Technical Information

Liquiline M CM42
pH/ORP/conductivity/concentration/resistivity/digital sensors
Two-wire transmitter for Ex and non-Ex areas

68901

Application

Your benefits

Liquiline M CM42 is a modular two-wire transmitter for all

areas of process engineering.
Depending on the ordered version, Liquiline has one or two
analog current outputs or it can be connected to field buses as
per FOUNDATION Fieldbus, PROFIBUS PA and Hart protocol.
Liquiline is developed acc. to the international safety standard
IEC 61508.

Cost-saving:
Simple commissioning with Quick Setup and Navigator
(multifunction button)
Thanks to Memosens technology, a calibration in the plant
is not required
Predictive maintenance system detects when a sensor has
to be cleaned, calibrated or replaced
Less storage thanks to modular design
Safe:
Active display of cable interruption with Memosens
version
Red alarm LED reports error immediately
User-guided commissioning, graphic display and plain text
guidance
SIL 2, ATEX, FM, CSA, NEPSI, TIIS, IP 67, NEMA 4X
Code-protected commissioning and calibration
Connection of all types of pH sensors (glass, ISFET, digital
sensors) and conductivity sensors
Industry solutions:
Modular concept: sensor module replaceable
Asset management (Fieldcare, W@M)

The extremely robust, corrosion-resistant plastic version and

the hygienic stainless steel version are designed for the
following applications:
Chemical processes
Pharmaceuticals industry
Foodstuff technology
Ex applications

TI381C/07/en/05.05
51517610

Liquiline M CM42

General features . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

Mechanical construction . . . . . . . . . . . . . . . . . . . . . . 23

Modular design . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Quick setup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Navigator and plain text . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Sensor monitor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Process check system (PCS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Software packages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Dimensions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
Weight . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
Material . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24

Special features . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
pH / ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Conductivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Digital sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Human interface . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
Operating elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24

Ordering information. . . . . . . . . . . . . . . . . . . . . . . . . 25
Product structure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
Scope of delivery . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26

Certificates and approvals . . . . . . . . . . . . . . . . . . . . . 26

Measuring system . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Input . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
pH / ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Conductivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Digital sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

Output . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Output signal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Signal on alarm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Load . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Output signal range . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Ex specification current output 4/20 mA . . . . . . . . . . . . . . . . . . 10
Ex specification PROFIBUS PA and FOUNDATION Fieldbus . . . . 10

4 approval . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
Ex approval . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26

Accessories . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
pH / ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
Conductivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
Digital sensors (additional) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30

Documentation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
Operating Instructions CM42 . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

Wiring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Housing grounding . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Supply and signal circuit . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Sensor connection: pH / ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Sensor connection: conductivity . . . . . . . . . . . . . . . . . . . . . . . . . 17
Sensor connection: digital sensors . . . . . . . . . . . . . . . . . . . . . . . . 18

Performance characteristics. . . . . . . . . . . . . . . . . . . . 19
pH / ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Conductivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Digital sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

Installation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Mounting plate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Weather protection cover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Installation in Ex area . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

Environment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Ambient temperature range . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Ambient temperature limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Storage temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Electromagnetic compatibility . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Ingress protection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Relative humidity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

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Liquiline M CM42

General features
Modular design

a0001296

Inside Liquiline (version with sensor module, without wiring)

a0001979

CPU and sensor module

Quick setup

To the first measuring value within 1 minute

After setting up the few parameters in the Quick Setup menu, the measuring point is ready to measure. You
can be sure, to have set up the most important settings.
The first measuring value is reliably displayed.

Navigator and plain text

The unique operating concept sets new standards:

Fewer user errors thanks to very easy operation
Quick configuration with the Navigator.
Intuitive configuration and diagnosis due to plain text display

a0001984

Navigator

Sensor monitor

a0001985-en

Plain text display

Pressing the DIAG key takes you to the sensor monitor. All the important sensor data, incl. warning and alarm
limits, are graphically displayed in one go.

a0001771-en

Sensor monitor (example)

Process check system (PCS)

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This function checks the measuring signal for stagnation. If the measuring signal does not change for some time
(several measured values), an alarm is triggered. Soiling, blockage or similar could be the cause of such
behaviour.

Liquiline M CM42

Software packages

The standard software contains the following features:

Features

Safety

pH /ORP

Conductivity

Offset and two-point

calibration
Sample calibration
Calibration with standard and
special buffers
Manual buffer
Temperature compensation
Temperature adjustment
Simulation of current output
Self-diagnosis

Digital sensors

Offset and two-point

Sample calibration
calibration
Temperature calibration: one-point
Sample calibration
Simulation of current output
Calibration with standard and
Self-diagnosis
special buffers
Concentration measurement
Manual buffer
Temperature compensation
Temperature adjustment
Simulation of current output
Self-diagnosis

Safety integration level acc. to IEC 61508 (SIL 2)

Liquiline is the first analysis transmitter to be developed to IEC 61508 and specified for use under SIL 2.
The development to SIL 2 reduces the probability of hidden errors and stands for the highest degree of
reliability.
Alarm LED
A bright, red LED draws your attention to an error (22 mA alarm).
Code protection
Liquiline is supplied without access protection.
You can specify passwords linked to relevant access rights for various user groups:
Specialist
Service
Operator...
To guarantee the highest degree of safety and security in the pharmaceuticals sector, you can specify user roles
with IDs and passwords as per 21CFR11.
Reordering validated software
You can order new devices with older, validated software so you do not have to constantly validate new
software versions of new devices. This is possible as long as allowed by the hardware version.

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Liquiline M CM42

Special features
pH / ORP

Sensor Condition Check (SCC)

This function monitors the state of the electrodes or the degree of electrode ageing. The "Electrode OK", "Low
wear" or "Replace electrode" messages inform you on the state of the electrode. The electrode state is updated
after each calibration. When the "Replace electrode" message appears, an error message is displayed.
Sensor Check System (SCS)
The sensor check system alerts to deviations of the pH glass impedance or reference impedance from the
normal range, thus indicating possible failure due to pH electrode blocking or damage.

Conductivity

Polarisation monitoring
Polarisation effects in the boundary layer between the sensor and the solution to be measured limit the
measuring range of conductive conductivity sensors.
The transmitter can detect and indicate polarisation effects using an innovative, intelligent signal evaluation
process.
United States Pharmacopeia (USP) and European Pharmacopoeia (EP)
The requirements on ultrapure water in the pharmaceutical industry are specified by the American USP and
the European EP.
The transmitter meets the USP/EP requirements on conductivity measuring systems:
Precise temperature measurement at point of conductivity measurement
Simultaneous display of uncompensated conductivity values and temperature
Display resolution 0.01 S/cm
Exact adjustment of the transmitter in the factory with traceable precision resistances (optional)
Exact adjustment of the sensors in the factory in accordance with ASTM D 1125-9 resp. ASTM D 5391-99
(optional)
Temperature-dependent measured value monitoring acc. to USP and EP.

Digital sensors

Memosens
The measuring point is safer with Memosens:
No-contact, inductive signal transmission, thus optimum galvanic separation
No contact corrosion
Completely water-tight
Automatic error message if data flow interrupted
Sensor calibration possible in laboratory
Look-ahead maintenance thanks to recording of sensor data, e.g.:
Total hours of operation
Hours of operation for very high or very low pH values
Hours of operation for high temperatures above 80 C (176 F) and 100 C (212 F)
Number of steam sterilisations

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Liquiline M CM42

Measuring system

a0002012

Measuring system: Examples

pH / ORP
CM42-P/R...
Measuring cable CPK9
Assembly Cleanfit CPA471
Sensor Orbisint CPS11

Conductivity, inductive
measurement
CM42-I...
Assembly Dipfit CLA111
Sensor Indumax CLS50

Conductivity, conductive
measurement
CM42-C...
Measuring cable CPK9
Sensor Condumax CLS16

Digital sensor
CM42-M...
Measuring cable CYK10
Assembly Unifit CPA442
Sensor Oxymax COS22

Note!
You can select from a wide variety of assemblies and sensors to set up your measuring point. You can find the
corresponding information in the chapter "Accessories" resp. in the referenced documentations.

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Liquiline M CM42

Input
pH / ORP

Measured variable
pH value
Oxidation-reduction potential (ORP)
Temperature
Measuring range
pH value

2 to 16

ORP

2000 to +2000 mV

Temperature

25 to + 150 C (13 to 302 F)

Cable specification
Without SCS

50 m (164.05 ft) max. cable length

With SCS

20 m (65.62 ft) max. cable length

Applicable temperature sensors

Pt100
Pt1000
NTC 30K
Ex specification

0 Intrinsicallay safe sensor circuit with protection type: EEx ia IIC

Max. output voltage Uo
Max. output current Io
Max. output Po
Max. outer inductance Lo
Max. outer capacity Co

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Glass electrode
10.08 V
4.1 mA
10.2 mW
200 H
150 nF

ISFET
10.08 V
50.7 mA
128 mW
200 H
150 nF

Liquiline M CM42

Conductivity

Measured variable
Conductivity
Resistivity
Concentration
Measuring range
Conductivity, conductive measured
Two-polar sensor
Four-polar sensor

0.1 S.k1) to 20 mS.k

0.1 S.k to 1.5 S.k

Conductivity, inductive measured

1.7 S.k2) to 1 S.k

Resistivity, conductive measured

10 M/k ... 50 /k

Concentration

NaOH: 0...15% (0...100 C / 32...212 F)

HNO3: 0...25% (0...80 C / 32...176 F)
H2SO4: 0...30% (0...100 C / 32...212F)
H3PO4: 0...15% (0...80 C / 32...176 F)
HCl: 0...20% (0...65 C / 32...149 F)
4 user tables

1)

k = cell constant in cm-1

Example: 2-polar sensor, k=0.01 cm1, resulting measuring range is from 0.001 to 200 S/cm.

2)

k=cell constant in cm1

Example: sensor, k=2 cm1, resulting measuring range is from 3.4 S/cm to 2 S/cm.

Cable specification
Conductivity/resistivity, conductive measured1)
Two-cell sensor
100 m (328.10 ft) max. cable length
10 S.k to 20 mS.k / 0.1 M/k to 50 /k
5 S.k to 20 mS.k / 0.2 M/k to 50 /k
50 m (164.05 ft) max. cable length
0.1 S.k to 20 mS.k / 20 M/k to 50 /k
15 m (49.22 ft) max. cable length
Conductivity, conductive measured
Four-cell sensor
10 S.k to 1.5 S.k
0.1 S.k to 20 mS.k

100 m (328.10 ft) max. cable length

15 m (49.2 ft) max. cable length

Conductivity, inductive measured2)

55 m (180.46 ft) max. cable length

1)

with CYK71 or CPK9 cables or sensor fixed cable

2)

with CLK5 cable or sensor fixed cable

Temperature sensor
Pt100
Pt1000
Ex specification, conductive sensors

0 Intrinsicallay safe sensor circuit with protection type: EEx ia IIC T6

Max. output voltage Uo
Max. output current Io
Max. output Po
Max. outer inductance Lo
Max. outer capacity Co

10.08 V
23 mA
57 mW
335 H
4 nF

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Liquiline M CM42

Ex specification, inductive sensors

0 Intrinsicallay safe sensor circuit with protection type: EEx ia IIC

Max. output voltage Uo
Max. output current Io
Max. output Po
Max. outer capacity Co

10.08 V
64 mA
128 mW
62 nF

For connection of the inductive sensor CLS50

Digital sensors

Measured variable
pH value
Oxidation-reduction potential
Temperature
Measuring range
pH value

2 to 16

ORP

2000 to +2000 mV

Temperature

25 to + 150 C (13 to 302 F)

Cable specification
With Memosens

100 m (328.10 ft) max. cable length

Ex specification

0 Intrinsically safe sensor circuit with protection type: EEx ia IIC T6

Max. output voltage Uo
Max. output current Io
Max. output Po
Max. outer inductance Lo
Max. outer capacity Co

Endress+Hauser

5.04 V
70 mA
128 mW
447 nF
105.6 H

Liquiline M CM42

Output
Output signal

4 to 20 mA, potentially isolated against sensor circuit

0.8 to 1.2 mA peak to peak1
PROFIBUS PA2
FOUNDATION Fieldbus3

Signal on alarm

21.5 mA
digital via field bus4

Load

Max. load with an supply voltage of 24 V: 500

Max. load with an supply voltage of 30 V: 750

Output signal range

Ex specification
current output 4/20 mA

pH

adjustable, pH > 0.5

ORP

adjustable, U > 5 mV

Conductivity, conductive measured

none

Conductivity, inductive measured

none

Temperature

adjustable, T > 2 C

0 Intrinsically safe supply and signal circuit with protection type: EEx ia IIC T6 passive
Max. input voltage Ui
Max. input current Ii
Max. input Pi
Max. inner inductivity Li
Max. inner capacity Ci

Ex specification PROFIBUS PA
and FOUNDATION Fieldbus

0 Suitable for use in a FISCO system

Max. input voltage Ui
Max. input current Ii
Max. input Pi
Max. inner inductivity Li
Max. inner capacity Ci

1)
2)
3)
4)

10

30 V
100 mA
750 mW
221 H (output 1)
neglegiable (output 2)
1.2 nF (output 1)
neglegiable (output 2)

17,5 V
380 mA
5.32 W
38.4 H
neglegiable

only for Hart

for version with PROFIBUS PA
for version with FOUNDATION Fieldbus
with Profibus PA or FOUNDATION Fieldbus only

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Liquiline M CM42

Wiring
Housing grounding

Plastic housing

"

Caution!
You must connect the "EMC barrier" to the foundation earth with a separate 4 mm2 functional earth line.

a0003617

Housing grounding

1
2

EMC barrier
4 mm2 functional earth

Stainless steel housing

"

Caution!
You must connect the outer earth connection of the housing to the foundation earth with a separate 4 mm2
line (GN/YE).

2
a0003616

Housing grounding

Note!
Connect the transmitter via a two-wire cable screened on each end.

133
134

4 ... 20 mA

Outer earth connection

4 mm2 line (GN/YE)

4 ... 20 mA / Hart

234 233 232 231 134 133 132 131

Supply and signal circuit

1
2

133

134

a0001092

Wiring diagram

a0001091

View in device (CPU module)

Endress+Hauser

11

Liquiline M CM42

PROFIBUS PA and FOUNDATION Fieldbus

Note!
Always use a fieldbus cable that is grounded on both sides (device and PCS).
You can connect Profibus and FOUNDATION Fieldbus devices in three ways:
Screened two-wire cable, "Hard grounding"
(generally to be preferred to capacitive grounding)
Screened two-wire cable, "Capacitive grounding"
(if there is a risk of high equalizing currents)
Using the fieldbus connection socket (accessories)
Version 1: "Hard grounding"
1.

Place the cable screen on the "EMC barrier".

2.

Connect the cable wires as per the assignment.

997

998

a0001640

Wiring diagram
a0004060

View in device (CPU module)

Version 2: "Capacitive grounding"

Strip back the screen braiding, push the extension wire onto the exposed screen and fasten the clip:

2.

Place the extension wire on the "EMC barrier".

3.

Connect the cable wires as per the assignment.

998

133 132

998

997

997

1.

a0004073

Wiring diagram
EY
/NG

a0004071

View in device (CPU module)

12

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Liquiline M CM42

Version 3: Fieldbus connection socket (accessories):

1.

Screw the fieldbus connection socket (accessories) into the housing bushing.

2.

Trim the connection cores of the socket to approx. 15 cm (5.9 ").

3.

Connect the cable cores as per the assignment. In doing so, you must place the cable screen (GN/YE) on
the "EMC barrier".

997

998

a0004062

Wiring diagram

a0002378

View in device (CPU module)

Supply voltage
Current output 4 to 20 mA without Hart:
Current output 4 to 20 mA with Hart:
PROFIBUS / FOUNDATION Fieldbus:
(max. 22 mA)

12.5 to 30 V DC
12.5 to 30 V DC
9 to 32 V DC (non-hazardous area) /
9 to 17.5 V DC (hazardous area)

Sensor connection
Explanation of abbreviations in the following diagrams:

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Abbreviation

Meaning

pH
Ref
Src
Drn
PM
U+
U
Com A
Com B

d.n.c.

Signal from pH membrane glass

Signal from reference electrode
Source
Drain
Potential matching
Digital sensor supply
Digital sensor communication
Temperature signal
Do not connect!

Note!
Cable colours indicated as per IEC 757 (see CD-ROM).
You must connect shielded connections and terminals with functional earth ()) (there is no protective earth
(*) for plastic housings).

13

Liquiline M CM42

Sensor connection: pH / ORP

Glass electrodes with PML (symmetrical)

112
113
111

320
318
317

319 317 318 320 316 315 111 113 112

CM42

CPK9

Sensor

GN
WH
YE

112

BN

113

GN

WH

BK

111

YE

315
CPK1
316

320
BN

318

BN

PM

BK

Ref

317

pH

319
PM

a0001088

View in device

a0001079

Wiring diagram

Glass electrodes without PML (asymmetrical)

CPK9 / CPK1

112
113
111

320
317

319 317 318 320 316 315 111 113 112

CM42

Sensor

GN
WH

112

YE

GN

J
113

BK
BN

111

WH

YE

315

CPK1

316

320
BN

BK

318

Ref

317

pH

d.n.c.

319

d.n.c.
BN

a0001089

View in device

14

a0001080

Wiring diagram

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Liquiline M CM42

319 317 318 320 316 315 111 113 112

ISFET sensors with PML (symmetrical)

112
113
111
315
316
320
318

GN

CM42

CPK12

Sensor

WH
YE

112
RD
BN
BK

113

111

GN

WH

YE

315

Src
Ref

316

320

RD

Drn

BN

PM

BN

318

BK

317
PM

319

a0001090

View in device

a0001076

Wiring diagram

112
113
111
315
316
320

319 317 318 320 316 315 111 113 112

ISFET sensors without PML (asymmetrical)

CPK12

CM42

GN
WH
YE

112

RD
BK

113

Sensor

GN

WH

BN

111

YE

Src

315

Ref
316

320

RD

Drn

BK

BN

318

d.n.c.

317

d.n.c.

319

BN

a0001084

View in device

Endress+Hauser

a0001077

Wiring diagram

15

Liquiline M CM42

Overview, pH signal assignment

Version: CM42-P...
Terminal

Glass/redox

ISFET

with PML

without PML

with PML

without PML

112

(GN)

(GN)

(GN)

(GN)

(GN)

113

(WH)

(WH)

(WH)

(WH)

(WH)

111

(YE)

(YE)

(YE)

(YE)

(YE)

Src

Src

Drn

Drn

PM

Ref

315
316
320

PM

318

Ref

317

pH

Ref

Difference
electrode

PM

Ref
pH

pH

319

pH

Version: CM42-R...
As version CM42-P and also:
Terminal

pH+redox

pH+pH

with PML

without PML

with PML

without PML

112

(GN)

(GN)

(GN)

(GN)

113

(WH)

(WH)

(WH)

(WH)

111

(YE)

(YE)

(YE)

(YE)

PM

Ref (pH)

PM

Ref (pH-1)

318

Ref (pH+ORP)

Ref (ORP)

Ref (pH-1 + pH-2) Ref (pH-2)

317

pH

pH

pH

pH

319

ORP

ORP

pH

pH

315
316
320

16

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Liquiline M CM42

Sensor connection:
conductivity

Conductive sensors, two-cell sensors

112
113
111
219
220

221 222 220 219 111 113 112

CM42

CPK9 / CYK71

Sensor

GN
WH
YE

112

BK

113

GN

WH

BN

111

YE

219

220

BK
d.n.c.

222

221

BN

a0001086

View in device

a0001083

Wiring diagram

112
113
111
219
220
222
221

221 222 220 219 111 113 112

Conductive sensors, four-cell sensors

CM42

GN
WH
YE

Sensor

112

BK
BK

113

111

219

220

222

221

a0002363

View in device (sensor module)

Endress+Hauser

a0002371

Wiring diagram

17

Liquiline M CM42

215
216
112
113
111
218
217

217 218 111 113 112 216 215

Inductive sensors

CM42

RD
RD
GN
WH
YE
WH
WH

CLK5

Sensor

215

216

112

113

111

GN

WH

YE

218

217

a0001085

View in device

a0001082

Wiring diagram

187
188
197
198

588 587 388 387 198 197 188 187

Sensor connection:
digital sensors
BN
WH
GN
YE

a0001087

View in device

18

a0001078

Wiring diagram

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Liquiline M CM42

Performance characteristics
pH / ORP

Reference temperature
25 C (77 F)
Measured value resolution
pH:
Glass electrodes:
ISFET sensors:
ORP:

0.01 pH
0.01 pH
1 mV

Temperature:
NTC30k:
Pt100 / Pt1000:

0.1 C (0.1 F)
0.1 C (0.1 F)

SCS glass electrodes:

Glass:
Reference:
Leak current, ISFET sensors:

100 k
100
100 nA

Maximum measured error1

pH:
Glass electrodes:
ISFET sensors:
ORP:

0.02 pH
0.02 pH
1 mV

Temperature:
NTC30k:
Pt100 / Pt1000:

0.5 K
0.25 K

SCS glass electrodes:

Glass:
Reference:
Leak current, ISFET sensors:

Conductivity

200 M
200
100 nA

Reference temperature
25 C (77 F)
adjustable from 5 to 100 C (23 to 212 F)2
Measured value resolution
Conductivity
minimum, at:
cell constant k 0.15 cm-1
cell constant k 1.5 cm-1
cell constant k > 1.5 cm-1

1)
2)

< 0.1% from the measured value (4 digits)

0.001 S/cm
0.01 S/cm
0.1 S/cm

Temperature (Pt100 / Pt1000)

0.01 C (0.01 F)

Resistivity
minimum

< 0.1% from the measured value (4 digits)

1 k.cm

acc. to DIN IEC 746 part 1, under nominal operating conditions

with software package "Advanced" or "Advanced Plus"

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19

Liquiline M CM42

Maximum measured error1

Conductivity, conductive measured
Two-polar sensors

0.5 % from measured value 0.01 S.k

Four-polar sensors

0.5 % from measured value 0.01 S.k 1)

1.0 % from measured value 0.01 S.k 2)
2.0 % from measured value 0.01 S.k 3)

Conductivity, inductive measured

0.5 % from measured value 1.7 S.k

Resistivity, conductive measured

(two-cell sensors)

0.5 % from measured value 0.01 S.k 4)

1)

from 0.1 S.k to 20 mS.k (max. cable length 15 m (49.22 ft))

2)

from 10 S.k to 1000 mS.k (max. cable length 100 m (328.1 ft))

3)

from 10 S.k to 1500 mS.k (max. cable length 100 m (328.1 ft))

4)

from 10 M/k to 50 /k (max. cable length 15 m (49.22 ft))

from 200 k/k to 50 /k (max. cable length 50 m (164.05 ft))

Temperature compensation
Type of compensation
none
linear
NaCl acc. to IEC 746-3
natural waters acc. to IEC 7888
Ultra-pure water NaCl
Ultra-pure water HCl

Range
= 0.00 to 20.00 % / K
0 to 100 C (32 to 212 F)
0 to 35 C (32 to 95 F)
0 to 100 C (32 to 212 F)
0 to 100 C (32 to 212 F)

Temperature adjustment
Temperature offset

Digital sensors

5 to +5 C (23 to 41 F)

Measured value resolution

pH
Glass electrodes
ISFET sensors

1)

20

0.01 pH
0.01 pH

ORP

1 mV

Temperature

0.1 C (0.1 F)

acc. to DIN IEC 746 part 1, under nominal operating conditions

Endress+Hauser

Liquiline M CM42

Installation
Mounting plate

a0001075-en

Mounting plate

Weather protection cover

Plastic housing

a0001671-en

Weather protection cover

Stainless steel housing

300 / 11.81

320 / 12.60

270 / 10.63

mm / inch
a0001676-en

Weather protection cover

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21

Liquiline M CM42

Installation in Ex area

a0001312-en

Installation in Ex area
Sensor in Ex version
1
Intrinsically safe sensor circuit EEx ia
2
Transmitter
3
Supply and signal circuit EEx ib (4...20 mA)
4

5
6
7
8

Active barrier, e.g. Preline RN221

Signal line Hart/PROFIBUS/FF
Fieldcare via PROFIBUS/FF
Hart handheld terminal

Environment
Ambient temperature range

Non-hazardous area version

30 to 70 C (22 to 158 F)
Hazardous area version
T6: 20 to 50 C (4 to 122 F)
T4: 20 to 55 C (4 to 131 F)

Ambient temperature limits

-30 to +80 C (22 to 176 F)

Storage temperature

40 to 80 C (40 to 176 F)

Electromagnetic compatibility

Interference emission and interference immunity as per EN 61326: 2004

Ingress protection

IP 67

Relative humidity

10 to 95%, not condensing

22

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Liquiline M CM42

Mechanical construction
Dimensions

Plastic housing

a0001074-en

Plastic housing

160 / 6.30

110 / 4.33

145 / 5.71

134 / 5.28

Stainless steel housing

26 /
1.02

136.5 / 5.37
220 / 8.66

3 / 0.12

132.5 / 5.22

134.5 / 5.30
136.5 / 5.37

10/
0.39

95 / 3.74

174 / 6.85

174 / 6.85

mm / inch
a0001073-en

Dimensions

Endress+Hauser

23

Liquiline M CM42

Weight

Plastic housing
1.5 kg (3.3 lb)
Stainless steel housing
2.1 kg (4.6 lb)

Material

Plastic housing
Housing:
Housing seals:

Polycarbonate
EPDM

Stainless steel housing

Housing:
Housing seals:

Stainless steel 1.4301 (AISI 304)

Foamed silicone, EPDM

Human interface
Operating elements

a0001301

Overview of operation
1
2
3-6
7

24

Display, current display: pH measuring mode

Navigator
Soft keys
Soft key function (depends on menu)

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Liquiline M CM42

Ordering information
Product structure

Sensor input
A
C
I
M
P
R

No Module
Conductivity, conductive measurement
Conductivity, inductive measurement
Digital sensor, Memosens
pH (glass/ISFET) or ORP
pH (glass/ORP redundant) or ISFET

Approval
A
G
H
N
P
S
T

Non-hazardous area, CSA GP

Atex II (1)2G EEx ia/ib IIC T6 / II 3 D
Atex II 3G EEx na II T6
NEPSI Ex nA II T6
FM IS NI Cl. I, II, III, Div. 1&2, Groups A-G
CSA IS NI Cl. I, II, III, Div. 1&2, Groups A-G
TIIS

Certificate
A
B
C

not selected
Test certificate acc. to EN 10204, 3.1
Test certificate acc. to EN 10204, 3.1, factory calibration certificate

Output
0
1
2
3

1 current output 4 to 20 mA, Hart

2 current outputs 4 to 20 mA, 1x Hart
PROFIBUS PA
FOUNDATION Fieldbus

Housing
0
1

Plastic
Stainless steel 1.4301 (AISI 304)

Cable entry
0
1
2

M20 x 1.5
NPT "
G

Software
EA
EB
EC

Standard version
Advanced version
Advanced Plus version

Device language
C
D
E
F
J
N
P
S
T

Zh/En (Chinese docs)

De/En (German docs)
En/De (English docs)
Fr/En (French docs)
Ja/En (Japanese docs)
Nl/En (Dutch docs)
Pl/En (Polish docs)
Es/En (Spanish docs)
It/En (Italian docs)

Documentation
0
1

Installation and configuration

Installation and configuration + safety manual

Additional equipment
0
CM42-

Endress+Hauser

Basic version
complete order code

25

Liquiline M CM42

Scope of delivery

The scope of delivery comprises:

A transmitter acc. to the ordered version
A mounting plate including 4 screws
A cable gland plate and 2 cable glands (in the packaging)
A sticker sheet (embedded in the housing, containing nameplates and terminal assignment stickers)
A test certificate acc. to EN 10204-3.1 (optional)
A factory calibration certificate
An Operating Instructions BA381C "Commissioning"
An Operating Instructions BA382C "Operation"
A Safety Manual acc. to SIL 2 (optional)
A CD ROM with additional documentation

Certificates and approvals

4 approval

Declaration of conformity
The product meets the legal requirements of the harmonized European standards.
The manufacturer confirms compliance with the standards by affixing the 4 symbol.

Ex approval

Depending on the version ordered:

ATEX II (1)2G, EEx ia/ib IIC T6 / II 3D
ATEX II 3G, EEx na II T6
NEPSI Ex nA II T6
CSA IS NI Cl.I, II, III, Div. 1&2, Grps. A-G
FM IS NI Cl.I, II, III, Div. 1&2, Grps. A-G
TIIS

26

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Liquiline M CM42

Accessories
pH / ORP

Glass electrodes
Orbisint CPS11/CPS11D
pH electrode for process applications, with PTFE diaphragm, Memosens technology as option;
Ordering acc. to product structure, see Technical Information (TI028/C07/en)
Orbisint CPS12/CPS12D
ORP electrode for process applications, with PTFE diaphragm, Memosens technology as option;
Ordering acc. to product structure, see Technical Information (TI367/C07/en)
Ceraliquid CPS41/CPS41D
pH electrode with ceramics diaphragm and KCl liquid electrolyte, Memosens technology as option;
Ordering acc. to product structure, see Technical Information (TI079/C07/en)
Ceraliquid CPS42/CPS42D
ORP electrode with ceramics diaphragm and KCl liquid electrolyte, Memosens technology as option;
Ordering acc. to product structure, see Technical Information (TI079/C07/en)
Ceragel CPS71/CPS71D
pH electrode with double chamber reference system and integrated bridge electrolyte,
Memosens technology as option;
Ordering acc. to product structure, see Technical Information (TI245/C07/en)
Ceragel CPS72/CPS72D
ORP electrode with double chamber reference system and integrated bridge electrolyte, Memosens
technology as option;
Ordering acc. to product structure, see Technical Information (TI374/C07/en)
Orbipore CPS91/CPS91D
pH electrode with open aperture for media with high dirt load, Memosens technology as option;
Ordering acc. to product structure, see Technical Information (TI375C/07/en)
ISFET sensors
Tophit CPS471
Sterilisable and autoclavable ISFET sensor for food and pharmaceuticals, process technology, water
treatment and biotechnology;
Ordering acc. to product structure, see Technical Information (TI283/C07/en)
Tophit CPS441
Sterilisable ISFET sensor for media with low conductivity, with liquid KCl electrolyte;
Ordering acc. to product structure, see Technical Information (TI352/C07/en)
Tophit CPS491
ISFET sensor with open aperture for media with high dirt load;
Ordering acc. to product structure, see Technical Information (TI377/C07/en)

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27

Liquiline M CM42

Assemblies
Cleanfit P CPA471
Retractable assembly for tank and pipe installation,
Cleanfit P CPA473
Pneumatically or manually driven retractable assembly with ball valve for reliable process termination, parts
in contact with medium of 1.4404 (AISI 316L) stainless steel
Cleanfit P CPA474
Pneumatically or manually driven retractable assembly with ball valve for reliable process termination, parts
in contact with medium of PP, PEEK or PVDF

a0001305

Fig. 1:

Cleanfit P CPA471

a0001306

Fig. 2:

Cleanfit P CPA473

a0001307

Fig. 3:

Cleanfit P CPA474

Cleanfit H CPA475
Retractable assembly for tank and pipe installation under sterile conditions,
Dipfit W CPA111
Immersion and installation assembly for open and closed tanks,
Unifit H CPA442
Installation assembly for food industry, biotechnology and pharmaceutical industry, with EHEDG and 3A
certificate,

a0001308

28

Fig. 4:

Cleanfit H CPA475

a0001309

Fig. 5:

Dipfit W CPA111

a0001310

Fig. 6:

Unifit H CPA442

Note!
All the assemblies can be ordered using the product structure. Please refer to the Technical Information of the
desired assembly in question.

Endress+Hauser

Liquiline M CM42

Measuring cables
CPK9 special measuring cable
For sensors with TOP68 plug-in head, for high-temperature and high-pressure applications, IP 68
Ordering acc. to product structure, see Technical Information (TI118C/07/en)
CPK12 special measuring cable
For pH/redox glass electrodes and ISFET sensors with TOP68 plug-in head
Ordering acc. to product structure, see Technical Information (TI118C/07/en)
Buffer solutions
Technical buffer solutions, accuracy 0.02 pH, acc. to NIST/DIN
pH 4.0 red, 100 ml (0.026 US gal.), order no. CPY 2-0
pH 4.0 red, 1000 ml (0.264 US gal.), order no. CPY 2-1
pH 7.0 green, 100 ml (0.026 US gal.), order no. CPY 2-2
pH 7.0 green, 1000 ml (0.264 US gal.), order no. CPY 2-3
Technical buffer solutions for single use, accuracy 0.02 pH, acc. to NIST/DIN
pH 4.0 20 x 20 ml (0.005 US gal.), order no. CPY 2-D
pH 7.0 20 x 20 ml (0.005 US gal.), order no. CPY 2-E
Technical buffer solutions for ORP electrodes
+225 mV, pH 7, 100 ml (0.026 US gal.); order no. CPY3-0
+468 mV, pH 0, 100 ml (0.026 US gal.); order no. CPY3-1
Conductivity

Conductive sensors
Condumax W CLS12
Conductive conductivity sensor for standard, Ex and high temperature applications;
Ordering acc. to version, see Technical Information TI 082/C07/en
Condumax W CLS13
Conductive conductivity sensor for standard, Ex and high temperature applications;
Ordering acc. to version, see Technical Information TI 083/C07/en
Condumax W CLS15
Conductive conductivity sensor for pure and ultra-pure water applications (incl. Ex);
Ordering acc. to version, see Technical Information TI 109/C07/en
Condumax H CLS16
Hygienic conductive conductivity sensor for pure and ultra-pure water applications (incl. Ex);
Ordering acc. to version, see Technical Information TI 227/C07/en
Condumax W CLS19
Conductive conductivity sensor for pure and ultra-pure water applications;
Ordering acc. to version, see Technical Information TI 110/C07/en
Condumax W CLS21
Conductive conductivity sensor for applications with middle to high conductivity
(incl. Ex); Ordering acc. to version, see Technical Information TI 085/C07/en
Inductive sensors
Indumax P CLS50
Inductive conductivity sensor for standard, Ex and high temperature applications;
Ordering acc. to the sensor version, see Technical Information (TI118C/07/en)
Indumax H CLS52
Inductive conductivity sensor with short response time in hygienic design;
Ordering acc. to the sensor version, see Technical Information (TI167C/07/en)

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Liquiline M CM42

Assemblies
Dipfit W CLA111
Immersion assembly for open and closed tanks with flange DN 100;
Order depending on version, see Technical Information (TI135C/07/en)
Dipfit P CLA140
For the inductive sensor CLS50
Immersion assembly with flange connection for processes with high requirements;
Order depending on version, see Technical Information (TI196C/07/en)

a0001303

Fig. 7:

Dipfit W CLA111 Fig. 8:

a0001304

Dipfit P CLA140

Measuring cables
Special measuring cable / extension cable CYK71
for two-polar conductivity sensors with integrated temperature sensor,
one low-noise coaxial line, four auxiliary cores at 0.75 mm2 each with a common screen,
outer diameter 7 mm (0.25")
sold by the metre:
(minimum) length 5 m / 15 ft; order no. 50085333
length 5 m / 15 ft; order no. 50088280
length 10 m / 30 ft; order no. 50088281
length 50 m / 150 ft; order no. 50088284
length 100 m / 300 ft; order no. 50088285
Special measuring cable / extension cable CYK71-Ex
for Ex applications,
see CYK71, but with a blue sheath
sold by the metre, minimum length 5 m / 15 ft; order no. 50085673
Calibration solutions
Precision calibration solutions, acc. to SRM (Standard reference material) of NIST, error limit 0.5 %,
reference temperature 25 C (77 F), with temperature table
CLY11-A, 74.0 S/cm, 500 ml (0.132 Us.gal); order no. 50081902
CLY11-B, 149.6 S/cm, 500 ml (0.132 Us.gal); order no. 50081903
CLY11-C, 1.406 mS/cm, 500 ml (0.132 Us.gal); order no. 50081904
CLY11-D, 12.64 mS/cm, 500 ml (0.132 Us.gal); order no. 50081905
CLY11-E, 107.0 mS/cm, 500 ml (0.132 Us.gal); order no. 50081906
Digital sensors (additional)

Measuring cables
CYK10 Memosens data cable
For digital pH sensors with Memosens technology (CPSxxD)
Ordering according to product structure, see Technical Information (TI376C/07/en)

30

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Documentation
Operating Instructions CM42

Liquiline M CM42, Operating Instructions, KA381C/07/en and BA382C/07/en

The Operating Instructions correspond to the device version.
Methods for (re-) ordering:
Re-order the KA/BA by specifying the serial number of your device (via your local Sales Office)
Order a specific KA/BA by specifying a valid Liquiline order code (via Internet).

International Head Quarters

Endress+Hauser
GmbH+Co. KG
Instruments International
Colmarer Str. 6
79576 Weil am Rhein
Deutschland
Tel. +49 76 21 9 75 02
Fax +49 76 21 9 75 34 5
www.endress.com
info@ii.endress.com

TI381C/07/en/05.05
Printed in Germany / FM+SGML 6.0 / POD/

51517610