Professional Documents
Culture Documents
Food Chemistry
journal homepage: www.elsevier.com/locate/foodchem
a r t i c l e
i n f o
Article history:
Received 18 October 2012
Received in revised form 11 March 2013
Accepted 30 April 2013
Available online 24 May 2013
Keywords:
Red- and blue-eshed potato,
Glycoalkaloids
Technological factors
Dehydrated potatoes
a b s t r a c t
The aim of this study was to determine the effect of different temperatures of blanching and pre-drying
used in the laboratory production of dried potato dice on the content of glycoalkaloids in red and blue
eshed potato varieties.
Studied potatoes of coloured eshed varieties were characterised by a low glycoalkaloids content at
5.47 mg 100 g 1. The production of dehydrated potato dice inuenced on the decrease in glycoalkaloids
content in potato products. The majority of these compounds were removed during the peeling (70%) and
blanching process (29%). Potato dice blanched at the highest temperature (85 C) and pre-dried at 120 C
was characterised by the lowest quantity of glycoalkaloids content, whereas the highest content of these
compounds was found in dice blanched potato at the lowest temperature (65 C) and pre-dried at 120 C.
The blanching process much inuenced on the decrease in glycoalkaloids content than pre-drying
process.
2013 Elsevier Ltd. All rights reserved.
1. Introduction
Over the last few years, red- and blue-eshed potatoes and related products have appeared in the retail trade in some European
countries and the U.S. market. They are quite popular in the countries of southern Africa, where they originate from (Mulinacci et al.,
2008), while in Europe the varieties are an attractive novelty and
an interesting alternative to the traditional white or creamcoloured potato esh. With the ever-increasing consumption of potato products, such as French fries, chips and dehydrated potatoes,
the introduction of new products with coloured esh should interest consumers looking for original snacks. In addition, the coloureshed potatoes are a good source of phenolic compounds, which
play an important role in foods, especially for their sensory attributes. Phenols give a specic acrid and bitter taste, and are responsible for colour and appearance, and may result in sedimentation
and turbidity, particularly in juices, wine or soft drinks (Alasalvar,
Grigor, Zhang, Quantick, & Shahidi, 2001).
The introduction of new varieties of potatoes for consumption
or food processing requires the checking of not only substances
of pro-nutritional functioning on the human body, but should
examine the content of toxic compounds, such as glycoalkaloids.
Potatoes contain two glycoalkaloids, a-chaconine (ca. 60%) and
Corresponding author. Tel.: +48 71 3205239; fax: +48 71 3205221.
E-mail addresses: elzbieta.rytel@wnoz.up.wroc.pl, elzbieta.rytel@up.wroc.pl (E.
Rytel).
0308-8146/$ - see front matter 2013 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.foodchem.2013.04.131
2496
compounds, and in production practice it is most desirable to preserve the maximum amount of nutrients and minimise the concentrations of anti-nutritional compounds or toxins. The quality of the
nal product depends not only on a properly performed manufacturing process, but also on the use of appropriate materials with
interesting appearance. The inuence on the quality of the ready
product is not only dependent on the production process, but also
the appropriately selected of raw material with interesting properties of consumption.
Knowledge instead of learning about the factors that contribute
to the loss of toxic compounds is a signicant issue, especially in
the introduction of new varieties in production. Accordingly, the
aim of this study was to determine the effect of different temperatures of blanching and pre-drying used in the laboratory production of dried potato dice on the content of glycoalkaloids in redand blue-eshed potato varieties.
Unpeeled potato
peel
Pre-drying potato
120 C/1 h
140 C/1 h
160 C/1 h
Peel
Dehydrated dice
50 C/12 h
(moisture 10-11%)
Fig. 2. The scheme of the dehydrated dice processing, pre-drying at different
temperatures.
(rm Edwards). These prepared samples and potato dice were then
dried and ground using an electric grinder (rm Retsch). Afterwards, the content of glycoalkaloids (a-chaconine and a-solanine)
were determined in the samples.
2.3. The concentrations of a-solanine and a-chaconine
2.3.1. Apparatus
A high-pressure liquid chromatography HPLC (pro Star) was
used (Varian, Walnut Creek, CA, USA). The HLPC was equipped with
a UV detector 310 type, Microsorb NH2 analytical column
(25 46 cm LD) (Rainin Instrument, Woburn, MA, USA), and a software rm Varian Chromatography System for monitoring the
chromatograph.
2.3.2. Conditions of glycoalkaloids separation
A mixture of tetrahydrofuran (Merck, Germany), acetonitrile
and water 50:20:30 + KH2PO4 (1.02 g) per 1 l was used as an eluent. The process was carried out at a temperature of 35 C, with
a speed of ow of 2 cm3 min 1 and pressure of 11.2 MPa, applying
a light wavelength of 208 nm.
65 C/5min
75 C/5min
85 C/5min
Pre-drying potato
(120 C/ 1 h)
Dehydrated dice
50 C/12 h
(moisture 10-11%)
2497
Table 1
Total glycoalkaloids content (mg100 g
Analysed compounds
Red-esh potatoes
Peel
a-chaconine
a-solanine
Unpeeled potatoes
a-chaconine
a-solanine
TGA
TGA
Blue-esh potatoes
Rote Emma
Rosemarie
Mean
Blaue Annelise
Mean
10.12a 0.11
5.21a 0.09
15.33a 0.10
3.74bc 0.06
1.74b 0.03
5.48c 0.07
12.20c 0.19
7.17d 0.07
19.37d 0.08
3.41a 0.04
1.63a 0.03
5.04a 0.06
11.16b 0.18
6.19c 0.02
17.35b 0.05
3.58b 0.10
1.69ab 0.04
5.26b 0.05
15.66e 0.09
8.79f 0.02
24.45f 0.11
3.65b 0.05
1.76b 0.04
5.41c 0.04
11.96c 0.10
6.09b 0.03
18.05c 0.06
3.85c 0.05
2.09d 0.03
5.94d 0.06
13.81d 0.08
7.44e 0.04
21.25e 0.10
3.75bc 0.04
1.93c 0.03
5.68e 0.07
2498
Table 2
Total glycoalkaloids content (mg 100 g
Technological factors
Unpeeled potatoes
Peeld potatoes
Potatoes after cutting
Rote Emma
Rosemarie
Mean
Blaue Annelise
Mean
25.32b 0.28
6.55a 0.05
6.04a 0.08
23.49c 0.13
5.48b 0.06
4.99a 0.05
24.41c 0.12
6.02b 0.07
5.52a 0.09
21.39c 0.12
7.17b 0.03
6.19a 0.08
29.94c 0.09
8.28b 0.02
7.55a 0.05
25.67c 0.10
7.73b 0.08
6.87a 0.03
a,b,c
Table 3
TGA content (mg 100 g
Technological factors
Red-esh potato
Blanching
65 C/5 min
75 C/5 min
85 C/5 min
After blanching in 65 C
After blanching in 75 C
After blanching in 85 C
Blue-esh potato
Rote Emma
Rosemarie
Blaue Annelise
5.52e 0.06
5.08d 0.02
3.99b 0.08
5.47e 0.03
4.93c 0.08
3.30a 0.02
4.19d 0.06
3.14bc 0.06
2.77b 0.02
3.40c 0.05
3.14bc 0.07
2.54a 0.06
5.37e 0.04
4.91d 0.09
3.66b 0.04
4.82d 0.07
4.42c 0.09
3.24a 0.06
5.40f 0.03
5.04d 0.08
3.73b 0.06
5.19e 0.04
4.73c 0.07
3.31a 0.05
a,b,c,d,e,f
7
temp. of blanching in 65C/pre-drying in 120C
LSD=0.23
5.72
5.05
5
LSD=0.13
4.43
4.15
4.09
4
E
3.5
b
3.12
3.74
b
2.67
a
A
0
red - fleshed
blue - fleshed
Fig. 3. TGA content (mg 100 g 1) in dehydrated dice potato. (AE) Indicate signicant differences between red-eshed potatoes (Duncan test, p < 0.05). (ad) Indicate
signicant differences between blue-eshed potatoes (Duncan test, p < 0.05).
cutting stage. Raising the temperature by 10 C resulted in a further signicant TGA loss, by an average of 26% (compared to potatoes after cutting). In the blanched red-eshed Rosemarie potatoes,
TGA decreased by 37% compared to samples after cutting. The
highest TGA decrease was observed after blanching at the highest
temperature (85 C), on average by 42% in relation to those of potato after cutting.
The aim of the study was mainly the improvement the colour of
ready products, and temperature and time of this process depended on the quality of raw material (reducing sugars content)
and degree of granulation. Temperature and time of hot water or
steam treatment on the raw material should be kept to a minimum, due to unnecessary loss of pro-healthy compounds, like C
vitamin. The potato dice is generally blanched at 75 C because this
is enough temperature to deactivate enzymes taking part in darkening process of potato pulp and improve the colour of ready product. Whereas treatment time is selected depending on the degree
of granulation the raw material and its destiny.
Usually blanching is performed at 75 C and the duration is selected depending on the neness of the material and its intended
use. Blanching of 10 10 mm dice at 85 C did not adversely affect
the quality of the raw material. After 5 min blanching, the dices
maintained their shape and were not disintegrating.
Maintaining the proper shape and texture of raw material after
blanching depends on the chemical composition of material used.
Examined varieties were characterised by proper content of dry
matter and starch, recommended for dried products production,
on average 2025% and 1519%, respectively.
2499
d.m.) in potato after blanching in 75 C/5 min and pre-drying 1 h in different temperature.
Pre-drying temperature
120 C
140 C
160 C
Red-esh potato
Blue-esh potato
Rote Emma
Rosemarie
Blaue Annelise
4.93c 0.08
4.86bc 0.04
4.78a 0.07
3.14c 0.07
2.82b 0.03
2.35a 0.05
4.42a 0.09
4.80b 0.07
4.68b 0.08
4.73c 0.07
3.72b 0.07
3.34a 0.03
a,b,c
2500
in pigmented potatoes (Solanum tuberosum L.) and correlations with variety and
geographical origin. Food Chemistry, 125, 750759.
_
c, Nauka, Technologia,
Leszczynski, W. (2000). The quality of table potato. Zywnos
Jakosc, 4(25), 527. 7, (in Polish).
Machado, R. M. D., Toledo, M. C. F., & Garcia, L. C. (2007). Effect of light and
temperature on the formation of glycoalkaloids in potato tubers. Food Control,
18, 503508.
Mder, J., Harshadrai, R., & Kroh, L. W. (2009). Composition of phenolic compounds
and glycoalklaoids a-solanine and a-chaconine during commercial potato
processing. Journal of Agricultural and Food Chemistry, 57, 62926297.
Mulinacci, N., Ieri, F., Giaccherini, C., Innocenti, M., Andrenelli, L., Canova, J., et al.
(2008). Effect of cooking on the anthocyanins, phenolic acids, glycoalkaloids,
and resistant starch content in two pigmented cultivars of Solanum tuberosum L.
Journal of Agricultural and Food Chemistry, 56, 1183011837.
Onyeneho, S. N., & Hettiarachchy, N. S. (1993). Antioxidant activity, fatty-acids and
phenolic-acids compositions of potato peels. Journal of the Science of Food and
Agriculture, 62, 345350.
Ostry, V., Ruprich, J., & Skarkova, J. (2010). Glycoalkaloids in potato tubers: The
effect of peeling and cooking in salted water. Acta Alimentaria, 39(2), 130135.
Peksa, A., Goubowska, G., Anioowski, K., Lisinska, G., & Rytel, E. (2006). Changes of
glycoalkoaloids and nitrate contents in potatoes during chips processing. Food
Chemistry, 97, 151156.
Peksa, A., Goubowska, G., Rytel, E., Lisinska, G., & Anioowski, K. (2002). Inuence of
harvest date on glycoalkaloid contents of three potato varieties. Food Chemistry,
78, 313317.