Reza Syandika

1206240013
3. a)

PV
PV =nRT R=
nT

F
V
A
FV
the units are
=
nT
AnT

kg . m. s2 . m3
kg . m2
= 2
m2 . mol . K
s . mol . K

b) R = 0.0821
n

mol

c) V =0.03 L

L . atm 103 m3 101325 N .m2

N .m
J

=8.31
=8.31
mol . K
1L
1 atm
K . mol
K . mol

5
and P = 0.96 10 Pa=0.96 atm

then, T =

PV
1
=P
=389.77 K
nR
Rn /V

d) PV= nRT
M gas =

n
P
=M =
V
RT

. The T is constant, so

M gas M tot
=
Pgas Ptot

M tot
4.5
3
Pgas =
M tot = M tot . If we assume that the system is in standard
Ptot
6
4

state, then the T is 298 K and the Mgas is

P gas
4.5 atm
=
=0.1839 M
RT 0.0821 298

e) A gas most likely to be ideal when its temperature is high and its pressure is
low, because in that state the intermolecular force is low. And least likely to be
ideal when its temperature is low and its pressure is high, because in that state
the intermolecular force is high.
f) Tank 1 : P=500torr, 50moles of water vapor, 30moles of water, and T=70C.

Tank 2 : P=400torr and T=70C. The V and the ratio of moles water vapor to
moles water of these two tanks are the same.
Tank 3 : V and T are the same as first two tanks.
The volume of the water can be neglected because it is too small in compare to
the volume of the tank (i.e. the volume of 30moles of water is obviously too
small to the volume of the 50moles of water vapor )
Then the pressure of the third tank : if V and T are constant, then the total
pressure is just the sum of the pressure in the first two tanks, so P3 = 500torr +
400torr = 900torr. It is beyond the capacity of the tank, so the tank will blow up.

1. a) Percent of water in the original solution is

mass of water
1200 g100 g
100 =
100 =91.67
mass of solution
1200 g

b) Water evaporated = 1200g 100g = 1100g = 1.1L (=1kg/L). The amount of

the remains water is : water evaporated water added back to the salt = 1.1L
0.1L = 1.0L
c) The osmotic pressure of the human body liquid is about 20-25mmHg,
whereas the osmotic pressure of the salt solution is about 57760mmHg and
therefore so hypertonic to the human body liquid and therefore it is not safety to
drink.
2. a) Amount of slabs the company can make in a day is :
3 trucks 3000 kg limestone
1 slab
30 miles
1 route
24 h ours
slabs

=81000
1 route
1trucks
2 kg limestone 1 h our 2 20 miles
1 day
day

b) The plant become more efficient when the distance of the quarry and the plant
is enclosed and the capacity of the trucks is enlarged.

Graph of the slabs the company can make as a function of distance from the
quarry:
350000
300000
250000
200000
150000
100000
50000
0
4

10

12

14

16

18

20

22

Graph of the slabs the company can make as a function of capacity of the trucks:
150000
100000
50000
0
2500 3000 3500 4000 4500 5000 5500

If the amount of truck and average speed of trucks are increased, the company
can simply moving as close to the quarry as possible and using the largest trucks
possible.
3. = 1.5
v=5
mass flow rate = 0.500/60 (these units are in SI)
The volumetric flowrate is : Q =

mass flow rate

0.500 kg
60 s
1.5 kg m3

1 3 1
= 180 m s

The area of the pipe is : A =

1 2
2
m = r
900

Q
v

1 2
m
900

so the radius of the pipe is : r =

1
900

1.88cm

4. r1 = 0.5cm
r2 = 0.2cm
1
v1 = 0.5m s

A1v1 = A2v2 v2 =

A1v 1
A2

r 21 v 1
s1
2
=
3.125m
r2

2
5. a) 10000mol/s = 1.8 10 kg /s (assume that all of the rivers fluid is water)

m3
8
500000 s =5 10 kg / s . So the mass flow rate of the river downstream of the
2
8
intersection if we assume steady state is (1.8 10 +5 10 kg /s= 500,000,180

kg/s
b) The steady state assumption in this situation is very low feasible because the
flow rate of the larger river is very high, resulting the high value of Reynolds
number, resulting the flow of that river tend to the turbulent flow. And the
probability that the flowrates are actually constant is very improbable associated to
the low feasibility of the steady state assumption.