Physics

1.

C
Consider the situation of figure. The work done
q
in taking a point charge from P to A is WA ,
from P to B is WB and from P to C is WC .
B
(a) WA < WB < WC
(b) WA > WB > WC
(c) WA = WB = WC
(d) none of these.

2.

Figure shows a closed surface which intersects a

conducting sphere. If a positive charge is placed at
the point P, the flux of the electric field through the
closed surface
(a) will remain zero
(b) will become positive
(c) will become negative
(d) will become undefined.

3.

5.

Closed
Surface

Conducting
Sphere

V
Figure shows two capacitors connected in series
and joined to a battery. The graph shows the
x
variation in potential as one moves from left to
C
C
right on the branch containing the capacitors.
(a) C1 > C2
(b) C1 = C2
(c) C1 < C 2
(d) The information is not sufficient to decide the relation between C1 and C2 .
A capacitor of capacitance C is charged to a potential V. the flux of the electric field
through a closed surface enclosing the capacitor is
CV
2CV
(b)
(a)
0
0
CV
(c)
(d) zero.
2 0
1

4.

A current passes through a resistor. Let K1 and K 2 represent the average kinetic energy
of the conduction electrons and the metal ions respectively.
(a) K1 < K 2
(b) K1 = K 2
(c) K1 > K 2
(d) any of these three may occur.
1

6.

A uniform wire of resistance 50 is cut into 5 equal parts. These parts are now
connected in parallel. The equivalent resistance of the combination is
(a) 2
(b) 10
(c) 250
(d) 6250 .

7.

Two inductances L1 and L2 are placed far apart and in

parallel. Their combined inductance is
L1 L2
(b) ( L1 + L2 )
(a)
L1 + L2
L
(c) ( L1 + L2 ) 1
L2
L
(d) ( L1 + L2 ) 2 .
L1

8.

9.

L1

i1

L2

i2

The current in an L R circuit builds up to 3 / 4th of its steady state value in 4 seconds.
The time constant of this circuit is
1
2
(a)
(b)
sec
sec
ln 2
ln 2
3
4
(c)
(d)
sec
sec .
ln 2
ln 2
Four particles, each having a charge q, are placed at
the four vertices of a regular pentagon. The electric
field at the centre of the polygon is
q
(b)
(a)
4 0 a 2
q
0 a 2
2q
q
(c)
(d)
2
0 a
0 a

.
10.

Electric potential is given by : V = 6 x 8 xy 2 8 y + 6 yz 4 z 2 . Electric field at the origin

is
(b) 6i 8 j
(a) 6i + 8 j
(c) i + j
(d) zero.

11.

12.

13.

14.

15.

16.

Two identical capacitors have the same capacitance C. One of them is charged to
potential V1 and the other to V2 . The negative ends of the capacitors are connected
together. When the positive ends are also connected, the decrease in energy of the
combined system is
1
1
(a)
(b)
C(V12 V22 )
C(V12 + V22 )
4
4
1
1
(c) C(V1 V2 )2
(d)
C(V1 + V2 )2 .
4
4
The electric field at the centre of an uniformly charged ring is zero. What is the electric
field at the centre of a half ring if the charge on it be Q and its radius be R ?
1
Q
1
Q
(b)
(a)

2
2
4 0 R
4 0 R
1
2Q
1
2Q
(c)
(d)

2.
2
4 0 R
4 0 R
In the network shown in the figure, each resistance is
equal to 2 the resistance between the points A and B
is
(b) 4
(a) 1
(c) 3
(d) 2 .

Figure shows a network of 9 identical resistors. The

resistance of the whole circuit is 1.5 . The resistance
R is :
(a) 1.1
(b) 3.3
(c) 1.4
(d) 1.8 .
In the network shown in figure, the ring has zero
resistance. The equivalent resistance between the points
A and B is :
(a) 2 R
(b) 4 R
(c) 7 R
(d) 10 R.

A
B

R
R

R
R

R
R

3R
B

3R

A
R
3R

A proton moving with a speed of 107 m s 1 enters the region of a uniform, perpendicular
magnetic field of 0.4 T. The radius of the circular path described by proton is (mass of
proton = 1.6 1027 kg)
(a) 0.25 m
(b) 0.25 mm
(c) 4 mm
(d) 4.25 mm.
3

17.

Two capacitor C and 2C in parallel are charged with a battery of voltage V and then
isolated. Now a dielectric of relative permittivity k is filled in C
V
(a) the final p.d. across the combination is
3k + 1
3V
(b) the final p.d. across the combination is
k+2
2V
(c) the final p.d. across the combination is
k
V
.
(d) the final p.d. across the combination is
2k + 1

18.

A coil of inductance 8.4 mH and resistance 6 is connected to a 12 V battery. The

current in the coil is 1.0 A at approximately the time.
(a) 500 s
(b) 20 s
(c) 35 s
(d) 1 s.

19.

The conductor AD moves to the right in a uniform

magnetic field directed into the paper. Mark the correct
option.
(a) the free electrons in AD will move towards A
(b) D will acquire a positive potential with respect to
A
(c) If D and A are joined by a conductor externally, a
current will flow from A to D in AD
(d) all the above.
Lenzs law is consistent with law of conservation of
(a) current
(b) emf
(c) energy
(d) all of the above.

20.

21.

Two particles X and Y having equal charges, after being accelerated through the same
potential difference, enter a region of uniform magnetic field and describe circular paths
of radii R1 and R2, respectively. The ratio of the mass of X to that of Y is
(a) ( R1 / R2 )

(b) R2 / R1

(c) ( R1 / R2 )2
22.

(d) R1 / R2 .

A regular loop carrying a current i is situated near a

long straight wire such that the wire is parallel to one of
the sides of the loop and is in the plane of the loop. If a
steady current I established in the wire as shown in the
figure, the loop will :
4

i
I

(a)
(b)
(c)
(d)
23.

24.

25.

rotate about an axis parallel to the wire

move away from the wire
move towards the wire
remain stationary.

Two equal point charges are fixed at x = - a and x = + a on the x-axis. Another point
charge Q is placed at the origin. The change in the electrical potential energy of Q, when
it is displaced by a small distance x along the x-axis, is approximately proportional to :
(a) x
(b) x2
(c) x3
(d) 1/x.
A certain charge Q is divided into two parts q and (Q-q). For the maximum coulomb
force between them, the ratio (q/Q) is :
(a) 1/16
(b) 1/8
(c) 1/4
(d) 1/2.
A/2
A/2
A parallel plate capacitor of area A, plate separation d
k
k
and capacitance C is filled with three different
d
dielectric materials having dielectric constants k1, k2
k
and k3 as shown. If a single dielectric material is to be
A
A = area of plates
used to have the same capacitance C in this capacitor,
then its dielectric constant k is given by :
1 1 1
1
1
1
1
(a)
(b)
= + +
=
+
k k1 k2 2k3
k k1 + k2 2k3
kk
(c) k = 1 2 + 2k3
(d) k = k1 + k2 + 2k3 .
k1 + k 2
1

d/2

26.

27.

Find the charge flown through the switch when it is

closed
(a) 20 C
(b) 30
C
(c) 42 C
(d) 60
C.
A solid conducting sphere of radius a having a charge
Q is surrounded by a concentric conducting spherical
shell of inner radius 2a and outer radius 3a as shown in
figure. Find the amount of heat produced when switch
is closed.
Kq 2
Kq 2
(b)
(a)
2a
3a
5

10F
5V
2F
10V
6F

a
s
3a

2a

(c)
28.

(c)

Kq 2
.
6a

+
+
+

+
+
+
+

(b)
(d)

+
+
+
+

+
+
+
+

-.

Consider two thin concentric shells of masses M and 2M and radii R1 and R 2 ( R1 < R 2 ).
Magnitude of the gravitational force experienced by a particle of mass m placed at a
R + R2
from the common centre will be
distance 1
2
8GMm
4GMm
(A)
(B)
2
(R1 + R2 )2
(R1 + R2 )

(C)

30.

(d)

An uncharged sphere of metal placed inside a charged parallel plate capacitor. The lines
of force look like :

(a)

29.

Kq 2
4a

2GMm
(R1 + R2 )2

(D)

12GMm
(R1 + R2 )2

r
A uniform gravitational field E = ai + bj N/kg exists in a region. Work done in displacing

a particle along a straight line represented by ax + by = c will be (a, b and c are

constants)

31.

32.

(A) a x 2 + y 2

(B)

(C) ax+by

(D) zero.

a2 + b2

x2 + y2

A pendulum oscillates with an angular amplitude < . The ratio of the maximum
2
tension to the minimum tension in the string will be [ is the angle made by the string
with the vertical]
(A) 3cos + 1
(B) 3 sec 2
(C) 1 + 2sin
(D) 2 + 3 cos
A particle moves in the x-y plane such that the radius vector of its instantaneous position
r
is r = 2i + 3j Acos t . Which of the following statement is true

(A) path of motion in an ellipse.

(B) motion is periodic but not simple harmonic
(C) motion is simple harmonic with amplitude 13 A
(D) none of the above.

33.

A power radiated by a black body is P0 and the wavelength corresponding to the

maximum energy is around 0 . On changing the temperature of the black body, it was
observed that the power radiated is increased to

34.

corresponding to the maximum energy will be

(A) + 0
(B) + 0
4
2

(C) 0
(D) 0
4
2
A gas undergoes a process in which its pressure p and volume V are related as pn V m
=constant, where m and n are dimensionless constants. The bulk modulus for the gas in
this process will be
n
m
(A) p
(B) p
m
n
(D) (m n)p

(C) (m+n)p
35.

256
P0 . The shift in the wavelength
81

The adiabatic exponent of a gas

Cp
Cv

= and its molecular weight = M. The difference of

its molar heat capacity and specific heat capacity (both at constant pressure) will be
R (M 1)
R
(B)
(A)
(M 1)
1
1 M
R
(C) M

(D)

R
M( 1)

36.

Two organ pipes A and B have their lengths in the ratio n : m. Pipe A is open at both
ends while B is closed at one end only. The ratio of the frequencies of first overtones
produced by each of them will be
m
2m
(B)
(A)
2n
n
3n
4m
(D)
(C)
4m
3n

37.

Match the following column (I) and (II).

(I)

(II)

(a) Conservative force field

(i)

Work done is stored.

(b) Energy and frequency relationship

(ii)

Plancks law

(c) sound waves

(iii) decrease in temperature

(d) Adiabatic expansion

(iv) longitudinal wave motion.

(A) (a)-(i), (b)-(ii), (c)-(iii) and (d) - (iv)

(B) (a)-(ii), (b)-(iii), (c)-(iv) and (d) - (i)

7

38.

(C) (a)-(i), (b)-(ii), (c)-(iv) and (d) - (iii)

Match the following column (I) and (II).

(D) (a)-(iv), (b)-(iii), (c)-(ii) and (d) - (i)

(I)
(a) Periodic time of spring mass system

(II)
(i)

central forces

(b) Escape velocity

(ii)

Doppler effect.

(c) Conservation of angular momentum.

(iii) independent of gravity.

(d) Apparent change in pitch

(iv) independent of mass of the object.

(A) (a)-(iii), (b)-(iv), (c)-(i) and (d) - (ii)

(C) (a)-(iv), (b)-(iii), (c)-(ii) and (d) - (i)
39.

(B) (a)-(iv), (b)-(iii), (c)-(ii) and (d) - (i)

(D) (a)-(i), (b)-(ii), (c)-(iii) and (d) - (iv)

From a solid sphere of radius R and mass

M a small sphere of radius R/4 is scooped
out and placed on the surface of the
original solid sphere on a diametrically
opposite point as shown in the figure. The
gravitational potential of the resulting
system at a point P (as shown in the
figure) is

(A)

(C)

R/4
R

P
R/4
O

R/4

GM
R

(B)

GM

d2 +

4GM

R2
4

(D) zero.

16d2 + R2

40.

Three particles are thrown at regular interval of 2 sec, with a speed of 60 m/s vertically
upward. The ratio of their speeds at the end of 7 sec is
(A) 1 : 1 : 3
(B) 1 : 1 : 3
(C) 1 : 1 : 1
(D) 1 : 2 : 3

41.

The velocity vector of a particle moving over a horizontal plane is given by v = 2t i +

3t 2 i . The ratio of the magnitude of instantaneous acceleration of the particle at t = 2 sec
to the magnitude of displacement of the particle during the interval of first 2 sec is
37
37
(A)
(B)
20
20

20
(D) cannot be determined
37
An external force is applied on a body of mass 10 kg placed over a rough horizontal
surface having coefficient of friction 0.2. The momentum of the body is found to be
r
P = 80ti + 60tj . The applied force is
(A) 80 i + 60 j
(B) 74 i + 48 j
(C)

42.

(C) 16 i + 12 j

(D) 96 i + 72 j

43.

A block of mass 2kg was moving along a straight line on a smooth surface with a speed
of
5 m/s. At t = 0, a force given by F = (3 + 2t)N directed in the direction of motion of the
body starts acting on the block. The kinetic energy of the block after 2 sec is
(A) 20 J
(B) 200 J
(C) 100 J
(D) none of these.

44.

A wide vessel and a tube is connected as shown in the figure.

Water is filled inside vessel and tube. When tube is opened the
water flows out as shown in the figure. The pressure at point P, at
mid point of tube is (cross section of the tube is very-very small)
(A) P0 + 3gH
(B) P0 + gH
(C) P0
(D) P0 gH

45.

2H

F=kt

A block of mass m is placed on an inclined surface.

Coefficient of friction between plane and block is > tan.
A force F = kt is applied on block at t = 0 then which of the
following represents variation of magnitude of frictional
force with time.

m
>tan

(A)

(B)
fr

fr
Time

Time

(C)

(D)
fr
fr

Time
Time

46.

A right circular cone of base radius R and height H is hanging

horizontally via a string inside liquid of density . Tip of the cone is at a
distance h below the free surface of liquid. The force due to liquid on the
surface of cone is

R gH
3
2
(C) R gH
2

(B) R

(A)

(D) zero

(R

+ H2 gH

h
H

47.

Match the following column (I) and (II).

(I)

(II)

(a) First law of thermodynamics

(i)

conservation of kinetic energy.

(b) Elastic collision

(ii)

conservation of energy.

(c) Absence of dissipative force

(iii) conservation of volume.

(d) equation of continuity

(iv) conservation of mechanical energy.

(A) (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)

(C) (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)
48.

(B) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)

(D) none of these

The time period of a simple pendulum is T0 for small oscillation. When the simple
pendulum is immersed in a fluid its time period is T, then the correct option is
(A) T = T0
(B) T > T0
(C) T < T0

49.

(D) none of these.

In the shown figure a cube of mass m is attached with a cylinder

of same mass and radius r through an ideal string-pulley
system. The string is wound over the cylinder. If is the angular
acceleration of the cylinder then the linear acceleration of ae

a
m

and the linear acceleration of cube A, are related as

(A) ae = A
(B) A = ae 2
(C) ae + r = A
50.

(D) ae = A + r

A block of mass m, when placed on an incline plane fixed with an

elevator, which is moving with constant downward acceleration g/2,
remain stationary. If the coefficient of friction between the plane and
block is , the magnitude of force of friction acting on the block is

g
(B) m cos
2
g
(D) m sin
2

(A) mg cos

(C) m

ae

g
sin
2

m
g/2

Chemistry
51.

The hydride ion H is stronger base than its hydroxide ion OH. Which of the following
reaction will occur if NaOH is dissolved in water?
(a) H(aq) + H2O H2O
(b) H(aq) + H2O(l) OH+H2
(d) None of these
(c) H + H2O No reaction
10

52.

The ionisation constant for CH3COOH is 1.75 105. What is the pH of a buffer solution
containing 0.1 mole of CH3COOH and 0.15 mole of CH3COONa?
(a) 3
(b) 3.7
(c) 4.3
(d) 4.9

53.

2SO3. Starting with 2 mol SO2 and 1 mol O2 in 1 L flask, mixture

2SO2 + O2
required 0.4 mol MnO4 in acidic medium. Hence KC is
(a) 2
(b) 0.4
(c) 1.6
(d) 2.6

54.

2C + D, initial mole of A is double of B. At equilibrium mol of A and

For 3A + 2B
D are equal. Hence percentage dissociation of A is
(a) 50%
(b) 25%
(c) 75%
(d) none of these

55.

Addition of solid potassium cyanide to water would cause

(a) Increase in pH
(b) Decrease in pH
(c) No change in pH
(d) no change in electrical conductivity

56.

A certain buffer solution contains equal concentration of X and HX. The Kb for X is 10
. The pH of the buffer is
(a) 4
(b) 7
(c) 10
(d) 14

10

57.

C H 3 , N H 2 ,O H, F in increasing pKb values

58.

(a) C H 3 < N H 2 < O H < F

(c) OH < NH 2 < CH3 < F
Most stable carbonium ion is

(b) F < O H < NH 2 < CH 3

(d) none is correct
+

59.

(a) CH2 = C H

(b)

(c)

(d) (CH3)3C+

+
CH2

Which one of the following will be aromatic?

(a)
(b)

(d)

(c)

11

60.

The Ka values of alcohols, water and phenol are of order 1017, 1014 and 1010
respectively. Which of the following reactions is possible?
(a) C6H5O + H2O C6H5OH + OH (b) C2H5O + H2O C2H5OH + OH
(c) both A & B
(d) neither of two
CH3 Cl

61.

HCl

A. A is
R O

H3C

2 2

CH3
H5 C2

CH3 Cl

(a)
H3C

CH3 Cl

CH3 Cl

(b)
H3C

CH3H
CH3 Cl

(c)
H3C

(d)

Cl
and formed through carbocation formation
C 2 H5
and formed through carbon free radical
C 2 H5

CH3 Cl
CH3 Cl

Cl

CH3H

and formed through carbon free radical

C 2 H5

H3C

62.

and formed through carbocation formation

C 2 H5

H5 C 2
80C
+ Br2
(A). (A) is

H5 C 2

CH2
H5 C 2

C 2 H5 Br

(a)

H5 C 2

(b)
Br

CH2

H5 C 2
Br

C 2 H5

(c)

Br

C 2 H5 Br

H5 C 2

(d)
Br

H3C
Br

Br

12

CH2

63.

CH3

Clemenson

X is
reduction at 60C

HO

CH3

(a)

CH3

(b)
Cl
O

CH3

(c)

(d)

CH3

HO
Br

64.

alc . KOH

A, A is

Br
Br

(a)

(b)
Br

(d)

(c)

Br

Br

65.

OH
trans 2 butene
A
B, B is
CHF2Br

(a)

Br

CH3

CH3

CH3

(b)

(c)

(d)
H3C

66.

Br

CH3

CH3

An open chain compounds

Match list I with list II and select the correct answer using the codes given below:
List I (stability)
List II (Reason)
13

H3C

CH3

a)

1.

Inductive effect

2.

Resonance

3.

Hyperconjugation and
resonance

4.

Hyperconjugation and
Inductive

+
> CH3

CH3

b) H3C

< CH3

CH3
CH3

c) H3C

<H C
3

CH2

CH3
H3C

d)

67.

CH2

CH2
CH3

>

Codes
a
b
c
d
(a) 2
3
4
1
(b) 3
1
4
2
(c) 4
3
1
2
(d) 3
4
2
1
Match list I with list II and select the correct answer using the codes given below:
List I
List II
a. CH3COONa
1. Strong electrolyte with pH > 7
b. NH4Cl
2. Strong electrolyte with the pH < 7
c. Bi2S3
3. Weak electrolyte with Ksp = S2
d. CdS
4. Weak electrolyte with Ksp = 108S5
Codes
a
(a) 2
(b) 1
(c) 1
(d) 1

b
3
2
3
3

c
1
4
2
4

d
4
3
4
2

14

68.

Which one of the following has the lowest dipole moment?

H3C

CH3

(a)
H

(c)

(b)

H3C

(d)

H2 C

CH3

H3 C

CH

CH

69.

40% of a mixture of 0.2 mol of N2 and 0.6 mol of H2 react to give NH3 according to the
2NH3(g) at constant temperature and pressure. Then the ratio
equation N2(g) + 3H2(g)
of the final volume to the initial volumes of gases is as
(a) 4:5
(b) 5:4
(c) 7:10
(d) 8:5

70.

Two systems PCl5(g)

PCl3(g) + Cl2(g) and COCl2(g)
CO(g) + Cl2(g) are
simultaneously in equilibrium in a vessel at constant volume. If some CO is introduced
into the vessel then at the new equilibrium the concentration of
(a) PCl5 is greater
(b) PCl3 remains unchanged
(c) PCl5 is less
(d) Cl2 is greater
The precipitate of CaF2(Ksp = 1.710-10) is obtained when equal volumes of the following
are mixed
(b) 10-2 M Ca2+ + 10-3 MF(a) 10-4 M Ca2+ + 10-4 MF(c) 10-5 M Ca2+ + 10-3 MF(d) 10-3 M Ca2+ + 10-5 MF-

71.

72.

The maximum number of isomers for an alkene with the molecular formula C4H8 is:
(a) 2
(b) 3
(c) 4
(d) 5

73.

In the following reaction

BH3
CH3COOH
CH3 CH = CH 2
A
B

A and B are,
H3C
B ,

(a)

(b)
(c)

H3C

H3C

CH2

H3C

CH2

H3C
CH3
CH2

CH2

B,

H3C

CH3

O
O

B,

H3C

15

CH3

H3C
B ,

(d)
H3C

74.

H3C
CH3

Which of the following is the diastereoisomer of the compound?

CH 3
H

HO

H
CH3

OH

CH3
H

(a)

OH

(b)

H3C

CH3

CH3

OH

(c)
75.

H3C
I

OH

(d)

CH3

H3C
H

H
CH3

I
H
If the molecular weight of Ba(MnO 4 )2 is M, then the equivalent weight of Ba(MnO 4 )2 in
acidic medium is:
M
M
(A)
(B)
5
10
M
(D) M
(C)
3

76.

280 ml of H2O2 reacts completely with 15.8g of KMnO 4 in acidic medium, then the
volume strength of H2O2 is:
(A) 10
(B) 100
(C) 5
(D) 20

77.

The velocity of electron in the second orbit of He + will be

(A) 2.18 106 m/s
(B) 1.09 10 6 m/s
(C) 4.36 106 m/s
(D) None

78.

If the 1.58g of KMnO 4 in acidic medium completely reacts with ferrous oxalate
(FeC2O 4 ), the what weight (in g) of ferrous oxalate is required?
(A) 2.73
(B) 4.73
(C) 11.19
(D) 8.5

16

79.

Applying the principle of equipartition of energy, what will be total Cv values of H2

molecule, assuming 100% contribution of vibrational degree of freedom?
(A) 3.5R
(B) 2.5R
(C) 5R
(D) 4.5R

80.

The values of vander Waals constant `a (atm2 L2 mol2 ) for the gases N2 , H2 NH3 and
SO2 are given 0.25, 3.5, 4.9 and 6.9 respectively. Which will have the highest ease of
liquification?
(A) SO2
(B) NH3

(C) N2
81.

82.

(D) H2

The activation energy of the forward reaction and backward reaction decreases by 30
kcal then which of the following statement is correct?
(A) H will remain constant
(B) H will decrease
(C) H will increase
(D) The reaction will be exothermic
N
30 ml of CH3COOH is added in NaOH solution, then at the end point of the
5
reaction, the equilibrium constant of the reaction at 25C (given that K a(CH3COOH) = 10 5 )
will be
(A) 109
1
(C) 109
5

(B) 10 9
(D) None

83.

For the radioactive sequential chain reaction

A B C
for the steady state of B, assuming that the no. of atoms of A is half of the no. of atoms
of B then if the half life of B is 2 hours then the half of life of A (in hours) will be
(A) 4
(B) 2
(C) 1
(D) 3

84.

The compressibility factor for an ideal gas is:

(A) 0
(B) 1
(C) 2
(D) 4

85.

Two gram of hydrogen diffuse from a container in 10 minutes. How many grams of
oxygen would diffuse through the same container in the same time under similar
conditions?
(A) 0.5 g
(B) 4 g
(C) 6 g
(D) 8 g

17

86.

K a for HCN is 5 10 10 at 25C. For maintaining a constant pH = 9, the volume of 5 M

KCN solution required to be added to 10 ml of 2 M HCN solution is
(A) 4 ml
(B) 7.95 ml
(C) 2 ml
(D) 9.3 ml

87.

A buffer solution is prepared by mixing 10 ml of 1.0 M CH3COOH and 120 ml of 0.5 M

CH3COONa and then diluted to 100 ml with distilled water. If pK a of CH3COOH is 4.76,
what is the pH of the buffer solution
(A) 5.53
(B) 4.76
(C) 4.34
(D) 5.8
88.
89.

The pH of solution formed by mixing 40 ml of 0.1 M HCl with 10 ml of 0.45 M of NaOH is

(A) 10
(B) 12
(C) 8
(D) 6
Which of the following bromide will undergo faster dehydrobromination?
Br

Br

(B)

(A)

(D)

(C)
Br

90.

Which of the following carbocation is more stable?

(A)
(C)

91.

Br

(B)

CH 2
CH3

H3C

(D)

H2C
F
O

H3C

CH3

Which of the following keto compound will give the least stable enol?
O
O

(A)

(B)
O

(D)

(C)

92.

How many optically active fractions can be produced by monochlorination of the

compound
H3C
H3C

CH3

18

(A) 1
(C) 4
93.

94.

(B) 3
(D) Zero

Which of the following is the least stable?

(A)

(B)

(C)

(D)

Which of the following is the most reactive towards electrophilic aromatic substitution?
O

(A)

(B)
NH2

OH

(D)

(C)

95.

Which of the following will show Friedal Crafts alkylation?

NH2

COO

OH

NO 2

(D)

(C)

Which of the following is most basic in protic polar solvent?

H3C

H3C

NH

(A)
(C)

CH3

H3C

H3C

NH2

(D)

NH3

Which of the following is the correct order of reactivity towards nitration?

(B) C6D6 > C6H6 > C6 T6
(A) C6H6 > C6D6 > C6 T6
(C) C6 T6 > C6D6 > C6H6

98.

(B)

H3C

97.

(B)

(A)

96.

CH3

(D) C6 T6 = C6D6 = C6H6

Which of the following carbon has the most acidic hydrogen?

O
N

CH3

19

(A) 5
(C) 3
99.

(B) 4
(D) 1

Which of the following alkene has the lowest heat of hydrogenation?

H

CH2

(A)
H

H3C

(C)

CH3

(D)
H3C

100.

CH3

(B)

H3C

Which of the following imene is least stable?

NH

HN

(B)

(A)

HN

HN

NH

NH

(C)

(D)
NH

NH

Maths
101. If ax2 y2 + 4x y = 0 represents a pair of lines, then a is equal to
(a) 16
(b) 16
(c) 4
(d) 4
102. What is the equation of the locus of a point which moves such that 4 times its distance
from the x-axis is the square of its distance from the origin?
(a) x2 + y2 4y = 0
(b) x2 + y2 4|y| = 0
(c) x2 + y2 4x = 0
(d) x2 + y2 4|x| = 0
103. Equation of the straight line making equal intercepts on the axes and passing through
the point (2, 4) is
(a) 4x y 4 = 0
(b) 2x + y 8 = 0
(c) x + y 6 = 0
(d) x + 2y 10 = 0

20

104. If the area of the triangle with vertices (x, 0), (1, 1) and (0, 2) is 4 square units, then the
value of x is
(a) 2
(b) 4
(c) 6
(d) 8
105.

lim 2

x cot
2

(a) 0
(b) 1
(c) 1
(d)
106. The co-axial system of circles given by x2 + y2 + 2gx + c = 0 for c < 0 represetns
(a) intersecting circles
(b) non intersecting circles
(c) touching circles
(d) touching or non-intersecting circles
107. The radius of the circle passing through the point (6, 2) and two of whose diameters are
x + y = 6 and x + 2y = 4 is
(a) 4
(b) 6
(c) 20
(d) 20
108. If (0, 6) and (0, 3) are respectively the vertex and focus of a parabola, then its equation
is
(a) x2 + 12y = 72
(b) x2 12y = 72
(c) y2 12x = 72
(d) y2 + 12x = 72
109. For the ellipse 24x2 + 9y2 150x 90y + 225 = 0 the eccentricity e is equal to
2
5
4
(c)
5

3
5
1
(d)
5

(b)

(a)

110.

If the foci of the ellipse

x2
y2
1
x2 y2

=
coincide, then the
+ 2 = 1 and the hyperbola
144 81 25
16 b

value of b2 is
(a) 1
(b) 7
(c) 5
(d) 9
111. The differential coefficient is f(sinx) with respect to x where f(x) = logx is
(a) tan x
(b) cot x
(c) f(cos x)
(d) 1/x
112.

1 cos x
, x0

is continuous at x = 0, then the value of k is

x

k,
x=0

If f(x) =

(a) 0
(c)
113.

If =

(a) 16
(c) 16

(b)
(d)
1 + 3 i
then (3 + + 32 )4 is
2

(b) 16
(d) 16 2
21

114.

If y = tan1(sec x tan x), then

(a) 2

(b) 2

1
(c)
2

(d)

115.

If x +

(b) 2n cos n
(d) 2cos n

1| 1 x |dx

is equal to

(a) 2
(c) 2
117.

(b) 0
(d) 4
dx

x(x7 + 1)

is equal to

x7

(a) log 7 + c
x + 1
x7 + 1
+c
7

(c) log
118.

(b)

x7
1
log 7
+c
x + 1
7

(d)

x7 + 1
1
log 7 + c
x
7

xe x dx is equal to

(a) 2 x e

4 xe

+c

(b) (2x 4 x + 4)e

+c

(c) (2x + 4 x + 4)e

+c

(d) (1 4 x )e
119.

1
2

1
1
= 2cos then xn + n is equal to
x
x

(a) 2n cos
(c) 2isin n
116.

dy
is equal to
dx

dx

x 2 + 2x + 2

+c

is equal to

(a) sin-1(x + 1) + c
(b) sin h-1(x + 1) +c
(c) tan h-1 (x + 1) +c
(d) tan-1(x + 1) +c
120. If a tangent to the curve y = 6x x2 is parallel to the line 4x 2y 1 = 0, then the point
of tangency on the curve is
(a) (2, 8)
(b) (8, 2)
(c) (6, 1)
(d) (4, 2)
121. 0.5737373.... is equal to
284
497
568
(c)
999

(a)

284
495
567
(d)
990

(b)

22

122.
(a)
(c)
123.
(a)
(c)

The number of solutions for the equation x2 5|x| + 6 = 0 is

4
(b) 3
2
(d) 1
How many numbers of 6 digits can be formed from the digits of the number 112233?
30
(b) 60
90
(d) 120

124. The last digit in 7300 is

(a) 7
(b) 9
(c) 1
(d) 3
log x log y log z
, then xyz is equal to
=
=
ab bc c a

125.

If

(a)
(c)
126.
(a)
(c)
127.
(a)
(c)

0
(b) 1
1
(d) 2
The smallest positive integer n for which (1 + i)2n = (1 i)2n is
1
(b) 2
3
(d) 4
If cos1 p + cos1 q + cos1 r = then p2 + q2 + r2 + 2pqr is equal to
3
(b) 1
2
(d) 1

128.

If sin1 + cos ec 1

x
5

(a) 1
(c) 3
129.

(b) 4
(d) 5
2

If 0 x and 81sin x + 81cos

(a)
6

(c)
4

130.

5
= , then x is equal to
4 2

= 30 , then x is equal to

(b)
2
3
(d)
4

The equation of the director circle of the hyperbola

x2 y2

= 1 is given by
16 4

(a) x2 + y2 = 16
(b) x2 + y2 = 4
(c) x2 + y2 = 20
(d) x2 + y2 = 12
131. If Q1 is the set of all relations other than 1 with the binary operation * defined by a * b =
a + b ab for all a, b in Q1, then the identity in Q1 with respect to * is
(a) 1
(b) 0
(c) 1
(d) 2
132. The circle x2 + y2 8x + 4y + 4 =0 touches
(a) x-axis
(b) y-axis
(c) both axis
(d) neither x-axis nor y-axis
23

133. Which of the following is true?

(a) The set of all fourth roots of unity is a multiplicative group
(b) The set of all cube roots of unity is an additive group
(c) (ab)1 = a1b1 for all ab,b in any group G
(d) If (ab)2 = a2b2 for all a, b in any group G, then the group G is non abelian
134. The set of all integral multiples of 5 is a subgroup of
(a) The set of all reational numbers under multiplication
(b) The set of all integers under multiplication
(c) The set of all non zero rational numbers under multiplication
(d) The set of all integers under addition
135. The value of k so that x2 + y2 + kx + 4y + 2 = 0 and 2(x2 + y2) 4x 3y + k = 0 cut
orthogonally is
10
3
10
(c)
3

(b)

(a)

lim 1
x
x 1

136.
(a)
(c)

e12
e4

(d)

8
3

8
3

3x 1

is equal to
(b)
(d)

e12
e3

If A + B + C = 180 then tan

137.

A
B
tan is equal to
2
2

(a) 0
(b) 1
(c) 2
(d) 3
138. In a triangle ABC if b = 2, B = 30 then the area of the circumcircle of triangle ABC in
square units is
(a)
(b) 2
(c) 4
(d) 6
139. If sin x + sin2 x = 1, then
cos12 x + 3cos10 x + 3cos8 x + cos6 x is equal to
(a) 1
(b) 2
(c) 3
(d) 0
140. If R deontes the set of all real numbers, then the function f : R R defined f(x) = |x| is
(a) one-one only
(b) onto only
(c) both one-one and onto
(d) neither one-one nor onto
141.If 1, , 2 are cube roots of unity, then (1 + )3 (1 + 2)3 is
(a) 0
(b) -1
(c)
(d) 2
142.If

z i
=1, then the locus of z is:
z+i

(a) x = 0
(c) x = 1

(b) y = 0
(d) y = 1
24

143.The condition that one root of the equation ax2 + bx + c = 0 may be square of the other, is:
(a) a2c + ac2 + b3 3abc = 0
(b) a2c2 + ac2 + b2 3abc = 0
(c) ac2 + ac b3 3abc = 0
(d) a2c + ac2 b3 3abc = 0
144.If and are roots of the equation 4x2 + 2x 1 = 0, then the value of 2 + 2 is:
3
4
1
(c) 3
(d)
4
a
b
145.If the root of the equation
+
= 1 are equal in magnitude and opposite in sign, then:
x a xb

(a) 2

(b)

(a) a = b
(b) a + b = 1
(c) a b = 1
(d) a + b = 0
146.The equation of smallest degree with real coefficients having 2 + 3i as one of the roots, is:
(b) x2 + 4x 13 = 0
(a) x2 + 4x + 13 = 0
2
(c) x 4x + 13 = 0
(d) x2 4x 13 = 0
147.If the expression
a(b c) x2 + b(c a) xy + c (a b)y2 is a perfect square, then a, b, c are in:
(a) AP
(b) HP
(c) GP
(d) Both AP and GP
148.The value of n for which the expression

x n +1 + y n + 1
is arithmetic mean between x and y, is:
xn + yn

(A)
0 (b) 1
(c) -1
(d) 2
149.The angles A, B, C of a triangle ABC are in AP and side b and c are in the ratio
then the angle A is:
(a) 105
(b) 60
(c) 45
(d) 75
150.The sum of the series
1+ 2.2 + 3.22 + 4.23 + 5.24 + + 100.299 is
(a) 99.2100
(b) 100.2100
100
(c) 99.2
(d) 1000.2100
151.The sum to n terms of the series
1 3 7 15
+ + +
+ ... is:
2 4 8 16

3: 2,

(b) 1 2n
(a) 2n 1
n
(c) n + 2 1
(d) n 1 + 2n
152.If A, G, H denotes respectively the AM, GM and HM between two unequal positive
numbers, then
(b) G2 = AH
(a) A = G2H
2
(c) A = GH
(d) A = GH
153.If nPr = 720 nCr, then r is equal to:
(a) 6
(b) 5
(c) 4
(d) 7

25

154.Everybody is a room shakes hands with everybody else. The total number of handshakes is
66. The number of persons in the room is:
(a) 11
(b) 12
(c) 13
(d) 14
155.The number of four digit even numbers that can be formed using 0, 1, 2, 3, 4, 5, 6 without
repetition is:
(a) 120
(b) 300
(c) 420
(d) 20
156.The number of circular permutations of n different objects is:
(a) n!
(b) n
(c) (n 2)!
(d) (n 1)!
9

x2 2
is:
2 x

157.The coefficient of x9 in the expansion of

(a) 512
(c) 521

(b) 512
(d) 251

158.If the coefficients of the rth term and the (r + 1)th term in the expansion of (1 + x)20 are in
the ratio 1 : 2, then r is equal to:
(a) 6
(b) 7
(c) 8
(d) 9
159.The number of ways in which 21 objects can be grouped into three groups of 8, 7 and 6
objects, is:
20!
8!+ 7!+ 6!
21!
(c)
8!7!6!

21!
8!7!
21!
(d)
8!+ 7!+ 6!

(a)

(b)

12

22

32

160.The value of 22 32 42 is:

32

(a) 8
(c) 400

42

52

(b) 8
(d) 1

1 2

n
161.If A =
, then A is equal to:
0
1

1 2n

0 1
1 n
(c)

0 1

(a)

2 n

(b)

0 1
1 n

(d)

0 1
162.If A2 A + I = 0, then the inverse of A is:
(a) A2
(b) A + I
(c) I A
(d) A I

26

2 + x 3 4
1 2 is a singular matrix, then x is:
163.If 1
x
1 5
13
25
(b)
(a)
25
13
5
25
(c)
(d)
13
13

164.If A and B are square matrices of order 3 such that |a| = 1, |B| = 3, then the determinant
value of the matrix 3AB is equal to:
(a) -9
(b) -27
(c) -81
(d) 81
a + b a + 2b
a

a
a + b is equal to:
165.If value of a + 2b
a + b a + 2b
a

(a) 9a2 (a + b)
(c) a2 (a + b)

(b) 9b2 (a + b)
(d) b2 (a + b)

1 1 0
166.For the matrix A = 1 2 1 which is correct?
2 1 0

(a) A3 + 3A2 I = 0
(c) A3 + 2A2 I = 0

(b) A3 3A2 I =0
(d) A3 A2 + I = 0

r r r

167.If a, b, c are any three mutually perpendicular vectors of equal magnitude a, then | a + b + c | :
(a) a
(b) 2a
(c) 3a
(d) 2a
r r
r
r
168.If x and y are two unit vectors and the angle between them, then | x y | is equal to:

(b) 2cos
2

(d) cos
(c) sin
2
2
r
rrr
r
r
169.If a = (2, - 3, - 7), b = (3, - 1, 2), c = (4, 5, -1), then the scalar triple product [a b c] is equal

(a) 2sin
2

to:
(a) 180
(b) 184
(c) -184
(d) 84
r r r
r r r
170.The value of a . {(b c) (a + b + c)} is equal to:
r r r

(a) 0
(b) [a b c]
r
r
(d) a
(c) 2a
r
r
r r
r
r
171.If | a | = 6, | b | = 8, | a b | = 10, then | a + b | is equal to:
(a) 10
(b) 24
(c) 40
(d) 36
27

172.If | a | =3, | b | =5, | c | = 7 and a + b + c = 0 , then the angle between a and b :

2

(b) cos1
3
(c) 30
(d) 60
r
r
173.The area of a parallelogram with diagonals as a = 3 i + j 2k and b = i 3j + 4k is:
(a) 15

(a) 10 3

(b)

(c) 5 3

(d)

10
3
5
3

174.The position vectors of A, B and C are (1, 1, 1), (1, 5 1) and (2, 3, 5), then the greatest
angle of the triangle is:
(a) 135
(b) 90
2

(c) cos1
(d) cos1
3
7
r
r
r
r
175.If a is a unit vector perpendicular to b and c , then second unit vector perpendicular to b
r
and c is:
r r
r r
(a) b c
(b) a b
r
r r
(d) a c
(c) c
r
r
= 1 , then ar is equal to:
176.If a.i = a.(i + j + k)
(a) i

(b) j

(c) k
(d) i + j
177.If is the angle between the planes 2x y + 2z = 3, 6x 2y + 3z = 5, then cos is equal to
21
20
20
(c)
21

(a)

11
21
12
(d)
23

(b)

178.The direction cosines of the normal to the plane 6x 3y 2z = 1 are:

2
6
7
7
1
(c) (6, -3, -2)
7

(a) , 3,

(b) (6, -3, -2)

(d)

1
(6, 3, 2)
7

179.If , , are the angles made by a straight line with the co-ordinate axes, then sin2 + sin2
+ sin2 is equal to:
(a) 0
(b) 1
(c) 2

(d)

3
2

180.The equation of the plane through the intersection of the planes x + 2y + 3z 4 = 0 and 4x
+ 3y + 2z + 1 = 0 and passing through the origin, is:
(a) 17x + 14y + 11z = 0
(b) 7x + 14y + 11z = 0
(c) x + 14y + 11z = 0
28

(d) x + y + 11z =0
181. The number of real values of a satisfying the equation a 2 2 a sin x + 1 = 0 is
(a) Zero
(b) One
(c) Two
(d) Infinite
n1
3 n1
n
,
n
182. For positive integers 1 2 the value of the expression (1 + i) + (1 + i ) + (1 + i 5 )n2 + (1 + i7 )n2
where i = 1 is a real number if and only if
(c) n1 = n 2
(d) n1 > 0, n 2 > 0
(a) n1 = n 2 + 1
(b) n1 = n 2 1
183. If the angles of a quadrilateral are in A.P. whose common difference is 10 o , then the
angles of the quadrilateral are
(a) 65 o , 85 o , 95 o , 105 o
(b) 75 o , 85 o , 95 o , 105 o
(b) 65 o , 75 o , 85 o , 95 o
(d)
65 o , 95 o , 105 o , 115 o

184. If the sum of first n terms of an A.P. be equal to the sum of its first m terms, (m n) , then
the sum of its first (m + n) terms will be
(c) m
(d) m + n
(a) 0
(b) n
185. If x = 1 + 1 + 1 + ....... to infinity , then x =
(a) 1 + 5

(b) 1 5

(c) 1 5

these
186. For the equation | x 2 | + | x | 6 = 0 , the roots are
(a) One and only one real number
one
(c) Real with sum zero
187. The value of 2 n {1 .3 . 5 .....( 2n 3) (2n 1)} is
(a)

(2n) !
n!

(b)

(2 n ) !
2

(b)

of

Real with sum

(d) Real with product zero

(c)

(d) None

n!
(2n) !

(d) None

of

these
188. A question paper is divided into two parts A and B and each part contains 5 questions. The
number of ways in which a candidate can answer 6 questions selecting at least two
questions from each part is
(a) 80
(b) 100
(c) 200
(d) None
of
these
189. The value of ( 2 + 1)6 + ( 2 1)6 will be
(a) 198
(b) 198
(c) 99
190. If (1 + ax )n = 1 + 8 x + 24 x 2 + ...., then the value of a and n is
(a) 2, 4
(b) 2, 3
(c) 3, 6
a b

(d) 99
(d) 1, 2

2
191. If A =
and A =
, then
b
a

(a) = a 2 + b 2 , = ab
(b) = a 2 + b 2 , = 2ab

= 2ab, = a 2 + b 2

29

(c) = a 2 + b 2 , = a 2 b 2 (d)

192. For non zero,

a, b , c

if =

1+a
1
1
1+b
1

(b)

(a) abc

1
1

=0

, then the value of

1+c

1
abc

1 1 1
+ + =
a b c

(c)

(a + b + c)

(d) None

(c)

tan x

(d) sin x

of

these
x
193. If u = log tan + , then cosh u is equal to
4

(a) sec x

(b) cosec x

194. If cosh = sec x , then tan 2 x =

2

(a) cos 2

(b) sin 2

(c) cot 2

(d) tanh 2

195. The number of integral values of m, for which the x-co-ordinate of the point of intersection
of the lines 3 x + 4 y = 9 and y = mx + 1 is also an integer is
(a) 2
(b) 0
(c) 4
(d) 1
196. A ray of light coming from the point (1, 2) is reflected at a point A on the xaxis and then
passes through the point
(5, 3). The coordinates of the point A are
(a) (13 / 5, 0 )
(b) (5 / 13, 0 )
(c) ( 7, 0)
(d) None
of
these
197. The equation of the locus of foot of perpendiculars drawn from the origin to the line
passing through a fixed point (a, b), is
(a) x 2 + y 2 ax by = 0
(b) x 2 + y 2 + ax + by = 0
(c) x 2 + y 2 2ax 2by = 0 (d) None
of
these
198. The orthocentre of the triangle formed by the lines xy = 0 and x + y = 1 is
(a) (0,0 )
(b) (1/2, 1/2)
(c) (1/3, 1/3)
(d) (1/4, 1/4)
199. ABCD is a square, the length of whose side is a. Taking AB and AD as the coordinate
axes, the equation of the circle passing through the vertices of the square, is
(a) x 2 + y 2 + ax + ay = 0
(b) x 2 + y 2 ax ay = 0
(c) x 2 + y 2 + 2ax + 2ay = 0 (d)
x 2 + y 2 2 ax 2 ay = 0
a(1 t 2 )
200. Locus of the point given by the equations x = 2at 2 , y =
(1 t 1) is a
2
1+t

(a)

Straight line

(b)

Circle (c)

30

1+t

Ellipse (d)

Hyperbola