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This paper deals with the mechanical properties and degree of swelling (DS) of starch/PVA
blend lm with the functional groups i.e., hydroxyl and carboxyl group, of additives. Starch/
PVA blend lms were prepared by using the mixing process. Glycerol (GL) with 3 hydroxyl
group, sorbitol (SO) with 6 hydroxyl group, succinic acid (SA) with 2 carboxyl group, malic
acid (MA) with 1 hydroxyl and 2 carboxyl group, tartaric acid (TA) with 2 hydroxyl and 2
carboxyl group and citric acid (CA) with 1 hydroxyl and 3 carboxyl group were used as
additives. The results of measured tensile strength (TS) and elongation (%E) veried that both
hydroxyl and carboxyl group as a functional groups increased the exibility and strength of
the lm. Values of DS for GL-added and SA-added lms were low. However, DS values of the
lms added MA, TA or CA with both hydroxyl and carboxyl group were comparatively high.
When the lm was dried at low temperature, the properties of the lms were evidently improved. The reason is probably because the hydrogen bonding was activated at low
temperature.
KEY WORDS: Starch/PVA blend lm; functional group; additives; mechanical properties; degree of
swelling.
INTRODUCTION
Nowadays, about 150 million tons of plastics
are produced annually all over the world, and the
production and consumption continue to increase.
Most of these plastics are crude oil based, and an
increase in their production results in an increase of
oil use and causes serious environmental pollution,
due to wasted and undegraded polymers. One of
the strategies to solve the difcult questions related
1
71
1566-2543/06/0100-00071/0 2006 Springer Science+Business Media, Inc.
72
EXPERIMENTAL
Materials
Starch (cornstarch) was obtained from Doosan
Corn Products Korea, Inc. (Korea). PVA, reagent
grade GL, SO, SA, MA, TA and CA were purchased from Aldrich chemical company Inc.(Milwaukee, USA). PVA was 99% hydrolyzed with a
molecular weight average of 89,00098,000. The
water used to prepare starch/PVA blend films was
redistilled after deionization.
OH
HO
OH
OH
HO
OH
OH
HO
OH
OH
(b)
OH
HO
OH
OH
(d)
(a)
OH
(c)
HO
OH
O
OH
(e)
OH
HO
O
HO
OH
O
(f)
Fig. 1. Chemical structures of the additives used in this work. (a) GL; (b) SO; (c) SA; (d) MA; (e) TA; (f) CA.
73
pre-warmed (75C) teon mould (200 200
2 mm). Water was evaporated from the moulds in a
ventilated oven at 50C for 12 hour and in a cold
lab. chamber at 5C for 72 hour. Dried lms were
put in open polyethylene bags and stored at 20C
and at RH 53% for 1 week before the measurements were made performed.
Starch
PVA
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
GL
10
20
30
40
50
wt.%
wt.%
wt.%
wt.%
wt.%
SO
10
20
30
40
50
wt.%
wt.%
wt.%
wt.%
wt.%
SA
10
20
30
40
50
wt.%
wt.%
wt.%
wt.%
wt.%
MA
10
20
30
40
50
wt.%
wt.%
wt.%
wt.%
wt.%
TA
10
20
30
40
50
CA
wt.%
wt.%
wt.%
wt.%
wt.%
10
20
30
40
50
wt.%
wt.%
wt.%
wt.%
wt.%
74
20
70
15
60
10
Elongation(%)
Tensile strength(MPa)
25
80
50
5
40
0
20
40
60
80
100
0
120
Mixing time(min)
Fig. 2. TS and elongation (%E) of starch/PVA blend lm versus
mixing time.
As the contents of GL, SO, MA, TA and CA increased from 10 to 50 wt.%, TS decreased while %E
increased. However, in the SA-added lm TS increased while %E decreased, as the content of SA
increased.
The comparison of results between the GL
(with 2 hydroxyl group)-added and SA (with 2 carboxyl group)-added starch/PVA blend lms showed
that TS of GL-added lm was lower than SA-added
lm when the same contents were added. However,
%E of GL-added lm was higher than that of SAadded lm. SA-added lms were too brittle to apply.
Also, the results of comparison between the
GL and SO (with 6 hydroxyl group)-added lms
Starch
PVA
GL
SO
SA
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5%
5 wt.%
10 wt.%
15 wt.%
20 wt.%
25 wt.%
5 wt.%
10 wt.%
15 wt.%
20 wt.%
25 wt.%
5 wt.%
10 wt.%
15 wt.%
20 wt.%
25 wt.%
5 wt.%
10 wt.%
15 wt.%
20 wt.%
25 wt.%
75
Fig. 5. TS of starch/PVA blend lms adding GL, SO, SA, GLSA and SO-SA as additives. where, SPGL is lm added GL,
SPSO is lm added SO, SPSA is lm added SA, SPGLSA is lm
added GL-SA as the mixed additives, SPSOSA is lm SO-SA as
the mixed additives.
76
TS (MPa)
Elongation (%)
SP
SP
SPGL30
SPGL30
SPSO30
SPSO30
SPSA30
SPSA30
SPMA30
SPMA30
SPTA30
SPTA30
SPCA30
SPCA30
SPGLSA30
SPGLSA30
SPSOSA30
SPSOSA30
55.58
60.97
7.3
8.5
9.3
10.42
68.7
70
13.1
15.79
17.4
19.19
32.39
35.3
24.6
26.9
35
37.88
20.27
40.74
87.7
93.6
97.2
100.7
5.12
6.39
108.1
120.6
126
140.2
141.9
162.9
48.31
53.39
58.7
62.18
Fig. 9. DS of starch/PVA blend lms adding GL, SO, SA, GLSA and SO-SA as additives. where, SPGL is lm added GL,
SPSO is lm added SO, SPSA is lm added SA, SPGLSA is lm
added GL-SA as the mixed additives, SPSOSA is lm SO-SA as
the mixed additives.
77
Fig. 10. DS of drying starch/PVA blend lms at 50 and 5C. Where, SP, SPGL30, SPSO30, SPSA30, SPMA30, SPTA30 and
SPCA30 are lms dried at 5C.
DS values of the lms to which MA with 2 carboxyl and 1 hydroxyl group, TA with 2 carboxyl
and 2 hydroxyl group and CA with 3 carboxyl and
1 hydroxyl group as the functional group had a
comparatively high value. As the number of the
carboxyl and hydroxyl group of additive increased,
DS values increased. DS value increases because
MA, TA and CA are easily soluble and combine
with H2O molecule and attributed to the hydrophilism of PVA, MA, TA and CA.
Figure 9 represents the DS values of lms prepared by adding the same content GL-SA and
SO-SA in starch/PVA blend lms. DS values of
GL-SA-added and SO-SA-added lm were lower
than those of GL-added, SO-added and SA-added
lms. These results showed the same characteristics
as those of the MA-added TA-added and CA-added
lms.
DS values of the starch/PVA blend lms
dried at 50 and 5C are shown in Fig. 10. When
the same contents of GL, SO, SA, MA and TA
was added to additive, the lms dried at 5C
showed low DS value. As discussed earlier, DS
values are low because hydrogen bonding is activated at low temperature.
CONCLUSIONS
Starch/PVA blend lms were prepared successfully by using starch, PVA, GL, SO, SA, MA, TA
and CA for the mixing process. Materials with hydroxyl and carboxyl group as functional group
cross-linked between starch and PVA were used to
as additive for starch/PVA blend lms. Values of
TS and %E were investigated. The results veried
that hydroxyl and carboxyl group as a functional
group increased the exibility and strength of the
lms. DS values of the MA-added or TA-added
lms were higher than GL-added, SO-added and
SA-added lms. The reason is because materials
having both hydroxyl and carboxyl group, i.e., MA,
TA or CA are the highly hydrophilic.
TS, %E and DS values were superior when the
lm was dried at 5C than at 50C. This is considered to result from the occurrence of hydrogen
bonding at the lower temperature.
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