Resinas Hojas de Seguridad

SAFETY DATA SHEET
Issue Date 19-Nov-2013
Revision Date 22-May-2014
Version 2
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product identifier
Product Name
SUBSTANCE G+
Other means of identification

Synonyms
SubG+
Recommended use of the chemical and restrictions on use

Recommended Use
General Purpose UV Cure Resin
Uses advised against
No information available
Details of the supplier of the safety data sheet
Manufacturer Address
MakerJuice Labs LLC
14100 Santa Fe Trail Drive
Suite #105
Lenexa, KS 66215 USA
Email: josh@makerjuice.com
Website: http://www.makerjuice.com
Emergency telephone number
Company Phone Number
(913) 777-4996 [9-5PM CST, M-F]
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation
Serious eye damage/eye irritation
Skin sensitization
Category 2
Category 1
Category 1
Label elements
Emergency Overview
Danger
Hazard statements
Causes skin irritation
Causes serious eye damage
May cause an allergic skin reaction
Appearance viscous
Physical state liquid
Odor Ester
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SubG+
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Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace
Precautionary Statements - Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/physician
IF ON SKIN: Wash with plenty of soap and water
Take off contaminated clothing and wash before reuse
If skin irritation or rash occurs: Get medical advice/attention
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not Applicable
Other Information
Unknown Acute Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
acrylate ester
photoinitiator
CAS No.
proprietary
proprietary
Weight-%
>60
<1
Trade Secret
*
*
* If CAS number is "proprietary", the specific chemical identity has been withheld as a trade secret. The exact percentage
(concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES

First aid measures
General advice
If symptoms persist, call a physician.
Eye contact
Immediately flush with plenty of water. After initial flushing, remove any contact lenses
and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If
symptoms persist, call a physician.
Skin Contact
Avoid UV-radiation/sunlight. Wash off immediately with soap and plenty of water while
removing all contaminated clothes and shoes. If skin irritation persists, call a physician.
Wash contaminated clothing before reuse.
Inhalation
If fumes from reactions are inhaled, move to fresh air immediately. If symptoms persist,
call a physician.
Ingestion
Rinse mouth. Drink plenty of water. Do NOT induce vomiting. Call a physician immediately.
Self-protection of the first aider
Use personal protective equipment as required.
Most important symptoms and effects, both acute and delayed

Symptoms
May cause allergic skin reaction.
Indication of any immediate medical attention and special treatment needed
Note to physicians
May cause sensitization of susceptible persons. Treat symptomatically.
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SubG+
_____________________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Dry chemical, CO2, alcohol-resistant foam or water spray.
Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from the chemical
In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal
decomposition can lead to release of irritating and toxic gases and vapors.
Hazardous combustion products: Formaldehyde.
Explosion data
Sensitivity to Mechanical Impact: None.
Sensitivity to Static Discharge: None.
Protective equipment and precautions for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Personal precautions
Ensure adequate ventilation, especially in confined areas. Use personal protective

equipment as required. Avoid contact with eyes and skin. Evacuate personnel to safe
areas. Keep people away from and upwind of spill/leak.
Environmental precautions
Environmental precautions
Do not flush into surface water or sanitary sewer system. See Section 12 for additional
ecological information.
Methods and material for containment and cleanup

Methods for containment
Methods for cleaning up
Prevent further leakage or spillage if safe to do so.

Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.
After cleaning, flush away traces with water.
7. HANDLING AND STORAGE

Precautions for safe handling
Advice on safe handling
Use only in well-ventilated areas. Avoid breathing fumes from hot material. Use personal
protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray.
Conditions for safe storage, including any incompatibilities

Storage Conditions
Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated
place. Keep in properly labeled containers. Protect from direct sunlight and ultraviolet (UV).
Keep away from heat.
Incompatible materials
Strong oxidizing agents. Strong acids. Strong bases.
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SubG+
_____________________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Exposure Guidelines
This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.
Appropriate engineering controls

Engineering Controls
Ensure adequate ventilation, especially in confined areas.
Individual protection measures, such as personal protective equipment

Eye/face protection
Tight sealing safety goggles.
Skin and body protection
Wear protective nitrile rubber gloves.
Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment.
General Hygiene Considerations
When using do not eat, drink or smoke. Wash face, hands and any exposed skin thoroughly
after handling. Wash contaminated clothing before reuse. Regular cleaning of equipment,
work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Physical state
Appearance
Color
liquid
viscous
red, yellow, green, blue, black, white
Property
pH
Melting point/freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Specific Gravity
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Values
> 100 C (> 212 F)
Softening
point
Other Information
Molecular weight
VOC Content (%)
Density
Bulk density
Approx. 1
Low solubility
90 cP
Odor
Odor threshold
Ester
Remarks Method
@ 20 C
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SubG+
_____________________________________________________________________________________________
10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight. To avoid thermal decomposition, do not overheat. UVradiation/sunlight.
Incompatible materials
Strong oxidizing agents. Strong acids. Strong bases.
Hazardous Decomposition Products
Formaldehyde.
11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure
Product Information
Inhalation
No data available.
Eye contact
Risk of serious damage to eyes.

May cause sensitization by skin contact.
Skin Contact
Ingestion
No data available.
Component Information
Chemical Name
acrylate ester
Oral LD50
= 4600 mg/kg ( Rat )
Dermal LD50
> 2 g/kg ( Rabbit )
Inhalation LC50
-
Information on toxicological effects

Symptoms
May cause an allergic skin reaction.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Corrosivity
Sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Aspiration hazard
Risk of serious damage to eyes.

May cause sensitization by skin contact.
No information available.
May release formaldehyde when heated to high temperatures [> 150 C (> 212 F)] in
the presence of air. Formaldehyde is a known skin and lung sensitizer and is regulated
as a carcinogen.
Numerical measures of toxicity - Product Information

Unknown Acute Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
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SubG+
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12. ECOLOGICAL INFORMATION

Ecotoxicity
Toxic to aquatic life
Persistence and degradability

Bioaccumulation
Other adverse effects
13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging
Do not reuse container.
14. TRANSPORT INFORMATION

DOT
Not regulated
TDG
Not regulated
IATA
Not regulated
IMDG
Not regulated
ADR
Not regulated
15. REGULATORY INFORMATION

International Inventories
TSCA
Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories

Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
Yes
No
No
No
No
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SubG+
_____________________________________________________________________________________________
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
This product does not contain any substances regulated by state right-to-know regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR WHMIS Hazard Class
D2B - Toxic materials
16. OTHER INFORMATION

NFPA
Health hazards 2
Flammability 0
Instability 0
Physical and Chemical

Properties -
HMIS
Health hazards 2
Flammability 0
Issue Date
19-Nov-2013
Revision Date
22-May-2014
Physical hazards 0
Personal protection X
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
MATERIAL SAFETY DATA SHEET
FILE NO.: 004

MSDS DATE: 08 / April / 2012
Spot-HT
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Spot-HT
SYNONYMS: Sundog
PRODUCT CODES:
MANUFACTURER: Spot-A Materials
DIVISION: Spot-A Materials
ADDRESS:
EMERGENCY PHONE (Europe): 112
CHEMTREC PHONE:
OTHER CALLS: +34 654 89 51 38
FAX PHONE:
CHEMICAL NAME:
CHEMICAL FAMILY: Acrylate, Acrylate Oligomers
CHEMICAL FORMULA:
PRODUCT USE: Photoactive Resin
PREPARED BY:
SECTION 1 NOTES:
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT:
REPORTABLE
Aliphatic Acrylate
Aliphatic Acrylates
Urethane Acrlylate
CAS NO.
% WT
50-80%
10-20%
20-30%
A PEL or TLV has not been established
SECTION 2 NOTES:
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: WARNING
Warning
Irritant
Flamability: 0
Health: 1
Reactivity: 0
Other: 0
ROUTES OF ENTRY: May be absorbed through the skin
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH HAZARDS:
EYES: Moderate eye irritant
SKIN: Slight skin irritant/may cause skin sensitization
INGESTION: No data found; not expected to be an ingestion hazard
PAGE 1 OF 8
% VOL
SARA 313
FILE NO.: 004

Spot-HT
INHALATION: May cause respiratory tract irritation

CHRONIC HEALTH HAZARDS: No appropriate human or animal chronic health effects data known to exist.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
SECTION 3 NOTES:
SECTION 4: FIRST AID MEASURES
INHALATION
If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medical
attention. Prompt action is essential.
EYE CONTACT
In case of eye contact, immediately rinse with clean water for 20-30 minutes. Retract eyelids often. Obtain emergency medical attention.
SKIN CONTACT
Remove contaminated clothing as needed. Wash skin thoroughly with mild soap/water. Flush with lukewarm water for 15 minutes. If sticky, a
waterless cleaner may be used.
INGESTION
Ingestion unlikely. However, if ingested, obtain emergency medical attention.
EMERGENCY MEDICAL TREATMENT PROCEDURES
If pain, blinking, tears, or redness continue, patient should contact ophthalmologist.
SECTION 4 NOTES:
SECTION 5: FIRE-FIGHTING MEASURES
FLASH POINT METHOD=(PMCC)
GT 93C/200F
AUTOIGNITION TEMP. METHOD=

N/DA
FLAMMABLE LIMITS (% VOLUME IN AIR)

LOWER: N/DA
UPPER: N/DA
FIRE AND EXPLOSION HAZARDS

High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may cause spontaneous polymerizing
reaction generating heat/pressure. Closed containers may rupture or explode during runaway polymerization.
EXTINGUISHING MEDIA
Dry chemical
CO2
Water spray
Foam
Water fog
PAGE 2 OF 8
FILE NO.: 004

Spot-HT
SPECIAL FIREFIGHTING PROCEDURES

Do not enter fire area without proper protection. See Section 4 - decomposition products possible. Fight fire from safe distance/protected
location. Heat/impurities may increase temperature/build pressure/rupture closed containers, spreading fire, increasing risk of burns/injuries.
Water may be ineffective in firefighting due to low solubility. Use water spray/fog for cooling. Pressure relief system may plug with solids,
increasing risk of overpressure. Notify authorities if liquid enters sewer/public waters.
SECTION 5 NOTES:
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES:
PRECAUTIONS IF MATERIAL IS SPILLED OR RELEASED
Spilled or released material may polymerize and release heat/gases. Extinguish all ignition sources and ventilate area. Wear protective
equipment during clean-up. Dike and recover large spill. Soak up small spill with inert solids (such as vermiculite, clay) and sweep/shovel into
vented disposal container. Wash spill area with a strong detergent and water solution; rinse with water but minimize water use during
clean-up. For spills on water, contain, minimize dispersion and collect. Dispose/report per regulatory requirements.
WASTE DISPOSAL METHODS
Non-contaminated, properly inhibited material is not a RCRA hazardous waste. However, contaminated material/soil/water may be
RCRA/OSHA hazardous waste due to potential for internal heat generation (see 40 CFR 261 and 29 CFR 1910).
It is the responsibility of the generator to determine at the time of disposal whether the material meets the criteria of a hazardous waste.
Comply with all applicable federal, state and local regulations. Use registered transporters. Disposal options include landfilling solids at
permitted sites; fuel blending or incinerating liquids. Assure emissions comply with applicable regulations. Dilute aqueous waste may
biodegrade; avoid overloading/poisoning plant biomass. Assure effluent complies with applicable regulations.
SECTION 6 NOTES:
SECTION 7: HANDLING AND STORAGE

HANDLING AND STORAGE PROCEDURES
Wear appropriate protective equipment when handling this material (See Section 8 of MSDS). Most acrylic monomers have low viscosities;
hence, pouring, material transfer and processing of these materials do not necessitate heating. Viscous monomers may require heating to
facilitate handling. To facilitate product transfer from original container, product may be heated to 60C/140F for not more than 24 hours. Do
NOT use localized heat sources such as band heaters to heat/melt product. Do NOT use steam. Hot boxes or hot rooms are recommended
for heating/melting material. The hot box or hot room should be set at a maximum temperature of 60C/140F. Do not overheat--this may
compromise product quality and/or result in an uncontrolled hazardous polymerization. If product freezes, heat as indicated above and mix
gently to redistribute the inhibitor. Product should be consumed in its entirety after heating/melting--avoid multiple "re-heats" which may affect
product quality or result in product degradation. Product is packaged with inhibitor(s). Unless inhibited, product can polymerize, raising
temperature and pressure possibly rupturing container. Check inhibitor content periodically, adding to bulk material if needed. In addition, the
product's inhibitor(s) require the presence of dissolved oxygen. Maintain, at a minimum, the original headspace in the product container and
do not blanket or mix with oxygen-free gas as it renders inhibitor ineffective. Ensure air space (oxygen) is present during product
heating/melting.
SECTION 7 NOTES:
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
RESPIRATORY PROTECTION
:
If this material is handled at elevated temperature or under mist forming conditions, NIOSH/MSHA approved respiratory protection equipment
should be used.
PAGE 3 OF 8
FILE NO.: 004

Spot-HT
EYE PROTECTION
Eye protection such as chemical splash goggles and/or face shield must be worn when possibility exists for eye contact due to splashing or
spraying liquid, airborne particles, or vapor. Contact lenses should not be worn.
SKIN PROTECTION
Depending on the conditions of use, protective gloves, apron, boots, head and face protection should be worn. This equipment should be
cleaned thoroughly after each use.
ENGINEERING CONTROLS
If this material is handled at elevated temperature or under mist forming conditions, NIOSH/MSHA approved respiratory protection equipment
should be used.
OTHER HYGIENIC PRACTICES

Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.
OTHER WORK PRACTICES

Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Promptly remove soiled
clothing/wash thoroughly before reuse. Shower after work using plenty of soap and water.
SECTION 8 NOTES:
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear, light yellow liquid
ODOR: Low odor
PHYSICAL STATE: Liquid
pH AS SUPPLIED: AP 6.8 to 7.2
pH (Other):
BOILING POINT: N/DA
MELTING POINT: N/DA
FREEZING POINT: N/DA
VAPOR PRESSURE (mmHg): Negligible
VAPOR DENSITY (AIR = 1): N/AP
SPECIFIC GRAVITY (H2O = 1): AP 1.10-1.12 at 25C/77F
EVAPORATION RATE: Negligible
BASIS (=1):
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (cont)
SOLUBILITY IN WATER: Negligible
PERCENT SOLIDS BY WEIGHT: 2%
PERCENT VOLATILE: 0%
VOLATILE ORGANIC COMPOUNDS (VOC): Nil
PAGE 4 OF 8
FILE NO.: 004

Spot-HT
MOLECULAR WEIGHT: N/DA

VISCOSITY: AP 100 to 150 cps at 25C/77F
SECTION 9 NOTES:
SECTION 10: STABILITY AND REACTIVITY

STABLE
UNSTABLE
STABILITY: Stable
CONDITIONS TO AVOID (STABILITY):
High temperatures, localized heat sources (ie, drum or band heaters), oxidizing conditions, freezing conditions, direct sunlight, ultraviolet
radiation, inert gas blanketing; Strong oxidizers, strong reducers, free radical initiators, inert gases, oxygen scavengers
INCOMPATIBILITY (MATERIAL TO AVOID):
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
Acrid smoke-fumes/carbon monoxide/carbon dioxide and perhaps other toxic vapors may be released during a fire involving this product.
HAZARDOUS POLYMERIZATION: May occur
CONDITIONS TO AVOID (POLYMERIZATION): Leave appropriate headspace above surface level to provide Oxygen inhibition for
best stability.
SECTION 10 NOTES:
SECTION 11: TOXICOLOGICAL INFORMATION
ROUTES OF EXPOSURE
INHALATION
No significant signs or symptoms indicative of any adverse health hazard are expected to occur at standard conditions due to the low volatility
of this material. However, aerosols, or vapors which may be generated at elevated processing temperatures, may cause respiratory tract
irritation. Symptoms of irritation may include coughing, mucous production and shortness of breath.
EYE CONTACT -- PRIMARY ROUTE

May cause moderate irritation with symptoms including burning sensation, tearing, redness or swelling.
SKIN ABSORPTION -- PRIMARY ROUTE

Some acrylate materials are absorbed through the skin. Although no appropriate human or animal health effects data are known to exist, the
potential for skin absorption does exist for this material.
SKIN IRRITATION -- PRIMARY ROUTE

May cause minor skin irritation. Symptoms of irritation may include a slight localized redness or rash and swelling. Although no appropriate
human or animal health effects data is known to exist, this material may cause an allergic skin reaction (sensitization) in susceptible
individuals upon repeated exposure.
INGESTION
PAGE 5 OF 8
FILE NO.: 004

Spot-HT
Although no appropriate human or animal health effects data is known to exist, this material is not expected to be an ingestion hazard.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

This material or its emissions may induce an allergic or sensitization reaction and thereby aggravate systemic disease.
SECTION 11 NOTES:
SECTION 12: ECOLOGICAL INFORMATION

ECOLOGICAL INFORMATION:
DECONTAMINATION PROCEDURES
Follow standard plant procedures or supervisor's instructions for decontamination operations.
SECTION 12 NOTES:
SECTION 13: DISPOSAL CONSIDERATIONS
PRECAUTIONS IF MATERIAL IS SPILLED OR RELEASED
Spilled or released material may polymerize and release heat/gases. Extinguish all ignition sources and ventilate area. Wear protective
equipment during clean-up. Dike and recover large spill. Soak up small spill with inert solids (such as vermiculite, clay) and sweep/shovel into
vented disposal container. Wash spill area with a strong detergent and water solution; rinse with water but minimize water use during
clean-up. For spills on water, contain, minimize dispersion and collect. Dispose/report per regulatory requirements.
WASTE DISPOSAL METHODS

Non-contaminated, properly inhibited material is not a RCRA hazardous waste. However, contaminated material/soil/water may be
RCRA/OSHA hazardous waste due to potential for internal heat generation (see 40 CFR 261 and 29 CFR 1910).
It is the responsibility of the generator to determine at the time of disposal whether the material meets the criteria of a hazardous waste.
Comply with all applicable federal, state and local regulations. Use registered transporters. Disposal options include landfilling solids at
permitted sites; fuel blending or incinerating liquids. Assure emissions comply with applicable regulations. Dilute aqueous waste may
biodegrade; avoid overloading/poisoning plant biomass. Assure effluent complies with applicable regulations.
SECTION 14: TRANSPORT INFORMATION

U.S. DEPARTMENT OF TRANSPORTATION
PROPER SHIPPING NAME:
HAZARD CLASS:
ID NUMBER:
PACKING GROUP:
LABEL STATEMENT:
WATER TRANSPORTATION
HAZARD CLASS:
ID NUMBER:
PACKING GROUP:
LABEL STATEMENTS:
AIR TRANSPORTATION
HAZARD CLASS:
ID NUMBER:
PACKING GROUP:
LABEL STATEMENTS:
PAGE 6 OF 8
FILE NO.: 004

Spot-HT
OTHER AGENCIES:
SECTION 14 NOTES:
SECTION 15: REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS
TSCA (TOXIC SUBSTANCE CONTROL ACT):
TSCA status: All components of this product are listed, or excluded from
listing, on the United States Environmental Protection
TSCA Section 12(b):
TSCA Section 12(b) - Export Notification: This product does not contain any
chemicals at concentrations subject to Section 12(b) export notification.
CALIFORNIA PROPOSITION 65:
California Proposition 65 Information: This product contains, or may contain,
trace quantities of a substance(s) known to the state of California to cause
cancer and/or reproductive toxicity.
Agency Toxic Substances
Control Act (TSCA) inventory.
CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT):
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT):
311/312 HAZARD CATEGORIES:
NPCA - HMIS RATING
Health
2
Flammability
1
Reactivity
2
Personal protection**
D
**Respiratory protection may be necessary depending on conditions of use.
Refer to Section 8 of this MSDS for respiratory protection guidelines.
313 REPORTABLE INGREDIENTS:
STATE REGULATIONS:
INTERNATIONAL REGULATIONS:
SECTION 15 NOTES:
This material contains an inhibitor (HQ, MEHQ, etc.) at <1%. The type and
amount meet product specifications.
PAGE 7 OF 8
FILE NO.: 004

Spot-HT
*Note - qualifiers and codes used in this MSDS

EQ = Equal; AP = Approximately; LT = Less Than; GT = Greater Than;
TR = Trace; UK = Unknown; N/AP = Not Applicable; N/P = No Applicable
Information Found; N/DA = No Data Available
SECTION 16: OTHER INFORMATION

OTHER INFORMATION:
PREPARATION INFORMATION:
DISCLAIMER:
PAGE 8 OF 8
3D-Materials
Advanced Photopolymer Resins

according to regulation (EC) No 1907/2006 (REACH)
HARMFUL & IRRITANT SUBSTANCE

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identification : Photopolymer 3DM-ABS series
Product Class : Mixture of acrylic acid esters, acrylated monomers, oligomers and photoinitiators.
Product Use : Use for stereolitography 3D printers with UV-light systems (Laser or LED).
Company :
3D-Materials
France
Mail : justprintit-3d-materials@hotmail.fr
Website : www.3d-materials.org
Date of Preparation: 09/30/2013
For Emergencies: call 112 (for UE) or 911 (for USA)
A. EMERGENCY OVERVIEW
This product is a liquid acrylic based resin with a characteristic light odor. This product may cause
skin, eyes and respiratory system irritation, and skin sensitization/allergic reaction by skin contact.
Inhalation of high vapor concentration may cause headaches and nausea.
B. TARGET ORGANS OR SYSTEMS
Skin, Eyes, Respiratory System, Central Nervous System
C. ROUTE OF EXPOSURE:
Skin Contact, Eye Contact, Inhalation, Ingestion
D. SIGNS AND SYMPTOMS OF EXPOSURE:
Acute:
Skin Contact -- May cause skin irritation. Symptoms may include a slightly localized redness or rash
and swelling. Repeated exposure may cause sensitization and allergic skin reaction in some
individuals resulting in contact dermatitis, severe irritation, dryness and cracking.
Eye Contact -- May cause eye irritation. Symptoms may include excessive tearing, itching, irritation,
blinking and redness.
Inhalation -- This product is a suspect slight respiratory tract irritation hazard, especially if used at
elevated temperature or processes which may generate aerosols or mists. Symptoms of irritation may
include coughing, headache and nausea, mucous production and shortness of breath.
3D-Materials - Advanced Photopolymer Resins - 3DM-ABS series / MSDS - - update 22/08/2014
Ingestion -- The product may be harmful if swallowed. It may cause nausea, headache, vomiting,
diarrhea, and/or central nervous system effects. Keep all food in an area separate from storage and
use locations.
Prohibit eating, drinking and smoking in areas where there is a potential for significant exposure to this
material. Thoroughly wash hands before eating.
Chronic:
Inhalation -- Prolonged or repeated overexposure may cause irritation, headache, and nausea.
Skin Contact -- May cause sensitization and allergic reaction. May cause more significant irritation in
people with pre-existing skin conditions.
Eye Contact -- May cause redness of eye tissue.
Ingestion -- May be a slight ingestion hazard if swallowed. Chronic ingestion of high doses may cause
damage to testes, as shown in animal studies.
Carcinogens:
There are no carcinogens in concentrations of 0.1 percent or greater in this product.
Potential Environmental Effects: Not readily biodegradable. Avoid release to the environment. Dispose
of in accordance with all applicable federal, state and local regulations.
Components
Approximate
% by weight
C.A.S. No. &

EINECS No.
UK/EU Classification
Directive 67/548/EEC
Acrylated momomer
Proprietary
Proprietary
Xi(Irritant),N(Harmful),
R36/37/38
R43/51/53
S3, S7/9, S20, S26,
S29,S37/39
Acrylated oligomer
Proprietary
Proprietary
Xi(Irritant), R36/37/38,
R43
S3, S7/9, S20, S26,
S29, S37/39
Photoinitiators
Proprietary
Proprietary
H303, H402
4. FIRST-AID MEASURES
Emergency Overview: This product is a liquid acrylic based resin with an acrylat characteristic odor.
This product may cause skin and eye irritation. The inhalation of high vapor concentration may cause
a headache and nausea.
Inhalation: In case of exposure to a high concentration of vapor or mist, remove person to fresh air.
If breathing has stopped, administer artificial respiration and seek medical attention.
Eye Contact: Immediately flush with plenty of clean water (under eye lids) for at least 20 minutes.
Hold eyelids apart to ensure flushing.
Washing within one minute of contact is essential to achieve maximum effectiveness. Seek medical
attention immediately. Do not apply oil or oily ointments unless ordered by a physician.
Skin Contact: Remove contaminated clothing and rinse contact area thoroughly with soap and water.
Particular attention should be paid to hair, nose, and ears, and other areas not easily cleaned. Wash
clothing before reuse. If irritation develops, consult a physician.
Ingestion: If ingested dilute with water by giving glasses of water or milk to the victim. Do not give
anything by mouth if the victim is rapidly losing consciousness, is unconscious, or convulsing. Do not
induce vomiting. If vomiting occurs naturally, keep airways clear. Get medical attention. Provide an
estimate of the time at which the material was ingested and the amount of the substance that was
swallowed.
Flash point: > 100C / 212F
Method: Setaflash
Ignition temperature: n.d
Lower explosion limit: n.d
Upper explosion limit: n.d
Extinguishing media: Use carbon dioxide or dry chemical for small fires; aqueous foam or water
spray for large fires.
Special firefighting procedures: Firefighters should wear full protection clothing and self-contained
breathing apparatus (SCBA).
Thoroughly decontaminate firefighting equipment including all firefighting apparel after the incident.
Unusual Fire & Explosion: Emits irritating vapors. High temperatures, accidental impurities, or
exposure to radiation or oxidizers may cause spontaneous polymerization generating heat/pressure
and rupture/explosion of closed containers.
Exposure Hazard(s): Material Harmfull & Irritant

Procedures of Personal Precautions: Wear adequate personal protective clothing and equipment,
as outlined in Section 8.
Environmental Precautions: Contain spill to prevent spread into drains, sewers, water supplies, or
soil. Avoid release to the Environment. Dispose of in accordance with all applicable federal, state and
local regulations.
Methods of Cleaning Up: In the event of a spill, immediately remove all sources of ignition. Cover the
liquid with inert absorbent. Using appropriate personal protective equipment and non-sparking tools,
contain spilled material.
Waste Disposal Method: Do not dispose to sewers, lakes, rivers or streams. Scoop all contaminated
material into compatible bottles or drums for proper disposal. Dispose of in accordance with all
applicable federal, state and local regulations. National or regional provisions may also be in force.

Handling Precautions: User Exposure -- This product should be used in well-ventilated areas.
Product may cause irritation. Avoid contact with eyes. Avoid prolonged or repeated contact with skin.
Wash hands with soap and water before eating, drinking, smoking, applying cosmetics, or using toilet
facilities. Launder contaminated clothing before reuse. Contaminated leather articles, including shoes,
cannot be decontaminated and should be destroyed to prevent reuse. Solvents should never be used
to clean hands or skin because they increase the penetration of the material into skin.
Storage Precautions: Suitable -- Store in a cool, dry place out of direct sun light, in opaque or amber
containers. Store the containers at 10-35C (50-95F). Do not exceed 50C (122F) when in storage.
Keep containers closed. Avoid ignition sources.
Special Requirements: Do not heat containers with steam or electrical equipment. Heating this
product above 100C (210F) in the presence of air may cause slow oxidative decomposition; above
150C (300F) polymerization may occur. Fumes and vapors from this thermal decomposition may be
dangerous for health (nitrous vapors, carbon monoxide-carbon dioxide). Do not breathe fumes.
8. EXPOSURE CONTROLS & PERSONAL PROTECTION

EXPOSURE LIMITS:
Components
Acrylated monomer
Acrylated oligomer
Photoinitiators
HSIS Australia
None
None
None
IOELVs (UK)
None
None
None
ACGIH TLV
None
None
None
OSHA PEL
None
None
None
WEEL
None
None
None
No occupational exposure limit values exist for the materials contained in this product.
Notations:
IOELVs (Indicative Occupational Exposure Limit Values)
TWA (time weighted average)
OEL (Occupational Exposure Limits)
PEL (Permissible Exposure Limit)
TLV (Threshold Limit Value)
STEL (Short Term Exposure Limit)
WEEL (Workplace Environmental Exposure Level by the American Industrial Hygiene Association)
EXPOSURE CONTROLS:
Ventilation Controls: Ensure adequate ventilation.
Respiratory Protection: Respirators are generally not needed under normal conditions of use. If this
material is handled at elevated temperature, under mist forming conditions or in case of accidental
release of large quantities of product use a full-face respirator with multi-purpose combination (US) or
type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or
CEN (EU).
Protective Gloves: Wear impervious gloves (nitrile or neoprene) for routine handling.
Eye and Face Protection: Chemical splash goggles or a face shield is recommended during
operations where splashing could occur.
Skin Protection: Avoid all skin contact. Depending on the conditions of use, cover as much of the
exposed skin area as possible by wearing gloves, aprons, long pants, and long sleeved shirts.
Other Controls: For operations where contact can occur a safety shower and eye wash facility should
be available. Always use good personal hygiene and housekeeping practices. Wash thoroughly after
handling.
Environmental Exposure Controls: Keep product from waterways and watersheds. This substance
is not readily biodegradable and dangerous for the environment. Avoid release to the environment.
9. PHYSICAL & CHEMICAL PROPERTIES
Appearance:
Odor:
Specific Gravity:
Boiling Point:
Flash Point:
Ignition Temperature:
Lower Explosion Limit:
Upper Explosion Limit:
Viscosity @ 25C (77F)
Vapour pressure:
Solubility in water:
Solubility in organic solvents:
Volatile characteristics:
Electrostatic discharge:
Electric conductivity:
Liquid resin
Characteristic / Acrylate
1.11 1.18 g/cm
> 100 C
> 100 C
n.d.
n.d.
n.d.
n.d.
not established
not established
soluble in organic solvents
negligible
safe
dielectric

Stability: Stable when stored in original container designed for use with light sensitive materials under
35C (95F) in dark, cool place.
Conditions to Avoid: Storage > 40C (100F),exposure to light, loss of dissolved air, and
contamination with incompatible materials.
Incompatible Materials to Avoid: Polymerization initiators, including peroxides, strong oxidizing
agents, alcohols, copper, copper alloys, carbon steel, iron, rust, and strong bases.
Hazardous Decomposition Products: Hazardous decomposition products may include oxides of
carbon, nitrogen and various hydrocarbon fragments.
Hazardous Polymerization: Hazardous polymerization may occur. Uncontrolled polymerization may
cause rapid evolution of heat and increase in pressure that could result in violent rupture of sealed
storage vessels or containers.

Acrylated monomer
Acute Oral toxicity LD50 > 5300 mg/kg body weight (supplier info)
Acrylated oligomer
Photoinitiators
Acute Oral Toxicity LD50 > 2500 mg/kg body weight (tested in rats)
(supplier info)
Acute Dermal Toxicity LD50 > 5000 mg/kg body weight (supplier info)
Individual components of this product are not reported to produce mutagenic effects in humans.
None of the components of this material are listed by IARC, NTP, OSHA or ACGIH as carcinogens.

Keep product from waterways and watersheds. This substance is not readily biodegradable. Dispose
Acrylated monomer
No data available
Acrylated oligomer
No data available
Photoinitiators
No data available

Dispose of in accordance with governmental regulations (community, national or regional). Contact a
licensed professional waste disposal service to dispose of this mixture. As with all foreign substances,
do not allow to enter the storm or sewer drainage systems. Avoid release to the Environment.
Contaminated Packaging: Dispose of as unused product. Expose the open emptied container to light,
then dispose.

Department of transportation classification: Not hazardous by D.O.T. regulations
D.O.T. proper shipping name: Not regulated
Other requirements: N/A

The following provides a summary of the legal requirements.
EUROPEAN ECONOMIC COMMUNITY (EEC)
CANADA REGS
---------------------------------------------------------------------------------------------------------------------------------------Composants EPA* CA
EINECS European
Listed as
EEC Symbol
DSL
NDSL
TSCA Prop65
Community dangerous
Standards
chemicals
per ESIS
Acrylated
monomer
Yes
No
Yes
None
Acrylated
oligomer
Yes
No
Yes
None
Photoinitiators
Yes
No
Yes
None
No
No
No
Xi : Irritant,
N : Harmful
R36/37/38,
R43/51/53
Yes
S3,S7/9,S20,
S26,S29,S37/39
Yes
Xi; Irritant,
R36/37/38,
R43
Yes
S3,S7/9,S20,
S26,S29,S37/39
Yes
H303, H402
No
Yes
All the components present in this product at concentrations equal to or greater than 0.1% are listed,
or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Substance Preparation Classification : Harmful & Irritant

FULL TEXT OF ANY R-PHRASES AND S-PHRASES:
Risk Phrases:
R36/37/38 -- Irritating to eyes, respiratory system and skin
R43 -- May cause sensitization by skin contact
R51/53 -- Toxic to aquatic organisms, may cause long-term adverse effects inthe aquatic environment.
Safety Phrases:
S3 -- Keep in a cool place
S7/9 -- Keep container
S20 When using do not eat or drink
S26 -- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S29 Do not empty into drains
S36 -- Wear suitable protective clothing
S37/39 -- Wear suitable gloves and eye/face protection
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302.
Pursuant to Title III of the Superfund Amendments and Reauthorization Act of 1986, (SARA) and 40
CFR 372 Part 372, this product does not contain chemicals subject to the reporting requirements
under Section 313.
California Proposition 65: This product does not contain chemicals which are known to the state of
California to cause cancer.

HMIS (Hazardous Materials Information System) for secondary labeling:
HEALTH
FIRE HAZARD
REACTIVITY
PERSONAL PROTECTIVE EQUIPMENT
REFERENCES:
1. 2011 Threshold Limit Values and Biological Exposure Indices. American Conference of
Governmental Industrial Hygienists.
2. MSDS + Cheminfo CD-ROM, Canadian Centre for Occupational Health and Safety
3. SAXS Dangerous Properties of Industrial Materials, Tenth Edition
4. TSCA & SARA Title III, U.S. Environmental Protection Agency and the National Technical
Information Services
5. Raw Material Manufacturers Material Safety Data Sheets
6. US National Institute of Medicines Toxnet current edition
7. ESIS: European Chemical Substance Information System, http://ecb.jrc.it/esis
8. NOHSC Hazardous Information Substances Information System, Department of Employment and
Workplace Relations, Australian Government, 2005
To the best of our knowledge the information contained herein is accurate. However, 3D-Materials makes
no warranty, expressed or implied regarding the accuracy of these results to be obtained from the use
thereof. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist. 3D-Materials assumes no responsibility for injury from the use of the product
described herein.
DISCLAIMER OF LIABILITY: The following supersedes any provision in the forms, letters and agreements
between your business and 3D-Materials.
3D-Materials makes no direct or indirect guarantee for this product, including warranties of
merchantability or fitness for a particular purpose. 3D-Materials shall in no event be liable for incidental,
consequential or other resulting from alleged negligence, breach of warranty, strict liability or any other
theory is, after the use or handling of this product. The sole liability of 3D-Materials, as part of an
application any compensation in connection with the manufacture, use or sale of its products is limited to
the purchase price paid by the purchaser. The content of this MSDS may be changed without notice.
3D-Materials invites you to periodically check their website to make sure you have the most recent MSDS.
3D-Materials
Advanced Photopolymer Resins

according to regulation (EC) No 1907/2006 (REACH)
HARMFUL & IRRITANT SUBSTANCE

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identification : Photopolymer 3DM-Cast series
Product Class : Mixture of acrylic acid esters, acrylated monomers, oligomers, synthetic waxes and
photoinitiators.
Product Use : Use for stereolitography 3D printers with UV-Visible light systems.
Company :
3D-Materials
France
Mail : justprintit-3d-materials@hotmail.fr
Website : www.3d-materials.org
Date of Preparation: 06/21/2014
For Emergencies: call 112 (for UE) or 911 (for USA)
A. EMERGENCY OVERVIEW
This product is a liquid acrylic based resin with a characteristic light odor. This product may cause
skin, eyes and respiratory system irritation, and skin sensitization/allergic reaction by skin contact.
Inhalation of high vapor concentration may cause headaches and nausea.
B. TARGET ORGANS OR SYSTEMS
Skin, Eyes, Respiratory System, Central Nervous System
C. ROUTE OF EXPOSURE:
Skin Contact, Eye Contact, Inhalation, Ingestion
D. SIGNS AND SYMPTOMS OF EXPOSURE:
Acute:
Skin Contact -- May cause skin irritation. Symptoms may include a slightly localized redness or rash
and swelling. Repeated exposure may cause sensitization and allergic skin reaction in some
individuals resulting in contact dermatitis, severe irritation, dryness and cracking.
Eye Contact -- May cause eye irritation. Symptoms may include excessive tearing, itching, irritation,
blinking and redness.
Inhalation -- This product is a suspect slight respiratory tract irritation hazard, especially if used at
elevated temperature or processes which may generate aerosols or mists. Symptoms of irritation may
include coughing, headache and nausea, mucous production and shortness of breath.
3D-Materials - Advanced Photopolymer Resins - 3DM-Cast series / MSDS - update 14/11/2014
Ingestion -- The product may be harmful if swallowed. It may cause nausea, headache, vomiting,
diarrhea, and/or central nervous system effects. Keep all food in an area separate from storage and
use locations.
Prohibit eating, drinking and smoking in areas where there is a potential for significant exposure to this
material. Thoroughly wash hands before eating.
Chronic:
Inhalation -- Prolonged or repeated overexposure may cause irritation, headache, and nausea.
Skin Contact -- May cause sensitization and allergic reaction. May cause more significant irritation in
people with pre-existing skin conditions.
Eye Contact -- May cause redness of eye tissue.
Ingestion -- May be a slight ingestion hazard if swallowed. Chronic ingestion of high doses may cause
damage to testes, as shown in animal studies.
Carcinogens:
There are no carcinogens in concentrations of 0.1 percent or greater in this product.
Potential Environmental Effects: Not readily biodegradable. Avoid release to the environment. Dispose
Components
Approximate
% by weight
C.A.S. No. &

EINECS No.
UK/EU Classification
Directive 67/548/EEC
Acrylated momomer
Proprietary
Proprietary
Xi(Irritant),N(Harmful),
R36/37/38
R43/51/53
S3, S7/9, S20, S26,
S29,S37/39
Acrylated oligomer
Proprietary
Proprietary
Xi(Irritant), R36/37/38,
R43
S3, S7/9, S20, S26,
S29, S37/39
Synthetic waxes
Proprietary
Proprietary
None
Photoinitiators
Proprietary
Proprietary
H303, H402
4. FIRST-AID MEASURES
Emergency Overview: This product is a liquid opaque acrylic based resin with an acrylate
characteristic odor. This product may cause skin and eye irritation. The inhalation of high vapor
concentration may cause a headache and nausea.
Inhalation: In case of exposure to a high concentration of vapor or mist, remove person to fresh air.
If breathing has stopped, administer artificial respiration and seek medical attention.
Eye Contact: Immediately flush with plenty of clean water (under eye lids) for at least 20 minutes.
Hold eyelids apart to ensure flushing.
Washing within one minute of contact is essential to achieve maximum effectiveness. Seek medical
attention immediately. Do not apply oil or oily ointments unless ordered by a physician.
Skin Contact: Remove contaminated clothing and rinse contact area thoroughly with soap and water.
Particular attention should be paid to hair, nose, and ears, and other areas not easily cleaned. Wash
clothing before reuse. If irritation develops, consult a physician.
Ingestion: If ingested dilute with water by giving glasses of water or milk to the victim. Do not give
anything by mouth if the victim is rapidly losing consciousness, is unconscious, or convulsing. Do not
induce vomiting. If vomiting occurs naturally, keep airways clear. Get medical attention. Provide an
estimate of the time at which the material was ingested and the amount of the substance that was
swallowed.
Flash point: > 100C / 212F
Method: Setaflash
Ignition temperature: n.d
Lower explosion limit: n.d
Upper explosion limit: n.d
Extinguishing media: Use carbon dioxide or dry chemical for small fires; aqueous foam or water
spray for large fires.
Special firefighting procedures: Firefighters should wear full protection clothing and self-contained
breathing apparatus (SCBA).
Thoroughly decontaminate firefighting equipment including all firefighting apparel after the incident.
Unusual Fire & Explosion: Emits irritating vapors. High temperatures, accidental impurities, or
exposure to radiation or oxidizers may cause spontaneous polymerization generating heat/pressure
and rupture/explosion of closed containers.
Exposure Hazard(s): Material Harmfull & Irritant

Procedures of Personal Precautions: Wear adequate personal protective clothing and equipment,
as outlined in Section 8.
Environmental Precautions: Contain spill to prevent spread into drains, sewers, water supplies, or
soil. Avoid release to the Environment. Dispose of in accordance with all applicable federal, state and
local regulations.
Methods of Cleaning Up: In the event of a spill, immediately remove all sources of ignition. Cover the
liquid with inert absorbent. Using appropriate personal protective equipment and non-sparking tools,
contain spilled material.
Waste Disposal Method: Do not dispose to sewers, lakes, rivers or streams. Scoop all contaminated
material into compatible bottles or drums for proper disposal. Dispose of in accordance with all
applicable federal, state and local regulations. National or regional provisions may also be in force.

Handling Precautions: User Exposure -- This product should be used in well-ventilated areas.
Product may cause irritation. Avoid contact with eyes. Avoid prolonged or repeated contact with skin.
Wash hands with soap and water before eating, drinking, smoking, applying cosmetics, or using toilet
facilities. Launder contaminated clothing before reuse. Contaminated leather articles, including shoes,
cannot be decontaminated and should be destroyed to prevent reuse. Solvents should never be used
to clean hands or skin because they increase the penetration of the material into skin.
Storage Precautions: Suitable -- Store in a cool, dry place out of direct sun light, in opaque or amber
containers. Store the containers at 10-35C (50-95F). Do not exceed 50C (122F) when in storage.
Keep containers closed. Avoid ignition sources.
Special Requirements: Do not heat containers with steam or electrical equipment. Heating this
product above 100C (210F) in the presence of air may cause slow oxidative decomposition; above
150C (300F) polymerization may occur. Fumes and vapors from this thermal decomposition may be
dangerous for health (nitrous vapors, carbon monoxide-carbon dioxide). Do not breathe fumes.
8. EXPOSURE CONTROLS & PERSONAL PROTECTION

EXPOSURE LIMITS:
Components
Acrylated monomer
Acrylated oligomer
Synthetic waxes
Photoinitiators
HSIS Australia
None
None
None
None
IOELVs (UK)
None
None
None
None
ACGIH TLV
None
None
None
None
OSHA PEL
None
None
None
None
WEEL
None
None
None
None
No occupational exposure limit values exist for the materials contained in this product.
Notations:
IOELVs (Indicative Occupational Exposure Limit Values)
TWA (time weighted average)
OEL (Occupational Exposure Limits)
PEL (Permissible Exposure Limit)
TLV (Threshold Limit Value)
STEL (Short Term Exposure Limit)
WEEL (Workplace Environmental Exposure Level by the American Industrial Hygiene Association)
EXPOSURE CONTROLS:
Ventilation Controls: Ensure adequate ventilation.
Respiratory Protection: Respirators are generally not needed under normal conditions of use. If this
material is handled at elevated temperature, under mist forming conditions or in case of accidental
release of large quantities of product use a full-face respirator with multi-purpose combination (US) or
type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or
CEN (EU).
Protective Gloves: Wear impervious gloves (nitrile or neoprene) for routine handling.
Eye and Face Protection: Chemical splash goggles or a face shield is recommended during
operations where splashing could occur.
Skin Protection: Avoid all skin contact. Depending on the conditions of use, cover as much of the
exposed skin area as possible by wearing gloves, aprons, long pants, and long sleeved shirts.
Other Controls: For operations where contact can occur a safety shower and eye wash facility should
be available. Always use good personal hygiene and housekeeping practices. Wash thoroughly after
handling.
Environmental Exposure Controls: Keep product from waterways and watersheds. This substance
is not readily biodegradable and dangerous for the environment. Avoid release to the environment.
9. PHYSICAL & CHEMICAL PROPERTIES

Appearance:
Odor:
Specific Gravity:
Boiling Point:
Flash Point:
Ignition Temperature:
Lower Explosion Limit:
Upper Explosion Limit:
Viscosity @ 25C (77F)
Vapour pressure:
Solubility in water:
Solubility in organic solvents:
Volatile characteristics:
Electrostatic discharge:
Electric conductivity:
Liquid resin
Characteristic / Acrylate
0.98 1.05 g/cm
> 100 C
> 100 C
n.d.
n.d.
n.d.
n.d.
not established
not established
soluble in organic solvents
negligible
safe
dielectric

Stability: Stable when stored in original container designed for use with light sensitive materials under
35C (95F) in dark, cool place.
Conditions to Avoid: Storage > 40C (100F),exposure to light, loss of dissolved air, and
contamination with incompatible materials.
Incompatible Materials to Avoid: Polymerization initiators, including peroxides, strong oxidizing
agents, alcohols, copper, copper alloys, carbon steel, iron, rust, and strong bases.
Hazardous Decomposition Products: Hazardous decomposition products may include oxides of
carbon, nitrogen and various hydrocarbon fragments.
Hazardous Polymerization: Hazardous polymerization may occur. Uncontrolled polymerization may
cause rapid evolution of heat and increase in pressure that could result in violent rupture of sealed
storage vessels or containers.

Acrylated monomer
Acrylated oligomer
Synthetic waxes
Photoinitiators
Acute Oral Toxicity LD50 > 2500 mg/kg body weight (supplier info)
Individual components of this product are not reported to produce mutagenic effects in humans.
None of the components of this material are listed by IARC, NTP, OSHA or ACGIH as carcinogens.

Keep product from waterways and watersheds. This substance is not readily biodegradable. Dispose
Acrylated monomer
No data available
Acrylated oligomer
No data available
Synthetic waxes
No data available
Photoinitiators
No data available

Dispose of in accordance with governmental regulations (community, national or regional). Contact a
licensed professional waste disposal service to dispose of this mixture. As with all foreign substances,
do not allow to enter the storm or sewer drainage systems. Avoid release to the Environment.
Contaminated Packaging: Dispose of as unused product. Expose the open emptied container to light,
then dispose.

Department of transportation classification: Not hazardous by D.O.T. regulations
D.O.T. proper shipping name: Not regulated
Other requirements: N/A

The following provides a summary of the legal requirements.
EUROPEAN ECONOMIC COMMUNITY (EEC)
CANADA REGS
---------------------------------------------------------------------------------------------------------------------------------------Composants EPA* CA
EINECS European
Listed as
EEC Symbol
DSL
NDSL
TSCA Prop65
Community dangerous
Standards
chemicals
per ESIS
Acrylated
monomer
Yes
No
Yes
None
No
No
Xi : Irritant,
N : Harmful
R36/37/38,
R43/51/53
Yes
S3,S7/9,S20,
S26,S29,S37/39
Yes
Xi; Irritant,
R36/37/38,
R43
Yes
S3,S7/9,S20,
S26,S29,S37/39
Yes
Acrylated
oligomer
Yes
No
Yes
None
Synthetic
waxes
Yes
No
Yes
None
No
None
Yes
Yes
Photoinitiators
Yes
No
Yes
None
No
H303, H402
Yes
No
All the components present in this product at concentrations equal to or greater than 0.1% are listed,
or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Substance Preparation Classification : Harmful & Irritant

FULL TEXT OF ANY R-PHRASES AND S-PHRASES:
Risk Phrases:
R36/37/38 -- Irritating to eyes, respiratory system and skin
R43 -- May cause sensitization by skin contact
R51/53 -- Toxic to aquatic organisms, may cause long-term adverse effects inthe aquatic environment.
Safety Phrases:
S3 -- Keep in a cool place
S7/9 -- Keep container
S20 When using do not eat or drink
S26 -- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S29 Do not empty into drains
S36 -- Wear suitable protective clothing
S37/39 -- Wear suitable gloves and eye/face protection
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302.
Pursuant to Title III of the Superfund Amendments and Reauthorization Act of 1986, (SARA) and 40
CFR 372 Part 372, this product does not contain chemicals subject to the reporting requirements
under Section 313.
California Proposition 65: This product does not contain chemicals which are known to the state of
California to cause cancer.

HMIS (Hazardous Materials Information System) for secondary labeling:
HEALTH
FIRE HAZARD
REACTIVITY
PERSONAL PROTECTIVE EQUIPMENT
REFERENCES:
1. 2011 Threshold Limit Values and Biological Exposure Indices. American Conference of
Governmental Industrial Hygienists.
2. MSDS + Cheminfo CD-ROM, Canadian Centre for Occupational Health and Safety
3. SAXS Dangerous Properties of Industrial Materials, Tenth Edition
4. TSCA & SARA Title III, U.S. Environmental Protection Agency and the National Technical
Information Services
5. Raw Material Manufacturers Material Safety Data Sheets
6. US National Institute of Medicines Toxnet current edition
7. ESIS: European Chemical Substance Information System, http://ecb.jrc.it/esis
8. NOHSC Hazardous Information Substances Information System, Department of Employment and
Workplace Relations, Australian Government, 2005
To the best of our knowledge the information contained herein is accurate. However, 3D-Materials makes
no warranty, expressed or implied regarding the accuracy of these results to be obtained from the use
thereof. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist. 3D-Materials assumes no responsibility for injury from the use of the product
described herein.
DISCLAIMER OF LIABILITY: The following supersedes any provision in the forms, letters and agreements
between your business and 3D-Materials.
3D-Materials makes no direct or indirect guarantee for this product, including warranties of
merchantability or fitness for a particular purpose. 3D-Materials shall in no event be liable for incidental,
consequential or other resulting from alleged negligence, breach of warranty, strict liability or any other
theory is, after the use or handling of this product. The sole liability of 3D-Materials, as part of an
application any compensation in connection with the manufacture, use or sale of its products is limited to
the purchase price paid by the purchaser. The content of this MSDS may be changed without notice.
3D-Materials invites you to periodically check their website to make sure you have the most recent MSDS.

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SAFETY DATA SHEET

Issue Date 19-Nov-2013

Revision Date 22-May-2014

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Other means of identification

Recommended use of the chemical and restrictions on use

(913) 777-4996 [9-5PM CST, M-F]

Physical state liquid

0% of the mixture consists of ingredient(s) of unknown toxicity

4. FIRST AID MEASURES

If symptoms persist, call a physician.

Self-protection of the first aider

Use personal protective equipment as required.

Most important symptoms and effects, both acute and delayed

May cause allergic skin reaction.

Indication of any immediate medical attention and special treatment needed

May cause sensitization of susceptible persons. Treat symptomatically.

6. ACCIDENTAL RELEASE MEASURES

Ensure adequate ventilation, especially in confined areas. Use personal protective

Methods and material for containment and cleanup

Prevent further leakage or spillage if safe to do so.

7. HANDLING AND STORAGE

Conditions for safe storage, including any incompatibilities

Strong oxidizing agents. Strong acids. Strong bases.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Appropriate engineering controls

Ensure adequate ventilation, especially in confined areas.

Individual protection measures, such as personal protective equipment

Tight sealing safety goggles.

Skin and body protection

Wear protective nitrile rubber gloves.

In case of insufficient ventilation, wear suitable respiratory equipment.

General Hygiene Considerations

9. PHYSICAL AND CHEMICAL PROPERTIES

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION

Risk of serious damage to eyes.

Information on toxicological effects

May cause an allergic skin reaction.

Risk of serious damage to eyes.

Numerical measures of toxicity - Product Information

0% of the mixture consists of ingredient(s) of unknown toxicity

12. ECOLOGICAL INFORMATION

Persistence and degradability

Other adverse effects

13. DISPOSAL CONSIDERATIONS

Do not reuse container.

14. TRANSPORT INFORMATION

15. REGULATORY INFORMATION

SARA 311/312 Hazard Categories

D2B - Toxic materials

16. OTHER INFORMATION

Physical and Chemical

MATERIAL SAFETY DATA SHEET

FILE NO.: 004

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

A PEL or TLV has not been established

MATERIAL SAFETY DATA SHEET

FILE NO.: 004

INHALATION: May cause respiratory tract irritation

AUTOIGNITION TEMP. METHOD=

FLAMMABLE LIMITS (% VOLUME IN AIR)

FIRE AND EXPLOSION HAZARDS

MATERIAL SAFETY DATA SHEET