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Charge
Mass
ARRANGEMENT OF ELECTRONS
AROUND THE NUCLEUS
There are
PRINCIPLE QUANTUM SHELL, i.e. 1, 2, 3, 4
Electrons can be described by quantum numbers.
The principal quantum number, n , describes the main energy level of an electron.
It also indicates the relative size of the orbital and therefore relative distance of the electron
from the nucleus. The larger the value of n, the higher the energy level and the further the
electron from the nucleus.
The maximum number of electrons that can occupy each principal quantum shell is 2n2 .
Number of subshells in a principal quantum shell is same as its principal quantum number.
Subshells within a given quantum shell differ slightly in energy, the energy of the subshell
increasing according to the following order: s, p, d, f
2s1
Subshells
Orbitals
1s
one 1s orbital
2s
one 2s orbital
2p
three 2p orbitals
n=3
3s
one 3s orbital
3p
three 3p orbitals
3d
five 5d orbitals
n=4
4s
one 4s orbital
4p
three 4p orbitals
4d
five 4d orbitals
4f
seven 4f orbitals
The number of subshells in a principal quantum shell is the same as its principal quantum
number.
1
contains 1 s orbital
contains 3 p orbitals
contains 5 d orbitals
contains 7 f orbitals
Orbitals
An atomic orbital is defined as the region of space with a 90% probability (or more) of finding an
electron.
The distribution of the probability of finding an electron at a certain position is the electron
density.
Each subshell (s, p, d, f) has one or more orbitals at the same energy level (degenerate) but
different orientations in space.
Each orbital can contain up to a maximum of 2 electrons. These electrons are of opposite spins.
The s Orbital
The p Orbital
The d Orbital
When filling subshells that contain more than one orbital with the same energy (p, d and f
subshells), each orbital must be singly occupied before electrons are paired.
An orbital cannot hold more than two electrons and the two electrons sharing the same orbital
must have opposite spins.
Explanation: Both of these configurations have a symmetrical 3d cloud of electrons which screens
the outermost electrons from the nucleus more effectively than other configuration, resulting in
lowest energy for the system.
Electronic Configuration and Periodicity
while most of the d-block elements are considered as transition metals, there are exceptions:
A transition metal is a d-block element that forms some compounds containing its ion with an
incomplete d-subshell.
d-block elements such as scandium and zinc are not considered to be transition elements:
- scandium forms only the Sc3+ which has the 3d0 configuration
3
Nuclear charge, and shielding effect, and hence effective nuclear charge
Electrostatic force of attraction between the positively charged nucleus and the outermost
electrons (whether they are pulled closer to the nucleus)
Relatively invariant
Nuclear charge increases due to increasing number of protons
Electrons are added to the inner 3d subshell, which contributes to the screening effect
Screening effect increases and nullifies, to a considerable extent, the influence of additional
proton in the nucleus
Effective nuclear charges remains almost constant
There is a sharp increase in ionic radius from the cationic series of Na+ to Al3+ to the anionic
series of P3- to Cl-, because the anions have one more quantum shell of electrons than the
cations.
IONISATION ENERGY
X+ (g) + e
X+(g)
X2+ (g) + e
Hence,
nth ionisation energy is the energy needed to remove 1 mole of electrons from 1 mole of gaseous
ions with (n-1)+ charge to form 1 mole of gaseous ions with n+ charge.
X(n-1)+(g)
Xn+ (g) + e
Nuclear charge
Shielding effect
Effective nuclear charge
Electrostatic force of attraction between nucleus and outermost electrons
Mg
Al
The 3p subshell of Al is further away from the nucleus than the 3s subshell. There is weaker
attraction between the nucleus and the outermost electron. Less energy is required to remove the
3p electron from Al, resulting in a slower ionisation energy for Al.
All the 3p electrons in P are unpaired. In S, two of the 3p electrons are paired. There is some
inter-electronic repulsion between the paired electrons in the 3p subshell in S. Thus less energy
than expected is required to remove one of these paired electrons from S.
First Ionisation Energy Across Transition Elements:
Differentiate trend across period and trend across each isoelectronic series. (E.g. explain the
trend for atomic radii from Na+ to Cl-)
For electronic configurations of ions, write the electronic configuration of the neutral atom first,
and then add/remove valence electrons from the outermost shell (e.g. 4s instead of 3d)
Take note when to use the word atom and when to use the term ion
Take note when to use the term "hence lower amount of energy is required to... and "the
increase in energy needed..."
Inter-electronic repulsion does not just apply to nitrogen & oxygen (when comparing first IE,
etc), it applies to all Group V and adjacent Group VI elements (applies to all periods).
Note: deflection of charges/ions must not be drawn in straight lines [class test Q1]
Valence electrons refer to those in the entire highest principal quantum shell. E.g. valance
electrons in N atom are those in 2s2 and 2p3 and not just 2p3. [LT Q2 (a)]
First ionization energy of period 3 atoms are lower than those in period 2. Take note of this
when drawing the graph for first I.E. [LT Q2 (b)]
It is important to state the principle quantum shell number. E.g. electrons in the 2p orbital,
not just .. in the p orbital. When the principle quantum shell number is unknown, use ns, np,
etc. [LT1 Q2 (b)]