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Absorbance
550 nm
2 M
0.065
6 M
0.205
10 M
0.338
14 M
0.474
18 M
0.598
unknown
0.402
at
Determine the concentration of unknown, find the slope and intercept of the
calibration curve
3. EDTA forms colored complexes that may serve as the basis for the
quantitative spectrophotometric method of analysis. The molar absorptivites
of the EDTA complexes of Cu 2+, Co 2+, Ni 2+ at threee different wavelength are
summarized in the following table (all values of are in M-1 cm-1)
Metal
462,9
732.0
378.7
Co2+
15.8
2.11
3.11
Cu2+
2.32
95.2
7.73
Ni2+
1.79
3.03
13.5
0.223
0.294
0.361
Report the part per billion of Mn2+ in the sample of sea water
5. Glodenins describes the use of ICP to analyze samples containing Pb and NI in
brass. The analysis for Pb uses external standard prepare from brass samples
containing known amounts of lead. The analysis for Ni uses an internal
standard. Results for a typical calibration are shown in the following table
% w/w Ni
0.000
0.00267
0.0140
0.00154
0.0330
0.00312
0.130
0.120
0.280
0.246
0.280
0.247
0.560
0.533
1.30
1.20
4.82
4.44
What is the % w/w Ni in a sample for which the ratio of emmision intensity is
1.10 x 10-3