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J. FERNANDEZ
INSTIUTE OF BIOLOGY, COLLEGE OF SCIENCE
UNIVERSITY OF THE PHILIPPINES, DILIMAN, QUEZON CITY 1101, PHILIPPINES
DATE SUBMITTED: DECEMBER 13, 2013
DATE PERFORMED: DECEMBER 6, 2013
ABSTRACT
Chemical kinetics determines the rate of a certain reaction. Rate of reaction can be expressed as the ratio of the
change in concentration of a reactant/product over the change in time. There are many factors that affect the rate of
reaction and three of these factors were investigated in this paper. Different runs of the used mixture were subjected
to varying parameters. The effect of concentration was first examined. Based on the results, the higher the
concentration, the immediate is the reaction. The effect of temperature was also observed and it was very evident in
the results that rate and temperature are directly related. The presence of catalyst was the last factor to be studied
wherein the change in rate was very evident. The presence of catalyst resulted to very fast reaction. The effect of
these factors can be attributed to the changes that happen in the collision of reacting particles. The catalyst worked
by lowering the activation energy which is the minimum energy required for a reaction to take place.
INTRODUCTION
Chemical kinetics is the branch of chemistry that
deals with how fast a reaction occurs. Unlike
thermodynamics that just tells us if a reaction can
occur spontaneously, chemical kinetics determines
the reaction rates. The rate of reaction reflects the
rate of change in the concentrations of the reactants
and products of a reaction. For a hypothetical reaction
below,
2
2
S2 O8
S O4
=
=
Rate=
[ I 2]
t
REFERENCES
APPENDIX
Calculations
0.02 x
0.02 x
0.08 y
k
k
Rate 1 2.4 x 103
=
=
Rate 2 1.6 x 103
0.02
0.04 x
y
0.04
0.04 y
k
k
Rate 2 1.6 x 1 03
=
=
Rate 5 3.4 0 x 103
log 0.34 = x log 0.5 + y log 1
x = 1.55 ~ 2
y= 0.6 ~ 1
Sample Calculations
Run 1
[S2O82-] = 0.1M x 5 mL / 25 mL = 0.02 M
[I-] = 0.2 M x 10 mL / 25 mL = 0.08 M
Rate = 1/t
Y = A + Bx
Y = 5.75 3657.1 x
Ea = m x R
Ea = (-3657.1) x (8.314)
Ea = 30.4 kJ/mol
A = e5.75
A= 314.2