5
15
CHAPTER 5
16
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17
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18
19
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20
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21
CHAPTER 5
22
CHAPTER 5
23
of the corroded material. - Carbon dioxide from the air, in the presence
of atmospheric moisture makes the poorly soluble calcium carbonate
calcium carbonate readily soluble, easily washed natural waters
- Sulfur dioxide present in the atmosphere as a result of
technological processes (burning coal in power plants) along with
atmospheric humidity changes CaCO3 of different materials (natural
stone - limestone construction, etc..) In soluble calcium sulfate as easily
washed (the levigheaz).
Corrosion processes with the formation of reaction products
Soft or low mechanical strength
The chemical reactions occur between the corrosive substances in
the environment and some components of building materials, resulting
reaction products with low mechanical strength, which weaken the
material etched. Thus:
Alkali oxides (Na and K) are combined with some of the structures
of silicon making them poorly soluble substances stable substances with
low resistance (typically type gel).
Organic acids, fats, etc.. attacking some of the material by
saponification oxide (forming calcium soaps) forming substances without
mechanical strength.
Corrosion processes with the formation of reaction products with
high volume (corrosion by expansion)
Environment corrosive chemical reaction in heterogeneous system,
resulting in reaction products with a high volume, especially after
crystallization, with setting a high percentage of water of crystallization.
The chemical reaction takes place in the structure of solid material,
which opposes free-formed development of new chemical structures
and therefore impede the freedom of education., The efforts appear
corroded material can overcome interparticulare links resulting in
material damage.
Such acts of sulphates and chlorides with the formation of cement
stone structure that crystallized with 31 molecules of water.
Corrosion can occur simultaneously oxide substances through the
three operating modes, making it very difficult to analyze and prevent.
5.4.7. Corrosion of polymeric materials
For polymeric materials, corrosion is identified with the dissolution in
different solvents and aging. Sometimes, the dissolution process is
accompanied by chemical reactions.
Dissolution of polymer materials is preceded by inflation, leading to
an increase in volume up to 10 times. Between macromolecules and
CHAPTER 5
24