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Butane
LSR Naphtha
HSR Naphtha
Reformate
FCC
Quantity
x
5000
4000
6000
7000
RVP, psi
52
11.1
1
2.8
13.9
8.40640214
xi
0.227
0.182
0.273
0.318
BI(RVP)
139.638
20.261
1.000
3.622
26.839
xi*BI(RVP)
4.605
0.182
0.988
8.540
14.314
17.7827941
22000
8.40640214
0.02767814 626.252544
Components
A
B
C
BPD
2500
3750
5000
SG
0.8
0.85
0.9
FP, oF
xi(fraction)
BI(FPi)
120
0.2064516129 319.996772
100
0.3290322581 728.242202
150
0.464516129 105.977821
117.482565
If the
resulted temperature is lower than 130
Components
A
B
C
D
BPD
2500
3750
5000
SG
0.8
0.85
0.9
0.95
FP, oF
120
100
150
220
130
Mass Flow
2000
3187.5
4500
X
BI(FPi)
319.996772
728.242202
105.977821
12.3472881
217.979347
%mass D =
0.39971984
X(Mass Flow) = 6450.79777
X(Volume)= 6790.31344
xi*BI(FPi)
66.0638496
239.615176
49.228407
354.907433
Riazi Method
Components
Catalytic cracked gas oil
Straight run gas oil
Light vacuum gas oil
Heavy vacuum gas oil
BPD
2000
3000
5000
1000
BPD
2000
3000
5000
1000
Pour Point, oC
-15
-3
42
45
Pour Point, oR
464.67
486.27
567.27
572.67
29.85
545.39
Pour Point, oC
-15
-3
42
45
Pour Point, oK
258.15
270.15
315.15
318.15
29.85
303.00
x(%vol)
0.182
0.273
0.455
0.091
x(%vol)
0.182
0.273
0.455
0.091
BI(PPi)
225.32
397.61
2728.08
3071.07
xi*BI(PPi)
40.97
108.44
1240.04
279.19
1668.63
BI(PPi)
1.40735E+030
2.48349E+030
1.70399E+031
1.91822E+031
xi*BI(PPi)
2.5588E+029
6.7732E+029
7.7454E+030
1.7438E+030
1.0422E+031
Components
A
B
C
BPD
1000
2000
3000
Cloud Point, oF
-5
5
10
6.37
CP, oK
BI(CPi)
252.594444 1.118087750E+048
258.15 1.727597583E+048
260.927778 2.139963231E+048
258.90986
xi
0.167
0.333
0.500
xi*BI(CPi)
1.86348E+047
5.75866E+047
1.06998E+048
1.83220E+048
Components
Light Diesel
Kerosene
LCO
BPD
4000
3000
3000
Aniline Point, oC
71.0
60.7
36.8
58.3
xi, %vol
0.4
0.3
0.3
BI(APi)
1.792
1.675
1.431
xi*BIi
0.717
0.502
0.429
1.649
Aniline Point, oC
50
60
55
54.6
SGBlend =
SG
0.75
0.8
0.85
0.795
23.88
xi, %vol
0.4
0.3
0.3
BI(APi)
1.561
1.667
1.613
xi*BI(APi)
0.624
0.500
0.484
1.609
xi*SGi
0.3
0.24
0.255
Components
Fraction - 1
Fraction - 2
Fraction - 3
BPD
2000
3000
4000
Viscosity, cSt
75
100
200
125.796
xi, %vol
0.222
0.333
0.444
BI(vis)
0.385
0.400
0.434
xi*BI(vis)
0.085
0.133
0.193
0.412
Calculate the RON by linear mixing of octane numbers and by linear mixing of octane number indices
Quantity
RON
Components
6000
97.3
Alkylate C4
4000
67.2
Coker Gasoline
5000
83.2
FCC Gasoline
Linear mixing of octane numbers
Quantity
Components
6000
Alkylate C4
4000
Coker Gasoline
5000
FCC Gasoline
RON
97.3
67.2
83.2
xi, %vol
0.400
0.267
0.333
RON =
xi*RONi
38.92
17.92
27.73
84.57
88.08
xi, %vol
0.400
0.267
0.333
BI(RONi)
67.660459267
53.690805179
58.780019968
xi*BI(RONi)
27.064
14.318
19.593
60.975
60.975
It is required to produce gasoline with a RON of 95 from the blending the above product with MTBE.
Calculate the amount of the oxygenate MTBE with a RON of 115 to be added in order to adjust the blend RON to 95.
Quantity
RON
xi, %vol
BI(RONi)
xi*BI(RONi)
Components
6000
97.3
0.400
67.660459267
27.064
Alkylate C4
4000
67.2
0.267
53.690805179
14.318
Coker Gasoline
5000
83.2
0.333
58.780019968
19.593
FCC Gasoline
X
115
MTBE
BI(RON MTBE) =
BI(RON Product) =
126.772825
65.558875
number indices
TPSD
43
489
1291
883
BPSD
452
4690
9820
7765
Characteristics
RON
Density, kg/l
98.7
0.593
86.4
0.656
102
0.827
91.7
0.715
91.59
BPSD
0
32775
9700
28307
Density
0.776
0.811
0.830
0.860
Sulfur, ppm wt
50
200
290
50
BPSD
2387
232
Density
0.83
0.86
Sulphur, ppm
290
50
0.833
Riazi (2005)
Hu and Burn 1970
RVP, kPa
441
88
18
51
xi, %vol
0.020
0.206
0.432
0.342
xi, %mass
0.016
0.181
0.477
0.326
BI(RON)
71.033
105.609
72.971
82.628
57.517
Pour Point, oC
-58
-3
20
-19
Cetane Index
49
63
64
42
xi,%mass
0.000
0.451
0.137
0.413
xi,%vol
0.000
0.463
0.137
0.400
-2.36
Cetane Additive
54.74
Pour Point, oC
20
-19
Viscosity, cSt
5.8
2
18.2
18.4
5.2
xi,%mass
0.908
0.092
xi, %vol
0.911
0.089
xi(vol)*BIi
1.413
21.794
31.530
28.231
RON(additive)
1.963
17.830
44.073
31.331
82.967
82.967
95.20
Density*xi
0.000
0.376
0.114
0.344
Sulphur*xi
0.000
92.608
39.742
19.996
0.833
152.346
BI(PP)
6.89642E+030
1.15778E+030
Pour Point, oR
527.67
457.47
6.38807E+030
524.783
Density
0.012
0.135
0.357
0.244
RVP, psi
63.962
12.763
2.611
7.397
BI(RVP)
3.597
4.978
1.434
4.168
0.749
8.342
14.178
BI(PP)
1.443001825E+029
2.483488472E+030
6.896420458E+030
1.157781019E+030
2.558064486E+030
BI(PPi)
1104.114
185.360
BI(vi)
0.203
0.091
0.193
1022.728
89.38
79.47
9.91
941.74
824.67
28.11
1852.38
34.44
1821.11
xi, vol
0.41
0.04
0.32
0.09
0.14
RON
97.8
70.4
92.6
96.8
58
92.69
MON
87
65.1
80.2
82.3
58
%Olefin
1.4
32.5
53.3
100
1.3
%Aromatic
63.1
9.8
23.9
0
3.8
Sensitive
10.8
5.3
12.4
14.5
0
BI(RONi)
68.164
54.529
63.706
67.174
51.516
63.772
63.772
RS(RONxSensitive)
1056.24
373.12
1148.24
1403.6
0
MS(MONxSensitive)
939.6
345.03
994.48
1193.35
0
%O^2
1.96
1056.25
2840.89
10000
1.69
%A^2
3981.61
96.04
571.21
0
14.44
DATA
DATA
Given Data
Calculated Data
Barrels
RVP, psi
Component
3000
12.1
LSR Gasoline
2000
15.5
Hydrocracker Gasoline
6013.5
4.8
FCC Gasoline
638.5
51.6
n-Butane
Calculate the amount of FCC Gasoline and n-Butane that must be added to the blend to produce a gasoline of
RVPBlend(BI) =
VisBlend(BI) =
22.335
-0.103
The blend is performed for LSR, Hydrocracker, FCC Gasoline and n-Butane
Calculate the amount of each component that must be added to produce gasoline blend of maximum octane nu
Problem 2:
Barrels
RVP, psi
Component
X1
12.1
LSR Gasoline
X2
15.5
Hydrocracker Gasoline
X3
4.8
FCC Gasoline
X4
51.6
n-Butane
XT
12
Blend
The maximum blend storage capacity is 15000 barrels
Redo the calculation if the available amount of FCC gasoline is 6000 barrels.
Component
LSR Gasoline
Hydrocracker Gasoline
FCC Gasoline
n-Butane
Storage Capacity
Blend
Barrels
0
0
4257
559
4816
RVP, psi
12.1
15.5
4.8
51.6
12
X1 + X2 + X3 + X4 <= 15000
X1, X2, X3, X4 > = 0
MAX(RON)
RVP = 12 pis
Viscosity, cSt
RVP (BI)
Vis(BI)
0.2886
22.567
-0.219
0.4140
30.755
-0.146
0.8607
7.105
-0.022
0.3500
138.297
-0.179
d to the blend to produce a gasoline of 12 psi RVP and 0.525 cSt viscosity.
22.335
-0.103
MON
81
85.5
96
92
RON
91
89.5
97
93
MON
81
85.5
96
92
Max
96.6
BI(RVP)
22.567
30.755
7.105
138.297
22.335
22.335
xi*RVP(BI)
5.810
5.279
3.667
7.579
BI(RON)
62.638
61.741
67.367
63.993
MAX
66.975
66.975
xi*RVP(BI)
-0.056
-0.025
-0.011
-0.010