Name

: Ardiano Fauzy
Number : 11/316879/PA/14000

Material Safety Data Sheet

Oxalic acid, 0.1 N standard solution

ACC# 97193

Section 1 - Chemical Product and Company Identification

MSDS Name: Oxalic acid, 0.1 N standard solution
Catalog Numbers: AC124280000, AC124280010
Synonyms: Ethanedioic acid
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS#
144-62-7
7732-18-5

Chemical Name

Percent

EINECS/ELINCS

<5.0

205-634-3

Balance

231-791-2

Oxalic acid
Water

Hazard Symbols: XN
Risk Phrases: 21/22

Section 3 - Hazards Identification

EMERGENCY OVERVIEW
Appearance: clear, colorless. Caution! May cause kidney damage. May cause central
nervous system effects. May cause eye and skin irritation. May cause respiratory and
digestive tract irritation. May cause cyanosis with bluish skin.
Target Organs: Kidneys.
Potential Health Effects
Eye: May cause eye irritation. May result in corneal injury.
Skin: Causes skin irritation. May cause irritation with pain and stinging, especially if the
skin is abraded.
Ingestion: May cause irritation of the digestive tract.
Inhalation: May cause kidney damage. Exposure may lead to shock, convulsions, and
collapse.
Chronic: No information found.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the
upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid if irritation develops or persists. Flush skin with plenty of soap and
water.
Ingestion: Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4
cupfuls of milk or water.
Inhalation: Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Firefighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section
8.
Spills/Leaks: Absorb spill with inert material, (e.g., dry sand or earth), then place into
a chemical waste container.

Section 7 - Handling and Storage

Handling: Not available.
Storage: Not available.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use adequate general or local exhaust ventilation to keep
airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name
Oxalic acid
Water

ACGIH
1 mg/m3; 2 mg/m3
STEL
none listed

NIOSH

OSHA - Final PELs

1 mg/m3 TWA 500

mg/m3 IDLH

1 mg/m3 TWA

none listed

none listed

OSHA Vacated PELs: Oxalic acid: 1 mg/m3 TWA Water: No OSHA Vacated PELs are
listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin: Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved fullfacepiece airline respirator in the positive pressure mode with emergency escape
provisions.

Section 9 - Physical and Chemical Properties

Physical State: Not available.
Appearance: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: soluble in water
Specific Gravity/Density:.9900g/cm3
Molecular Formula:C2H2O4
Molecular Weight:90.04

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Not available.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:
CAS# 144-62-7: RO2450000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 144-62-7:
Oral, rat: LD50 = 7500 mg/kg;<br.
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;<br.
Carcinogenicity:
CAS# 144-62-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5:
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.

Neurotoxicity: No data available.

Mutagenicity: No data available.
Other Studies: No data available.</br.
</br.

Section 12 - Ecological Information

Ecotoxicity: Not available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as
a hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT

IATA

RID/ADR

IMO

No
Shipping Name: information
available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL
TSCA
CAS# 144-62-7 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes

Canada
TDG
No
informatio
n
available.

CAS # 144-62-7: acute, chronic, flammable.

Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not
contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone
depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the
CWA. None of the chemicals in this product are listed as Priority Pollutants under the
CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 144-62-7 can be found on the following state right to know lists: California, New
Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are
listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 21/22 Harmful in contact with skin and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 144-62-7: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 144-62-7 is listed on Canada's DSL/NDSL List.
CAS# 7732-18-5 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 144-62-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 144-62-7: OEL-ARAB Republic of Egypt:TWA 1 mg/m3 OEL-AUSTRALIA
:TWA 1 mg/m3;STEL 2 mg/m3 OEL-BELGIUM:TWA 1 mg/m3;STEL 2 mg/m3 OEL-D
ENMARK:TWA 1 mg/m3 OEL-FINLAND:TWA 1 mg/m3;STEL 3 mg/m3 OEL-FRANCE:T
WA 1 mg/m3 OEL-THE NETHERLANDS:TWA 1 mg/m3 OEL-THE PHILIPPINES:TWA 1
mg/m3 OEL-SWITZERLAND:TWA 1 mg/m3 OEL-UNITED KINGDOM:TWA 1 mg/m3;ST
EL 2 mg/m3 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV

Courtesy : http://avogadro.chem.iastate.edu/MSDS/oxalic_acid-0.1M.htm