Professional Documents
Culture Documents
R.nandini 1, K. Mythili2
1 Research Scholar, Department Of Civil Engineering, Aurora's Scientific Technological & Research Academy, Hyderabad, India
2 Associate Professor, Department Of Civil Engineering, Aurora's Scientific Technological & Research Academy,Hyderabad, India
Abstract
The environment in some concrete structures can become very acidic due to formation of sulphuric acid converted from hydrogen sulphide by bacterial action. Significant deteriation of concrete in such harsh environments has
been reported world wide. Deteriotation of sewer system may result in serious problem such as the loss of ability to
transport sewerage, contamaniation of ground and ground water, excessive ground settelements.
Very high costs are involved with the repair of deteriorated concrete structures. In the USA, sulphuric acid is
responsible for billoins of dollars of damage to concrete waste water collection and treatment systems. In the state of
south Australia alone an estimated budjet for maintaining the existing waste water infra structure is A $ 48 million
per anum. Although it has been reported that some new materials can be more acid resistant such as concretes using
melted sulphur as the binder or high proportions of polymer modified binders, these materials are too expansive for most
practical applications. Therefore, the research into improvement of acid resistance of normal concretes is still attractive.
Over the past 20 years the use supplementary cementitious materials (SCM) in concrete has become very common due to their technological, economical and environmental benefits. The use of SCM such as Micro silica and fly ash
in concretes has been found to improve the resistance of concrete sulphuric acid attack because of the reduced presence of calcium hydroxide, which is most vunerable to acid attack. Using Micro silica in binary cement system as partial
replacement of ordinary portland cement was found to be effective in reduciton of acid attack.
In the present investigation, 5% Micro Silica and 15 % Fly Ash is added by the weight of the cement as additional ingredients in concrete with different water/ binder ratios 0.55, 0.45 and 0.35 of Ordinary concrete and Ternary concrete mix
. The behaviour of this Ordinary concrete and Ternary concrete mix studied for durablity properties like % Weight loss,
% Loss of Compressive strength and Durability Factors by the immersion concrete specimens in 5% H2SO4 and 5 % HCl
solution for 28 days,90 days and 180 days.
*Corresponding Author:
R.nandini,
INTRODUCTION
GENERAL
Concrete is one of the most extensively use construction materials in the world, with about two
billion tons of utilization worldwide each year. It
is attractive in many applications because it offers
considerable strength at a relatively low cost. Concrete can generally be produced of locally available
constituents, can be cast in to wide variety of structural configurations, and requires minimal maintenance during service. However, environmental concerns, stemming from high-energy expense and CO2
emission associated with cement manufacture, have
brought pressures to reduce consumption through
the use of supplementary materials.
In general concrete is said to be a very durable one.
Very high costs are involved with the repair of deteriorated concrete structures. In the USA, sulphuric
acid is responsible for billoins of dollars of damage
to concrete waste water collection and treatment
systems. In the state of south Australia alone an
estimated budjet for maintaining the existing waste
water infra structure is A $ 48 million per anum.
Although it has been reported that some new materials can be more acid resistant such as concretes
using melted sulphur as the binder or high proportions of polymer modified binders, these materials
are too expansive for most practical applications.
Therefore, the research into improvement of acid resistance of normal concretes is still attractive.
Over the past 20 years the use supplementary cementitious materials (SCM) in concrete has become
very common due to their technological, economical
and environmental benefits. The use of SCM such
as Micro silica and fly ash in concretes has been
found to improve the resistance of concrete sulphuric acid attack because of the reduced presence of
calcium hydroxide, which is most vunerable to acid
attack. Using Micro silica in binary cement system
as partial replacement of ordinary portland cement
was found to be effective in reduciton of acid attack.
In the present investigation, 5% Micro Silica and 15
% Fly Ash is added by the weight of the cement as
additional ingredients in concrete with different water/ binder ratios 0.55, 0.45 and 0.35 of Ordinary
concrete and Ternary concrete mix . The behaviour
of this Ordinary concrete and Ternary concrete mix
studied for durablity properties like % Weight loss,
% Loss of Compressive strength and Durability Factors by the immersion concrete specimens in 5%
H2SO4 and 5 % HCl solution for 28 days,90 days
and 180 days.
EXPERMENTAL INVESTIGATION
Introduction:
The present investigations are aimed at to study
durability of Ternary Blended concrete, having 5%
Silica fume and 15% Fly Ash by weight of cement
with different W/B ratios 0.55, 0.45and 0.35. In the
laboratory after the age of 28 Days, 90 Days and
180 Days.
MATERIALS
Cement
Locally available 53 grade of Ordinary Portland Cement (Ultra Tech Brand.) confirming to IS: 12269
was used in the investigations. Table 4.1 gives the
physical properties of OPC used in the present investigation and they conform to IS specifications.
71
Coarse Aggregates:
Machine crushed angular granite metal of 20mm
nominal size from the local source is used as coarse
aggregate. It is free from impurities such as dust,
clay particles and organic matter etc. The course
aggregate is also tested for its various properties.
The specific gravity, bulk density and fineness
modules of coarse aggregate are found to be 2.70,
1560 kg/cum and 7.1 respectively.
Water:
Locally available water used for mixing and curing
which is potable, shall be clean and free from
injurious amounts of oils, acids, alkalis, salts,
sugar, organic materials or other substances that
may be deleterious to concrete or steel.
72
Superplasticizer:
Superplasticizer CONPLAST 430 of Fosroc Chemical
India Ltd. Was used as water reducing admixture. It
increases workability
Mix Proportion in the Laboratory:
The proportion used in preparation of mix is
calculated as per BIS Method.
ii.
iii.
iv.
Fine Aggregate
0.98=
[178+
(323.6/2.95)+
(1/0.42)*(F.A/2.53)]*1/100=736 Kgs.
Coarse Aggregate
0.98= [178+ (323.6/2.95)+ (1/1-0.42)*(C.A/12.2.7)]*1/100= 1084 Kgs.
v.
S.No.
1
2
3
4
5
Property
Normal Consistency
Initial Setting time
Final Setting time
Specific Gravity of Cement
Compressive Strength
(at 28 days)
Test Results
32%
90 min
250 min
2.95
56.3 N/mm2
Fine Aggregate:
Physical Properties:
S.No
1
2
3
Property
Fineness
modulus
Specific gravity
Bulk density
a).Loose
b). Compacted
Test Results
2.48
2.53
1600 kg/m3
1720 kg/m3
Mix Design:
S.No.
I.S
Sieve
Size
Wt.
Retained
(gms.)
Cumulative
Wt. Retained
(gms.)
Cumulative %
of wt
Retained
% Passing
4.75
mm
0.61
0.61
0.061
99.939
2.36
mm
2.6
3.21
0.321
99.679
1.18
mm
40
43.21
4.32
95.68
600
463
506.21
50.62
49.38
300
432
938.21
93.82
6.18
150
59.8
998.01
99.8
0.2
<150
1000
100
Total
1000
--
248.94
--
Fineness modulus
Ternary
Blended
Concrete
Mixes
(5%Micro
Silica-15%
Fly ash)
= 248.94/100 = 2.48
W/B
Type of Concrete
Coarse Aggregate:
Physical Properties
Property
Fineness modulus
Specific gravity
Bulk density
a).Loose
b). Dense
4
5
Flakiness index
Elongation index
Test Results
7.17
2.70
Ternary
Blended
Concrete
1390 kg/m3
1560 kg/m3
2.41%
12.80%
0.45
IS
Sieves
size
Wt. Retained
(gms.)
Cumulative wt.
Retained
(gms)
Cumulative % of
wt. Retained
% Passing
40 mm
100
20 mm
915
915
18.30
100
10 mm
3994
4909
99.09
81.70
4.75mm
45
4954
100
0.92
2.36
mm
5000
100
1.18
mm
5000
100
600
5000
100
300
5000
100
150
5000
100
Total
5000
Fineness modulus
717.8/100 = 7.17
Coarse
Ordinary
Concrete
100
100
0.35
100
0.55
80
15
0.45
80
15
0.35
80
15
5% H2SO4 Solution
65.80
45.37
68.01
47.84
33.08
71.89
51.08
36.06
Ternary
Blended
Concrete
0.35
aggregate
Ordinary
Concrete
74.35
53.34
75.89
56.80
43.92
Ternary
Blended
Concrete
% of Fly ash
0.55
41.41
77.80
59.45
46.67
5% HCl Solution
28
180
D.F
10.23
Sr
90.62
28
180
D.F
14.03
90
180
22.68
80.40
90
180
40.20
180
180
31.70
74.89
180
180
74.89
28
180
10.57
91.61
28
180
14.25
90
180
23.92
85.99
90
180
42.99
180
180
33.08
77.39
180
180
77.39
28
180
11.18
92.44
28
180
14.37
90
180
25.54
87.58
90
180
43.79
180
180
36.06
80.09
180
180
80.09
28
180
11.56
93.58
28
180
14.55
90
180
26.67
88.10
90
180
44.05
180
180
41.41
81.75
180
180
81.75
28
180
11.80
94.66
28
180
14.72
90
180
28.40
89.50
90
180
44.75
180
180
43.92
83.77
180
180
83.77
28
180
12.10
95.49
28
180
14.85
90
180
29.72
91.45
90
180
45.72
180
180
46.67
84.84
180
180
84.84
717.38
of
Ordinary
Concrete
% of Micro
Silica
0.45
31.70
% of Cement
Sr
0.55
S.No
1
2
3
W/C
GRAPHS
76
77
5% H2 SO4 solution
Table 4.12 gives Durability Factors of W/C ratios
0.55, 0.45 and 0.35 of ordinary concrete after
immersing in 5% H2 SO4 solution. These values
are observed to be ranges from 10.23 to 11.80 for 28
days, 22.68 to 28.4 for 90 days, and 31.70 to 43.92
for 180 days respectively.
Table 4.12 gives the percentage Loss of Compressive
strength of W/B ratios 0.55, 0.45 and 0.35 of
Ternary Blended Concrete after immersing in 5%
H2 SO4 solution. These values are observed to
be ranges from 10.57 to 12.10 for 28 days, 23.92
to 29.72 for 90 days, 33.08 to 46.67 for 180 days
respectively.
Durability Factors of Ordinary and Ternary
Blended concrete specimens after immersing in
5% HCl solution
Table 4.12 gives Durability Factors of W/C ratios
0.55, 0.45 and 0.35 of ordinary concrete after
immersing in 5% HCl solution. These values are
observed to be ranges from 14.03 to 14.72 for 28
days, 40.20 to 44.75 for 90 days, and 74.89 to 83.77
for 180 days respectively.
Table 4.12 gives the percentage Loss of Compressive
strength of various W/B ratios 0.55, 0.45 and 0.35
of Ternary Blended Concrete after immersing in
5% HCl solution. These values are observed to
be ranges from 14.25 to 14.85 for 28 days, 42.99
to 45.72 for 90 days, 77.39 to 84.84 for 180 days
respectively.
CONCLUSIONS:
The Following Conclusions are drawn from the
Experimental Investigation in present Thesis:
1.
From the visual observation of test specimens
immersed in 5% H2SO4 solution for 28 days, 90
days and 180 days, the specimens has undergone
deterioration. Which are viewed in photograph
enclosed.
2.
The investigation shows that percentage
of weight loss of specimens increased as days of
immersion in 5% H2SO4 is increased for Ordinary
concrete and Ternary concrete for all W/C ratios. In
case of Ordinary concrete for 0.55 Water/ Cement
ratio the percentage of weight loss is 4.87 at 28 days
immersion and it is 17.16 for 180 days immersion.
In case of Ternary Blended concrete for 0.55 Water/
Binder ratio the percentage of weight loss is 3.43
at 28 days immersion and it is 15.21 for 180 days
immersion.
3.
From the visual observation of test specimens
immersed in 5% HCl solution for 28 days, 90 days
and 180 days, the specimens has undergone
deterioration.
78
4.
The investigation shows that percentage
of weight loss of specimens increased as days of
immersion in 5% HCl is increased for Ordinary
concrete and Ternary Blended concrete for all W/B
ratios. In case of Ordinary concrete for 0.55 Water/
Cement ratio the percentage of weight loss is 3.52
at 28 days immersion and it is 12.41 for 180 days
immersion. In case of Ternary concrete for 0.55
Water/ Binder ratio the percentage of weight loss is
2.82 at 28 days immersion and it is 10.21 for 180
days immersion.
5.
The percentage weight loss of Ordinary
concrete and Ternary Blended concrete after
immersing in 5 %
H2SO4 solution increases
corresponding to the time.
6.
The percentage weight loss of Ordinary
concrete and Ternary Blended concrete after
immersing in 5 %
HCl solution increases
corresponding to the time.
7.
The percentage loss compressive strength
of Ordinary concrete and Ternary Blended concrete
after immersing in 5 % H2SO4 solution and 5% HCl
solution increases corresponding to the time.
8.
The Durability Factors of Ternary Blended
concrete mixes are more than those of Ordinary
concrete mixes.
9.
Higher the Durability Factor higher will be
the resistance to the Acids and Sulphates attacks.
10.
A reduction in pores in concrete improves
the surface integrity of concrete, improves its
homogeneity good bonding and reduces the
probability of cracks.
PHOTOGRAPHS:
79
80
81
82
16.M.I.Khan, C.J. Lynsdale, P.Waldron. Porosity and Strength of PFA/SF/OPC Ternary blende
paste. Cement and Concrete Research 30(2000) Pg
1225-1229.
83
Author
Ramanujapuram.Nandini
Aurora's Scientific Technological
Academy,Hyderabad,India
&
K. Mythili,
AssociateProfessor,
Department of Civil Engineering,
Aurora's Scientific Technological & Research Academy, Hyderabad, India
Research
84