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SURFACE EMITTANCE
BY L. P. HERRINGTON1
SYNOPSIS
Current interest in the measurement of infrared heat emission and absorption of structural materials is discussed. Distinctions between the emission characteristics of materials in the visible and heat radiation regions of
the spectrum are made. The terminology of radiation exchange is reviewed
from the standpoint of simplicity and usefulness in a standardized test suitable for use with structural materials as non-incandescent temperature radiators. Basic laws of radiation exchange are briefly reviewed. On the basis
of the foregoing considerations, the plan 'oi an apparatus construction for
surface ^mittance measurement in the 0 to 300 F range is described.
Visual Reflectivity
Reflectivity:
and Long
Infrared
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trolling the properties of opaqueness and none of the radiation falling on it. In the
surface roughness.
visual field, actual visible blackness is a
In regard to the term reflectivity and cue to this property, but for heat rays,
its correlate, absorptivity, it is pointed radio waves, or other regions of the
out that in the visual region, reflectivity electromagnetic spectrum, visual blackand absorptivity are, respectively, the ness is not necessarily correlated with
ratios of rates of reflection or absorption high absorbing ability. With this basic
of radiant energy by opaque polished information experimenters soon estabsurfaces hi relation to incident radiant lished a number of generalizations.
energy on the surface, and have subjecStefan and Boltzmann demonstrated
tive correlates in visual sensation. The that black bodies do not radiate heat in
numerically complementary nature of proportion to temperature but hi proporthe terms arises from the fact that all tion to the 4th power of absolute temperincident energy is either reflected or ab- ature. Equation 1 describes this fact:
sorbed. For practical comparisons of the
heat emission, reflection, or absorption
characteristics of a product, the terms
Sigma, the constant hi this equation
emittance, reflectance, and absorbance, which is required to compute g/j, the
can conveniently be used.
black body emission for a given temperAt the present time, the practical need ature, T, is the well known Stefanhi the product field seems to be for a Boltzmann universal constant hi which
rapid comparison method which affords
<r = 5.735 X 10~* erg per sec per sq cm
a good estimate of the relative heat
per deg K*
radiation emittance of a product surface
in relation to a black body standard. or
Before describing a method which ap1.37 X 10~u gm cal per sec per sq
pears to be convenient for this comparicm per deg K*
(2)
son, it will be useful to review briefly
some basic facts on radiation exchange.
To this fundamental relationship
Kirchoff added the deduction known as
Basic Laws of Radiation Exchange:
Kirchoff's law which may be given this
Early investigators noted that hot statement"... at any given temperature
bodies lost heat by essentially two a body which is a good absorber of
methods. Air surrounding the object radiation is also a correspondingly good
became heated, and this loss may be de- radiator of energy."
scribed as conduction-convection. In
One of the fundamental facts noted in.
addition, they noted a further flow of experimental work was that the waveheat to the environment which occurred length of the energy peak in the total
in air but did not depend on the presence radiation spectrum of a black body
of air. This flow of heat to surrounding shifted with its absolute temperature*
surfaces does not depend upon the pres- Theories of classical physics could not
ence of an intervening medium and a hot explain this highly important fact. We
object will lose heat by radiation to a owe to Planck and his quantum concooler one in a vacuum. It was also noted ception the famous radiation law which
that the radiant loss of an object was reconciled this difference. Planck's law
affected by its surface condition, and for black body radiation states that the
this led "to the concept of the black body. amount of energy radiated at waveA "black" body is one which reflects length X and included in the small
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ature than the outer junctions. Differences hi heat capacity of the junctions,
high conductivity between the junctions,
and the small heat capacity of the middle
junction causes a steady emf to be set up.
The instrument shown hi Fig. 3 was
constructed around this basic Moll unit.
This Moll base, essentially a brass
chamber 4 cm in diameter, 3 cm high,
containing the thermopile construction,
is not water jacketed. Since it was intended to use the pile in atmospheres
ranging from 0 to 120 F, a water-jacketed
cone was constructed. This is the outer
aluminum shell seen in Fig. 3. This shell
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has a wall thickness of 1.2 cm and overall diameter o 6.2 cm. A cone was
machined out of a solid cylinder to give a
collecting well of 3.8 cm tapering to 2 cm
at a depth of 7 cm. Directly behind this
2-cm opening the pile unit was mounted,
its metal walls seated in a machined
contact with the water-circulated aluminum shell. In the shell proper a watercirculating grid was drilled, providing a
0.8 cm water channel traversing the
length of the cylinder in ten channels
from entry to exit point.
FIG. 4.Apparatus Used for Surface Emittance Determinations on Various Material (description in text)..
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TECHNIQUES OF MEASUREMENT
Electromotive forces in relation to the
surface temperature of calibration plates
varying hi percentages of reflective area
from 0 to 100 per cent were determined
for a constant pile temperature. Utilizing
this primary calibration, the emf recorded from a surface of known temperature and unknown emittance could be
expressed as a simple ratio which provided a serviceable measure of the test
surface emittance relative to black body
emission. Calibration curves for the
particular pile used in these-studies could
be reproduced here, but as the procedure
is a common laboratory operation and
was not extended to any variety of
structural materials, it would not add
materially to the foregoing discussion.
Most of the measurements made with
this apparatus were on fabrics. The
majority of these were black body
radiators in the heat spectrum. Exceptions were metal-coated fabrics which
varied from 25 to 60 per cent of black
body emittance, dependent on the
method of metal film application, those
with evaporated films giving the lower
emittances.
CONCLUSIONS
The apparatus presented here constitutes our present experiencevin this field
and it is offered as a preliminary suggestion relative to emittance test methods.
The apparatus described, when operated
under optimum conditions, vvfos capable
of rather precise deterniuiations which
might or might not be co^icfered of importance in the testing of structural
materials. In the textilefieldthere was no
immediate interpretation of practical
significance for emittance differences of
the order of 5 per cent, hence the sensitivity of the Moll apparatus was not
really required. If grosser measurements
were acceptable, the expense of the above
equipment might be considerably re-
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REFERENCES
(1) C. E. A. Window and L. P. Harrington,
Temperature and Human Life, Princeton
University Press, Princeton, N. J. (1949).
(2) J. D. Hardy and T. W. Oppel, "Studies in
Temperature Sensation," Journal, Clinical
Investigation, Vol. 17, pp. 771-778 (1938).
(3) L. P. Herrington, and J. D. Hardy,
"Temperature and Humidity in Relation to
the Thermal Interchange Between the Human Body and the Environment," Chapter
13, Human Factors in Undersea Warfare,
National Research Council (1949).
DISCUSSION
MR. W. H. NiCHOLS.1Almost all of upon these pure sensations, but also
the literature that I have been able to reflect individual judgment as to whether
find specifically refers to the fact that the a pure sensation of coolness or heat is
human sensation of warmth or cold is preferable for a given activity. A convery difficult to determine and hi many stant slight rate of cooling is preferred by
cases impossible. However, what I many for clerical or mental work requirwanted to know is, whether Mr. Herring- ing several hours of sedentary posture.
ton knows of any processes or procedures The same individuals, in the same
that are being followed today to attempt posture for the same period, but unto determine the human sensation of occupied by a task, select an air temperature of maximum comfort which is 5 to
warmth or cold?
MR. L. P. HERRINGTON (author).The 8 F higher, and which involves a slight
bulk of human thermal sensation is ex- gradient of continued skin warming.
Research effort hi climatic hygiene is
perienced within a skin temperature
range from 70 to 95 F. Within this range directed primarily, toward determining
the thermal sensation experienced is the environments which are subjectively
rather exactly correlated with the rate most favorable for different classes of
and direction of thermal gradient changes activity;
MR. NICHOLS.Do you by any chance
within the first millimeter of skin thickness. Increases of temperature at this know whether or not encephalographs
tissue level, at a rate in excess of 0.0064 F have been used successfully or unsuccessper sec, stimulate the heat-sensitive fully hi that effort?
MR. HERRINGTON (author's closure).
thermal receptors located at this depth
hi the skin, ^lightly peripheral to these The response of brain wave patterns of
receptors are cold-sensitive receptors electrical activity to light, sound, heat,
which respond to rates of decrease hi and other sensory stimuli, is currently an
temperature of approximately the same object of research study. A marked
change in pattern occurs with many
order.
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Generalized perceptions of thermal sensory stimuli. Firm correlations be
comfort or discomfort are built in part tween pattern form and specific subjective reports relative to such factors as
thermal comfort have not yet beetf
i Chief Engineer, H. J. Rand & Associates, Inc.'
established.
Cleveland, Ohio
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