Professional Documents
Culture Documents
FUEL QUALITY
comparative analysis of the quality of fuels available
in Poland and in selected European Union countries
(Germany, Austria, Latvia, Ireland and the Czech Republic)
The study with its summary
Agnieszka Jankw
ukasz Garstecki
Warsaw 2007
The following publication was prepared for the Oce of Competition and Consumer
Protection within the Transition Facility Project No. 2004/016-829.02.04 System of Consumer
Protection.
ISBN 978-83-60632-12-3
Warsaw 2007
TABLE OF CONTENTS
I. The study
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1. Organization of fuel quality scrutinizing system . .
1.1. Introduction (Community requirements, standards)
1.2. System in Poland . . . . . . . . . . . . . . . . . . . .
1.3. System in Germany . . . . . . . . . . . . . . . . . . .
1.4. System in Austria . . . . . . . . . . . . . . . . . . . .
1.5. System in Latvia . . . . . . . . . . . . . . . . . . . . .
1.6. System in Ireland . . . . . . . . . . . . . . . . . . . .
1.7. System in the Czech Republic . . . . . . . . . . . . .
1.8. Comparative table January 2005 . . . . . . . . . . .
1.9. Summary . . . . . . . . . . . . . . . . . . . . . . . . .
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11
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31
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51
51
54
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64
INTRODUCTION
Introduction
Fuel quality is one of the most signicant reasons why drivers choose a particular lling
station. Trust in good fuel quality inuences client satisfaction and loyalty. This is conrmed
by the marketing researches which the authors of this study have been carrying out for years
now, inter alia at the request of fuel companies. Practically, in every project concerning drivers behaviour and their satisfaction with the services of the given networks of lling stations,
the respondents are asked the same question: Why do you use the services of these lling
stations?. The three most popular answers (usually given in the following order) are: station
location, condence in fuel quality and the price of fuel.
Results of one of the marketing researches mentioned above (carried out in autumn
2005) are available e.g. on the website of Roland Berger Strategy Consultants Sp. z o.o.
(www.rolandberger.pl), which also contains a description of the introduction of the new
lling station brand BLISKA, due to the PKN ORLEN lling station network being divided
into the premium and the economic segment. The starting point was the segmentation of
clients of the lling stations. It occurred that the most signicant criterion is the relation
between the clients condence in the quality oered (mostly the quality of fuels but also
the quality of services) and the prices of fuel. It was found that most clients of lling stations aim at reaching a compromise between price and quality. Two groups of clients were
identied:
!
quality purchasers for whom high quality (of fuel and services) is the most important and who are ready to pay more for that;
!
value seekers i.e. drivers expecting quality, however at a reasonable price.
In the case of both of the groups quality of fuel is of key importance. The former expect
the highest quality, the latter satisfying quality at lowest possible price, but the minimum
level of condence that the fuel tanked up does not harm the engine is always the necessary
condition.
The price and location are easy for the consumers to verify. However, the perception of
fuel quality is usually based on the skill of the branding experts and not on the observations,
experience and knowledge of the clients. The quality of fuel can be objectively assessed only
by testing the samples according to applicable standards and procedures in a professional
laboratory.
The above mentioned asymmetry of knowledge between the buyer of fuel and its seller
requires a great deal of trust on the part of the clients and at the same time constitutes a great
temptation for the sellers to abuse their favourable position. The media have broadly covered
this issue a few years ago.
In order to reduce the abovementioned asymmetry and consequently to make sure that the
fuel meets the quality standards, Poland and other countries established authorities acting as
impartial, objective experts scrutinizing the quality of fuels placed on the market.
In Poland such an authority is the Oce of Competition and Consumer Protection (OCCP,
www.uokik.gov.pl). Fuel quality monitoring plays a signicant role in the OCCPs operations.
The Oce is responsible for enabling Poland to discharge its obligations resulting from its
European Union membership and related to monitoring the quality of liquid fuels placed on
the market, as well as drawing up reports for the European Commission presenting the results
of liquid fuels quality inspections carried out across the whole country. To this end, the system
of monitoring and scrutinizing of the quality of liquid fuels and bio-fuels was established and
implemented in Poland (according to the guidelines set forth in the applicable EU directives
and standards). The system has been in operation since 1 May 2004.
7
INTRODUCTION
Of course similar systems operate in other EU countries. Adopting the Directive 98/70/EC
in 1998, the European Parliament specied requirements concerning quality of fuels placed on
the market, whilst, the Member States, accepting the directive and the applicable standards as
the starting point, developed appropriate regulations and organized systems of fuel quality
monitoring within their territories.
One of the objectives of this study was to describe the systems in Poland and in other selected countries (Germany, Austria, Latvia, Ireland and the Czech Republic), by presenting:
!
review of the legal basis;
!
outline of the authorities involved in the monitoring and scrutinizing of fuel quality;
!
description of time and territorial scope of the inspections;
!
organization of the inspections (what parameters are analysied, what types of fuels are
inspected, how samples are selected, etc.).
The comparative analysis showed that the organization of the fuel quality monitoring and
scrutinizing system in Poland is not only not worse from the systems in more developed countries of the EU, but stands out in a positive sense, as it responds to notications sent by consumers who suspect that non-compliant fuel is in circulation.
Due to the educational and popularising role of the study, issues related to fuel quality
and scrutiny are discussed from the technical and chemical point of view (e.g. presenting
the consequences for the engine). The essence of a fuel quality inspection is checking if a
given parameter meets the requirements of a standard or not. Therefore, it is worth knowing what a given parameter means and what the consequences of exceeding or failing to
meet its acceptable values are e.g. for a car engine or the environment. That shows what a
complex product fuel is (both petrol and diesel), how important the optimum composition
of its components is and what the possible threats for fuel quality occur in the process of
fuel production and distribution. Moreover, the Reader, having acquainted him or herself
with the introduction and the theoretical background of the study, will be fully prepared to
comprehend the results of the inspections carried out in dierent countries, to interpret the
data and to draw conclusions.
Another objective of the analysis is to present and review the results of the inspections
of fuels sold in Poland against the background of the results of the inspections carried
out in selected countries of the European Union (Germany, Austria, Latvia, Ireland and
the Czech Republic). The following criteria were applied for selection of the countries for
comparison:
!
widest possible cross-section of dierent countries (old and new EU Member
States, more and less developed economies, large and small countries), without, however, blurring the transparency of the study by too many countries and making it difcult for the Reader to grasp the entire material;
!
Comparing the situation in Poland and in the countries which obtained the best results
of fuel quality inspections in the 2nd half of the 2004 (i.e. Germany, Austria and Latvia),
as well as in the countries where similar levels of irregularities were found as in Poland
in the same period (Ireland and the Czech Republic).
The data concern inspections carried out in the selected countries in 2005. This is because
Poland, the Czech Republic and Latvia were not obliged to run a system of fuel quality monitoring and scrutinizing until their accession to the European Union, i.e. the 2nd half of 2004. It
was only in 2005 that the samples of fuels were collected and tested in the course of the whole
year, taking into consideration the division into summer and winter period. As for the data for
2006, the Member States are obliged to make them known to the European Commission only
by the end of June 2007.
The table below contains an index of the sources of information used for elaboration and
analysis of the results of fuel quality inspections in 2005 and the systems of fuel quality monitoring in the dierent countries.
INTRODUCTION
DATA - COUNTRY
SOURCE
Poland
Germany
Austria
Latvia
Ireland
Czech Republic
European Commission
The results of the drivers opinion polls referred to at the beginning show that fuel quality
is of key importance both in the premium and the economic segment. By making this distinction we touch upon the issue of the relation of fuel quality to its price. Therefore, this study
contains also a comparison of fuel prices in the discussed co untries.
The analysis was made for the Oce of Competition and Consumer Protection. The authors are fuel market experts cooperating with the European Training and Expertise Center
(www.csee.pl) on the project: Transition Facility 2004/016-829.02.04.0 /P Part 1 Consumer Protection System Consumer studies and expertise.
The authors would like to thank all the persons who contributed to the preparation of this
analysis.
Agnieszka Jankw (ajankow@pentor.pl)
ukasz Garstecki (lgarstecki@pentor.pl)
Warsaw, 20 April 2007
Dividing the country into regions determines the choice of one of the three possible monitoring system models pursuant to the EN 14274:2003 standard A, B or C.
Model A is based on the division of the country into geographical macro regions in a way
where in every region the entire amount of the fuel being analysed and the number of distribution places are similar. Such an action mode is recommended for all the countries, as it enables
to depict eciently fuel multiplicity, and as a result lesser number of taken samples. If region
grouping in terms of geographical, administration or other division does not help to meet all
of the criteria in order to design this recommended model, then subsequently B model is taken
into account, which is based on geographical and administration country division. Instead,
C model is selected in case of a small country where the division of the territory into macro
regions or regions is impossible.
The chosen regional division format, country size, calculated on the basis of yearly sales
and the share of a given fuel type in the sales, all determine the minimum number of distribution outlets in a particular country where samples ought to be taken.
The minimum number of distribution outlets in a particular country where samples of the
fuel types with the market share of 10 % and more should be taken is shown in the Table 1,
pursuant to the provisions of EN 14274:2003.
Table 1. Minimum number of samples of each fuel type in the winter and summer periods
Model
Small country
Petrol of a given type
Diesel
Big country
Petrol of a given type
Diesel
50
50
100
100
50
50
100
100
200
200
The minimum number of samples of a particular fuel type with the market share of 10 %
is calculated in proportion to the number of samples of its corresponding native fuel type, according to the following formula:
N fuel typeX =
Conformity with the requirements provided for in the Directives with respect to the petrol
and diesel sold in the Member States is monitored on the basis of the analytic methods set forth
in the European standards EN 228 and EN 590, accordingly.
Each year, all Member States send a report to the European Commission on the quality of
fuels sold on their territory.
12
System in Poland
No 4, item 25 as amended) and the executive acts issued on its basis, constitute the legal basis
for liquid fuel quality monitoring and scrutinizing system functioning in Poland.
THE BODIES INVOLVED IN THE MONITORING AND SCRUTINIZING OF FUEL QUALITY IN POLAND
The President of the Oce of Competition and Consumer Protection is responsible for the
operation of the system and performs his duties in cooperation with the Trade Inspection responsible for fuel scrutiny. His primary responsibilities include:
!
keeping the register of enterprises, lling stations (both open access and company stations) and warehouses trading in fuel on the basis of the data made accessible by the
General Statistical Oce, the Energy Regulatory Oce, the State Fire Service and the
Oce of Technical Inspection:
!
assigning identication numbers to the enterprises, lling stations, company stations
and warehouses, for the System purposes;
!
keeping the register of accredited laboratories authorised to carry out the fuel tests on
the basis of the data made available by the Polish Centre for Accreditation;
!
dening the minimum number of open access and company lling stations where inspections are to be carried out;
!
setting up fuel quality scrutiny programs, dening the activities of the Trade Inspection;
!
setting up the manner of sample marking in order to prevent identication of the enterprises, lling stations or plants stations, in the course of the inspections;
!
drawing up yearly common reports on the performance of the liquid fuel and biofuel quality inspections, which are submitted to the European Commission and Polish
Council of Ministers;
!
gathering and keeping the statistical data on liquid fuel and biofuel quality for the System purposes.
The above mentioned obligations are vested in the President of the Oce of Competition
and Consumer Protection under the Act of 23 January 2004. They are maintained in the Act on
fuel quality monitoring and scrutinizing, of 25 August 2006, which additionally sets forth the
following obligations:
!
to keep the register of enterprises dealing with fuel production, transport and
storage;
!
to keep the register of the owners and users of the selected eets;
!
to keep the register of the agriculturists producing liquid biofuel for their own use, on
the basis of the data made available by the Agricultural market Agency;
!
to assign identication numbers to the enterprises dealing with fuel production and
storage and to assign identication numbers to the agriculturists who produce biofuel
for their own use, for the System purposes;
!
to dene the minimum number of fuel warehouses, enterprises whose operations involve fuel production and storage as well as introducing light heating oil to the market,
who will be subject to scrutiny ;
!
to dene the minimum number of lling stations (both open access and company stations), where liqueed gas (LPG) or compressed natural gas (CNG) quality scrutiny is
to take place;
!
to draw up yearly common reports on the quality of liqueed gas (LPG) and natural
gas (CNG);
!
to draw up the yearly common reports on the content of sulphur in light heating oil,
heavy heating oil, oil for engines applied in the ships designed for inland shipping and
in the shipping fuel used in sea ships.
14
System in Poland
Liquid fuels samples taken for inspection purposes, have been inspected in terms of all the
quality parameters listed in Directive 98/70/EC of 13 October 1998 on the petrol and diesel fuel
quality (as amended by Directive 2003/17/EC of 3 March 2003), which are also listed in the
Resolution on the qualitative requirements for liquid fuel.
For each of the fuel types listed above, the minimum number of lling stations in which the
scrutiny took place in each monitoring period (summer and winter) equalled 100 for the entire
country. It was the result of fuel sales volume during the whole year on the territory of Poland
and applying the division into the regions in accordance with the administrative division. On
the basis of the fuel sold during the year (approximately 11 mln tons), in accordance with the
EN 14274:2003 standard, Poland has been classied as a small country. Samples taken for inspection purposes have been selected at random by the computer system for each monitoring
period, separately for each voivodship and within each fuel type.
The number of stations, where inspections have been carried out on the territory of a particular voivodship, has been established pursuant to the Resolution on the method of liquid
fuel and biofuel quality monitoring.
The number of stations in particular voivodships, for the purpose of selecting the stations,
in which inspections took place during the monitoring period starting in a particular calendar
year, has been accepted on the basis of the data at the end of the previous year.
Moreover, in order to test each fuel type in a particular voivodship, 10% stations has been
selected at random, in case any of the selected stations to be inspected was temporarily closed
or liquidated.
Table 2. Schedule with the number of samples (in total 600) taken in Poland within the frames
of the European part of fuel quality monitoring and scrutinizing system
95 lead-free petrol
98 lead-free petrol
diesel fuel
Summer period
100 samples (+10%)
100 samples (+10%)
100 samples (+10%)
Winter period
100 samples (+10%)
100 samples (+10%)
100 samples (+10%)
System in Poland
tion, these entities may also be appointed to be scrutinized in case of receiving the information about improper fuel quality or if circumstances occur which indicate the possibility of
improper fuel quality.
The scrutiny at the open access and company lling stations, where the liquid fuels and
biofuels are sold (as in the previous case, that is within the period when the Act of 23 January 2004 on liquid fuel quality monitoring and scrutinizing system was in force), are carried
out upon receiving the information on improper fuel quality or if circumstances occur which
indicate the possibility of improper fuel quality. In practice, this kind of scrutinises result from
the complaints of the drivers, information acquired from the Police, including Central Bureau
of Investigation.
The same procedure of appointing the scrutinises pertains as well to the owners and users
of the selected eets and the agriculturists producing biofuels for their own use.
The samples taken in the course of the scrutiny are inspected in the laboratories having the
accreditation certicates issued by the Polish Centre for Accreditation. Petrol and diesel fuel
samples are tested with regard to all of the or some of the qualitative parameters. However,
biofuels and LPG and CG samples are subject to the detailed scrutiny in terms of all the parameters dened in the relevant resolutions on the qualitative requirements (in the Resolution of 8
September 2006 on the qualitative requirements for biofuels, in the Resolution of 28 December
2006 on the qualitative requirements for the liqueed gas (LPG) and in the Resolution of 28
December 2006 on the qualitative requirements for the natural gas (CNG)).
A signicant change in comparison with the previous Act on liquid fuel and liquid biofuels
quality monitoring and scrutinizing system is that the President of the Oce of Competition
and Consumer Protection or the Chief Inspector of the Trade Inspection immediately appoints
for scrutiny the supplier of a particular enterprise where an inadequate fuel quality has been
stated. In case, there is no stationary fuel tank, the Trade Inspection undertakes the scrutiny
activities in order to select another enterprise, from whom the fuel called into question comes
from, and who does have the stationary tank.
The Oce of Competition and Consumer Protection is responsible for drawing up the reports for:
!
The European Commission (until 30 June) on:
liquid fuel quality and liquid biofuels quality;
content of sulphur in the light heating oil, in the heavy heating oil (on the basis of the
Chief Inspectors for the Environment Protection data), in the oil for the engines in
the ships for the inland shipping (on the basis of the Chief Inspectors for the Environment Protection data), in the shipping fuels applied in the sea ships (on the basis
of the reports drawn up by the Directors of the Maritime Authorities);
!
the Council of Ministers (until 31 May) on:
the quality of liquid fuels, liquid biofuels, liqueed gas (LPG) and compressed natural gas (CNG).
18
System in Austria
a summer product must be oered within the period from 1 May to 30 September. Petrol vapour pressure must reect the values stated in the standard from 40 kilo Pascals
(kPa) to 60 kPa;
!
a winter product is sold within the period from 16 November to 15 March. Vapour
pressure equals then from 60 kPa to 90 kPa;
!
within the period from 1 October to 15 November, and from 16 March to 30 April (so
called the interim period), the pressure of vapour can not exceed the maximum value
from the winter period (90 kPa) and can not be lower than the value from the summer
period (40 kPa).
Samples are taken every month of the year.
The scrutiny is carried out on the territory of the whole country. For fuel quality scrutinizing purposes, the territory of Germany has been divided into the areas corresponding to the
16 political regions (Lnder) of Germany, without taking into consideration the method of fuel
distribution in the country.
!
State legislation:
Federal Act on motorization (Kraftfahrgesetz (KFG) Novelle, 1967, BGBl. No 267, and its subsequent amendments: Bundesgesetz BGBl. I No 175/2004, Bundesgesetz BGBl. I No 117/2005 and
Bundesgesetz BGBl. I No57/2006 of 9 May 2006).
THE INSTITUTIONS INVOLVED IN THE MONITORING AND SCRUTINIZING OF FUEL
QUALITY
The quality of motor petrol and diesel fuels sold at the lling stations in Austria is under
scrutiny of the Federal Environment Oce (Umweltbundesamt UBA, www.umweltbundesamt.at)
and submitted to the Ministry of Agriculture, Forests, Waters and Environment (Bundesministeriums fr Land- und Forstwirtschaft, Umwelt und Wasserwirtschaft, www.lebensministerium.at) in
the form of the report. Then, the Ministry submits this report to the European Commission.
The diagram presented below illustrates the institutions and their tasks within the fuel
scrutinizing system.
Diagram 1. Institutions and scope of responsibilities
Ministry of
Finance
Information on fuel
production, sales,
inventory, import/
export
Customs Service
Federal Environment
Office
Project
concept
Report
Sampling
Laboratory
analysis
21
System in Austria
22
N for X type =
The number of scrutinized stations with regard to the 98 Super Plus fuel quality during the
whole year, for several years oscillates between 5-6 lling stations which results from:
Super Plus 98 market shareN Super Plus 98 =
- N Super 95 petrol the number of stations to be scrutinized with regard to the quality of 95
Super fuel within the entire year equals 100.
The registration and the selection of lling stations to be scrutinized are performed due to
the following schedule:
Diagram 2. The registration of lling stations in Austria
23
System in Latvia
Diagram 3. Facilities selection for the purposes of scrutinizing of the quality of fuels sold
The samples for inspection purposes are taken in accordance with the EN 14275:2003 standard. In case, the station refuses to have the fuel samples taken by the representative of the Federal Environment Oce, pursuant to the Act on motorization, he is entitled to take samples
even with the help of the Police. In practice however, the representatives of the Environment
Oce make a phone call to the relevant persons in a particular concern or the owner of the
stations, if the refusal was given by the independent station.
While carrying out the analyses of both motor petrol and diesel fuels, all parameters are
examined pursuant to Directive 2003/17/EC and the EN 14274:2003 standard.
Most of the parameters are measured in the accredited laboratory of the Federal Environment Oce, in Vienna. In the external laboratories only the octane number values are dened
(for petrol) and the cetane number (for diesel fuel).
to the system, the State Internal Revenue Service has concluded an agreement on the bilateral
cooperation with other state institutions, the most important of which is Latvian Certication
Centre (Latvas sertikcas cents - LATSERT, www.latsert.lv) and the economic Police division
by the State Police. These institutions are responsible for complaints gathering on the low fuel
quality and taking certain actions in order to prevent from such situation in the future.
In order to carry out the testing of the taken samples, the District Internal Revenue Service manages three express laboratories, which are authorised to scrutinize fuel quality on the
territory of Latvia. In case of more detailed inspections to be carried out, SRS hands over the
taken samples for the analyses to the accredited laboratories.
PERIODIC AND TERRITORIAL SCOPE OF THE SCRUTINY, INSPECTED FUEL
Fuel quality inspections are organised in a way which enables to cover all the entities trading in fuel. The entities need special licences to trade in fuel on the territory of Latvia. The
number of issued and valid licences is a basis to register/ update the list of the companies
which are subject to scrutinises. On the territory of Latvia there are approximately 600 lling
stations which operate, 216 of which were issued the licences to carry out business operations.
Wholesale is conducted on the basis of approximately 47 licences.
The samples are taken from the enterprises possessing the licence to trade in fuel (lling
stations and warehouses) and from the tax warehouses. Most of the samples (approximately
90%) are taken at the lling stations. It is also possible to take samples from the places supervised by the customs service (terminals and customs warehouses), however, it is not practiced.
The selection of places to take samples is performed in accordance with the fuel type. The
samples are taken each month of the year.
The laboratory analysis with regard to all the parameters included in the Resolution No 332
on the evaluation of petrol and diesel fuels quality, covers samples of the fuel available on the
Latvia fuel market, that is:
!
92 Lead-free petrol (corresponding to the lead-free petrol 91 included in the directives
and the European standards);
!
95 Lead-free petrol;
!
Diesel fuel.
System in Ireland
in Whitegate, each year in each of the periods July/ August and December. The fuel companies
association takes in total 48 samples per year, and their results are included into the yearly
report for the European Commission.
fuel consumption, which is approximately 6,5 million ton per year. It has also been acknowledged that the entire territory of the country may be regarded as a one region. As a result the
entire monitoring system is based on the statistical C model described in the EN 14274:2003
standard as a model suitable for a small country without the regional dierentiation. Pursuant
to the model, Czech Trade Inspection ought to take samples at least from minimum 59 distribution outlets (lling stations) for each fuel, which accounts for more than 10% of sales for a
particular fuel type (petrol, diesel fuel), in each scrutiny period.
The number of distribution places from which samples ought to be taken for the fuel with
the market share less than 10% is calculated on the basis of the following formula:
X type fuel with market share of less than 10%,
N the number of taken samples
N for X type =
Because of the fact, that the Czech fuel quality monitoring system has not only been
launched to inspect the parameters required under the EU Directives in order to protect the
environment, but also for the consumers protection, the state Resolution has imposed an obligation to scrutinize a greater number of samples by dening their number at the following
minimum levels:
Table 3. Minimum number of samples to be taken with regard to the particular fuel types
In accordance with
the Resolution
229/2004
In accordance with
the Resolution
311/2006 prevailing
from 1 July 2006.
Petrol
(all petrol
in total)
Diesel fuels
Summer period:
1 May 31 October
350
350
Winter period:
1 November 30 April
350
350
Summer period:
1 May 31 October
500
500
Winter period:
1 November 30 April
500
500
The Ministry of Industry and Trade keeps an electronic register of lling stations. The controllers from 13 inspectorates after the prior schedule preparation (sampling date and number
of sample) take samples from the entire area of the Czech Republic.
The samples are taken pursuant to the EN 14275:2003 standard. While carrying out the
analysis of both motor petrol and diesel fuels, all of the parameters are taken into account in
accordance with Directive 98/70/EC, as well as in accordance with the Resolution of the Ministry of Industry and Trade No 229/2004.
28
Inspected fuels
Minimum number of
samples taken each
period, for each fuel
type
Place of sampling
Organizations
responsible for sales
data gathering
Organizations
responsible for the fuel
quality monitoring
system
Federal Environment
Oce
(Umweltbundesamt =
UBA)
Germany
92 lead-free petrol,
95 lead-free petrol,
98 lead-free petrol,
diesel fuel
lead-free petrol
91 Normal,
95 lead-free petrol
Super,
98 lead-free petrol
Super Plus,
diesel fuel
lead-free petrol
91 Normal,
95 lead-free petrol
Super,
98 lead-free petrol
Super Plus, diesel fuel
95 lead-free
petrol,
98 lead-free
petrol, diesel fuel
95 lead-free petrol,
diesel fuel
50
lead-free petrol
91 Normal,
95 lead-free petrol
Super,
98 lead-free petrol
Super Plus,
diesel fuel
350
Filling stations
Whitegate Renery,
petrol terminals, state
reserves bank, road
cisterns, lling stations,
lorries and delivery
trucks.
Filling stations,
terminals and fuel
warehouses
No entry
small
Statistical C model, EN
14274:2003
Statistical C model in
accordance with EN
14274:2003 with regard
to the number, kind,
manner of sampling and
samples inspection.
small
Ministry of Industry
and Trade
Ministry of Industry
and Trade
(Ministerstvo
prmyslu a obchodu)
Department of Transport
Department of
Environment, Heritage
and Local Government
Ireland
small
50
Filling stations
small
200
Filling stations
big
National System
No entry
Ministry Of Economy
and Labour
(Bundesministerium fr
Wirtschaft und Arbeit)
Statistical C model
compliant with EN
14274:2003
Ministry of Economy
(Latvas Republikas
Ekonomikas
Ministra)
Latvia
Federal Environment
Oce
(Umweltbundesamt =
UBA)
Austria
100
Filling stations
small
Ministry of
Economy
Oce of
Competition
and Consumer
Protection
Poland
29
Summary
1.9. Summary
Undoubtedly, international regulations on fuel quality are necessary. The European Union
is rst of all a common economic area, common market. Its participants include both individual clients and companies as well as institutions. For all of them, road transport plays an
important role and concerns private and company cars, by delivery trucks, lorries or buses. It
is not easy to evaluate the benets resulting from the possibility of refuelling in any country.
It is as well a factor which stimulates motorization industry development. Let us add to it environment protection and care for the health and consumer protection against unfair practices
or producers negligence and fuel dispensers (what may have a negative impact on the engine,
but the next chapter touches on the subject).
Therefore, fuel quality scrutinizing system is necessary and useful both at the national and
international level. Hence, there is a need to create and implement such systems at a level of
government ministries or central oces having wide scrutinizing authorities.
Each system under the analysis uses the statistic principles and is based on the random selection of samples. Control of all the lling stations would be too expensive and troublesome
in terms of organization. That is why the specic and minimum number of stations is selected
at random. It is important so that the random selection rule would be observed (each station
has the same chance to be found among the scrutinized ones) most often it is assured by the
relevant computer programme, which draws at random from the lling station list in a particular country. This selection takes into account the territorial dispersion, thanks to which the
scrutiny will cover the fuels from dierent producers, from various sources. In the presented
systems, dierent periods division has been applied, which results from the multiple fuel
properties in dierent temperatures.
The general principles of system functioning are set forth by the European Union directives. Each country, however, constructs its system in a slightly dierent way. These dierences do not have practical signicance for fuel users, it means that 95 petrol, octane or diesel
fuel are more or less the same in the entire Europe. Modication in particular countries may
be based on the selection of the parameters, other than the recommended one (the example
of Germany). The Member States are obliged to run the system, which provides the data for
the EU. Some of the countries (Poland or the Czech Republic) create just by the way so called
country systems, thanks to which they achieve more promptly the fuel quality level comparing with other EU members.
30
31
Light
petrol
0.580
0.655
0.655
0.810
0.740
0.720
97
70
88
100
92
94
93
68
84
88
80
91
Pressure [kPa]
Benzene content [% of volume]
420
No
114
2
100
No
30
6
55
0.7
60
No
Properties
Density in 15 C [g/m]
Research octane number
(RON)
Isomerise Reformat
Alcohols
Properties
Density in 15 C [g/m]
Research octane number
(RON)
Motor octane number
(MON)
Pressure [kPa]
Oxygen content [% of
weight.]
Cracking
Alkyl
petrol
Ethers
Methanol
Ethanol
MTBE
ETBE
TAME
0.796
0.794
0.75
0.75
0.78
125
120
118
118
112
100
105
101
101
98
350
250
54
35
20
50
35
18.2
15.7
17.7
Ennobling additives are not extorted by the qualitative standard, however, the professional
producers use them in the companies fuels. The additives are to improve the use properties of
fuel and, thanks to their activity, prolong engine operation without breakdowns. They are add
in a form of so called packages, which are selected individually for petrol characteristic for a
particular producer. Such a package may include [1]:
!
detergent (prevents from sediments to deposit in the fuel supply system on the inlet
valves and injectors),
!
corrosion inhibitor (slows down the process of corrosion in the metal engine parts,
which have contact with fuel),
!
deemulgator (prevents from forming the emulsion and at the same time it helps in
water separation),
!
antioxidant (prevents from resin creation),
!
other additives like the colouring ones, are used in order to distinguish and identify the
petrol types, aromatic additives are used where the petrol scent is an obstacle in its sales.
Applying the set of the additives concerns actually all petrol types, and it should not be
identied exclusively with so called premium fuels, like e.g. V-Power (Shell), 98 Verva (ORLEN),
98 Ultimate (BP), Suprema (Statoil). Of course, dierent additives packages are applied in
these types of petrol, but they are also dierentiated by the production process itself, which
subsequently results in a lesser content of sulphur (in accordance with standards, which will
come into force just in 2009). It is an issue for the following elaboration, which exceeds the
scope of this document.
32
95 lead-free
petrol
98 lead-free
petrol
min. 95.0
min. 98.0
min. 85.0
min. 88.0
Parameter
Density in 15C
kg/m
Fraction composition:
- distils up to 70C (E70)
% of capacity
% of capacity
% of capacity
C
% of capacity
min.720
max.775
kPa
Induction period
minutes
min. 360
Pattern
Class 1
mg/l
Max. 5
mg/kg
Max. 50
Hydrocarbon content:
- olen
- aromatic
% of capacity
% of capacity
Max. 18
max. 35
Benzene content
% of capacity
Max. 1
Oxygen content
% of capacity
Max. 2,7
% of capacity
Max.
3
5
10
10
7
15
10
Lead content
Sulphur content
33
34
The components named above are characterized by dierent physical and chemical properties and their proportions are carefully selected while composing diesel fuel, depending on
what properties do we want to achieve. The selection of proper components, like in case of
petrol, takes into account the required parameters of the nal product which meets a proper
quality and has suitable exploitation properties. The table below presents some of the properties of the potential components applied while composing diesel fuels [4].
Table 6. The components coming from the simple distillation
Properties
Paran oil
0.8
Density in 15C [g/cm]
2
1.2
Viscosity in 40C [mm /s]
Content of sulphur [% of weight]
0.1
-50
Opaqueness temperature [C]
Cetane index
43
LON
0.83
2
0.4
-30
48
SON
0.85
3
0.7
-12
54
CON
0.87
7
1.2
+12
60
HON
0.85
3.5
0.005-0.05
+12...-10
54
HCON
0.85
4
0
53
LCO
0.88-0.99
3.5
0.1-0.3
-10...+5
30
Just like in case of petrol, for the diesel fuels the ennobling additives have not been included
in the standard. The additives improving the usage properties of the oil are selected according
to individual needs of the producer in a form of a special package, which may include the following components [4,5]:
!
detergent most commonly used additive in modern diesel fuels which prevents from
sediments gathering in small and precise injectors, most sensitive to dirt,
!
lubricating additives present diesel fuels include less and less sulphur and aromatic
hydrocarbon. These positive tendencies have unfortunately negative impact as well,
as it deteriorates the lubricity of the entire fuel, and this may lead to injection pump
seizure,
!
additives improving the winter properties of oil prevent from precipitation of the oil
in low paran oils temperatures and their combining in larger clusters,
!
antioxidants, stabilisers are applied in order to prevent from chemical degradation of
fuel which relies on forming of large formations of polymer resin causing diculties in
the lters and injection equipments,
!
deemulgators prevent from creation of emulsion from the water,
!
corrosion inhibitors secure against the activity of the corrosion aggressive substances.
The products of corrosion may block the lters, fuel lines or other parts of the system
of fuel supply.
On the Polish market diesel fuels with various names can be met, like for example: Eurodiesel (from the LOTOS Group), Ekodiesel (from PKN ORLEN), or others. These oils dier
sometimes in the properties, as the specic character of their production is dierent, but all of
them have to meet the requirements of the PN-EN 590 standard on the Engine fuels. Diesel
fuels. Requirements and test methods, which is compliant with its European EN 590 counterpart.
35
Table 8. Basic normative parameters of the diesel fuels used in Poland pursuant
with the requirements of the PN-EN 590 standard
Parameter
Cetane number
Cetane index
Density in 15C
Viscosity in 40C
Fraction composition:
- distil up to 250C
- distil up to 350C
- 95% of capacity distils up to the temperature
Ignition temperature
Sulphur content
WWA content
Lubricity (wear-scar diameter)
Oxidation resistance
Remains after the incineration
Water content
Contaminants content
Unit measurement
kg/m3
mm2/s
PN-EN 590
min. 51.0
min. 46.0
min.820 maks.845
min.2.0 maks.4.5
% of capacity
% of capacity
C
C
mg/kg
% of the mass
m
g/m3
% of the mass
mg/kg
mg/kg
max.65
min. 85
max. 360
min. 55
max. 50
max. 11
max. 460
max. 25
max. 0.01
max. 200
max. 24
LIQUID
GAS
Liquid LNG
propane-butane
mixture (LPG)*
Compressed CNG
Natural gas **
Methanol
Ethanol
Ethers
hydrogen
* at the end of 2006, on Polish roads there was 1980 thousand of cars propelled by this fuel [6]
** currently, this kind of fuel is used mainly to propel the vehicles of urban transport.
36
LIQUID
GAS
Liquid LNG
Natural gas (natural)
Methanol
Compressed CNG
Ethanol
Coke gas
Dimethyl Ether
Hydrogen
ance, that is the highest power from the cubic capacity unit, as much the present requirements
are directed mainly into environment protection (minimum emission of exhaust fumes), minimization of fuel consumption (engine exploitation costs reduction), and only then into the
improvement of engine performance. These changes determine the requirements with regard
to the engine petrol as well [2].
Diagram 6. The basic requirements posed to the engine petrol
Requirements and properties of the engine petrol
Optimal combustion
density
Chemical composition
Chemical composition
Chemical stability
Fraction composition
Fraction Composition
Susceptibility of corrosion
Vapor pressure
Content of pollution
Evaporation
warmth
Resilience to
pinking
combustion (octane
number)
Low temperature
parameters
Leaning
properties
Susceptibility of
electrification
Density
Fire threat
Influence on the
environment
Toxic
components
emission
during the
combustion
Susceptibility of
biodegradation
Heating value
Viscosity
2.2.2. Requirements concerning fuels which feed compression ignition engines (ZI)
diesel fuel
Fuel for compression ignition engine ought to have the following properties [5]:
to ensure proper functioning of the entire supply system, especially of the injector
system,
!
to ensure proper and eective combustion,
!
to produce the least number of harmful components u the combustion process,
!
not to cause a risk to the natural environment.
!
38
Due to the above, while describing the fuel for ZS engines, it is possible to distinguish the
groups of its properties (most of them was included in the qualitative PN-EN 590 standard),
combined with the presented requirements (diagram 7) [5].
Diagram 7. The basic requirements for the diesel fuels
Requirements and properties of diesel fuel
Proper pulverization,
evaporation and
combustion in the engine
Ensuring proper
supply system
operation
Density
viscosity
density
Chemical stability
Surface tension
viscosity
Low temperature
parameters
Fraction composition
Low temperature
properties
Susceptibility of corrosion
Immunity to
microorganism
infection
Waciwoci
samozaponowe
Calorific value
Cleaning value
Impact on the
environment
Toxic
components
forming
during the
combustion
Susceptibility of
biodegradation
lubricity
Inclusion of
pollutants and
water
Susceptibility of
electrification
Susceptibility of foam
formation
Fire risk
39
Diagram 8. Possibility of a change in fuel quality in dierent outlets within the supply system [2]
Distributor
PRODUCER
RAILWAY
Tank
CISTERN
Railway
front
TRUCK
CISTERN
Road tanker
refilling point
Tank
Road tanker
Technological
pipeline
Vehicles
tank
In the fuel bases, fuel is stored in the tanks from several months up to even several years (as
the state reserves). Fuels designed for long storage (up to 4 - 5 years) are produced in a special
manner they do not have chemically unstable hydrocarbon components and they do have
antioxidant additives. Additionally, petrol designed for the state reserves can not include alcohols and ethers as these compounds (mainly methyl and ethyl alcohol) may absorb water from
the warehouses tanks. As a result stratication of petrol into two phases may occur: alcohol
and water, and hydrocarbon. Lack of these compounds and water in the tank prevents petrol
from ageing and makes it possible to store it for a period even as long as 5 years. However, petrol which does not include alcohols is kept no longer than 1.5 year in the underground tanks
and up to 1 year in the surface tanks.
A possibility to prolong fuel storage in the underground tanks results from the small
changes in the temperature within twenty-four-hours time. In the gas space of each
tank, both warehouse tank and of a vehicle, there is a mixture of petrol vapours, air and
steam.
While lowering the temperature (e.g. at night) the volume of a gas space is changing and
new air portion gets into it along with the steam. In case of a lower temperature of tanks walls,
on their inside, a water is excreted which accumulates at the walls and ow down to the bottom of the tank. A part of the water dissolves in fuel (more precisely speaking forms an
emulsion), and another part deposits on the form of separate phase.
Polluting fuel with water during the fuel storage, transport or pouring operations is only
one of the large number of factors causing a change in fuel quality, on the way from the producer to the user.
Fuel may also change its properties as a result of [2,5]:
!
disposal of light fractions if the pouring and storing activities with regard to fuel are
not hermetic;
!
air oxygen inuence, as a result, the oxidation occurs as well as the polymerization of
the reactive fuel components;
!
constant polluters elements entering into the fuel (e.g. particles of the dust from the air,
products of the tanks corrosion, pipelines corrosion, etc.)
40
The below diagram presents the sources and ways of pollutants entering to the fuel, at the
example of petrol.
Diagram 9. The sources and types of engine petrol pollutants [8]
ENGINE PETROL POLLUTION
EXTERNAL
PRODUCTIONAL
Derivatives of the raw
material (oil) e.g.
sulphur and its
compounds, which
were not disposed
while the production
process
Derivatives from
the technological
installations e.g.
catalyst particles
DISTRIBUTIONAL
From the atmosphere
(environment) e.g.
dust particles
INTERNAL
EXPLOITATIONAL
Getting into the
vehicle tanks
from the
atmosphere and
the environment
along with the air
while emptying
the tanks and
refuelling
Oxidation and
petrol
components
polymerizatio
n products
tarmac and
resin
substances
Products of
tanks as well as
the fuel supply
system wear and
corrosion
The total analysis, covers the complex inspections in terms of conformity with the requirements of the subject standard (PN-EN 228 for the petrol, or PN-EN 590 for diesel
fuels) for all of the parameters of a given fuel type. This analysis is carried out in:
the renery for the produced fuel portion;
upon the acceptance of fuel to the storage tank in the fuel basis or periodically during
the storage period in the fuel basis (every half-year)
after the fuel was handed out from the receivers fuel base tank (e.g. at the lling station).
Upon each total analysis, laboratory statement is drawn up, which includes the values of
all the inspected normative parameters.
!
Control analysis, includes the testing of the selected parameters, especially such as:
density, fraction composition, water content and the cold lter blocking temperature
with regard to diesel fuel. The analysis is carried out periodically on the samples taken
from the tanks at the fuel storage bases.
!
Abbreviated analysis, includes dening the density, fraction composition, water content and amount of pollutants with regard to the diesel fuels as well as appearance and
colour of petrol. It is performed for the fuel samples taken upon the preliminary receipt
of the fuel portion in order to conrm the declared quality by the supplier (e.g. prior the
unloading of the cisterns, tankers, before pumping through the pipeline is nished).
Each supplied fuel portion ought to be accompanied by the statement on the total analysis results.
Upon the acceptance of fuel at the lling station, the samples from the portion are taken,
which are stored for a period of at leas three following supplies. The amount of the suspension,
sediment or water in such a sample is a basis not to accept the fuel to the lling station tanks.
The scrutiny of fuel quality at the lling stations is carried out by the Trade Inspection. The
authorised inspectors take samples, and the fuel quality scrutiny is inspected by the accredited
laboratories. The most renowned laboratories in Poland are the following:
!
Institute for Fuels and Renewable Energy
!
ORLEN LABORATORIUM Sp. z o.o.
!
OBR Pock
!
SGS Polska Sp. z o.o.
!
International Inspection Services Euroservice Sp. z o.o.
!
Polcargo International Sp. z o.o.
!
J.S. Hamilton Poland Ltd. Sp. z o.o.
!
LOTOS Lab Sp. z o.o.
In addition to standard inspections of fuel quality at all of distribution levels, some of the
stations networks, carry out their own extra fuel quality scrutinises in order to ensure proper,
high fuel quality at their stations.
The biggest and most renowned programs dedicated to fuel quality are:
!
Quality of an Eagle (Jako Ora) a program implemented by PKN ORLEN since
2003;
!
No risk ll up (Tankowanie bez ryzyka) an agreement signed by the member
companies of the Polish Organisation of Oil Industry and Trade: BP, Statoil, Shell,
ConoccoPhilips JET, Neste A-24;
!
Golden Drop (Zota kropla) a symbol of participation in the Quality Mark program, which aimed at promoting lling stations of the Polish Chamber of Liquid Fuels
Members, by selling high quality fuel and services.
!
42
All of these programs are carried out on the basis of the internal inspection system, which
among others covers:
!
concluding contracts with reliable suppliers, who have their own, internal quality scrutinizing system;
!
having scrutiny procedures of the distribution process, starting from fuel loading, ending on
the sales at the station. The cisterns in which fuel is transported meet sticts requirements;
!
each fuel delivery has a quality certicate;
!
there are constant monitoring of the tanks at the lling stations the tanks are quipped
with the measurement system, which monitors the level of fuel in the tank, and detects
possible occurrence of water;
!
there are systematic fuel quality inspections carried out by the independent laboratories, e.g. fuel quality scrutiny at the BP stations is carried out by J.S.Hamilton Poland,
at Statoil SGS Polska;
!
systematic servicing of the fuel pipes installation at the stations by the specialized companies.
ent combustion process as the ame front of both ignition mediums is directed in otherwise
direction. Sound eect of this phenomenon is engine ringing [1]. The occurrence of such a
combustion causes deterioration of engine performance and may lead to its damage.
Engine supplied with petrol of LO higher that the required one, will not cause the improvement in the engine performance and will not reduce fuel consumption, unless its regulatory
parameters will be changed.
Octane number is determined by comparing the combustion of the inspected fuel and the
reference fuel, which is a mixture of isooctane (the agreed value of LO for isooctane is 100) and
n-heptan (with the agreed value of zero), in the reference engine. For the fuels with LO up to 100,
octane number equals the percentage isooctane content in the n-heptan mixture, which in the
normalized conditions has the same resistance as the inspected fuel. The single cylinder engine,
overhead-valve engine, with variable compression ratio is given as a reference engine. The measurement of fuels octane number consists in starting up and powering by means of inspected fuel.
Upon the achievement of the measurement normalized conditions, the compression engine ratio
is changed for so long as pinking combustion is achieved with the demanded intensity. Then,
maintaining compression ratio, the supply is switched into the supply with reference fuel of a
variable composition, up to the point when the same pinking combustion intensity as for the
inspected fuel, is achieved. Isooctane content (% of capacity) in the reference fuel, which is consumed just as the inspected fuel, equals the octane number of the inspected fuel [2].
While inspecting the octane number, various measurement activities are undertaken. Most
often, the researched octane number (LOB, RON) and octane number are determined by the
use of motor method (LOM, MON). Both dier only in the rotational speed of the reference
engine during the measurement:
!
while RON measurement it equals 600 rotations/min,
!
while MON measurement it equals 900 rotations /min.
RESEARCHED OCTANE NUMBER is marked in less strenuous work conditions of the
reference engine, which are similar to the conditions of engine exploitation in medium and
low speed and with partial load (for example while driving in the city).
MOTOR OCTANE NUMBER characterizes engine working conditions at the stated and high
load by high rotation speed, which corresponds to the car drive at the long out-of-town routes.
FUEL VOLATILITY characterizes the ability of a particular substance to evaporate. Because during the engine operation, the time for combustion is very short (1 2ms), quick and
total fuel evaporation is the main determinant of the combustion process.
Fraction composition and vapour pressure are mainly responsible for the ability to evaporate.
FRACTION COMPOSITION [1,2]. The less temperature of a liquid boiling point, the more
volatile it is. Petrol is a mixture of a large number of hydrocarbons (over a hundred) and other
compounds. There is no one, strictly determined boiling point temperature, which would be a
chemical feature of a homogenous liquid. Hence, the boiling point of particular components is
framed into certain temperature range. In order to achieve information on petrol volatility, it is
necessary to establish common percentage ratio of the components with dierent boiling point
temperature. It is determined in the distillation process in which petrol is subdivided into fractions, which dier from each other with regard to the boiling point temperature.
Usually the entire distillation process is not given, but the abbreviated notation. Most often
petrol capacity is presented, which distilled o:
up to 70C (E70),
up to 100C (E100),
up to 150C (E150),
up to 180C (E180).
44
The number of fraction which distils o up to 70C (E70), that is the number of light hydrocarbons, is assumed as a criteria of the engine start up values so called cold start, especially in
low ambient temperature. The standard sets forth the minimum number (15%) which is necessary to improve the engine start up, but the maximum number of this light fraction (45-50%)
is provided as well, in order to prevent the production of undesirable fuel stoppers in the fuel
supply system.
Establishing the number of fraction which distils up to 100C (E100), that is approximately
a half of our fuel (4070%), is also very important, as it inuences on the speed of heating and
regularity of engine operations. It denes the uency of engine operations in the unsettled
conditions (e.g. while speeding up) as well as the ability of the heated engine to achieve the
maximum power by pressing rapidly the accelerator pedal.
The percentage of distilling o to the temperature of 150C (E150) or 180C (E180) denes
the content of the heavier petrol substances, which evaporate more hardly. Limitation of petrol distillation end results from the fact that the occurrence of heavy fractions in fuel causes
irregular engine operation, which again results from possible forming of inhomogeneous mixtures. The possibility of incomplete evaporation and potential possibility of contact with lubricating oil, and that means reduction in oil viscosity and worse working conditions of some
of the engine parts, and hence, their wear and tear. Moreover, during incomplete combustion,
fuel consumption is increasing, reducing engine power, exhaust fumes emission increases and
susceptibility to carbon deposit forming at the elements of combustion chamber.
VAPOUR PRESSURE [2] it is a pressure caused by the vapours of liquids above their
surface. It is a signicant parameter inuencing the fuel ability to evaporate in the engine,
its power supply system as well as in the storage, transport and distribution processes. The
higher vapour pressure, the better ability of fuel to evaporates and the better start up properties it has. However, fuel with too high vapour pressure transforms partially into the volatile
state yet in the power supply system. By doing so it forms fuel clogs which interrupts engine
operations more dicult start up of a hot engine, mixture impoverishment and power
decrease.
That is why vapour pressure is normatively limited, among others with regard to the ambient
temperature. During the summer period, petrol with vapour pressure of 45 - 65 kPa ought to be
used, and during the winter period of 55 - 105 kPa with a tendency to reduce these values.
DENSITY IN THE TEMPERATURE OF 15C [1] it decides on the petrol mass, which is
dosed (in terms of capacity) into the combustion chamber, and at the same time on the engine
performance and fuel consumption. All of the power supply systems dose engine petrol by
measuring its dened capacity.
The amount of the energy, however, emitted during the combustion process, depends on
the mass of the consumed fuel, which is unchangeable. As the density of fuel decreases along
with the growth in the temperature with regard to the same capacity of petrol dose with higher temperature (as a result of heating in the tank, carburettor, bunker of the injector system),
the dosed mass will be smaller, and the formed mixture will be poorer.
Moreover, it is necessary to know it in order to calculate the petrol sales during all of the
distribution operations and scal fees calculation. Value of the density in the temperature of
15C equals 715 - 780kg/m3.
INDUCTION PERIOD [1] expressed in minutes (minimum 360 minutes). It is an indicator of chemical petrol fastness evaluation. During the test, fuel placed in a special, locked
vessel, is subject to a inuence of oxygen in the temperature of 100C. When petrol starts to
interact with oxygen, oxygen loses its pressure. Such a moment is marked, and the time, when
it happened is translated into the induction period read from the special tables. The longer the
induction period is, the higher resilience of fuel to ageing and the longer storage period is.
45
CORROSION [1] it is quite common phenomenon, which occurs there where fuel contacts with the metal parts. The hydrocarbons themselves do not cause corrosion but some of
the sulphur particles, as well as the elementary sulphur dissolved in the oil products, strongly attacks elements made of copper and iron. During the storage and transport often slight
damp occurs, what also inuence the corrosion processes, and the products of corrosion being
formed as the sediment, may cause the exploitation interruption in the power supply system.
In the petrol standard, the indicator of corrosion ratio is the one, in which the copper shim is
subject to the petrol interaction in the temperature of 50C for 3 hours and the corrosion ratio
is evaluated visually (comparing with the reference points). The colour of the copper shim
shouldnt be higher than the reference one No1.
SULPHUR CONTENT [1,2] sulphur content scrutiny in petrol is crucial due to the necessary decrease in emission of sulphoxide and solid particles to the atmosphere. Sulphoxides
with water form sulphuric acid which while being ejected with the exhaust fumes to the atmosphere pose a risk in a form of acid rain.
Sulphur contained in fuel, and then its compounds contained in the exhaust fumes cause a
decrease in catalysts performance. Sulphur accelerates the degeneration process of the catalyst by depositing on the surface of the precious metal, and hence it decrease the active surface
of the catalyst and its capability of conversion of toxic compounds. Moreover, sulphur is also
a cause of corrosion processes in fuel supply system, Therefore, currently binding standards
limit its maximum content up to 50 with a tendency to further decreasing uo to maximum 30
ppm (part per million) (0.003%) of the mass, and with a perspective to eliminate it totally from
petrol (5 - 10 ppm). Pursuant to the European Union regulations, in 2009 sulphur content in
petrol will come to maximum 10 mg/kg.
CONTENT OF OXYGEN COMPOUNDS [2] with regard to the limitation of aromatic
and olen hydrocarbons content and elimination of tetraethyl lead in order to provide the required octane number, petrol is supplemented with oxygen compounds (as described in chapter 2.1). The oxygen compound improve the formation of combustible mixture and the course
of the combustion process. As a result, the emission of carbon monoxide and hydrocarbons
is decreased, without an increase in the emission of nitric oxide. However, during the petrol
combustion process along with their content, in the exhaust fumes the aldehyde concentration
increases (these compounds have toxic properties).
CONTENT OF HYDROCARBONS [1,2] in present lead free petrol, certain groups and
types of hydrocarbons are limited, mainly due to the limitation of negative impact of petrol
On natural environment.
Most frequently the content of the following is limited:
!
aromatic hydrocarbons (WA) up to 35% of volume in case of higher content of aromatic hydrocarbons the emission of carbon monoxide in increased and the nitric oxygen decreases. Heavy WA in petrol contribute to the increase in the sediments in the
power supply system and in the combustion chamber. During the WA combustion
process cancerogenous benzene (carcinogenic). The decrease in WA content, signicantly decreases emission of benzene in exhaust fumes;
!
olen hydrocarbons up to 10 18% of volume as the chemically unstable, form the
sediments and resins in the engines inlet system, and this again contributes to the increase in the toxicity of exhaust fumes. They inuence as well the ratio of nitric oxides
emission. However much serious risk is posed by olen hydrocarbons which permeate
directly to the atmosphere they are conducive to form ozone and carbon monoxide;
!
benzene up to 1 2.5% volume benzene is one of the aroma which signicantly inuences on the high octane number of petrol. It is however toxic and carcinogenic and
hence the aim is to limit its content in fuel.
46
LEAD CONTENT [1,2] with regard to environment protection and lead unquestionable
harmfulness, once used leaded petrol (so called ethyl petrol) were ousted from the market
by lead-free petrol. Once added tetra-ethyl lead (so called tetraethyl lead) to improve the antiknock properties, was substituted, among others, with high-octane oxygen compounds. In
lead-free petrol the acceptable level of lead content is established at the level not exceeding
0.013 g/l (in accordance with the American ASTM D4814 standard, the European requirements
EN 228 dene the maximum at the level of 0.005 g/l), which secures the catalysts against the
poisoning and its irreparable damage, and the environment against harmful eects.
temperature (the standard denes how dense the lter ought to be). Along with the
lowered temperature more and more paran is precipitated up to the total plug of fuel
ow.
In Poland, in accordance with the standard, in the summer period (from 16 April to 30
September), in the interim period (from 1 March to 15 April and from 1 October to 15 November) and in the winter period (from 16 November to the end of February), three types of
oil are obligatory: B, D, F, with the plugging point for cold lter respectively 0C, -10C and
-20C;
!
turbidity it is a temperature in which the rst crystals of paran are appearing. The
turbidity temperature is a supportive parameter and is given normally for the arctic
ON.
SULPHUR CONTENT [4,5] it is recently most often limited parameter because of the
ecological reasons it is a source of the carbon dioxide emission to the air. Decreasing sulphur content is also a result of the inspections carried out on the Diesel engines in which a
signicant participation of sulphur compounds in forming very hard carbon deposits causing damage to the engine. Current standards on the diesel fuels dene their maximum content up to 50 mg/kg (0.005% of mass) with a downward tendency, and with a perspective its
almost total elimination (in the amounts of 8...10 ppm). In accordance with the Union law,
from 1 January 2009, all the diesel fuels for the diesel engines introduced for sales on the
territory of the Member State, will be allowed to have the sulphur content of 10 mg/kg at
maximum.
WATER CONTENT [5] water in diesel fuel in suspension (in a form of a separate phase)
causes:
!
the corrosion of precise elements of the equipment,
!
an increased consumption of sprayers due to the electromechanical corrosion,
!
worsening of ON ability to spray,
!
soaking of the porous materials of the fuel lters and decreasing their durability,
!
microorganisms development at the phase border: water-fuel.
In the temperature below 0C, water solidies and take forms of ice crystals which because of their too small size may stay for a long time in suspension in ON. These crystals
may plug the lters and fuel pipes. Moreover, while continuous fall of temperature of ON,
little ice crystals and solid contaminants particles form the nucleus of crystallization for the
releasing paran crystals and intensify their combination, which lead to the increase in the
temperature of the ON plugging pint for cold lter. Due to the above, diesel fuel should not
contain water and solid pollutants. Most of the standards allows the content of water up to
200 ppm.
IGNITION TEMPERATURE [4] it is a temperature, for which the diesel fuel has to be
heated in order to receive the combustible mixture on the surface. This property is present in
the standard due to the safety of fuel storage and trading during the transport and sales. This
parameter does not inuence directly the engine work.
CONTENT OF AROMATIC HYDROCARBONS (WA) [5, 7] in has a negative impact on
the fumes clarity. A higher number of WA in fuel results in an increase in the temperature in
the combustion chamber, and hence increased emission of nitric oxide. According to [7], decreasing WA content in ON from 30% to 10% causes a decrease in the nitric oxides emission by
app. 5.3% in truck engines. Multicyclic aromatic hydrocarbons contained in the oil inuence
the content of solid particles in the exhaust fumes while lowering the WA content form 9%
to 1%, the concentration of carbon black solid particles falls by app. 6.3% in automobile engine
and by app. 4.2 in truck engines.
49
Summary
2.6. Summary
The progress made over the last years in the construction of spontaneous ignition engines
(Diesel) lead to the point, where it is an equal competitor of the petrol motor for the automobiles in terms of performance, while it even surpasses the petrol engine in terms of cost effectiveness. Diesel fuel and petrol become similarly important on the market, and both types
together are main fuels available on the market.
As compression-ignition and spark ignition engines dier from each other, the same is with
the composition and properties of petrol and diesel fuels, though they do derive from the same
material. That it is why it is proper to test them separately, dierent parameters ought to be
analysed in order to state the conformity with the qualitative standards.
In general, fuel is very complicated product which requires top precision and care not only
during the production process, but also during transport, storage and distribution. It is impossible to achieve it in the garage conditions. To meet the requirements with regard to so
many parameters requires qualications, proper equipment and the entire process scrutinizing systems. It has been proved above, how many fuel parameters may have impact on the
work and durability of an engine. This gentle balance and optimal components composition
is impossible to be maintained by adding chemical compounds of similar properties (but
of course cheaper, as a lower, if any, excise is imposed on them) to fuel. The situation looks
the same while using the fuel produced for heating purposes as fuel for vehicles. The heating
stoves have dierent construction and functions than the combustion engines, that is why fuel
has dierent parameters.
Care for the tanks and installation has also a large importance for fuel quality. Hence, to
shape the image of high quality product with regard to fuels, is not just to care about marketing eorts behind it there lies real processes, qualications and costs.
So, fuel quality perception comes down to clients trust, that all of the aforementioned conditions will be met. It may be guaranteed by the producer and distribution network reputation. This, however, is not enough, what is required is an independent, unbiased fuel quality
scrutinizing system which is a motivator for the producers and dispensers, due to the fact that
their fuel may be tested and possible negligence may be made public. Being aware that they
are subject to the scrutiny, the consumers may trust in the fuel quality which are oered by the
famous and renowned producers and distribution networks.
Literature:
[1] Lewandowski J.: May poradnik uytkownika i operatora paliw pynnych i olejw silnikowych. Benzyny silnikowe.
Fascicle 1. Top Oil Sp. Z o.o., Gdask, 1999.
[2] Baczewski K., Kadoski T.: Paliwa do silnikw o zaponie iskrowym, WK Warszawa 2005.
[3] Kumierek J.: Jeszcze o benzynie uniwersalnej U95 .Paliwa, oleje i smary w eksploatacji No 84/2001.
[4] Lewandowski J.: May poradnik uytkownika i operatora paliw pynnych i olejw silnikowych. Oleje napdowe. Fascicle 2. Top Oil Sp. Z o.o., Gdask, 1999.
[5] Baczewski K., Kadoski T.: Paliwa do silnikw o zaponie samoczynnym, WK Warszawa 2004.
[6] Polska Organizacja Gazu Pynnego: Polski rynek gazu pynnego w roku 2006, Warszawa 12 April 2007, materials
from the press conference.
[7] Word-wide Fuel Charter, December 2002.
[8] Baczewski K.: Zanieczyszczenia pynw eksploatacyjnych. Paliwa, oleje i smary w eksploatacji No 33/1997.
50
95 Lead-free
petrol
Dolnolskie
19
Kujawsko - Pomorskie
15
Lubelskie
13
Lubuskie
7
dzkie
12
Maopolskie
20
Mazowieckie
25
Opolskie
6
Podkarpackie
14
Podlaskie
10
Pomorskie
14
lskie
27
witokrzyskie
6
Warmisko - Mazurskie
10
Wielkopolskie
25
Zachodnio - pomorskie
12
TOTAL
235
Region
98 Lead-free
petrol
14
8
8
6
6
9
20
5
8
7
8
18
4
6
18
12
157
Diesel
fuel
12
14
12
8
10
17
24
6
10
8
11
22
6
8
24
12
204
The number of
stations (in total)
45
37
33
21
28
46
69
17
32
25
33
67
16
24
67
36
596
51
Taking the European legislation requirements into account, the number of samples taken in 2005 in Poland is consistent with, or even higher then, the number required in the EN
14274:2003 standard.
Number of samples
Fuel type
95 lead-free petrol
98 lead-free petrol
Diesel fuel
Sales share
in %
Summer
period
Winter
period
Total
92.6%
7.4%
100%
110
100
100
135
57
104
245
157
204
Number of samples to be
taken in accordance with
EN 14274:2003 standard
200
15
200
95 lead-free petrol quality scrutiny proved that 13 out of 245 taken samples of this fuel type
did not meet one or several qualitative parameters. Most frequently exceeded parameter was
sulphur content and the researched octane number RON.
The maximum sulphur content which in accordance with the standard should be not more
than 50 mg/kg, was exceeded in 6 taken samples. The highest noted value of this parameter
was 276 mg/kg. It is more than a quintuple excess of the standard.
Inconsistency of the researched octane number RON was discovered in 6 samples of all
the taken samples as well. The lowest value was 87.8 while the acceptable standard is minimum 95.
Other parameters, the results of which turned out to be inconsistent with the acceptable
values, were:
!
motor octane number (MON), inconsistency of this parameter with the standard has
been found in 4 samples. The lowest result was 80.20 units, while the minimum standard 85;
!
maximum content of the aromatic type hydrocarbons (dened in the standard at the
level of 35% V/V) was exceeded in 2 samples. The highest result for this parameter was
38.6 % of volume;
!
in two samples, benzene content was exceeded as well (max 1% V/V). The worst sample exceeded the standard nearly threefold (2.6 % of volume);
!
ether content (with 5 or more carbon atoms in a particle) was exceeded in 2 taken samples. The highest spotted result was 20.5 while the standard is 15 % of volume;
!
moreover, the isolated examples of inconsistency with the standard were noted for the
vapour pressure and distillation for 100 and 150 C.
52
The number and share of samples of 95 lead-free petrol in which a particular parameter was exceeded
Inspected parameter
Researched octane number, RON
Motor octane number, MON
Vapour pressure, DVPE
Distillation in the temp. of 100C
Distillation in the temp. of 150C
Content of aromatic hydrocarbons
Content of benzene
Ether content
Sulphur content
Number of samples
% samples share
Number of
in which a particular in which a particular
inspected
parameter was
parameter was
samples
exceeded
exceeded
245
6
2.45%
245
4
1.63%
245
1
0.41%
245
1
0.41%
245
1
0.41%
245
2
0.82%
245
2
0.82%
245
2
0.82%
245
6
2.45%
98 lead-free petrol quality scrutiny proved that the normative values of the researched octane number RON and the maximum content of aromatic type hydrocarbons were exceeded
in 3 and 1 sample, respectively. Overall, 3 out of 157 taken samples of this fuel did not meet the
qualitative standards.
98 lead-free petrol number and share of samples in which a particular parameter was exceeded
Inspected parameter
Number of
inspected
samples
157
157
The number of
samples in which a
particular parameter
was beached
3
1
% samples share in
which a particular
parameter was
exceeded
1.91%
0.63%
The scrutiny of taken samples of the diesel fuel with regard to the 5 inspected parameters
proved that only of them (inclusion of cyclic aromatic hydrocarbons) met all of the analysed
samples. Most frequently exceeded parameter (in 14 out of 204 inspected samples) was the one
of sulphur content. The highest noted value was 2734 mg/kg (while the acceptable standard is
50 mg/kg), which exceeded the standard fty times.
The remaining parameters, the results of which exceeded the acceptable values, were: the
cetane number, density in the temperature of 15C and the temperature of distilling of 95% of
fuel volume (the highest spotted result was 400C while the standard denes the maximum at
the level of 360C).
The number and share of samples of diesel fuel in which a particular parameter was exceeded
Number of samples % samples share in
Number of
in which a particular which a particular
Inspected parameter
inspected
parameter was
parameter was
samples
exceeded
exceeded
Cetane number
204
1
0.49%
Density in the temp. of 15C
204
1
0.49%
Distilling o temperature 95% of volume
204
4
1.96%
Sulphur content
204
14
6.86%
53
74
108
108
120
410
Winter
period
Total
83
85
85
120
373
157
193
193
240
783
Number of samples to
be taken pursuant to EN
14274:2003
400
400
18
400
1218
Only for 98 lead-free petrol, a sucient number of samples was taken which is consistent
with EN 14274:2003.
The scrutiny results of taken samples of certain fuels proved that in Germany fuels of good
quality are sold. Infringements are rare.
Among 157 taken samples of 91 lead-free petrol, only one sample shown the vapour pressure exceeding parameter during the summer period. Inconsistency of this parameter was also
discovered in 1 (out of 193) sample of 95 lead-free petrol.
In case of 98 lead-free petrol, the scrutiny proved that one of the taken samples was inconsistent with the normative values for the vapour pressure during the summer period, content
of aromatic hydrocarbons and content of other oxygen compounds than specied in the standard.
The scrutiny of diesel fuel provided information on just one infringement of the inspected
parameters. A parameter which was not consistent with the assumed value was distilling o
temperature 95% V/V.
The number and share of the inspected fuel samples in which a particular parameter was exceeded
Fuel type
Inspected parameter
Number of
inspected
samples
Number of
% samples
samples in which share in which
a particular
a particular
parameter was parameter was
exceeded
exceeded
91 lead-free petrol
157
0.64%
95 lead-free petrol
190
0.53%
96
1.04%
81
1.23%
42
2.38%
240
0.42%
98 lead-free petrol
Diesel fuel
54
Summer
Trade share %
period
26.3%
70.8%
2.9%
100%
-
50
50
0
50
150
Winter
period
Total
50
50
5
50
155
100
100
5
100
305
Number of samples to
be taken in accordance
with the EN 14274:2003
100
100
3
100
303
The results of the scrutiny proved that in Austria, good quality fuel is sold. The infringements of the inspected parameters values, revealed from time to time, which are obligatory
under the present standards, are slight.
During the course of scrutiny it was discovered that:
!
for the 91 lead-free petrol there was one violation of the minimum value of the motor
octane number MON (the noted result is 80.9 units while the standard is minimum 81)
and two for vapour pressure during the summer period;
!
for the 95 lead-free petrol - 1 violation for motor octane number (the examined value
is 82.8 units while the normative minimum is set to be 85) and maximum content of
aromatic hydrocarbon (the noted result 36.5% of volume, while the standard sets the
level of 35% of volume);
!
for diesel fuel there was one violation of maximum temperature of distilling o 95% of
volume which was higher by 17C than the value set in the standard at the maximum
level of 360C, and two violations of sulphur content (the highest noted value was 87.5
mg/kg while the acceptable standard is 50 mg/kg).
Quality scrutiny of 98 lead-free petrol samples did not prove violations of normative parameters.
55
The number and share of the inspected fuel samples in which a particular parameter was exceeded
Fuel type
The inspected
parameter
The number of
% samples share in
The number of
samples in which a which a particular
the inspected
particular parameter
parameter was
samples
was exceeded
exceeded
Motor octane
91 lead-free number
petrol
Vapour pressure,
DVPE
Motor octane
95 lead-free number
petrol
Aromatic hydrocarbons content
Distilling o temperDiesel fuel ature 95% of volume.
Sulphur content
100
1%
100
2%
100
1%
100
1%
100
1%
100
2%
% trade share
Summer
period
Winter
period
Total
92 lead-free petrol
95 lead-free petrol
98 lead-free petrol
Diesel fuel
TOTAL
5.1%
83.7%
11.1%
100%
-
12
40
18
101
171
23
117
41
337
518
35
157
59
438
689
All of the samples were examined with regard to all of the parameters dened in Directive
98/70/EC.
The inspection of the taken samples proved:
!
1 violation of fractional distillation number up to 100C with regard to the 95 lead-free
petrol;
!
with regard to the diesel fuel the inconsistency of cetane number was revealed as well
as with regard to sulphur content, respectively for 1 and 8 samples. The measured value of cetane number amounted 41.7 units while the directive sets the minimum limit at
51. Sulphur content in the samples inconsistent with the normative values, uctuated
between 78 and 1560 mg/kg while the maximum standard is 50 mg/kg.
56
The number and share of the inspected fuel samples in which a particular parameter was exceeded
Fuel type
95 lead-free
petrol
Diesel fuel
The number of
The number
% samples share in
samples in which
of the
which a particular
a particular
inspected
parameter was
parameter was
samples
exceeded
exceeded
Inspected parameter
Distillation in the
temperature of 100C
Cetane number
Sulphur inclusion
157
0.64%
337
337
1
8
0.30%
2.37%
Fuel type
95 lead-free petrol
Diesel fuel
TOTAL
Summer
period
Winter
period
Total
41
36
77
77
59
136
118
95
213
For each of the taken samples of 95 lead-free petrol, 11 out of 18 parameters were measured,
which were pointed by Directive 98/70/EC. The samples were not examined with regard to the
lead content and particular oxygen compounds.
The samples of diesel fuel were examined in accordance with the premises of the Directive,
all of the required parameters were measured, which is 5.
Among the petrol samples, three of them proved a slight excess of parameters: the researched octane number, the aromatic hydrocarbons and benzene content. The researched
octane number in the inspected sample had 94 units, while the standard is minimum 95. Comparing with the standard (30% of volume), aroma content was exceeded by 5.3% of volume.
Benzene content, instead, was 1.2% of volume, comparing with the standard which denes the
maximum benzene content at 1.0% of volume.
With regard to the taken samples of diesel fuel, no excess of parameters was noted.
57
The number and share of the inspected fuel samples in which a particular parameter was exceeded
Fuel type
95 lead-free
petrol
The number of
The number
% samples share in
samples in which
of the
which a particular
The inspected parameter
a particular
inspected
parameter was
parameter was
samples
exceeded
exceeded
The researched octane
118
1
0.85%
number RON
Aromatic hydrocarbons
118
1
0.85%
content
Benzene content
118
1
0.85%
Summer
period
154
569
7
876
1606
Winter
period
143
503
5
777
1428
Total
297
1072
12
1653
3034
For all of the taken samples, the inspection of all the qualitative parameters dened in Directive 98/70/EC was performed.
The quality scrutiny of 91 lead-free petrol proved that the most frequently exceeded parameter was content of sulphur. The maximum content of sulphur, which pursuant to the standard
should be not more than 50 mg/kg was exceeded in 6 samples.
Other parameters, the results of which were inconsistent with the acceptable values, were
the following:
!
researched octane number (RON), the inconsistency with the standard of this parameter was reviled in 1 sample;
!
value of vapour pressure during summer period was inconsistent with the standard in
2 samples;
!
the maximum content of oxygen was inconsistent in 1 sample;
!
in two samples the maximum content of ethanol was also exceeded.
58
The number and share of 91 lead-free samples in which a particular parameter was exceeded
The number of
The number
samples in which a
of inspected
particular parameter
samples
was exceeded
297
297
297
297
297
% samples share in
which a particular
parameter was
exceeded
1
2
1
2
6
0.34%
0.67%
0.34%
0.67%
2.02%
The quality scrutiny of 95 lead-free petrol proved that in some of the 1072 taken samples,
the normative values of researched octane number (RON), monitor octane number and vapour
pressure were exceeded during summer period, distillation up to 100 and 150C, content of
aromatic hydrocarbons, benzene, oxygen, ethanol and sulphur.
The parameters which were exceeded most frequently were the researched and monitor
octane number. The abnormalities were discovered in 22 and 19 taken samples.
The number and share of 95 lead-free samples in which a particular parameter was exceeded
The number of
The number samples in which
of inspected
a particular
samples
parameter was
exceeded
1072
1072
1072
1072
1072
1072
1072
1072
1072
1072
22
19
1
4
1
4
4
7
8
2
% samples
share in which
a particular
parameter was
exceeded
2.05%
1.77%
0.09%
0.37%
0.09%
0.37%
0.37%
0.65%
0.75%
0.19%
All of the samples of 98 lead-free petrol were consistent with the all of the researched normative parameters.
During the course of diesel fuel samples scrutiny it was discovered that there were:
!
63 cases of exceeding maximum sulphur content;
!
42 cases of exceeding distillation temperature 95% V/V;
!
and 3 cases of exceeding density in 15C and 1 with regard to the cetane number.
59
Number and share of diesel fuel samples in which a particular parameter was exceeded
60
The number of
% samples
The number samples in which share in which
of inspected
a particular
a particular
samples
parameter was
parameter was
exceeded
exceeded
1653
1653
1653
1653
1
3
42
63
0.00%
0.18%
2.54%
3.81%
N
Researched octane number RON
245
Motor octane number MON
245
Vapour pressure, DVPE
245
Distillation up to 100C
245
Distillation up to 150C
245
Content of olen hydrocarbons
245
Content of aromatic hydrocarbons 245
Content of benzene
245
Content of oxygen
245
Content of methanol
245
Content of ethanol
245
Content of isopropyl alcohol
245
Content of tert butyl alcohol
245
Content of isobutyl alcohol
245
Content of ethers
245
Content of other compound with
245
oxygen
Content of sulphur
245
Content of lead
245
Parameter
6
-
84
-
Germany
N
A
B
62
155 190 1 0.53
164 164 193 193 193 155 106 96
66
66
67
161 -
2.45 193
24
-
Poland
A
B
6 2.45
4 1.63
1 0.41
1 0.41
1 0.41
2 0.82
2 0.82
2 0.82
100
100
100
Austria
N
A
100 100 1
100 100 100 100 100 1
100 100 100 100 100 100 100 100 -
B
1
1
157
157
157
N
157
157
157
157
157
157
157
157
157
157
157
157
157
157
157
-
Latvia
A
B
1 0.64
118
-
N
118
118
118
118
118
118
118
118
118
118
-
Ireland
A
B
1 0.85
1 0.85
1 0.85
-
The results of 95 lead-free petrol scrutiny in the countries subject to the analysis
1072
1072
1072
2
-
0.19
-
Czech Republic
N
A
B
1072 22 2.05
1072 19 1.77
1072 1
0.09
1072 4
0.37
1072 1
0.09
1072 1072 4
0.37
0.37
1072 4
1072 7
0.65
1072 1072 8
0.75
1072 1072 1072 1072 -
61
62
Parameter
Poland
N
A
B
157 3 1.91
157 157 157 157 157 157 1 0.63
157 157 157 157 157 157 157 157 157 157 157 -
Germany
N
A
B
39
77
96
1 1.04
85
85
50
81
1 1.23
81
77
57
34
23
37
37
70
42
1 2.38
96
20
-
Austria
N
A
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
B
-
N
59
59
59
59
59
59
59
59
59
59
59
59
59
59
59
59
59
59
Latvia
A
B
-
Ireland
N A
-
The results of 98 lead-free petrol scrutiny in the countries subject to the analysis
B
-
Czech Republic
N
A
B
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
-
Comparative analysis
204
204
204
204
204
Sulphur content
Cetane number
Density in the temperature of 15C
Parameter
14
1
1
6.86
1.96
0.49
0.49
Poland
240
191
240
240
240
0.42
Germany
100
100
100
Austria
100
100
337
337
337
337
337
1
-
Latvia
2.37
0.30
-
The results of diesel fuel scrutiny in the countries subject to the scrutiny
94
95
92
60
94
Ireland
1653
1653
1653
1653
1653
63
42
1
3
3.81
2.54
0
0.18
Czech Republic
63
91 petrol
95 petrol
The number of
taken samples
98 petrol
Diesel fuel
91 petrol
The number
95 petrol
of revealed
98 petrol
abnormalities
Diesel fuel
91 petrol
The number
95 petrol
of samples
inconsistent with 98 petrol
the standard
Diesel fuel
91 petrol
The percentage
95 petrol
of the samples
inconsistent with 98 petrol
the standard
Diesel fuel
3
12
18
2
72
3
4
0
0
0
20
3
109
0
3
no entry
13
2
no entry
3
3
0
no entry
15
3
no entry
0
3.0%
no entry
5.5%
2.0%
no entry
2.5%
1.9%
0.0%
no entry
7.4%
3.0%
no entry
0.0%
Latvia Germany
35
157
157
193
59
193
438
240
1
1
1
0
3
9
1
1
1
1
0
1
9
1
0.6%
0.6%
0.5%
0.0%
0.5%
2.1%
0.4%
In the above table, the eld marked with red denotes the countries for which the results in
Poland were strategically worse (more samples inconsistent with the standard). In case of the
Czech Republic there it was not possible to dene the number of faulty samples, however, on
the basis of the number of noted inconsistencies with the standard, in a proportion with the
number of taken samples, there is no basis to acknowledge the results achieved in the Czech
Republic to be worse than these achieved in Poland.
To sum up the results of fuel quality scrutiny in Poland and 5 states of European Union, it
ma be stated that the inconsistencies with the standard, in Poland occur more often than in other
countries (excluding the Czech Republic). Comparison with Austria does not provide statistically relevant results, however, it may be assumed that in case of a larger number of samples, in
Austria the dierence could turn out to be statistically relevant to Polands disadvantage.
64
65
Average net prices of the scrutinized fuels and sum total of the tax charges for 1000 litres
by the dispenser at the lling station in both half-years of 2005 in the countries subject to the
inspection
I half-year 2005
95 lead-free
Diesel fuel
petrol
No tax No tax No tax
Tax
The Czech Republic 289.21 519.89 356.78 458.52
Latvia
357.43 359.22 382.61 319.67
Poland
314.26 560.87 389.27 441.00
Austria
333.63 576.37 386.53 449.47
Germany
303.50 807.80 365.40 604.10
Ireland
335.01 605.99 416.24 532.76
II half-year 2005
95 lead-free
Diesel fuel
petrol
No tax
Tax
No tax
Tax
433.40 549.20 490.46 485.52
431.50 403.15 472.95 363.14
435.27 585.08 475.77 458.21
467.36 603.64 514.01 475.99
432.40 828.40 485.90 623.40
428.39 625.61 501.36 550.64
Source: Eurostat,
without tax net price for 1000 litres of fuel, that is without VAT, excise or fuel fee,
tax VAT, excise, fuel fee.
The dierences in the fuel tax burdens value between the examined countries are signicantly greater than the dierences in the net prices of fuel. Tax burdens indicate the dependence on the region (in EU-15 the burdens are higher than in the newly joined countries), these
are net fuel prices which do not show such a dependence. Incidentally, net price of 95 lead-free
petrol (Pb95) in Latvia, was the highest one out of the 6 examined countries in the I half of
2005. Quite average, the lowest fuel prices (both Pb95 and diesel fuel) in 2005 (a mean from the
two half-years) were noted in the Czech Republic, the highest Pb95 price was however noted
in Austria, and the highest price for diesel fuel was noted in Ireland.
The evidence of the progressive tax burden convergence with regard to the fuel trade, are
the dierences in the tax burdens between II half-year of 2004 and II half-year of 2005.
An increase in the rate of taxes imposed on the sold fuel (95 lead-free petrol and ON) in the
examined countries during the period of II half-year of 2004 - II half-year of 2005
Pb95
ON
7%
10%
Latvia
9%
13%
Poland
17%
23%
Austria
3%
8%
Germany
1%
4%
Ireland
2%
5%
Source: Eurostat
The data included in the above table show signicant dierences in the growth pace of tax
burdens among newly joined members of the European Union, which is signicantly higher
than the ratio of the old members (for which the burdens are higher). It ought to be stressed
that Poland is an unquestionable leader in this area. From among all of the members of the
European Union, tax burdens for Pb95 lead-free petrol trade, increased only in Denmark (by
22%), but with regard to diesel fuel, Poland overtakes only Lithuania where the taxation increased approximately by 32% during the II half of 2004 to the II half of 2005.
66
With respect to fuel quality, the attention ought to be drawn not only to the level of tax
burdens with regard to fuel trade, but also to the relative value of these burdens. There is need
for awareness of the fact that fuel spoiling is not something accidental and is not a result of
the dierences in the technological processes of fuel production in particular countries, but
it may be connected with the protability resulting from fuel dilution with the substances,
the prices of which are lower, or what is even more important are not subject to the taxation
(especially to excise) in the same manner as the engine fuels. It is conventional proverb that
says that the opportunity makes the thief, and relatively higher benets resulting from taxation frauds with regard to fuel trade take place in Poland, the Czech Republic and in Latvia
rather than in Austria, Germany and Ireland. In this elaboration, there is not place to establish
particular ways to avoid the taxation law, but there is no need for thorough insight in order to
spot such possibilities and their relations with the potential benets of their application.
Having in the above in mind, it is worth paying attention to the relation of tax burdens with
regard to fuels with the rate of an average remuneration in particular countries. This particular
statement may to some extent constitute a measure of a temptation to mix the forbidden substances with fuel at various distribution stages.
Tax burdens included in fuel price as a percentage of an average monthly gross income
in the examined countries
Monthly
income*
The Czech Republic
Latvia
Poland
Austria
Germany
Ireland
600.83
301.67
589.17
2 702.50
2 885.00
2 742.50
Source: Eurostat
* An average monthly gross remuneration in the production and service enterprises employing 10 and more employees in
2002.
The above table proves that despite signicantly higher fuel tax burdens in the countries of
the old EU, these kind of burdens are much more noticeable in Poland, the Czech Republic
and especially in Latvia. From the economic point of view it may be assumed that each potential criminal who may commit a tax fraud will consider both the benets from avoiding paying
taxes which are imposed on fuel, and the possible risk. To make it simple let us assume that in
all of the 6 examined countries, the risk is identical (the eciency of tax bodies and the police
is at the same level), then in case of the countries belonging to the old fteen countries of the
EU, a relative benet resulting from avoiding paying due taxes for 1000 litres of fuel amounts
to approximately 20% of average monthly remuneration, and in case of Poland, the Czech
Republic and Latvia they are not lower than 70%. Hence the temptation to fuel fake and to
avoid paying excise tax is visibly higher in Poland, the Czech Republic and Latvia rather than
in Germany, Austria or Ireland.
Due the fact, that the analysis concerns only 6 countries, while in 3 countries (Germany,
Austria and Latvia) the cases of exceeding the standard are incidental, it is hard to speak about
the correlation dependence between the average earnings, rate of taxes imposed on fuel trade
and a number of deviations from the fuel standards. The rates of tax burdens with relation
67
the rate of remunerations in a particular country may be regarded as an additional risk factor
which may adversely inuence the fuel quality in the taken samples.
According to the scal policy carried out by the European Union, what we observe is the
graduate equalization of fuel taxation rate. However, the dierences in the tax burdens rates
between the 6 markets under the analysis, exceed Euro 220 for 1000 litres of fuel. In the countries belonging to the old fteen countries of European Union, tax burden is higher that
in the newly joined countries, though the dierence are visible decreasing by more prompt
increase of burden in Poland, the Czech Republic and Latvia. Fuel net prices (without tax burdens) are clearly less diversied between the countries subject to the inspection, rather than
the scal burdens. An average price of PB95 without tax burden in the II half of 2005 oscillated
between 43150 Euro (in Latvia) and 467.36 Euro (in Austria).
In the context of fuel, the benets resulting form the quality frauds need to be taken into
consideration. It is easy to guess that a bad intention and a will to gain material benets is a
main trigger for the reviled fuel faults. Taking this hypothesis as a right one, it is justiable
to assume that a trigger factor to fake fuel may be not just a fuel price or tax burdens, but it is
more about a relative benets achieved in a particular country. Hence it is not about the rate
of tax burdens, but it is about their relation to the remuneration level in a particular country.
Avoiding paying taxes on 1000 litres of Pb95 in Poland, makes it possible to gain a income at
the amount of approximately of the average monthly remuneration. Though the benets resulting from committing such a fraud in Ireland, Germany and Austria is much higher (higher
taxation rate), the relative protability of an underhand tricks with regard to the risk is signicantly lower (approximately 20% of an average monthly remuneration).
68
Fuels
distribution is inspected - from lling stations to wholesale outlets, fuel depots and fuel
producers, and all types of fuels available on the market are subject to scrutiny.
Fuels
Contrary to the popular opinion, both petrol and diesel are technologically advanced
products. Their production requires a great professional technical base. From the chemical
point of view, the quality of fuel can be described using many parameters, each of them inuencing the work of the engine, its life-span and the toxicity of fumes. Consumers in any country are not able to assess that by themselves. In order to make the assessment it is necessary
to carry out laboratory analyses of the samples taken at the lling stations. Therefore, some
traders may be tempted, for example, to add various chemical compounds (cheaper from the
fuel) to the fuels they sell or to understate certain parameters (meeting of which increases the
production costs) since the average consumer is not able to tell the dierence. In particular
because one-time tanking up of a fuel slightly non-compliant with the standard, e.g. in respect
of the octane number, has no signicant negative eects. However, they do occur when such
fuel is tanked up regularly.
The risk of unfair practices exists in each country, and the scale of such behaviour is linked
i.a. with the eectiveness of the measures undertaken by the authorities responsible for market surveillance. On the basis of the results of fuel quality inspections, which improve every
year, it can be assumed that the measures implemented in Poland are as eective as in other
countries.
Inspection results
The results of the fuel quality inspections carried out between 1 January and 31 December 2005 in Poland and in 5 other countries show that the level of incompliance of the
tested parameters with the standard in Germany is negligible (below 1%). Therefore, as
it might have been expected, the fuel sold in Germany is without any fault. In respect of
the detected irregularities, Ireland, Latvia and Austria have only insignificantly worse
results. Slightly worse results were noted in the Czech Republic and Poland. However,
these are only small differences. The number of the samples, is, from the statistical point
of view, not large, therefore, there are no explicit statistical reasons for stating that the
fuel in Poland is of worse quality than in the other countries. From the point of view
of the average driver it is insignificant that the probability of tanking bad quality fuel
in Germany is less than 1% and in Poland 5%. In both cases the situation when the fuel
does not meet the standards is very rare. As mentioned before, one-time tanking of a
fuel which is slightly non-compliant with the standard has no significant negative consequences for the engine.
In the case of the Polish market, it also should be emphasized that the system of fuel quality monitoring and scrutinizing introduced in 2004 is eective, which can be proved by the
inspection results from 2006: out of 712 samples tested (taken from 712 randomly drawn lling
stations), only 17 did not meet the requirements, which constitutes only 2.39%. The following
comparison of the data for 2005 and 2006 speaks for itself:
Percentage of fuel samples incompliant with the standard
Diesel
Petrol
70
Surely, this study does not exhaust the topic of fuel quality and its scrutiny. However, it
shows that since Polands accession to the EU, a great improvement took place on the liquid
fuels market with respect to quality parameters and the gap between the Polish market and
the more developed markets of the Western Europe has been reduced. Undoubtedly, all credit
goes to the eective system of fuel quality monitoring and scrutinizing.
72
73
74
within the frame of the country part, the task of which was not only to disclose the cases
of trade in fuel which does not meet the quality standards, but also to check the quality
improvement degree of fuels oered at the stations where the abnormalities were discovered during the previous inspections; it covered as well the inspection at the petrol
stations registers due to the complain of the drivers, information acquired from the police and CB (Central Bureau of Investigation). Fuel warehouses were inspected as well.
Since 1 January 2007, the scrutiny has extended to a considerably larger scale. It covers the
entire fuel distribution chain starting from the petrol stations through the petrol bases and
warehouses, ending on the fuel producer. Moreover, the scrutiny encompasses all kinds of
liquid fuels in the market, i.e.:
!
95 lead-free petrol;
!
98 lead-free petrol;
!
diesel oil;
!
liquid biofuels (including the ones applied with the selected vehicle eet as well as the
ones produced by the farmers for their own use);
!
propane-butane (LPG);
!
compressed natural gas (CNG);
!
light heating oil.
In addition to inspecting the public and factory stations as well as the fuel warehouses,
which took place until the end of December 2006, the inspection also covers the following
entrepreneurs:
!
fuel producers;
!
enterprises who store fuel;
!
enterprises running the fuel transport business (scrutiny at the request of police);
!
owners and users of the selected vehicle eets;
!
the public and factory stations, in which the liquid biofuels, liqueed petroleum gas
(LPG) and compressed natural gas (CNG) are inspected;
!
enterprises launching new light diesel oil on to the market;
!
agriculturists producing liquid biofuels for their own use.
!
The Tenth Resolution to the Federal Act on the protection against emissions (Resolution on the quality and labelling of fuel quality 10. BImSchVo BundesImmissionsVerOrdnung of 22 December 1999) provides for adopting the European standards as
the minimum requirements for the labelling and the quality of engine petrol, engine
oils and liquid petroleum gas in Germany;
However, not all of the parameters included in the standards are used to monitor fuel
quality the system envisages measuring only the ones which are particularly signicant from the point of view of the environment, important for the protection of
consumers, or those which the previous inspections proved to be indicative of the defectiveness of the product. The above mentioned specics are distinctive enough to
consider the German fuel quality monitoring system as a national system falling outside the models prescribed by the EN 14274:2003 standard;
The Ministry of the Environment is responsible for the delivery of the yearly report
to the European Commission. The report is drawn up by the Federal Environment
Agency on the basis of the data supplied by the German federal authorities and the
statistics of the Federal Oce of Economics and Export Control (BAFA).
The quality of the motor petrol and diesel fuels sold at the lling stations is inspected
by the Federal Environment Agency and the ndings are passed on in the form of a
75
The main institution responsible for fuel quality monitoring in Latvia is the Excise Duty
Division of the Internal Revenue Service (IRS), which cooperates with other state institutions, the most important of which are the Latvian Centre of Certication (LATSERT)
and the economic police department of the State Police. In order to test the samples,
the Internal Revenue Service uses three express laboratories, which are authorised to
scrutinize fuel quality on the territory of Latvia;
Approximately 600 lling stations operate on the territory of Latvia under app. 216
issued licences; wholesale trade is being carried out on the basis of approximately 47
licences; the samples are taken at the lling stations and at the terminals as well as at
petrol warehouses;
Samples are taken at least once a month; in practice, sampling takes place everyday at
dierent sites and locations cross Latvia.
System in Ireland:
!
The quality of the motor petrol and diesel fuel being traded on the territory of the country is subject to the inspection of the Internal Revenue Services, and the taken samples
are analysed by the State Laboratory; information on yearly fuel sale are collected and
provided by the Ministry of Transport; the Ministry of Environment, National Heritage
and Local Governments, responsible for drawing up and sending out the yearly report
on fuel quality monitoring in Ireland;
The scrutiny is conducted on the whole territory of the country. Ireland has just one
petroleum renery in Whitegate, County Cork. The entire production, upon the overall
fuel quality inspection by the renery operator prior to the shipment is transported via
land and sea route to recipients;
Samples of the fuel products are taken by the Internal Revenue Service once every
three months in fuel terminals and upon each lling up of fuel in the state fuel reserve
bank in Bantry. Additionally, Internal Revenue Service take samples from the lling
stations, cisterns and lorries and vans in order to avoid failure to pay the excise;
The monitoring system also includes inspections carried out by the Irish Petroleum
Industry Association, which takes its own samples in order to carry out tests from
23 parking places, and in the Whitegate renery in July/August and in December
each year.
76
The institution responsible for fuel quality monitoring and sales data collection required to draw up a report for European Commission is Czech Ministry of Industry
and Transport; an yearly report for the European Commission is drawn up on the basis
of the data provided by Czech Trade Inspection, which is responsible for scrutinizing
the fuel distribution outlets;
The entire territory of the country may be treated as a one region. As a result, the whole
monitoring system is based on the statistical C model, described in EN 14274:2003
standard as the model suitable for a small country without regional dierentiations.
According to this model, the Czech Trade Inspection should take samples from at
least 50 distribution sites (lling stations) for each petrol type, which accounts for
more than 10% of sales for a given petrol type (petrol, diesel fuel) in each scrutiny
period;
However, the Czech fuel quality monitoring system has been launched not only to
measure the parameters required under the European Union directives for the purposes of environmental protection, but also to protect customers; a national resolution
creates the obligation to test signicantly greater number of samples as much as 2000
in total.
Quality scrutiny of 95 lead-free petrol proved that 13 out of 245 taken fuel samples of this
type did not meet one or several quality parameters. The most often deviated parameter was the
degree of sulphur and octane number RON. Maximum contents of sulphur, which with regard
to the standard ought to amount to 50mg/kg have been exceeded in 6 samples being taken. The
highest noted value of this parameter was 276 mg/kg. It is quintuple excess of the standard. Noncompliance of the inspected RON octane number was also discovered in 6 out of all the samples
being taken. The lowest value was 87,8 units while the minimum acceptable value is 95.
Quality scrutiny of 98 lead-free petrol proved that the normative values have been deviated
from the inspected RON octane number and maximum contents of the hydrocarbon of the
aromatic type, correspondingly in 3rd and 1st sample. All in all 3 out of 157 taken samples of
this petrol did not meet the quality standards.
The scrutiny of diesel fuel samples taken in Poland within 5 parameters being tested proved
that only one of them (contents of the aromatic annular hydrocarbon) was met by all of the
scrutinized samples. The most often exceeded parameter (in 14 out of 204 inspected samples)
was sulphur contents. The highest noted value was 2734 mg/kg (while the acceptable standard
is 50 mg/kg), that is over quintuple excess of the standard. The other parameters, results of
which also exceeded acceptable values were the following: cetane number, density in the temperature of 15C and the distil o temperature 95% of fuel capacity (the highest result is 400C
while the standard establishes the maximum at the level of 360C).
The fuel quality scrutiny results indicate that occurrence of non-compliance of the inspected
parameters in Germany comparing to the standard are minor (lower than 1% of non-compliance). Ireland, Latvia and Austria have marginally worse results. Still slightly worse is the situation in the Czech Republic and Poland. This, however, is only a demonstrative ranking and is
not based on statistical results. To measure the statistical signicance of the non-compliances
found in the samples, it is necessary to know the number of samples that are non-compliant
with the standard, not the number of non-compliances in the tested samples. Some of the
many parameters that are measured are correlated (e.g. RON and MON). Consequently, often
more than one non-compliance in a sample was found. Unfortunately, not all of the reports
make it possible to nd out the number of non-compliant samples. In the case of the Czech
Republic it is not possible at all and in the case of Latvia at one point it was assumed that the
number of non-compliances equals the number of non-compliant samples (diesel fuel: 8 cases
of sulphur contents exceeding the norm and one case of too low cetane number).
Comparing the results of fuel quality inspections in Poland and 5 other EU Member States,
it may be said that in Poland non-compliances occur more often than in other countries (except
for the Czech Republic). The comparison with Austria does not provide statistically signicant
results, however, it may be presumed that had more samples been taken in Austria, the results
might have shown statistically signicant dierences less favourable for Poland.
In case of a Polish market it needs to be additionally stated that the fuel quality monitoring
and scrutiny system implemented in 2004 is ecient, which is proved by the scrutiny results
for 2006; among 712 samples (taken from the 712 chosen stations), 17 samples did not meet
the requirements, that account for 2,39%. The comparison presented below for the year 2005
speaks for itself:
Share of fuel samples not complying with the standard
The comparison of the scrutiny results between 2005 and 2006 for particular countries presented before may be a subject of the subsequent paper. Particular countries are obliged to
submit the scrutiny results for 2006 to the European Commission by the end of June 2007. Data
gathering will be possible only after this date.
80