Analysis of Physics Test Paper 1

PT-01
Date: 10-08-2014
Syllabus:- Geometrical optics (upto Thin lens and lens formula), Rectilinear
motion complete
PT-1
S.No.
Subject
1 to 25
Nature of Questions
No. of Questions Marks Negative
SCQ
26 to 30
31 to 36
37 to 37
Maths/ MCQ
Physics/ Comprehension tough (3 Com. 2 Q.)
Chemistry
Match the Column (4 Vs. 5)
38 to 45
Integer Type Questions (Single Digit Answer)

Total
Total
25
75
20
18
32
Total
45
153
SECTION-1 : (Only One option correct type)

[k.M1 : (dsoy ,d lgh fodYi dkj)
This section contains 25 multiple choice qustions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
bl [k.M esa 25 cgqfodYi 'u gSA R;sd 'u esa pkj fodYi (A), (B), (C) vkSj (D) gS] ftuesa ls dsoy
,d lgh gSA
SCQ._(25)
1.
A particle leaves the origin at t = 0 with an initial velocity v 3V0 i . It experiences a constant
acceleration a 2a1 i 5a2 j . The time at which the particle reaches its maximum x coordinate in
positive direction is :
(V 0 , a1 and a2 are positive constants) [RM_AA]
,d d.k t = 0 ij ewy fcUnq ij gS rFkk mldk izkjfEHkd osx v 3V0 i gSA ;g ,d fu;r Roj.k
a 2a1 i 5a2 j ls xfreku gSA og le; D;k gksxk ftlesa d.k dk x funsZa'kkad /kukRed fn'kk esa vf/kdre~ gks%
(V 0 , a1 rFkk a2 /kukRed
fu;rakd gSa)
3V0
3V0
(B)
10 a2
2a1 5a2
For maximum x coordinate
vf/kdre~ x funsZa'kkad ds fy,
0 = 3V0 2a1t
(A)
Sol.
t=
2.
(C*)
3V0
2a1
(D)
3V0
2 a1 5 a 2
3V0
2 a1
A particle moves in such a way that its position vector as function of time is given by

r i 4t 2 j t k , where r is in (m) and t is in(s). Then the trajectory of the particle is :
[RM_DD]
,d d.k bl izdkj ls xfr djrk gS] fd mldk fLFkfr lfn'k le; ij fuEukuqlkj fuHkZj djrk gS

r i 4t j t k , tgkW r ehVj esa gS ,oa t lSd.M esa gSA rc d.k dk iFk gksxk :
2
(A*) A parabola
(B) An ellipse
(C) A circle
(D) None
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Sol.
3.
Sol.
(A*) ,d ijoy;
(B) ,d
x=1
y = 4t2
z=t
y = 4z2
Parabola passing from (1,0,0).
ijoy; fcUnq (1,0,0) ls xqtjrk gSA
nh?kZ o`
k
(C) ,d
o`
k
(D)
buesa ls dksbZ ughaA
1 2
x ), where
4
a is acceleration in m/s2 and x is position in meter. If velocity v = 17 m/s when x = 0, then the
velocity of the particle when x = 4 meter is :
[RM_AA]
1
ljy js[kk esa xfreku ,d d.k dk Roj.k laca/k a = 4x (1 + x2), ds }kjk ifjHkkf"kr fd;k tkrk gSA tgk a
4
Roj.k m/s2 esa gS rFkk x ehVj esa fLFkfr gSA ;fn x = 0 ij v = 17 m/s gks rks x = 4 m ij d.k dk osx gksxk :
(A) 12 m/s
(B*) 15 m/s
(C) 20 m/s
(D) 25 m/s
a = 4x (1 + 0.25 x2)
Acceleration of a particle moving in straight line is given by the relation a = 4x (1 +
vdv (4x x 3 )dx
17
1 2
4
1
(v 172) = (x 2 )04 (x 4 )40
2
2
4
1
v 2 172 = 4(42) (44 ) = 64 128
2
V 2 = 289 64 = 225
V = 15 m/sec.
4.
T he radius of curvature of a convex sp her ical m irror is 1.2 m . How far awa y from the
m irror is a n object of height 1.2 cm if the d istance between its virtual imag e an d th e
m irror is 0 .35 m? W hat is the he igh t of the im age ? [Apply form ula for par axia l r a ys]
[GO_SM]
,d mky xksyh; niZ.k dh ork f=kT;k 1.2 ehVj gSA 1.2 lseh- pkbZ dh ,d oLrq niZ.k ls fdruh nwjh ij
fLFkr gS ;fn blds vkHkklh frfcEc o niZ.k ds chp dh nwjh 0.35 ehVj gS ? frfcEc dh pkbZ D;k gS ?
[ v{k ds utnhd fdj.kksa ds fy, lw=k yxkus ij ]
( A*) 84 cm , 0.5 cm
( C) 84 cm, 1.2 cm
Ans. 84 cm , 0.5 cm
(B) 84 cm , 0.25 cm
(D) 8 0 cm , 0 .2 5 cm
Sol.
m =
5.
h2 v
h1
u
h2 =
v
0.35 1.2 cm
h1 =
= 0.5 cm .
u
0.84
A point object is moving along principal axis of a concave mirror with uniform velocity towards pole.
Initially the object is at infinite distance from pole on right side of the mirror as shown. Before the
object collides with mirror, the number of times at which the distance between object and its image
is 80 cm are.
[GO_SM]
,d fcUnq fcEc ,d vory niZ . k dh eq [ ; v{k ds vuq f n'k /kz q o dh vks j ,dleku os x ls xfr
dj jgk gS A iz k jEHk es a fcEc niZ . k ds nka ; h vks j /kz q o ls vuUr nw j h ij gS tS l k fd fn[kk;k x;k
gS A fcEc ds niZ . k ls Vdjkus ls igys ] fdrus ckj fcEc rFkk blds iz f rfcEc ds chp dh nw j h 80
c m gS A
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Sol.
( A*) more than two times

(B) less than two times
( C) two times
(D) D ata insufficie nt
( A) nks ckj ls T;knk
(B) nks ckj ls de
( C) nks ckj
(D) vk d M+ s vi;kZ I r
A s the o bject mo ves from infinit y to ce ntre of cur va ture, th e d istance betwe e n o bject
a n d image red uces fr om infinit y to ze ro .
A s th e object m oves fr om centre of cu rva tur e to focus, the d istance be twe en object
a n d image incr eases from zer o to infin ity.
A s the objec t moves from focus to po le, th e d istance b etween object and its image
r ed uces from infinit y to zero. He nce th e d istance b etwe en o bjec t and its im age sha ll
b e 4 0 cm thr ee times.
Sol.
tc fcEc vuUr ls ork ds U nz rd xfr djrk gS ] fcEc rFkk iz f rfcEc ds chp dh nw j h vuUr ls
'kw U ; rd ?kV tkrh gS A
tc fcEc ork dsUnz ls Qksdl dh vksj xfr djrk gS] fcEc rFkk blds izfrfcEc ds chp dh nwjh 'kwU; ls vuUr
rd c<+rh gSA
tgka fcEc Qks d l ls /kz q o dh vks j xfr djrk gS ] fcEc vkS j blds iz f rfcEc ds chp dh nw j h
vuUr ls 'kw U ; rd ?kVrh gS A blfy, fcEc rFkk blds iz f rfcEc ds chp dh nw j h 4 0 cm rhu
ckj gks x hA
6.
A particle is moving with velocity 5 m/s towards east and its velocity changes to 5 m/s north in 10
sec. Find the average acceleration in 10 seconds.
[RM_AV]
,d d.k 5 m/s ds osx ls iwoZ dh vksj xfr dj jgk gS rFkk 10 sec esa bldk osx ifjofrZr gksdj 5 m/s mkj
dh vksj gks tkrk gSA 10 lSd.M esa d.k dk vkSlr Roj.k Kkr djksA
(A)
2NW
(B*)
1
2
N W
(C)
1
2
NE
(D)
2 NE
Sol.
V f Vi
a =
t
5j 5i
a =
10
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5 2
|a| =
=
10
m/s2
2
Direction north west fn'kk
7.
mkj if'pe
In the figure shown find the total magnification of the image formed after two successive reflections
first on M1 and then on M2 . (Assume paraxial rays only)
[RM_SM]
n'kkZ;s x;s fp=k esa igys M1 o fQj M2 ij gksus okys nks mkjkskj ijkorZuksa ds ckn cus izfrfcEcksa dk dqy
vko/kZu Kkr dhft,A (dsoy lek+{kh; fdj.ksa ekusa)
(A) + 6
Sol.
For M1 ds
fy,
(B*) 6
(C) + 3
uf
(30) (20)
: v1 =
= 60
u f (30) (20)
(D) 3
v1
= 2.
u
For M2 ds fy, : u = + 20. f = 30
M=
1
1
1
+
=
v = 60
v
20
30
60
m2 =
= 3 m = m1 m 2 = 6
20
8.
Sol.
A body moves with constant velocity of 50 m/sec from the point (3, 4) m in a direction of 3 i 4 j .
The position vector of the body at t = 3 sec. is :
[RM_DD]
,d oLrq fu;r osx 50 m/sec ls xfreku gS] ;g fcUnq (3, 4) m ls izkjEHk gksdj fn'kk 3 i 4 j esa xfreku gSA
t = 3 sec. ds i'pkr~
(A) ( 51i 104j )m

s rf ri vt
oLrq dk fLFkfr lfn'k D;k gksxk :

(B) ( 5i 117j )m
(3i 4j)
rf (3i 4j) = 50
3
5
9.
(C*) ( 93i 124j )m
(D) ( 2i 10 j )m
rf 93i 124j
From a building two balls A and B are thrown such that A is thrown upwards and B downwards
(both
vertically with same speed). If VA and VB are their respective velocities on reaching the ground,
then
[RM_AA]
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(1) vB> vA
(3) vA> vB
(2*) vA =vB
(4) their velocities depends on their masses
,d bekjr ls nks xsansa A o B ,d leku pky ls Qsadh tkrh gSa, A dks /okZ/kj ij dh vksj o B dks /okZ/kj
uhps dh vksj Qsadrs gSaA ;fn Hkwfe ij igqWpus ij nksuksa ds osx e'k% VA o VB gSa, rks %
10.
(1) vB> vA
(2*) vA =vB
(3) vA> vB
(4)
muds osx nzO;eku ij fuHkZj djrs gSa
The speed of a particle moving along straight line becomes half after every next second. The initial
speed is v0. The total distance travelled by the particle will be [RM_DD]
,d lh/kh js[kk esa xfr'khy ,d d.k dh pky R;sd vxys lSd.M ds ckn vk/kh gks tkrh gSA kjfEHkd pky v0
gSA d.k }kjk r; dh xbZ dqy nwjh gksxh &
[P&R]
(A) v0
(B*) 2v0
(C)
(D) None buesa ls dksbZ
ughaA
v0
v
1 + 0 1 + ............
2
4
1 1
= v0 1 ..............
2
4
= 2v0
Sol.
Distance nwjh = v0 1 +
11.
A particle moves from xA = 0.5 m to positon x B = 1.5 m in 2s, then in another 4s it moves from xB =
1.5 m to xC = 2.5 m, then ratio of magnitude of it's average velocity to average speed for whole
time.
[RM_AV]
,d d.k xA = 0.5 m ls xB = 1.5 m rd 2s esa pyrk gS fQj vxys 4s esa xB = 1.5 m ls xC = 2.5 m rd
pyrk gS rks d.k ds vkSlr osx ds eku ,oa vkSlr pky ds eku dk vuqikr (iwjs le;kUrjky esa) D;k gksxk &
1
6

Vavg
V
avgspeed
(A)
Sol.
12.
(B*)
1
3
(C)
1
2
(D)
2
3
2
1
6
ratio =
6
3
6
It is fo und that all elec trom agnetic sig nals se nt from A towards B reach po int C. The
s pe ed of electr omag netic s ign als in g la ss ca n not be : [GO_RP]
;g ik;k tkrk gS fd fo|q r pq E cdh; la n s ' k tks fd fcUnq A ls B dh rjQ Hks t s x;s gS a ] fcUnq
C ij igq p rs gS a rks dk p es a fo|q r pq E cdh; la n s ' kks a dh pky ugha gks ldrh &
C
fuokZr
dkap
( A) 1.0 10 8 m /s
( C) 2 10 7 m/s
Sol.
(B*) 2.4 10 8 m/s

(D) 1 .4 10 7 m /s
T his is a cas e of tota l interna l r eflectio n.
;g iw.kZ vkUrfjd ijkorZu dh fLFkfr gSa
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fuokZr
dkap
Vaccum
glass
1
)
> C ( = s in 1
1
< sin
1
< sin 45
> 1/s in 45
> 2
c
v =
v <
3 108
2
2
v < 2.1 10 8
on ly ( B) is not possible.
dsoy (B) laHko ugha gSA
13.
The reflecting surface of a plane mirror is vertical. A particle is projected in a vertical plane which
is also perpendicular to the mirror. The initial speed of the particle is 10 m/s and the angle of
projection is 60 from the normal of the mirror. The point of projection is at a distance 5m from the
mirror. The particle moves towards the mirror. Just before the particle touches the mirror, the
velocity of approach (the rate at which separation is decreasing) of the particle and the image is ;
lery niZ.k dh ijkorZd lrg /okZ/kj gSA ,d d.k /okZ/kj ry esa iz{ksfir fd;k tkrk gS rFkk ;g /okZ/kj
ry niZ.k ds yEcor~ gSA d.k dh izkjfEHkd pky 10 m/s rFkk niZ.k ds vfHkyEc ds lkFk iz{ksi.k dks.k 60 gSA
iz{ksi.k fcUnq niZ.k ls 5m dh nwjh ij gSA d.k niZ.k dh rjQ xfr djrk gSA d.k ds niZ.k dks Li'kZ djus ds
Bhd igys d.k rFkk izfrfcEc dk lkehI; osx vFkkZr~ og nj ftlls d.k rFkk izfrfcEc ds e/; nwjh de gks jgh
gS gksxk ;
[GO_PM]
(A*) 10 m/s
(B) 5 m/s
(C) 10 3m / s
(D) 5 3m / s
Sol.
(V i,m)x = (Vo,m)x
(V i Vm)x = (Vo Vm)x
V ix O = Vox
V ix = 5m/s
V app = 5 (5) = 10 m/s
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14.
Given that, velocity of light in quartz = 1.5 108 m/s and velocity of light in glycerine = (9/4) 108
m/s. Now a slab made of quartz is placed in glycerine as shown. The shift in the position of the
object produced by slab is
[GO_RP]
8
DokVZt esa izdk'k dk osx = 1.5 10 eh@ls- ,ao fXyljhu esa izdk'k dk osx = (9/4) 108 eh@ls- fn;k x;k
gSA vc fp=kkuqlkj] DokV~Zt dh ,d iV~Vh fXyljhu esa j[kh tkrh gSA iV~Vh }kjk mRiUu oLrq dh fLFkfr esa
foLFkkiu gSA
(A*) 6 cm
Sol.
(B) 3.55 cm
(C) 9 cm
(D) 2 cm
nquartz DokVZt
4
2
3
n q u a r t z DokVZt = 2 ; n g l y c e r i n e fXyljhu =
=
=
= rel
2
3
nglycerine fXyljhu
4/3
s hift
15.
foLFkkiu = t 1
1
1
= 6 cm
= 18 1
3 / 2
rel
The figure shows a parallel slab of refractive index n2 which is surrounded by media of refractive
indices n1 and n3. Light is incident on the slab at angle of incidence ( 0). The time taken by the
ray to cross the slab is t1 if incidence is from n1 and it is t2 if the incidence is from n3. Then
assuming that n2 > n1, n2 > n3 and n3 > n1, value of t1/t2 is
[GO_RP]
fp=k esa ,d lekUrj ifdk ftldk viorZ u ka d n2 gS] nks ek/;eksa ls f?kjh gqbZ gS ftlesa ,d dk viorZ u ka d
n1 vkSj nwljs dk n3 gSA izdk'k ( 0) vkiru dks.k ij ifdk ij vkifrr gksrk gSA ifdk ls xqtjus esa
izdk'k fdj.k }kjk fy;k x;k le; t1 gS vxj vkiru n1 ls gks r k gS vkSj ;g t2 gS vxj vkiru n3 ls
gks r k gS rks ;g ekfu, fd n2 > n1, n2 > n3 vkSj n3 > n1, t1/t2 dk eku gksxk
(A) = 1
(B) > 1
(C*) < 1
(D) cannot be decided
fu.kZ ; ugh dj ldrs
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Sol.
Time taken by ray to cross the slab.
ifdk dks ikj djus esa izdk'k fdj.k }kjk fy;k x;k le;
(d / cosr)
d
dsin i
=
=
(V / )
V cosr
V cos 2 r
1
t
cos2 r
Given fn;k gS n3 > n1
n2 n2
n1 n3
t=
16.
r1 < r2
(r1 and r2 are angles of refraction in first and second case respectively)
r1 < r2 (izFke rFkk

cos r1 > cos r2.
t1 < t2
t1
1
t2
f}rh; fLFkfr esa r1 rFkk r2 e'k% viorZu dks.k gS )
A prism having refra ctive in dex

2 and refracting ang le 30 , has on e of the
r efractin g surfaces polished. A beam o f ligh t incident on the other refractin g surface
w ill retrace its path if th e an gle of inc id ence is:
[GO_PR]
3 0 viorZ d dks . k o
2 viorZ u ka d okys ,d fiz T e dk dks b Z ,d viorZ d i`
" B ikW f y'k fd;k
x;k gS A nw l js viorZ d i`
" B ij vkifrr ,d iz d k'k iq a t blds iFk dks iq u % vuq j s f [kr
( retrace) djs x k ;fn vkiru dks . k gS %
( A) 0
(C*) 45
(B) 30
(D) 60
Sol.
sin i
2
sin 30
sin i =
1
1
2
2
i = 45 .
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17.
Sol.
In the fig ure ABC is the cross section of a rig ht ang led prism and BCDE is the cross
s ectio n of a g lass s lab. The poss ible v alu e of so that light incid ent norm a lly on the
fa ce AB does not cr oss the face BC is
(given s in 1 (3/5) = 3 7)
[GO_PR]
fp=k esa ABC ledks.k fTe dk vuqizLFk dkV rFkk BCDE Xykl ifdk dk vuqizLFk dkV gSA dk eku
ftlds fy, fdj.k lrg AB ij yEcor~ vkifrr gks ijUrq lrg BC ls ikj u dj ldsA ( fn;k gS sin 1
( 3/5) = 3 7)
( A) = 45
A = 90
r 2 = A = 90 > C
c os > s in C =
18.
(B*)
6/5 4
=
3/2 5
= 30
< cos 1
(C)
= 6 0
(D)
= 5 3
4
= 37 .
5
An insect at point P sees its two images in the water mirror system as shown in the figure. One
image is formed due to direct reflection from water surface and the other image is formed due to
refraction, reflection & again refraction by water mirror system in order. The separation between
the two images is. (Mirror has focal length 60 cm.) (nw = 4/3)
[GO_RP]
fcUnq P ij ,d dhM+k fp=k esa iznf'kZr ikuh niZ.k fudk; esa vius nks izfrfcEc ns[krk gSA ,d izfrfcEc ikuh dh
lrg ls
lh/ks ijkorZu ds }kjk curk gS rFkk nwljk izfrfcEc ikuh niZ.k fudk; }kjk e'k% viorZu] ijkorZu rFkk iqu%
viorZu ds e esa curk gSA nksuksa izfrfcEcksa ds e/; nwjh Kkr djksA niZ.k dh Qksdl nwjh 60 cm gSA (nw =
4/3)
(A) 12 cm
Sol.
(B*) 24 cm
(C) 36 cm
(D) 48 cm
Due to reflection at plane water surface and other image formation is shown in the figure.
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ikuh dh lrg ij ijkorZ u ds dkj.k vU; iz f rfcEc fp=kkuq l kj curk gS A
due to refraction at water d1 =
12
= 16 cm.
1
4/3
for m, P1 is an object.
1
1
1
+
=
v = 24 cm this is at P2.
v
40
60
It will act as object for water surface which makes image at P.
24 24
d2 =
= 36 cm
4/3
final images are P and P
for this
distance P P = 36 12 = 24 cm. Ans.

12
ikuh ij viroZ u ds dkj.k d1 =
= 16 cm. m
1
4/3
1
1
1
blls
+
=
v = 24 cm ;g P2 ij
v
40
60
ds fy, , P1 oLrq gS
gS A
;g ikuh lrg ds fy, oLrq dh rjg dk;Z djs x h rFkk P ij iz f rfcEc curk gS
24 24
= 36 cm
4/3
vfUre iz f rfcEc P rFkk Pij
d2 =
curk gS A
nw j h P P = 36 12 = 24 cm. Ans.
19.
A uniform , horizo ntal p aralle l beam of lig ht is incident u pon a pr ism. The p rism is in
th e sh ape of a qu arter c ylin der, of ra d ius R = 5 cm , and has th e in de x of re fraction n
= 5/3. The shortest d istanc e of the p oint of con vergence at wh ich the inci dent ra ys
a fter n ormal incid ence on pla ne surfac e an d subs equen t refraction at curve d surface
in ters ect on x ax is fro m O as shown in figure is : (N eglect the r ay wh ic h tra ve ls
a long x-ax is as sho wn in figure)
[GO_RP]
,d ,dleku izdk'k dk {kSfrt lekUrj fdj.k iqat fizTe ij vkifrr gksrk gS tSlk fd fn[kk;k x;k gSA fizTe
fp=kkuqlkj pkSFkkbZ csyu ds vkdkj dk gS] ftldh f=kT;k R = 5 cm rFkk viorZukad n = 5/3 gSA lery lrg
ls vfHkyEcor~ vkiru rFkk fQj oh; lrg ij viorZu ds i'pkr~ x v{k ij fdj.ksa ftl fcUnq ij vfHklkfjr
gksrh gS] ml fcUnq dh O fcUnq ls y?kqke nwjh gksxhA og fdj.k tks x-v{k ds vuqfn'k gS mls NksM+ nhft, tSlk
fd fp=k esa fn[kk;k x;k gS
( A) 4 cm
(B) 5/4 cm
(C) 9 /4 cm
(D*) 25/4cm
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Sol.
3
= 37.
5
T he ra ys above the ra y incident on cur ved surface a t i = 37
s ha ll suffer TIR a nd ne ed n ot b e c onsi der ed.
T he ra y incid ent as c urved surface at = 37
a fter r efraction inters ect curved surfac e at (B) a distance x 2 from O.
T he critica l a ngle for a ir-glass interfac e is = sin 1
In PCB
3
4
= tan 53 =
1 x2
3
or
the requ ir e distanc e OB = 5
x2 =
5
4
5
4
25
4
gok&dka p ds vUrjki`
" B ds fy, ka f rd dks . k =
3
sin 1 = 3 7,
5
i = 37 ij o lrg ij vkifrr fdj.k ds ij fdj.kks a dk

iw . kZ vkUrfjd ijkorZ u (TIR) gks x k rFkk mUgs a ys u s dh vko';drk ugha gS A
= 37 ij o lrg ij vkifrr fdj.k viorZ u ds ckn o lrg ij
( B) ij O ls x 2 nw j h ij iz f rPNs n djrh gS A
PC B es a ]
3
4
= tan 53 =
1 x2
3
20.
vko';d pkS M + k bZ x = x 1 x 2 =
x2 =
5
4
15 5
25
=
cm
2 4
4
In the shown figure find the value of so that final image is 6 cm behind the silivered face :
(Consider only near normal incidence)
[GO_RP]
iznf'kZr fp=k esa dk eku Kkr dhft,] rkfd vfUre izfrfcEc ikWfy'k dh xbZ lrg ls 6 cm ihNs cus:
(fdj.ksa dsoy vfHkyEc vkiru ds lehi ekfu;saA)
(A) 4
Sol.
or
(B*) 2
(C) 6
(D) None
dksbZ ugha
6 2 2
8
=2
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21.
A sm all rod ABC is p ut in wa ter mak ing a n ang le 6 with vertical. If it is viewed
( par axia lly) from abo ve, it will look like be nt shaped ABC' . The an gle of bending
4
( CBC ' ) will b e in de gree .......... nw

[GO_RP]
3
,d Nks V h NM+ ABC dks m/okZ / kj ls 6 ds dks . k ij ikuh es a j[kk x;k gS A ;fn bls bldh v{k
ds utnhd fdj.kks a (para xia lly) ls ij ls ns [ kk tkrk gS ] rks ;g eq M + s vkdkj A BC' tS l h
iz r hr gks r h gS A eq M + u s dk dks . k ( CBC ' ) fMxz h es a gks x k ........ nw
3
4
A
6
B
C'
C
Sol.
( A*) 2
x
=
OC
(C) 4
OC '
1
=
=
OC
(B) 3
x
=
OC '
(D) 4.5
C'
4
= = (6) = 8
3
b e nding an gle = = 2
Sol.
x
OC
x
OC '
OC '
1
=
=
OC
C'
6
B
4
= = (6) = 8
3
?kq e ko dks . k = = 2
22.
A spher ical surface of radius of curvat ure R separ ates a ir (refractive ind ex 1.0) from
g lass (refr active index 1.5). The centr e of curvature is in th e glass. A poin t object P
p laced in a ir is foun d to ha ve a rea l im age Q in th e glass. The line PQ cuts th e
s urface at a p oin t O a nd PO = OQ. The distan ce PO is e qua l to:
[GO_RS]
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ork f=kT;k dk xksyh; i`

"B gok ( viorZukad = 1.0) dks dkp ( viorZukad = 1.5) ls i`
Fkd djrk gSA
ork dsUnz dkp esa fLFkr gSA gok esa fLFkr ,d fcUnqor~ oLrq P dk okLrfod frfcEc Q, dkp esa curk gSA
js[kk PQ i`
"B dks O ij dkVrh gS rFkk PO = O Q A nwjh PO cjkcj gS :
R
Sol.
( A*) 5 R
Let us say
ekuk
(B) 3 R
PO = OQ = X
(C) 2 R
2 1
1
= 2
iz ; q D r
v
u
R
Substituting the values with sign
Applying
(D) 1.5 R
djus ij
1.5 1.0 1.5 1.0
=
X X
R
(Distances are measured from O and are taken as positive in the direction of ray of light)
(nwfj;k O ls ekih xbZ gS o izdk'k lapj.k dh fn'kk esa /kukRed gSA
2.5
0.5
=
X
R
X=5R
mi;q D r fpUg ds lkFk eku j[kus ij
23.
2 has refracting angle 60. Angle of maximum deviation is :
A prism of refractive index
,d 60 viorZu dks.k okys fizT+e dk viorZukad

450
Sol.
(A)
for = max
(B)
sin-1 (
gSA egke fopyu dks.k gS %

(C*) 30 +
sin-1
( 2 sin15 )
[GO_PR]
(D) none dksbZ
ugha
ds fy,
e = 90
1
r2 = sin1
1
r2 = sin1
= 45
2
2 sin15 )
r1 = A r2 = 15
sini
2
sin15
sin i =
2 sin 15
1
i = sin ( 2 sin 15)

max = i + e A
24.
= 30 + sin1 ( 2 sin 15)
A balloon is moving upwards with velocity 10 ms1. It releases a stone which comes down to the
ground in 11 s. The height of the balloon from the ground at the moment when the stone was
dropped is :
[RM_DD]
,d xqCckjk 10 eh0@lS0 osx ls tehu ls ij dh vksj tk jgk gSA blls ,d iRFkj fxjk;k tkrk gS
ij 11 lSd.M esa igqprk gSA tc iRFkj fxjk;k x;k Fkk] ml le; xqCckjs dh tehu ls pkbZ D;k
(A*) 495 m
(B) 592 m
(C) 460 m
(D) 500 m
] tks tehu
Fkh\
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10 m/s
A
H
t = 11 sec
Sol.
1 2
at
2
H = 10 11 5 (11)2
H = 110 605
H = 495 m
As pwafd s = ut +
Aliter :
oSdfYid fof/k
At the time of release, velocity of stone will be same as that of balloon, hence
eqDr djus ds le; iRFkj dk osx xqCckjs ds osx ds rqY; gksxk vr%
u = 10 ms1 , t = 11 s
xqCckjs dh pkbZ gksxh

1 2
gt
2
= ( 10) 11 + (10) (11)2 = 110 + 605 = 495 m
h = ut +
25.
A ray of light travelling in the direction
1
i 3 j
2
(A*) 30
1
i 3 j is incident on a plane mirror. After reflection, it
2
1
i 3 j . The angle of incidence is :
2
1
vkifrr dk'k fdj.k dh xkeh fn'kk
i 3 j
2
travels along the direction
,d lery niZ.k ij
A Ans
[GO_PM]
gSA ijkorZu ds ckn xkeh fn'kk
gks tkrh gSA fdj.k dk vkiru dks.k gS :

(B) 45
(C) 60
(D) 75
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SECTION-2 : (One or more option correct type)

[k.M2 : (,d ;k vf/kd lgh fodYi dkj)
This section contains 5 multiple choice qustions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE are correct.
bl [k.M esa 5 cgqfodYi 'u gSA R;sd 'u esa pkj fodYi (A), (B), (C) vkSj (D) gS] ftuesa ls dsoy ,d
;k vf/kd lgh gSA
MCQ._(5)
26.
W hich of the follo wing statements are incorre ct for spher ical m irrors.
fuEu esa ls dkSulk dFku xksyh; niZ.k ds fy, xyr gS &
[GO_SM]
( A*) a concave m irror forms only virtua l im age s for an y position of re al obje ct
,d vory niZ.k okLrfod oLrq dh fdlh Hkh fLFkfr ds fy, dsoy vkHkklh frfcEc cukrk gSA
( B) a c onvex m irror form s only virtual images f or an y p ositio n of a rea l objec t
,d mky niZ.k okLrfod oLrq dh fdlh Hkh fLFkfr ds fy, dsoy vkHkklh frfcEc cukrk gSA
( C*) a concave m irror forms only a vir tu al dim inis he d im age of a n obje ct placed
b e tween its p ole a nd the foc us
,d vory niZ.k] /kzqo o Qksdl ds chp j[kh oLrq dk dsoy vkHkklh o NksVk frfcEc cukrk gSA
( D*) a co nvex m irror fo rms a virtual e n large d im age of an object if it lies b e twee n its
p o le an d the focus.
;fn oLrq /kzqo rFkk Qksdl ds e/; gks rks mky niZ.k vkHkklh rFkk vkof/kZr frfcEc cukrk gSA
Sol.
(A) No, when object is between infinite and focus ,image is real.
ugh , tc oLrq vuUr rFkk Qks d l ds e/; gS ] iz f rfcEc okLrfod
(C) when object is between pole and focus, image is magnified.
gS
tc oLrq /kz q o rFkk Qks d l ds e/; gS ] iz f rfcEc vkof/kZ r gks x k

(D) when object is between pole and focus image formed by convex mirror is real.
tc oLrq /kz q o rFkk Qks d l ds e/; gS ] mky niZ . k }kjk cuk iz f rfcEc okLrfod gks x k
27.
In the shown figure two long plane mirror are kept parallel to each other with their reflecting side
facing one another. A point object 'O' is situated at the distance of 20 cm from A then :
[GO_PM]
iznf'kZr fp=k esa nks yEcs lery niZ.k ,d nwljs ds lekUrj j[ks gq, gSA rFkk muds ijkorZd i`
"B ,d nwljs ds
vkeus lkeus gSA ,d fcUnq oLrq 'O'] A ls 20 cm dh nwjh ij fLFkr gS] rc %
(A*) distance of first image formed in A is 50 cm from B.

(B*) distance between fifth image formed in the two mirrors is 3 m
(C) distance between fifth image formed in the two mirrors is 240 cm
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(D*) total of infinite images are formed in the two mirrors

(A*) A esa cus izFke izfrfcEc dh B ls nwjh 50 cm gksxhA
(B*) nksuksa niZ.kksa esa cus ikposa izfrfcEc ds e/; nwjh 3 m gksxhA
(C) nksuksa niZ.kksa esa cus ikposa izfrfcEc ds e/; nwjh 240 cm gksxhA
(D*) nksuksa niZ.kksa ds e/; vuUr izfrfcEc cusxsaA
Sol.
28.
Two plane mirrors are inclined to each other with their reflecting faces making acute angle. A light
ray is incident on one plane mirror. The total deviation after two successive reflections is:
[GO_PM]
nks lery niZ.k vius ijkorhZ i`
"Bksa ds lkFk U;wu dks.k (acute angle) cukrs gq, ,d nwljs ds lkFk >qds gq,
gSA ,d dk'k fdj.k fdlh ,d lery niZ.k ij vkifrr gksrh gSA nks mkjkskj ijkorZuksa ds ckn dqy fopyu&
(A*) independent of the initial angle of incidence kjfEHkd vkiru dks.k ij fuHkZj ugha djrk gSA
(B) independent of the angle between the mirrors niZ.kksa ds chp dks.k ij fuHkZj ugha djrk gSA
(C) dependent on the initial angle of incidence kjfEHkd vkiru dks.k ij fuHkZj djrk gSA
(D*) dependent on the angle between the mirrors.
niZ.kksa ds chp dks.k ij fuHkZj djrk gSA
Sol.
i r
2
2
i + r =
.........(i)
= 2i + 2r
= 2 (Anticlock wise okekorZ)
29.
Two plane mirrors are inclined to each other at 300. A ray is incident on M1 at angle of incidence
40. Find deviation produced in it by three successive reflections due to mirrors. [GO_PM]
nks lery niZ.k ijLij 300 >qdko ij gSaA ,d fdj.k M1 ij 40 ij vkifrr gksrh gSA niZ.kkssa ls rhu ekxr
ijkorZuksa ds ckn fdj.k dk fopyu dks.k D;k gksxkA
(A*) 160 Clockwise

(C*) 200Anticlockwise
(B) 200 Clockwise

(D) 160 Anticlockwise
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Sol.
So
30.
= 160 clockwise
= (360 160) Anticlockwise
= 200 Anticlockwise
Position time graph for a particle moving on straight line is shown in figure. Assume same slope of
xt graph at t = 0 and t = 20 s. Select correct alternative/s :
[RM_AA]
ljy js[kk esa xfr dj jgs ,d d.k ds fy, fLFkfr le;&xzkQ fp=kkuqlkj gSA ;g ekfu, fd t = 0 rFkk t = 20 s
ij xt xzkQ dk <ky leku gSA lgh fodYi@fodYiksa dk p;u dhft, :
(A*) Average velocity of particle from t = 0 to t = 20 sec. is zero.

(B*) Acceleration of particle from t = 10 sec. to t = 15 sec. is positive.
(C*) Average acceleration of particle from t = 0 to t = 20 is zero.
(D) Average velocity & instantaneous velocity becomes same in magnitude and direction more
than once from t = 0 to t = 20 sec.
(A*) t = 0 ls t = 20 sec esa d.k dk vkSlr osx 'kwU; gksxkA
(B*) t = 10 sec ls t = 15 sec esa d.k dk Roj.k /kukRed gksxkA
(C*) t = 0 ls t = 20 sec esa d.k dk vkSlr Roj.k 'kwU; gksxkA
(D) t = 0 ls t = 20 sec ds nkSjku d.k dk vkSlr osx rFkk rkR{kf.kd osx ifjek.k rFkk fn'kk esa ,d ls vf/kd
ckj leku gks tk,xkA
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SECTION 3 : (Paragraph Type)

[k.M 3 : (vuqPNsn dkj)
This section contains 3 paragraphs each describing theory, experiment, data etc. Six questions
relate to four paragraphs with two questions on each paragraph. Each question of a paragraph has
only one correct answer among the four choices (A), (B), (C) and (D).
bl [k.M esa fl)karksa] ;ksxksa vkSj vkdM+ksa vkfn dks n'kkZus okys 3 vuqPNsn gSA pkjksa vuqPNsnksa ls lacaf/kr N% 'u
gSa] ftuesa ls gj vuqPNsn ij nks 'u gSaA fdlh Hkh vuqPNsn esa gj 'u ds pkj fodYi (A), (B), (C) vkSj (D) gSa]
ftuesa ls dsoy ,d gh lgh gSA
Comp._(3)_(2 Ques.)
Paragraph for Questions 31 and 32
iz'u 31 vkSj 32 ds fy, vuqPNsn
COMPREHENSION # 1
A particle moves in x-y plane with constant acceleration a 6i 8 j ( in m/s2). At time t = 0, the
particle is at point having coordinates (0, 20 metre) and its initial velocity is u 12i 16j (in m/s).
,d d.k x-y ry es a fu;r Roj.k a 6i 8j (m/s2 es a ) ls xfreku gS A t = 0 le; ij d.k ds
funs Z ' kka d (0, 20 metre) vkS j iz k jfEHkd os x u 12i 16j (m/s es a ) gS A
[RM_AA]
31.
The instant of time when speed of the particle is zero will be :
fdl le; ij d.k dh pky 'kw U ; gks x h &

(A) 1 sec
Sol.
32.
(B*) 2 sec
(C) 3 sec
The velocity vector at time t is

v u at = 12i 16j (6 i 8j)t
solving for v 0 we get t = 2 sec. Ans.
(D) 4 sec
.... (1)
The speed of the particle at the instant, position vector and velocity vector of the particle are
mutually perpendicular will be :
ftl le; ij d.k dk fLFkfr lfn'k vkS j os x lfn'k ijLij yEcor~ gks r s gS ] ml le; d.k dh
pky gks x h &
(A) 4 5 m/s
(B) 20 m/s
(C*) 12 5 m/s
(D) None of these bues a
ls dks b Z ugha
Sol.
The velocity vector at time t is

v u at = 12i 16j (6 i 8j)t
.... (1)
solving for v 0 we get t = 2 sec. Ans.

The position vector at any time t is
1
1
r r0 ut at 2 = ( 12i 16j)t (6i 8j)t 2 .... (2)
2
solving for r.v 0 we get t =
8
3 5 5
sec.
putting t in equation (1) we get
| v | 12 5 m/s Ans.
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JRPT1130714C0-18
gy%
fdlh le; t ij os x lfn'k
v0

v u at = 12i 16j (6 i 8j)t
.... (1)
ds fy, gy djus ij ge iz k Ir djrs gS t = 2 sec. Ans.

fdlh le; t ij fLFkfr lfn'k
1
1
r r0 ut at 2 = ( 12i 16j)t (6i 8j)t 2
2
r.v 0
ds fy, gy djus ij t =
8
3 5 5
.... (2)
sec.
lehdj.k (1) es a t dk eku j[kus ij ge iz k Ir djrs gS A
| v | 12 5 m/s Ans.
vr% le; ds Qyu ds :i es a x-funs Z ' kka d

x = x0 + u x t +
x = 0 ds
1
a t2 = 12 t + 3t2
2 x
fy, gy djus ij t = 5 sec. Ans.

COMPREHENSION # 2
An object O is placed 10 cm above the face AB of a homogenuous glass slab of refractive index
3
=
with lower face CD silivered as shown then answer following questions
2
(assume only paraxial rays) :
[GO_RP]
3
,d oLrq O] = viorZukad dh ,d lekax dkp dh ihdk dh lrg AB ls 10 cm ij fLFkr gSA
2
fupyh lrg CD dks fp=kkuqlkj ikWfy'k fd;k x;k gSA rc fuEu iz'uksa ds mkj nhft,A
(lekf{k; fdj.ksa ekfu;saA)
D
33.
Find the distance from CD of the image formed by the reflection of light from face CD :
(A) 11 cm
(B*) 18 cm
(C) 14 cm
(D) None
lrg CD izdk'k ds ijkorZu }kjk cus izfrfcEc dh CD ls nwjh Kkr dhft,A
(A) 11 cm
(B*) 18 cm
(C) 14 cm
(D) dksbZ ugha
34.
Find the distance of the final image formed by the slab from CD :
(A*) 11 cm
(B) 18 cm
(C) 14 cm
lrg CD ls ihdk }kjk cus vfUre izfrfcEc dh nwjh Kkr dhft,A
(A*) 11 cm
(B) 18 cm
(C) 14 cm
(D) None
(D)
dksbZ ugha
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JRPT1130714C0-19

COMPREHENSION # 3
A concave mirror of radius of curvature 20 cm is shown in the figure. A circular disc of diameter 1
cm is placed on the principal axis of mirror with its plane perpendicular to the principal axis at a
distance 15 cm from the pole of the mirror. The radius of disc starts increasing according to the
law r = (0.5 + 0.1 t) cm/sec where t is time is second.
[GO_SM]
,d vory niZ . k dh ork f=kT;k fp=kkuq l kj 20 cm gS A ,d o`
kkdkj pdrh ftldk O;kl 1 cm
gS ] dks niZ . k ds eq [ ; v{k ij eq [ ; v{k ds yEcor~ niZ . k ds /kz q o (pole) ls 15 cm dh nw j h ij
fp=kkuq l kj j[kk tkrk gS A vc pdrh dh f=kT;k fu;e r = (0.5 + 0.1 t) cm/sec ds vuq l kj c<+ u k
iz k jEHk djrh gS tgk t le; ls d .M es a gS A
35.
The area of image of the disc at t = 1 second is :

pdrh ds iz f rfcEc dk t = 1 ls d .M ij {ks = kQy gks x k &
(A) 1.2 cm2
(B*) 1.44 cm 2
(C) 1.52 cm2
(D) none of these
bues a
ls dks b Z ugha
Sol.
(M od era te)
At t = 1 sec.
r = 0.5 t + 0.1 t = 0.6 cm
f
10
m=
=
=2
f u
10 15
Radius of image = 2r = 1.2 cm
Area of image = (1.2)2 = 1.44 cm 2 .
iz f rfcEc dh f=kT;k = 2r = 1.2 cm
iz f rfcEc dk {ks = kQy = (1.2)2 = 1.44 cm2 .
36.
What will be the rate at which the radius of image will be changing
(A*) 0.2 cm/sec increasing
(B) 0.2 cm/sec decreasing
(C) 0.4 cm/sec increasing
(D) 0.4 cm/sec decreasing
iz f rfcEc dh f=kT;k ds ifjorZ u dh nj D;k gks x h &

(A*) 0.2 cm/sec c<+ r h gq b Z
(B) 0.2 cm/sec ?kVrh gq b Z
(C) 0.4 cm/sec c<+ r h gq b Z
(D) 0.4 cm/sec ?kVrh gq b Z
Sol.
dr
= 0.1
dt
rimage = |m|robject = 2robject
drimage
dr
= 2.
= 0.2 = 0.2 cm/sec.
dt
dt
(E as y)
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JRPT1130714C0-20
SECTION-4 : (Matrix - Match Type)

[k.M4 : (eSfVDl&lqesy izdkj)
This section contains 1 questions. Each question contains statements
given in two columns, which have to be matched. The statements in
Column-I are labelled A, B, C and D, while the statements in
Column-II are labelled p, q, r, s and t. Any given statement in
Column-I can have correct matching with ONE OR MORE statement(s) in Column-II.
The appropriate bubbles corresponding to the answers to these questions have to be
darkened as illustrated in the following example. If the correct matches are A-p, s and t ;
B-q and r; C-p and q; and D-s and t; then the correct darkening of bubbles will look like
the following :
bl [k.M esa 1 iz'u gSaA izR;sd iz'u esa nks dkWye esa oO; (statements) fn;s gq, gSa
ftudk lqesy (match) djuk gSA dkWye-I (Column-I) ds oO;ksa dks A, B, C
rFkk D ukfer fd;k x;k gSa tcfd dkWye-II (Column-II) ds oO;ksa dks p, q, r,
s rFkk t ukfer fd;k x;k gSaA dkWye-I (Column-I) esa fn, x, dksbZ ,d oO;
dkWye-I (Column-II) ds ,d ;k ,d ls vf/kd oO; oO;ksa ls lgh lqesy
djrk gSA bu iz'uksa ds mkj
fuEufyf[kr mnkgj.k ds vuqlkj mfpr cqYyksa dks dkyk djds n'kkZuk gSA
;fn lgh leqsy A-p, s vkSj t ; B-q vkSj r; C-p vkSj q; rFkk D-s vkSj t gS; rks lgh fof/k ls dkys fd, x,
cqYys ,sls fn[krs gSa tks fuEufyf[kr gSaA
MTC_(1)_(4 to 5)
37.
T he veloc ity tim e grap h for a particle movin g alon g a straight line is given in each
s itua tion of colum n-I . In th e tim e in ter v al 0 < t < , match th e gr aph in colu m n-I with
c orres pond ing statements in c olum n-I I .
[RM_AA]
lwph-I dh izR;sd fLFkfr esa ,d ljy js[kk ds vuqfn'k xfr djrs gq;s ,d d.k ds fy, osx≤ xzkQ fn;s x;s
gSA le;kUrjky 0 < t < esa] lwph-I ds xzkQksa dks lwph-I I esa laxr dFkuksa ls lqesfyr dhft;sA
List
List
lwph
lwph
v
( A)
(p)
sp eed
of
partic le
is
co ntinously
t
decreas ing .
d.k dh pky lrr :i ls ?kV jgh gSA
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JRPT1130714C0-21
v
( B)
(q) magnitu de of acce lera tion of par tic le is first
t
dec reas ing then incr easin g.
d.k ds Roj.k dk ifjek.k igys ?kV jgk gS rFkk fQj c<+ jgk gSA
( C)
(r) speed of the particle continuously increasing
d.k dh pky yxkrkj c<+ jgh gSA
( D)
v
t
(s) magnitud e of acceleratio n of partic le do es no t
cha ng e.
d.k ds Roj.k dk ifjek.k ifjofrZr ugh gksrk gSA

(t) magnitude of acceleration of particle is first increasing
then decreasing.
d.k ds Roj.k dk ifjek.k igys c<+ jgk gS ] rFkk fQj

?kV jgk gS A
Ans .
Sol.
( A) s ; (B) s ; (C) p ; ( D) p
In cas e P an d Q acceler ation is co nsta nt bu t spe ed first decreases and th en
in cr eases.
In case R and S, th e velocit y do es not ch ange sign h enc e direc tion of acceler ation is
c onsta nt. Sp eed a nd magnitud e of acc eleratio n decreases with tim e.
fLFkfr P rFkk Q esa Roj.k fu;r gS ysfdu pky igys ?kVrh gS rFkk fQj c<+rh gSA fLFkfr R rFkk S esa osx dk
fpUg ugh cnyrk gS blfy;s Roj.k dh fn'kk fu;r jgrh gSA Roj.k dk ifjek.k rFkk pky le; ds lkFk ?kVrs
gSaA
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JRPT1130714C0-22
SECTION-5 : (Integer value correct Type)

[k.M 5 : (iw.kkd eku lgh dkj)
This section contains 7 questions. The answer to each question is a single digit integer, ranging
from 0 to 9 (both inclusive)
bl [k.M esa 7 'u gSA R;sd 'u dk mkj 0 ls 9 rd nksauks 'kkfey ds chp dk ,dy vad h; iw.kkZad
gSA
Integer_(8)_(Single Digit)
38.
A small piece of wood is floating on the surface of a m deep lake. When the sun is vertically
above the piece its shadow is formed at A. When the sun is just setting the shadow of the piece is
formed at B. If the refractive index of water is 4/3 then find the distance between A and B in metre.
[GO_RP]
ehVj xgjh ,d >hy ds i`

"B ij ydM+h dk ,d NksVk VqdM+k rSj jgk gSA tc lw;Z VqdM+s ds m/okZ/kj ij
gksrk gS rks bldh ijNkbZ A ij curh gSA tc lw;Z Bhd vLr gksus dh fLFkfr esa gksrk gS rc VqdM+s dh ijNkbZ
B ij curh gSA ;fn ikuh dk viorZukad 4/3 gks rks A o B ds chp dh nwjh ehVj esa Kkr dhft,A
Ans.
1
1
3
=
=
(4 / 3)
4
3
AB
sin ic =
=
4
OB
sin ic =
ic
7
tan ic =
AB =
39.
AB
3
=
OA
7
3
7
= 3m
7
Image of an object approaching a convex mirror of radius of curvature 20 m along its optical axis is
25
50
observed to move from
m to
m in 30 seconds. What is the speed of the object in km per
7
3
hour.
[GO_SM]
20 m ork f=kT;k ds ,d mky niZ.k dh vksj dkf'kd v{k ij tkrs gq;s ,d fcac dk frfcac 30 sec. esa
25
50
m ls
m rd f[kldrk gSA fcac dh pky km/hour esa D;k gksxh \
3
7
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JRPT1130714C0-23
Ans.
Sol.
3
R = 20 m, f = 10 m
For mirror,
niZ.k ds fy,
1 1 1

v u f
1
1
1
25 / 3 u1 10
1
1
3
1
=
u1 10 25
50
&
rFkk
1
1
=
u2
25
vr% pky =
40.
u1 = 50 cm
1
1
1
=
50 / 7 u2
10
So, speed =
&
u2 = 25 cm
u
25
5
=
m/sec. = m/sec.
t
30
6
u
25
5
=
m/sec. = m/sec.
t
30
6
rFkk in km/hr esa =
5
18
= 3 km/hr.
6
5
O n a 2 lane roa d, car A is travelling with a speed of 3 6 k m/h. Two cars B a nd C

a p proac h car A in op posite d irectio ns with a spe ed of 54 km /h each. At a c erta in
in s ta nt, when the d istanc e AB is eq ual to AC , both be ing 1 km, B d e cid es to
o ver tak e A before C d oes. The m inimu m accelera tion of car B is requ ired to a vo id an
a ccident is x m/s 2 . Th erefore, find x.
,d nks ysu lM+d ij dkj A 36 km /h dh pky ls py jgh gSA nks dkj B vkSj C, izR;sd 54 km /h dh
pky ls dkj A dh vksj foijhr fn'kkvksa ls vk jgh gSA fdlh fuf'pr {k.k ij nwjh AC = AB = 1km gS ,oa
B , A dks C ls igys ikj djuk pkgrk gSA B dk U;wure Roj.k x m /s 2 gS rkfd nq?kZVuk ls cpk tk ldsA rc
x Kkr djksA
A ns. 1
Sol.
36 km/hr
C
54 km/hr
54 km/hr
T im e taken b y C to o ve rtake A is
1km
1
2
=
=
hr =
6 0 s ec . = 40 sec.
(36 54)km / h
90
3
L e t the minim um accele ratio n of B is a to o vertake A befor e C the n
C }kjk A ls vkxs fudyus ds fy, fy;k x;k le;
1km
1
2
=
=
hr =
60 sec. = 4 0 s ec.
(36 54)km / h
90
3
ekuk B dk U;w u re Roj.k a ftlls og A dks s ] C ls igys ikj dj tk;s ] rc

S = ut +
1
at 2
2
1
1
+
a
90
90 90 2
1
18
72
a = 1
=
90 90 2
90
90
1 km = (54 36)
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JRPT1130714C0-24
72
90 90 2 k m/h 2
90
70 90 2 1000
m/sec 2 = 1 m /sec 2 .
60 60 60 60
a =
41.
Sol.
Sol.
A particle is projec te d from ground in ver tic al direction at t = 0. At t = 0 .8 sec, it

x
r eac hes h = 14m . It will ag ain c ome t o same height a t t =
sec. after th e m otio n
2
b e gins, then find x : [ g = 1 0 m /s ]
[RM_AA]
,d d.k dks i`
F oh ry ls t = 0 ij m/okZ / kj ij dh vks j iz { ks f ir fd;k tkrk gS A t = 0.8 s ec
x
ij ;g d.k /kjrh ls h = 14m a p kbZ ij gks r k gS A ;g nq c kjk i`
F oh ls mruh a p kbZ ij t =
2
lS d .M ij vkrk gS ] rc x Kkr djks A
[ g = 10 m /s ]
A ns. 7
T ak ing upward d irectio n as pos itive
in itia l velocit y c an be o btained b y II e q u. of motion
i. e. s = ut + 1/2 at 2
c ons ider ing m otion from C to A
1
1 4 = u 0.8
1 0 0.8 2
2
43
s o, u =
m /s
2
L e t velocit y mag nitud e at point A = v
so, v = u gt
43
27
v =
10 0.8 =
m /s
2
2
2v
H e nce time take n from A to B i.e. till s am e level =
= 2.7 s
g
H e nce the tim e instant at whic h th e pa rticle co mes to s ame leve l
= 0.8 + 2.7 = 3.5 s Ans.
ij dh vks j fn'kk dks /kukRed ys r s gq ,

xfr ds nw l js lehdj.k ls kjfEHkd os x u Kkr fd;k tk ldrk gS %
i. e. s = u t + 1/2 at 2
C ls A rd dh xfr ds fy,
1
1 4 = u 0.8
1 0 0.8 2
2
43
vr% , u =
m/s
2
ekuk fd fcUnq A ij os x dk ifjek.k = v
vr% , v = u gt
43
27
v =
10 0.8 =
m/s
2
2
vr% A ls B rd fy;k x;k le; vFkkZ r ~ leku ry rd =
2v
= 2.7 s
g
vr% og {k.k tc d.k leku p kbZ ij gks r k gS

= 0.8 + 2.7 = 3.5 s
Ans.
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JRPT1130714C0-25
42.
A man is sitting in a room at 2 m from a wall W 1 wants to see the full height of the wall W 2 behind
him 4 m high and 6 m away from the facing wall W 1. What is the minimum vertical length in meter
of mirror on the facing wall required for the purpose ?
[GO_PM]
,d dejs esa ,d O;fDr nhokj W1 ls 2 m nwjh ij cSBk gSA ;g vius ihNs 4m ph ,oa lkeus dh nhokj W1
ls 6m nwjh ij fLFkr W 2 nhokj dh iwjh pkbZ ns[kuk pkgrk gSA bl m)s'; ds fy, lkeus dh nhokj W1 ij
yxs niZ.k dh /okZ/kj yEckbZ de ls de fdruh gksuh pkfg, ?
Ans.
Sol.
Let the min. length of mirror be L

L
2
L=1m
4
8
43.
1
(where V is the velocity of the particle) with respect to time.
V
Then find the value of acceleration at t = 3 sec in meter/sec2.
[RM_AA]
1
2
xzkQ esa
(tgk V d.k dk osx gS) dk le; ds lkFk ifjorZu nf'kZr gS rks d.k dk Roj.k t = 3 sec ij m/s
V
The graph shows the variation of
D;k gksxk&
Ans.
Sol.
3
At t = 3 ij
Slope <ky
44.
1
d
V
= = 1
dt
1 dV
= 1
V 2 dt
dV
dV
=1a=
= 3 m/s2
dt
dt
T here is a sm all air bubb le insid e a glass sphere ( = 1.5) of rad ius 5 cm. The
b u bble is at 'O' at 7.5 cm belo w th e su rfac e of th e glass. The sphere is plac e d insid e
4
w ater ( =
) such that the top surfac e of glass is 10 cm be low the surface of water .
3
27
T he bu bble is viewed n orm ally fr om air. The a ppare nt de pth of the bu bble is
cm,
x
find x.
[GO_RS]
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JRPT1130714C0-26
lseh- f=kT;k ds dkp ( = 1.5) ds ,d xksys ds vUnj gok dk ,d NksVk cqycqyk bl xksys ds i`
"B ls 7.5
lseh- uhps fcUnq 'O ij fLFkr gSA xksys dks ikuh ( =
4
)
3
ds vUnj bl dkj j[kk tkrk gS fd dkp dk ijh
i`
"B ikuh dh lrg ls 10 lseh- uhps gSA cqycqys dks gok ls vfHkyEcor~ ns[kus ij cqycqys dh vkHkklh xgjkbZ
27
cm
x
gS] rc x Kkr dhft,A

observer (s{kd)
10cm
glass
(dkp) C
water
(ikuh)
Ans.
2
observer (s{kd)
Sol.
10cm
glass
(dkp)
water
(ikuh)
C
O
F or firs t refraction, (at the g lass- wa ter in terfac e)

izFke viorZu ds fy, ( dkWp ikuh vUr% lrg ij)
4/3 3/2
4/3 3/ 2
=
v
7.5
5
4
3
1
=
3v 15
30
4
5
=
v = 8 cm
3v
30
F or s econd refractio n : (at a ir-water in terface)
f}rh; viorZu ds fy, ( gok ikuh vUr% lrg ij )
(10 8)
App are nt d epth vkHkklh xgjkbZ =
4/3
18 3
54
27
=
=
=
c m.
4
4
2
45.
The position vector of a particle is given as r (t 2 4t 6) i (t 2 ) j . The time in second, after

which the velocity vector and acceleration vector becomes perpendicular to each other is :
[RM_AA]
d.k dk fLFkfr lfn'k r (t 2 4t 6) i (t 2 ) j }kjk fn;k tkrk gSA og le; lSd.M esa Kkr dhft,]
ftlds i'pkr~ osx lfn'k rFkk Roj.k lfn'k ,d nwljs ds yEcor~ gksA
Ans.
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JRPT1130714C0-27
Sol.
r (t 2 4t 6) i t 2 j ;
dr
v
= (2t 4) i 2t j = (2t 4) + 2t ,
dt
dv
a
2i 2j
dt
if a and v are perpendicular
;fn a rFkk v ijLij yEcor~ gS

a. v 0
2i 2j).((2t 4) i 2t j) 0
8t 8 = 0
t = 1 sec.
Ans. t = 1 sec.
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JRPT1130714C0-28
DEPARTMENT OF MATHEMATICS
TEST PATTERN
BATCH : JR- PT-1
TEST DATE : 10-AUG-2014
SYLLABUS : Fundamentals of Mathematics (Gr aph s of poly nom ials, Wav y Cu r v e

I n equ alit ies and Modulus, Modu lus- equ at ion s an d in equat ion s, Graphical Tran sfor m at ion ,
I r r arat ional ineqaulit y, log equ at ion s, Logar it h m ic graphs an d in equ alit ies, GI F- equ at ions an d
in equat ion s, GI F- graph s and sgn ( Fx ) , Trigon om et ric- Equ at ion s, Trigonom et ric- I n equat ions )
PT-1
S.No.
Subject
Nature of Questions
1 to 25
SCQ
26 to 30
Maths/ MCQ
Chemistry
31 to 36
37 to 37
38 to 45

Total
1.
If sin
< 0, cos
<
1
and 0 <
2
1
2
;fn sin < 0, cos < rFkk 0 < < 2 , rc 2sin

(A) [2, 2]
Sol.
(B*) [2, 3 )
Let ekuk y = 2sin
2.
<
4
<
3
sin
2sin
If 4
75
20
18
32
Total
lies in the interval
[BAMS]
vUrjky eas fLFkr gS&
(C) 1,
153
1
2
(D) [1, 3 )
sin < 0, cos <

<
45
< 2 , then 2sin
Total
25
1
in (0, 2 )
2
4
3
3
<
5
3
<
<
3
2
3
x < 2, then ||x + 2| 5| lies in the interval :
[BAMD]
;fn 4 x < 2, rc ||x + 2| 5| vUrjky esa fLFkr gS&

(A*) (1, 5]
(B) [1, 5]
(C) (2, 6]
(D) [5, 8)
Page # 1
Sol.
x<2
2
0
x+2<4
|x + 2| < 4
5
3.
|x + 2| 5 < 1
1 < ||x + 2| 5|
Number of negative integral solutions of the in-equation
vlfedk
(x 1)3 (x 1)2
x 4 (x 2)(ex e)
(A) 0
(x 1)3 (x 1)2
x 4 (x 2)(ex e)
0 is
0 ds _.kkRed iw.kkd gyksa dh la[;k gS &
(B*) 1
(C) 2
[BARI]
(D) 3
Sol.
negative integral solution is 1 only.

Hindi :
_.kkRed iw.kkd gy dsoy 1 gSA
4.
Number of integers greater than 8 satisfying the inequation
vlfedk
(x 2)3 (x 5)4 (x 8)5

(x 10)2 (x 12)
(A) 8
Sol.
0 dks
(x 2)3 (x 5)4 (x 8)5

(x 10)2 (x 12)
0 are :
[BARI]
larq"B djus okys 8 ls cMs iw.kkdksa dh la[;k gS&
(B) 9
(C*) 10
(D) 12
gy fu:fir fd;k tk ldrk gS&
Solution can be represented as
8 ls
integers greater than 8 are
10
12
cMs iw.kkd gS
x = 5, 2, 3, 4, 5, 6, 7, 8, 9, 11
5.
What is the most general value of

tan
which satisfies both of the equations cos
=1?
1
2
and
[BAMS]
dk O;kid eku gksxk tcfd nksuksa lehdj.k cos =

(A) n +
,n
(B) n +
3
,n
4
1
2
vkSj tan = 1 dks larq"B djrk gSA
(C*) 2n +
5
,n
4
(D) 2n +
3
,n
4
Page # 2
Sol.
In interval 0
cos
2
=
3 5
,
and vkSj tan
4 4
general value of
dk O;kid eku
6.
= 2n +
= 2n +
5
,
4 4
5
,n
4
5
,n
4
Complete set of values of x satisfying inequality ||x 1| 5| < 2x 5, is

[BAMD]
vlfedk ||x 1| 5| < 2x 5 dks larq"V djus okys x ds ekuksa dk lEiw.kZ leqPp; gS (A)
Sol.
is
=1
5
,
2
11
,
3
(B*)
5
2
2x + 5 < |x 1| 5 < 2x 5
2x + 10 < |x 1| < 2x
2x 5 > 0
x>
(C)
1,
(D)
11
3
(1)
5
)
2
CasefLFkfr-1 : x 1 < 2x
x<1
x>1
(2)
CasefLFkfr-2 : x 1 > 2x + 10
3x > 11
11
x>
(3)
3
11
By (1) (2) (3) x
,
3
2x + 10 < x 1 < 2x (aspwfd x >
7.
The expression cos( n x).cos( n y)
O;atd cos( n x).cos( n y)

(A) 1
Sol.
1
cos
2
1
cos
2
n
x
y
x
y
cos( n(xy)
(B*) 0
E = cos ( nx) cos ( ny)

= cos ( nx) cos ( ny)
cos( n(xy)
is simplified to
[BAMS]
dks ljy djus ij
(C) 1
(D) 2
1
(cos ( nx ny) + cos ( nx + ny))
2
1
2 cos ( nx) cos ( ny)
2
=0
8.
The complete solution set of the equation |x 5x + 6| + |x + 12x + 27| =|17x + 21| is (A) x
(C*) x
[9, 3]
[9, 3]
[2, 3]
(B) x
[3, 2)
(D) x
(2, 3)
[BAMD]
(2, 3]
lehdj.k |x2 5x + 6| + |x2 + 12x + 27| =|17x + 21| dk lEiw.kZ gy leqPP; gS &
(A) x
(C*) x
[9, 3]
[9, 3]
[2, 3]
(B) x
[3, 2)
(D) x
(2, 3)
(2, 3]
Page # 3
Sol.
|a| + |b| = |a b|
a2 + b2 + 2 |ab| = a2 + b2 2ab or |ab| = ab
ab
(x 2) (x 3) (x + 3) (x + 9)
x
9.
(x 5x + 6) (x + 12x + 27)
[9, 3]
[2, 3]
3
The correct graph of curve y = x x 8x + 5 is
[BAMS]
o y = x3 x2 8x + 5 dk lgh vkjs[k gS&
10.
(A)
(B)
(C)
(D*)
The sum of all the values of x in the interval [2 , ) satisfying the equation
[BAMS]
cos 5x . tan(6 |x|) + sin 5x = 0 is
vUrjky [2 , ) esa x ds lHkh ekuksa dk ;ksxQy tks lehdj.k cos 5x . tan(6 |x|) + sin 5x = 0 dks larq"B djrs gS
(A*) 2
Sol.
(B) 3
(C) 0
(D) 4
cos 5x tan 6|x| + sin 5x = 0
Case fLFkfr
cos 5x tan 6x + sin 5x = 0

cos 5x sin 6x + sin 5x cos 6x = 0
sin 11x = 0
11x = n
x=
n
,n
11
x = 0,
2 3 4 5 6 7 8 9 10
, , , , , , , ,,
11 11 11 11 11 11 11 11 11 11
CasefLFkfr
x<0
cos 5x tan 6x + sin 5x = 0

cos 5x sin 6x + cos 6x sin 5x = 0
sin (5x 6x) = 0
sinx = 0
x=m ,m
x = , 2
sum
;ksxQy = 2
Page # 4
11.
Set of all values of x satisfying the inequation
16 2x 3x 2 < 1 + x is
[BAIR]
vlfedk 16 2x 3x < 1 + xdks lUrq"V djus okys x ds lHkh ekuksa dk leqPp; gSa
2
(A) ( , 5/2)
(C) ( , 5/2)
Sol.
(B) (1, 3/2)

3
(D*) , 2
2
(3/2, )
16 2x 3x2 0
3x2 + 2x 16 0
(3x + 8) (x 2) 0
8
x
, 2
3
..... (i)
Case fLFkfr I
1 + x < 0 solution not possible
Case fLFkfr I
1 + x < 0 gy lEHko ugha gS
Case fLFkfr I I 1 + x 0
x [1, )
squaring both side
nksuksa i{kksa dk oxZ djus
16 2x 3x2 < x2 + 2x + 1
4x2 + 4x 15 > 0
5
3
x
,
,
2
2
from (i), (ii) and (iii) we get
(i), (ii)
12.
vkSj (iii) ls
.... (ii)
ij
.... (iii)
3
, 2
2
3
, 2
2
Set of all the values of x satisfying |x2 + x 12| + |sin x| = |(x2 + x 12) + sin x|, where
|x2 + x 12| + |sin x| = |(x2 + x 12) + sin x|, tgk
, is
dks lUrq"V djus okys x ds lHkh ekuksa
dk leqPp; gSa&
Sol.
13.
[BAMD]
(A) [3, 3] { , }
(B*) [ , 0] [3, ]
(C) [3, 0] [3, ]
(D) [3, ]
(x2 + x 12) (sin x) 0
(x + 4) (x 3) sin x 0
clearly x = 3, , 0, are solutions
.........(i) {4 [ , ] }
Li"Vr;k x = 3, , 0, gy gS
.........(i) {4 [ , ] }
Case I when tc 0 x
then rks sin x 0
(x + 4) (x 3)
0
i.e
x 4 or x 3
[3, ] are solutions
[3, ] gy gS
.........(ii)
Case II when tc
x 0, then rc sin x 0
(x + 4) (x 3) 0
i.e
4 x 3
[ , 0] are solution
[ , 0] gy gS
.........(iii)
set of all solution is [ , 0] [3, ]
lHkh gyksa dk leqPp; [ , 0] [3, ]
Number of integral values of x satisfying the inequation |x + 11| + |x + 7| < 6, is
vlfedk |x + 11| + |x + 7| < 6 dks lUrq"V djus okys

(A) 6
(B*) 5
(C) 7
[BAMD]
ds iw.kkd ekuksa dh la[;k gS &

(D) 3
Page # 5
when tc
x < 11
x 11 x 7 < 6
i.e
2x > 24
i.e
x > 12
no integral solutions dksbZ iw.kkd gy ugha
Case II
when tc
11 x < 7
x + 11 x 7 < 6
i.e
4 < 6 true for all x
x + 11 x 7 < 6
i.e
4 < 6, x ds lHkh ekuksa ds fy, lR; gS
integral values 11, 10, 9, 8 are solutions. There are 4 integral solutions
iw.kkd eku 11, 10, 9, 8 gy gSA dqy 4 iw.kkd gy gSA
Case II I
when tc
x 7
x + 11 + x + 7 < 6
i.e
2x < 12
x < 6
7 x < 6
there is only one integral solution viz : 7
;gk dsoy ,d iw.kkd gy gS
viz : 7
total number of integral solutions is 5.
dqy iw.kkd gyksa dh la[;k = 5.
Sol.
Case I
14.
Set of all values of x for which

3
sin x
2
log0.1 sin2 x
(A)
(C) 2n
Sol.
3
2
log0.1 sin2 x
3
sin x
2
(B*) 2n
log0.1 sin2 x
, ( 2n 1)
3
2
, 2n
(D) no solution dksbZ
3
sin x
2
is defined, is
[BAMS]
ds ifjHkkf"kr gksus ds fy, x ds lHkh ekuksa dk leqPp; gS &
5
6
6
3
2
5
6
gy ugha
3
3
sin x +
1
..... (i)
2
2
3
3
3
9
3
9
sin2 x
sin x +
= sin2 x
sin x +
+
2
2
2
16 2 16
0 < sin2 x
(i)
= sin x
3
4
15
>0
16
Inequality vlfedk (i)
R
sin2 x
3
3
sin x +
1
2
2
2 sin2 x 3 sin x + 1 0
(sin x 1) (2 sin x 1) 0
1
sin x 1
2
5
2n +
x 2n +
6
6
15.
Number of solutions of 1 + tan2 x sec x tan x < 0 is

1 + tan2 x sec x tan x < 0 ds gyksa dh la[;k gS &
(A*) 0
(B) 2
(C) 3
[BAMS]
(D) infinite
vuUr
Page # 6
Sol.
16.
1 + tan2 x sec x tan x < 0

sec2 x sec x tan x < 0
sec x(sec x tan x) < 0
sec x
<0
sec x tan x
1
<0
1 sin x
no solution
{ 1 + sin x
dksbZ gy ugha
{ 1 + sin x
0}
0}
Number of solutions of [x] + 2x = 5 + 4 {x}, which lie in the interval [1, 5]

(where [.] and {.} represent greatest integral function and fractional part function)
[BAGI]
vUrjky [1, 5] esa lehdj.k [x] + 2x = 5 + 4 {x} ds gyksa dh la[;k gS &

(;gk [.] rFkk {.} e'k% egke iw.kkd Qyu rFkk fHkUukRed Hkkx Qyu dks iznf'kZr djrs gSA)
(A) 0
Sol.
17.
(B*) 1
[x] + 2x = 5 + 4 {x}
Let x = [x] + {x} = I + f
I + 2I + 2f = 5 + 4f
3I 5
0
<1
2
5
5 3I < 7
I<
3
1
5
I = 2, f =
x=
2
2
(C) 2
3I 5 = 2f
3I 5 < 2
7
3
Set of all real values of x satisfying inequation (x2 + 3x) (2x + 3) 16

2x
vlfedk (x2 + 3x) (2x + 3) 16
Sol.
(D) 3
x 3x
(A) x ( , 4] (3, 3/2] (0, 1]
(C) x [4, 3] [3/2, 0] [1, 2]
16
(2x + 3) x 2 3 x
0
2
x
3x
(2 x
3) ( x 2
x2
(2x
3) ( x 2
3 x )2 16
3x
3x 4) ( x 2
x( x 3 )
3x
4)
(B*) x [4, 3) [3/2, 0)

(D) x (4, 3/2] [1, )
[1,
0
+
4
[BARI]
(2 x
0 is
dks lUrq"V djus okys x ds lHkh okLrfod ekuksa dk leqPp; gS&
2x 3
x 2 3x
+
3
2
+
1
3) ( x 1) ( x 4)
0
x( x 3 )
[4, 3) [3/2, 0) [1, )
Page # 7
18.
If x
0, y
0, then area of the region bounded by [x] + [y] = 99 is
[BAGI]
(where [.] represent greatest integral function)

(A) 99 sq. unit
(B*) 100 sq. unit
(C) 101 sq. unit
(D) 120 sq. unit
;fn x 0, y 0 gks] rks [x] + [y] = 99 }kjk ifjc) {ks=k dk {ks=kQy gS &
(;gk [.] egke
(A) 99 oxZ
Sol.
iw.kkd Qyu dks iznf'kZr djrk gSA)
bdkbZ
(B*) 100 oxZ
bdkbZ
(C) 101 oxZ
bdkbZ
(D) 120 oxZ
bdkbZ
If [x] = 0, then [y] = 99

and the area enclosed = 1 unit
;fn [x] = 0 gks] rks [y] = 99 vkSj ifjc) {ks=kQy = 1 bdkbZ
If [x] = 1, then [y] = 98
If [x] = 2, then [y] = 97
If [x] = 99, then [y] = 0
the total enclosed area = 100 units
dqy ifjc) {ks=kQy = 100 bdkbZ
19.
x
x
= cosec x sin x, where x n then tan2 is equal to
2
2
x
x
tan
= cosec x sin x, tgk x n gks] rks tan2 =
2
2
If tan
;fn
(A) 2
Sol.
(B)
(C*) (9 4 5 ) (2 + 5 )
x
1
tan =
sin x
2
sin x
x
x
1 tan 2
2 tan
x
2
2
tan =
x
x
2
2 tan
1 tan2
2
2
y2 + 4y 1 = 0
[BAMS]
5 +2
(D) (9 + 4 5 ) (2 5 )
y = tan2
let
x
2
y = 5 2 = (9 4 5 ) (2 + 5 )
log21/ 4 a
20.
If a >
5 1
2
, then
2
log27 a2 1
4 log49 a
log21/ 4 a
5 1
2
;fn a >
, rks
2
(A) a2 a + 1
2a
+ a simplifies to :
[BALG]
a 1
3log27 a
4 log49 a
7
a 1
(B) (a 1)2
2a
+a
ds ljyhdj.k ls izkIr gksrk gS &
(C) a2 + a + 1
(D*) (a + 1)2
Page # 8
Sol.
log
21/ 4
3log27
4 log49 a
( a 2 1)3
2a
2log2 a 3log3 ( a
7
=
21.
log7 a2
1)
2a
a2 a 1
a 4 ( a 1)2
+ tan
+a
+ a = a2 + 2a + 1 = (a + 1)2
a2 a 1
If cot
+a
a1
a 4 (a 2 1) 2a
+a
a 1
= x, sec cos
= y, 0 <
<
, then
;fn cot + tan = x, sec cos = y, 0 < <

Sol.
[BAMS]
gks] rks
2
(A) (xy2)2/3 (x2y)2/3 = 1 (B*) (x2y)2/3 (xy2)2/3 = 1 (C) x2/3 + y2/3 = 1
1
cot + tan = x
i.e.
=x
sin cos
sec cos = y
i.e.
sin2 = y cos
1
x2 cos2 . y cos = 1
cos3 = 2
x y
and sin2 = y
1=
1
.
x sin
1
x 2y
sin3 =
2/3
y
x
2/3
(D) x2/3 y2/3 = 1
y
x
1
x 4 / 3y2 / 3
y2 / 3
x2 / 3
1 x2 / 3y4 / 3
x4 / 3y2 / 3
x4/3 y2/3 x2/3 y4/3 = 1

(x2y)2/3 (xy2)2/3 = 1
22.
The complete solution set of inequality
( x 5)2005 . ( x 8)2008 ( x 1)
x 2006 ( x
2)3 . ( x 3)5 . ( x 6) ( x
( x 5)2005 . ( x 8)2008 ( x 1)
vlfedk
Sol.
x 2006 ( x 2)3 . ( x 3)5 . ( x 6) ( x 9)2010

(A) ( , 9) (8, 0) (0, 1) (2, 3) [5, 6)
(B) ( , 9) (9, 0) (0, 1) (2, 3) (5, 6)
(C*) ( , 9) (9, 0) (0, 1] (2, 3) [5, 6)
(D) ( , 0) (0, 1] (2, 3) [5, 6)
x ( , 9) (9, 0) (0, 1] (2, 3) [5, 6)
23.
If sin A =
3
12
, cos B =
,A
5
13
;fn sin A =
3
12
, cos B =
,A
5
13
and B
,
rFkk B
0,
2
0,
0 is
[BARI]
dk lEiw.kZ gy leqPp; gSA
, then
9)2010
, gks]
[BAMS]
rks
3
16
and sin (A + B) =
2
65
16
(B*)
< A + B < and sin (A + B) =
2
65
33
(C)
< A + B < and cos (A + B) =
2
65
3
63
(D) < A + B <
and cos (A + B) =
2
65
(A)
<A+B<
Page # 9
Sol.
and
24.
4
5
36
20
16
, sin B =
sin (A + B) =
=
5
13
65
65
65
48
15
63
cos (A + B) =
=
65
65
65
cos A =
If in triangle ABC :
;fn f=kHkqt ABC esa
45 , then all the values of sin2A + sin2B lie in the interval
45
(A) [0, 1]
Sol.
[BAMS]
gks] rks (sin2A + sin2B) ds lHkh eku fuEu varjky esa gksxsa!
(B) (0, 1)
(C*)
1 1
2
,
2
2
(D)
1 1
,
2 2
= sin2A + sin2 (135 A) = 1 + sin2A sin2(45 A)

1
= 1 + sin 45 sin(2A 45) = 1 +
sin(2A 45)
2
0 < A < 135
0 < 2A < 270
45 < 2A 45 < 225
1
< sin (2A 45) < 1

2
1
1
2
< sin2A + sin2B <
2
2
25.
Number of real roots of equation 3log3 ( x
lehdj.k 3
log3 ( x 4 x
3)
(A) 2
Sol.
= x 3 ds
(B) 1
4x
3)
= x 3 is -
[BALG]
okLrfod ewyksa dh la[;k gS &

(C*) 0
(D) infinite
vuUr
x2 4x + 3 = x 3
x2 5x + 6 = 0
x = 3, 2
and vkSj
x2 4x + 3 > 0
(x 3) (x 1) > 0
x > 3 or ;k
x < 1 .......(i)
by (i) ls
x = 3, 2 (3, )
MCQ
26.
If the solution set of inequation
1 log1/ 2 ( x)
< 0 is (a, b) then
[BAIR]
2 6x
(A*) a and b are rationals
(B*) 2a 3b = 0
2
5
(C*) log36 6 (b a)
(D) sec
can take value between a and b for some
;fn vlfedk
1 log1/ 2 ( x)
2 6x
(A*) a vkSj b ifjes;
< 0 dk
gy leqPp; (a, b) gS] rc
gSA
(B*) 2a 3b = 0
(C*) log36 6 (b a)
(D) sec
fdlh
2
5
ds fy, a vkSj b ds e/; eku ys ldrk gS

Page # 10
Sol.
1 log1/ 2 ( x)
6x 2
6x 2 > 0
x<
1
3
(1)
and vkSj 1 log1/2 (x) < 0

log1/2 (x) > 1
x <
1
2
x>
1
2
(2)
Also x > 0
x<0
.............(3)
1 1
,
2 3
intersection of (1), (2), (3) gives x
1
3
ba=
log36
Sol.
28.
1
2
1
=y
6
1
6
(36 6 )y
2
5
y=
27.
1 1
,
2 3
ds frPNsnu ls x
(1), (2), (3)
If S and P are sum and product respectively of all real values of x satisfying equation
|4 |x 1|| = 3, then
[BAMD]
;fn lehdj.k |4 |x 1|| = 3 dks larq"V djus okys x ds lHkh okLrfod ekuksa dk ;ksx rFkk xq.kuQy e'k%
S rFkk P gS] rks &
(A*) S + P = 4
(B*) S P = 4
(C*) S2 P2 = 16
(D*) S2 + P2 = 16
||x 1| 4| = 3
|x 1| = 1, 7
x = 0, 2, 6, 8
S = 0 + 2 6 + 8 = 4, P = 0
If tan
= tan
;fn tan
= tan
and
vkSj
and
2
(B*)
rFkk
(0, 4 ), gks]
(A*) =
=n +
29.
If [ . ] represents greatest integer function, then 2[x]2 3[x] + 1 = 0 is true for

(A) no real value of x
(B*) 1
x<2
[BAMS]
rks fuEu esa ls dkSu&ls laHko gS&
Sol.
:n
= +
= , +
(0, 4 ), then which of following can be possible ?
(C)
(D*)
=2 +
,2 +
(C) x
(D*) x
[BAGI]
e
,2
;fn [ . ] egkeiw.kkd Qyu dks n'kkZrk gS] rks 2[x]2 3[x] + 1 = 0 lR; gksus ds fy,
(A) x dk dksbZ okLrfod eku ugha
(B*) 1 x < 2
(C) x
(D*) x
,2
Page # 11
Sol.
2[x]2 3[x] + 1 = 0
Let [x] = y
2y2 3y + 1 = 0
(2y 1) (y 1) = 0
y=1
or ;k
[x] = 1
y = 1/2
1
30.
x<2
The least positive solution of cot
sin 2 x =
3 lies in
[BAMS]
3 3
cot
sin 2x =
3 3
(A*)
Sol.
0,
cot
sin 2x
(B*)
=
dk U;wure /kukRed gy] fuEu varjky esa gS&

9
(C*)
sin 2x = 3 3 n +
sin 2x =
3
2
x=
3
2
(D)
sin 2x = n +
3 3
3 3
n=0
Comprehension # 1
Paragraph for Question Nos. 31 to 32
Consider the graph f(x) = 2x 1
ekukfd f(x) = 2x 1
2x 7
2x 7
2x 13
gSA
2x 13
[BAMD]
31.
If 15 < f(x) < 15, then complete set of values of x is

;fn 15 < f(x) < 15 gks] rks x ds lEiw.kZ ekuksa dk leqPp;
(A*) (2, 5)
(B) (3, 6)
gS&
(C) (3, 5)
(D)
1 13
,
2 2
Sol.
For
and
15 < f(x) < 15, the line y = 15 intersects the lines y = 2x + 19

y = 2x + 5 at x = 2 and x = 5 respectively
15 < f(x) < 15 if x (2, 5)
15 < f(x) < 15 ds fy, js[kk y = 15 js[kkvksa y = 2x + 19 vkSj y = 2x + 5 dks
e'k% x = 2 vkSj x = 5 ij izfrPNsn djrh gSA
15 < f(x) < 15 ;fn x (2, 5)
y
f(x
)
1
+2
=6
6x
21
f(x )
18
f(x
)
12
=
2x
+1
9
)
f(x
5
x+
=2
x
1
2
7
2
13
2
Page # 12
1
2
f(x) = 2x + 1 2x + 7 2x + 13
= 6x + 21
1
7
Case II
when
x<
2
2
f(x) = 2x 1 2x + 7 2x + 13
= 2x + 19
7
13
Case II I when
x<
2
2
f(x) = 2x 1 + 2x 7 2x + 13
= 2x + 5
13
Case IV when
x,
2
Case I
32.
when x <
If 13 < f(x) < 17, then complete set of values of x is

;fn 13 < f(x) < 17 gks] rks x ds lEiw.kZ ekuksa dk leqPp;
gS&
3 5
,
2 2
(A) (3, 4)
(B)
(4, 6)
(C) (1, 6)
(D*) (1, 3)
(4, 6)
Sol.
For

and
15 < f(x) < 15 if x (2, 5)
For
and
Again y = 17 intersects the lines y = 2x + 19 and y = 2x + 5 at x = 1 and x = 6 respectively
13 < f(x) < 17 if x (1, 3) (4, 6)
13 < f(x) < 17 ds fy, js[kk y = 13 js[kkvksa y = 2x + 19 vkSj y = 2x + 5 dks e'k% x = 3 vkSj x = 4
izfrPNsn djrh gSA

iqu%
y = 17 js[kkvksa y = 2x + 19 vkSj y = 2x + 5 dks e'k% x = 1 vkSj x = 6 ij izfrPNsn djrh gSA
13 < f(x) < 17 ;fn x (1, 3) (4, 6)
6x
f (x
)=
6x
21
f (x )
1
+2
18
f(x
)
12
+5
2x
)=
f(x
=
2x
+1
9
x
1
2
7
2
13
2
1
2
f(x) = 2x + 1 2x + 7 2x + 13
= 6x + 21
1
7
Case II
when
x<
2
2
f(x) = 2x 1 2x + 7 2x + 13
= 2x + 19
7
13
Case II I when
x<
2
2
Case I
when x <
Page # 13
f(x) = 2x 1 + 2x 7 2x + 13
= 2x + 5
13
when
x,
2
f(x) = 2x 1 + 2x 7 + 2x 13 = 6x 21
Case IV
Comprehension # 2
Given that N = 7
log49 900
log 4
A= 2 2
3log2 4 4log2 2 4log2 3
D = (log5 49) (log7 125)
Then answer the following questions : (Using the values of N, A, D)
fn;k x;k gS fd N = 7log
49
[BALG]
900
log 4
A= 2 2
3log2 4 4log2 2
D = (log5 49) (log7 125)
4log2 3
rks fuEufyf[kr iz'uksa ds mkj nhft,A (N, A, D ds ekuksa dk mi;ksx djrs gq,)
33.
If logA D = a, then the value of log6 12 is (in terms of a)
;fn logA D = a gks] rks log6 12 dk eku (a ds inksa esa) gS (A*)
1 3a
3a
(B)
1 2a
3a
(C)
1 2a
2a
(D)
1 3a
2a
Sol.
N = 30
A=8
D=6
log8 6 = a
log 2 log 3
=a
3 log 2
(log 2) (1 3a) + log 3 = 0
log 3 = (3a 1) log 2
log 12
Now log6 12 =
log 6
2 log 2 log 3
log 2 log 3
34.
The value of log

A
Sol.
N
10
(A) 1
N = 30
A=8
D=6
log
A
2 3a 1
1 3a
=
1 3a 1
3a
|N + A + D + 6| log5 2 =
(B*) 2
N
10
(C) 3
(D) 4
|N + A + D + 6| log5 2
log5 50 log5 2
=2
Page # 14
Comprehension # 3
If f(x) = g(x), then number of solutions can be evaluated by studying number of intersection points of
y = f(x) and y = g(x).
[BAMS]
;fn f(x) = g(x) rc y = f(x) vkSj y = g(x) ds izfrPNsn fcUnqvksa dh la[;k dk v/;;u djds gyksa dh la[;k Kkr dh tk
ldrh gSA
35.
Complete set of values of
ds ekuksa dk lEiw.kZ leqPp;

gS Sol.
for which there exist three real and distinct solutions of x 3x + 1 = 0

gksxk ftlds fy, lehdj.k x3 3x + 1 = 0 ds rhu okLrfod vkSj fofHkUu gy
(A)
(3, 2) (B)
(1, 1)
3
x 3x 1=
3
Let f(x) = x 3x 1
2
f ' (x) = 3x 3 = 3 (x + 1) (x 1)
(C)
(1, 5)
(1, 3)
1
m
(max )
(1,1)
(D*)
fo|eku
(min )
f(1) = 3
f(1) = 1
1
(0,1)
For three real and distinct solution

rhu okLrfod vkSj fofHkUu gyksa ds fy,
36.
Sol.
Number of solutions of 10 sin x = 5 x

lehdj.k 10 sin x = 5 x ds gyksa dh la[;k
(A) 6
(B) 5
10 sin x = 5 x
(1,3)
(3, 1)
(1, 3)
(3, 1)
(1, 3)
gS (C*) 7
(0,10)
3
2
3
3
10
=
2
2
Total number of solution gyksa
2
(0,10)
(D) 8
7
2
4 9
2
11
2
dh dqy la[;k 7
Match the column
Page # 15
37.
If graph of y = f(x) is given below :
[BAMS]
;fn y = f(x) dk vkjs[k fn;k x;k gS&

y-axis
x-axis
Column I
LrEHk I
Column II
LrEHk II
y-axis
(A)
y = f(|x|)
(p)
x-axis
y-axis
(B)
y = f(|x|)
(q)
x-axis
y-axis
(C)
y = f (| x |)
(r)
x-axis
y-axis
(D)
y= f
|x|
(s)
x-axis
Sol.
Ans. (A)
(r),
(B)
Using shifting of graph vkjs[k
(s),
(C)
(r),
(D)
(q)
ds :ikUrj.k ls
Integer
38.
If solution set of the inequation log3
| x 2 4x | 3
x2 | x 5 |
0, is (
, a]
[b, c], then find the value of
(3a + 2b + c).
[BAMD]
2
;fn vlfedk log3
| x 4x | 3
x2 | x 5 |
0, dk
gy leq P p; ( , a]
[b, c], gS ]
rc (3a + 2b + c) dk eku Kkr
dhft,A
Ans.
1
Page # 16
Sol.
| x 2 4x | 3
x2 | x 5 |
|x 4x| + 3
x + |x 5|
2
|x(x 4)| + 3
x
x + |x 5|
5
2
x 4x + 3
5x
x +x5
8
5
x
x
4
x<5
x 4x + 3
3x
x
x x+5
2
2
3
x
0
x<4
2
x + 4x + 3
x x+5
2x 5x + 2
1
2
IV x < 0
2
x 4x + 3
3x
2
3
x x+5
2
3
1
,2
2
3a + 2b + c = 1
39.
If a
1
a
=5]
gks] rks a 4
1
a4
1
a4
[BAMD]
dk eku Kkr dhft,A
[New, M]
Sol.
40.
= 5, then find the value of a 4

1
a
;fn a
Ans.
1
a
= a
If asin + bcos
1
a
2 =
= a cosec
1
a
b sec
2 = ( 5 2) 2 2 = 7
= 1. Then find the value of a + b + b

2
4/3
4/3
2/3
[BAMS]
2/3
;fn asin + bcos = a cosec b sec = 1 gks rc a + b + b b dk eku Kkr dhft,A

Ans.
Page # 17
Sol.
a sin
+ b cos
=1
(1)
and a cosec b sec
=1
acos b sin = cos
sin
(2)
Squaring and adding (1) and (2),

2
a + b = 1 + cos
= 1 + cos
= 1+ cos
b cos
cos
cos
(3)
+ b cos
+ b sin
(2) sin
sin
2
sin
=b
a cos
a +b =1+b
2
a +b +b
41.
5 3
Sol.
Let ekuk E =
2/3
is simplified to
50
[BAIR]
6
32
3
5 3
ljy djus ij
50
4 3
3 2
18
12
= 3 3
3 2
3 2
2 3
6
4 2
5 2
3
3
6
2
(3
6 )( 3
1
2)
3
The value of the given expression = ( 3 ) 2 = 3
42.
=1
= 3 3
cos sin
4/3
32
2 12
Ans.
= cos
(3) ls
2 12
5 3
1/3
+ b sin
2/3
4/3
sin
= cos (1 sin )
cos = b
fn;k x;k gS fd
gives
(3) becomes
2
o (2) dk oxZ djus ij
(1)
(1 cos )
(1) cos
acos
If x = 2 + 2
2/3
1/3
fn, x, O;a t d dk eku = ( 3 )2 = 3
+ 2 , then the value of x 6x + 6x =

2/3
1/3
[BAMS]
;fn x = 2 + 2 + 2 gks ] rks x 6x + 6x dk eku gS &

Ans.
Sol.
x2=2
1/3
+2
2/3
3
cubing both sides pw f d (x 2) = (2

3
x 8 6x + 12x = 2 + 4 + 3 2
3
1/3
1/3
2/3 3
+2 )
2/3
(2
1/3
dk U;w u re eku
2/3
+2 )
x 6x + 12x 8 = 6 + 6(x 2)
x 6x + 12x 8 = 6 + 6x 12
x 6x + 6x = 2
43.
Find the least value of the expression E = 2log10x logx (0.01) for x > 1.
x > 1 ds
Ans.
[BALG]
fy, O;a t d E = 2log10x logx (0.01) dk U;w u re eku Kkr dhft,A
Page # 18
Sol.
E = 2 log10x logx (10 )

= 2log10x + 2 logx 10
1
log10 x
= 2 log10 x
Since x > 1, log10x > 0
least value of log10x +
1
=2
log10 x
Emin = 2(2) = 4
44.
Find the number of solutions of the equation sin 2x cos 8x =
1
cos 10x lying in the interval 0,
.
2
2
[BAMS]
vUrjky
0,
es a fLFkr lehdj.k sin2 2x cos2 8x =
Ans.
Sol.
sin 2x cos 8x =
gyks a dh la [ ;k gS &
1
cos 10x
2
1
cos 10x ds
2
2 sin 2x 2 cos 8x = cos 10x

1 cos 4x 1 cos 16x = cos 10x
cos 14x + cos 10x + cos 16x = 0
2 cos 10x cos 6x + cos 10x = 0
cos 10x (2 cos 6x + 1) = 0
10x = (2n +1)
x = (2n + 1)
, n
20
,n
and vkS j cos 6x =
k
3
0,
If
1
,x=
1
Ans.
1
+
3 5 7 9
, , , ,
20 20 20 20 20
,k
4 2
,
,
9 9 9
+ = 2,
;fn
,x=
1
2
gyka s dh la [ ;k 8 gS A
no of solution are 8
45.
x = (3k 1)
In 0,
I;x
2
3
6x = 2k
x=
=6
[BAGQ]
1
then find the value of
2
+ = 2,
1
2
gks ] rks
=6
dk eku Kkr dhft,A
Page # 19
Sol.
=3
=3
+(
+( +
=3
+
2
Also rFkk ,
2
+ ) 2(
4 2(
+ ) 3(
+
2
2
+ ) (( +
+ 2 (4 3(
( +
)(
+
+
))
(1)
=6
)=6
)=6
=1
Also rFkk ,
(2)
1
1
2
1
2
1
1
2
= 2
= 2
(3)
Putting the values from (2) and (3) in (1),

3
(2) vkS j (3) ls (1)
es a eku j[kus ij
= 3(2) + 2(4 3 (1))
= 6 + 14
=8
Page # 20
Course : JR(ELPD)(PT1)
Paper
Test Date : 10- 08-2014

Time Duration : 2 Hrs.
PAPER LEVEL : MODERATE
Test Syllabus :
Syllabus : Complete Mole Concept, Quantum Numbers.

Test Syllabus :
IUPAC Nomenclature & Structure isomers,

Hydrogenation & Monochlorination
SYLLABUS SCHEDULED
SR.
NO.
TOPIC NAME
1.
IUPAC Nomenclature
2.
Structure isomers
3.
Hydrogenation
4.
Monochlorination
SYLLABUS SCHEDULED
WEIGHTAGE
(BY FC)
WEIGHTAGE IN PAPER
(BY FACULTY)
Test Pattern :
PT-1
S.No.
1 to 25
26 to 30
31 to 36
37 to 37
38 to 45
Subject
Nature of Questions
SCQ
Maths/ MCQ
Chemistry
Total
Total
25
75
20
18
32
45
Total
153
JEE (ADVANCED) CHEMISTRY PAPER SKELETON

Test Name : JR (PT-1)
Faculty preparing the TEST PAPER should fill it according to paper pattern and submit it with finalisaion of paper
at SMD.
PA PER - 1
DIFFICULTY LEVEL :
S.
No.
TYPE
(P)
SCQ
(I)
(O)
TOPIC(S)
SUBTOPIC(S)
Easy (E), Moderate (M),

Tough (T)
(P)
Mole concept
Basics
SCQ
(P)
Mole concept
Basics
SCQ
(P)
Mole concept
Empirical
formula
SCQ
(P)
Mole concept
Basics
SCQ
(P)
Mole concept
Limiting reagent
T
M
SCQ
(P)
Mole concept
Average molar
masss
SCQ
(P)
Mole concept
Pv=nRT
SCQ
(P)
Mole concept
Dilution of sol.
SCQ
(P)
Mole concept
Mixture analysis
10
SCQ
(P)
Mole concept
Con of atoms
11
SCQ
(P)
Atomic structure
12
SCQ
(P)
Atomic structure
13
SCQ
(P)
Atomic structure
Nodes
14
SCQ
(O)
15
SCQ
(O)
16
SCQ
(O)
17
SCQ
(O)
18
SCQ
(O)
19
SCQ
(O)
20
SCQ
(O)
SCQ
(O)
22
SCQ
(O)
23
SCQ
(O)
24
SCQ
(O)
25
SCQ
(O)
26
MCQ
(P)
Mole concept
Basics
27
MCQ
(P)
Mole concept
Basics
21
Electronic
configuration
Quantum
number
M
M
Atomic structure
Quantum
mechanical
hundred atom
(P)
Mole concept
Application of
gas law
Comp. 1
(Q.2)
(P)
Mole concept
Application of
gas law
33
Comp. 2
(Q.1)
(P)
Mole concept
Stoichionetry of
chemical r x n
34
Comp. 2
(Q.2)
(P)
Mole concept
Stoichionetry of
chemical r x n
Inter conversion
of atoms,
molecules &
moles
28
MCQ
29
MCQ
(O)
30
MCQ
(O)
31
Comp. 1
(Q.1)
32
35
36
(P)
Comp. 3
(Q.1)
Comp. 3
(Q.2)
(O)
(O)
37
MTC
(P)
Mole concept
38
Single
Integer
Type
(P)
Mole concept
39
Single
Integer
Type
(P)
Mole concept
Stoichionuly of
chemical r x n
40
Single
Integer
Type
(P)
Mole concept
Limits of
concentration
measurement/
Interconversion
41
Single
Integer
Type
(P)
Mole concept
Average
molecular mass
42
Single
Integer
Type
(O)
43
Single
Integer
Type
(O)
44
Single
Integer
Type
(O)
45
Single
Integer
Type
(O)
Physical Chemistry Paper

SCQ (13)
1.
Final Q. (SID sir)
1.
A compact fluorescent lamp (CFL) was filled with low pressure mixture of argon gas & small amount of
Mercury vapours. The volume of argon gas (At. mass = 40) at 0C and 1 atm pressure is found to be 100
mL. The number of atoms of argon present in the bulb is :
(Mole-1(P))(E)
,d Bksl izfnIr ysEi (CFL) esa vkWxZu xSl o FkksM+h ek=kk dh edZjh ok"i ds fuEu nkc feJ.k ls Hkjk x;k gSA 0C o 1
atm nkc ij vkWxZu xSl (ijek.kq Hkkj = 40) dk vk;ru 100 mL ls izkIr gqvkA cYc esa mifLFkr vkWxZu ds ijek.kqvksa dh
la[ ;k fuEu gSA

(B*) 2.68 1021
100
Number of Ar atoms =
NA
22400
100
Ar ijek.kqvksa dh la[;k =
NA
22400
(A) 40000
Sol.
(C) 3.3 1024
(D) 5.4 1021
602 1021
224
= 2.68 1021
=
2.
A mixture of HCl(g), PCl3(g) and PCl5(s), each have equal number of Cl-atom then their molar ratio in the
mixture is :
(Mole-1(P))[E]
,d HCl(g), PCl3(g) rFkk PCl5(s), ds ,d feJ.k esa izR;sd Cl-ijek.kq dh leku la[;k j[krs gS rks feJ.k esa budk
eksyj vuqikr Kkr djks &

(A) 1 : 3 : 5
Sol.
(B) 1 : 1 : 1
(C) 15 : 2 : 3
N
Let their are N atom in each then moles of Cl-atoms =
NA
;fn izR;sd esa N ijek.kq gSa rks Cl-ijek.kqvksa ds eksy =
(D*) 15 : 5 : 3
N
NA
HCl : PCl3 : PCl5

N
1 N
1 N
:
:
NA
3 NA
5 NA
15 : 5 : 3
3.
Sol.
In a hydrocarbon, the mass % of C and H are 90% and 10% respectively. If 20 g of given hydrocarbon in
vapour phase occupies a volume of 5.6 litre at STP , then the molecular formula of the hydrocarbon is :
(Take molar volume at STP as 22.4 litre for an ideal gas)
(Mole-1(P))[M]
,d gkbMksdkcZu esa dkcZu o gkbMkstu dh izfr'krrk e'k% 90% rFkk 10% gSA ;fn ok"i izkoLFkk esa fn;s x;s
gkbMksdkcZu ds 20 g dk vk;ru STP ij 5.6 yhVj gS rks gkbMksdkcZu dk v.kqlw=k gksxk (STP ij ,d vkn'kZ xSl ds 1
eksy dk vk;ru 22.4 yhVj gS)
(A) C3H4
(B) C5H20
(C*) C6H8
(D) C9H12
C
H
Mass %
90
10
90
10
mole %
12
1
Ratio
3
:
4
Empirical formula = C3H4
5.6 litre at NTP weighs 20 g
22.4 at NTP weighs 80 g
molar mass = 80
n = 2 and molecular formula = (C3H4)2 = C6H8
Sol.
nzO;eku%
eksy %
C
90
90
12
3
:
= C3 H4
H
10
10
1
4
vuqikr
ewykuqikrh lw=k
5.6 yhVj dk NTP ij Hkkj 20 g gSA
22.4 yhVj dk NTP ij Hkkj 80 g gSA
eksyj nzO;eku = 80
n = 2 rFkk v.kqlw=k = (C3H4)2 = C6H8
4.
A graph is plotted for an element, by putting its weight (in gm) on X-axis and the corresponding number of
atoms on Y-axis. The atomic weight of element (in amu) for which the graph is plotted would be:
(Mole-1(P))(M)
(A) 16
(B*) 20
(C) 35
(D) 40
,d rRo ds fy, X-v{k ij Hkkj xzke esa rFkk Y-v{k ij lEcfU/kr ijek.kqvksa dh la[;k ds e/; xzkQ vkysf[kr fd;k x;k
gSA rRo] ftlds fy, xzkQ fn;k x;k gS] dk ijek.kq Hkkj (amu esa) gksuk pkfg,A
(A) 16
Sol.
(B*) 20
No. of atoms =
wt
NA
Mol.wt
Y=X
NA
M0
slope =
NA
= 3 1022
M0
M0 =
6 10 23
3 10 22
= 20
gy- ijek.kqvksa dh la[;k =

Y=X
<ky =
(C) 35
wt
NA
Mol.wt
NA
M0
NA
= 3 1022
M0
; M0 =
6 10 23
3 10 22
= 20
(D) 40
5.
The number of moles of chromite ore (FeCr2O4) that can be produced by allowing 0.2 moles of Fe, 0.3
moles of Cr and 0.4 moles of O2 to combine according to the following reaction : (Mole-1(P))(T)
Fe + 2Cr + 2O2
FeCr2O4
fuEu vfHkf;k ds vuqlkj Fe ds 0.2 eksy] Cr ds 0.3 eksy o O2 ds 0.4 eksy la;qDr gksdj ksekbV v;Ld (FeCr2O4)
ds fdrus eksy mRiUu dj ldrs gS\
Fe + 2Cr + 2O2
(A) 0.2
Sol.
Mole
Fe + 2Cr
0.2
0.3
FeCr2O4
(B*) 0.15
+ 2O2
0.4
Fe + 2Cr
eksy
0.2
+ 2O2
0.3
L.R.
6.
(D) 0.3
FeCr2O4
0.3 1
=0.15 mole
2
L.R.
Sol.
(C) 0.9
FeCr2O4
0.4
0.3 1
=0.15 eksy
2
Which of the following statements is correct :
(Mole-1(P)) [M]
(A) A compound upon analysis was found to contain 2% Oxygen by mass. Then, the minimum molecular
mass of given compound (in amu) is 1600.
(B*) If the density of a gas at NTP is 0.0025 g/cm3, then the gas has same molecular mass as Butene.
(C) Carbon and Oxygen always combine in the ratio 3 : 8 by mass, according to law of constant
proportions.
(D) Average molecular mass of CO2 and SO3 mixture always more than 60.
fuEu esa ls dkSulk dFku lgh gS %

(A)
,d ;kSfxd dk fo'ys"k.k djus ij Kkr gqvk fd og vius nzO;eku dk 2 %, vkWDlhtu j[krk gSA rc fn;s x;s
;kSfxd dk U;wure vkf.od nzO;eku (amu esa) 1600 gSA
(B*) ;fn NTP ij ,d xS l dk ?kuRo 0.0025 g/cm3 gS ] rc xS l dk vkf.od nz O ;eku] C;w V hu ds leku
gS A
(C) fLFkj vuq i kr ds fu;e ds vuq l kj] dkcZ u rFkk vkW D lhtu ges ' kk nz O ;eku ds 3 : 8 vuq i kr es a
la ; ks f tr gks r s gS a A
(D) CO2 o SO3 feJ.k dk vkS l r vkf.od nz O ;eku ges ' kk 60 ls vf/kd gks r k gS A
Sol.
(A) Let mol. formula of compound is ...............O.

1 16
Mass % of O in compound =
100 = 2
Mol. mass
So, minimum molecular mass of given compound = 800 amu.
(B) (dgas)NTP =
2.5 =
gy
GMMgas
22.4
GMMgas
GMMgas = 56
22.4
Mol. Mass of Butene (C4H8) = 4 12 + 8 1 = 56
So, the gas has same molecular mass as Butene.
(C) Whenever Carbon and Oxygen combine to form CO2, they always
combine in the ratio 3 : 8 by mass, according to law of constant proportions.
(A) ekuk fd ;kSfxd dk v.kqlw=k ...............O gSA
1 16
;kSfxd esa O dk nzO;eku % =
100 = 2
vkf.od nzO;eku
blfy,, fn;s x;s ;kSfxd dk U;wure vkf.od nzO;eku = 800 amu.
(B) (dx S l )NTP =
GMMxSl
22.4
2.5 =
GMMxSl
22.4
GMMxSl = 56
C;wVhu (C4H8) dk vkf.od nz O ;eku = 4 12 + 8 1 = 56

vr%] xS l dk vkf.od nz O ;eku] C;w V hu ds leku gS A
(C ) tc Hkh dkcZ u o vkW D lhtu la ; ks f tr gks d j CO2 cukrs gS a ] os ges ' kk fLFkj vuq i kr ds fu;e ds
vuq l kj] nz O ;eku ds 3 : 8 vuq i kr es a la ; ks f tr gks r s gS A
7.
5.6 L of a gaseous alkane at STP, one molecule of which contains 6 H-atoms, is allowed to burn in
presence of 80 g air (containing 20% oxygen gas by mass). The maximum mass of CO2 that can be
(Mole-1(P)) [M]
produced is :
Sol.
(A) 22 g
(B*) 12.57 g
(C) 14 g
(D) 20 g
STP ij ,d 5.6 L xSlh; ,Ydsu] ftldk 1 v.kq 6 H-ijek.kq ;qDr gS] dks 80 g ok;q (tks Hkkj ls 20% vkWDlhtu
j[krh gS) dh mifLFkfr esa tyk;k tkrk gSA CO2 dk vf/kdre nzO;eku] tks mRikfnr gks ldrk gS] fuEu gS %
(A) 22 g
(B*) 12.57 g
(C) 14 g
(D) 20 g
General formula of alkane = CnH2n + 2
If 1 molecule contains 6 H-atoms, then 2n + 2 = 6.
n=2
Alkane = C2H6
Combustion reaction is :
7
C 2H 6 +
O
2CO2 + 3H2O
2 2
mole
5.6
22.4
= 0.25
mole
0.25
st. coeff.
1
20
100
xSl
80
32
= 0.5
0.5
7/2
1
7
(LR)
0.5 2
2
=
7/2
7
2
Mass of CO2 produced =
44 = 12.57 g.
7
dk lkekU; lw=k = CnH2n + 2
Moles of CO2 produced =
Sol.
,Ydsu
;fn 1 v.kq] 6 H-ijek.kq j[krk gS] rc 2n + 2 = 6.
n=2
,Ydsu = C2H6
ngu vfHkf;k fuEu gS %
C 2H 6 +
5.6
22.4
eksy
= 0.25
eksy
jllehdj.kferh
xq.kkad
mRikfnr
mRikfnr
8.
0.25
1
7
O
2 2
20
100
2CO2 + 3H2O
80
32
= 0.5
0.5
7/2
1
7
(LR)
0.5 2
2
CO2 ds eksy =
=
7/2
7
2
CO2 dk nzO;eku =
44 = 12.57 g.
7
How much volume of 63% w/w aq. HNO3 solution (d = 1.5 g/ml) is diluted with sufficient water to prepare
1 L of 3 M HNO3 solution
(Mole-1(P)) [M]
tyh; HNO3 foy;u (d = 1.5 g/ml) dk fdruk vk;ru i;kZ I r ty ls ruq fd;k tk;s fd 3 M
HNO3 dk 1 L foy;u iz k Ir gks tk;s A
63% w/w
(A*) 200 ml
Ans.
(B) 300 ml
(C) 120 ml
(D) 150 ml
200 ml
63 gm HNO3 is present in 100 gm solution
63 gm HNO3 is present in
M = 63
1.5
10
63
100
ml solution
1.5
so M1V1 = M2V2
15 V1 = 3 1
V1 = 0.2 Litre
100 xz k e
foy;u es a 63 gm HNO3 mifLFkr gS A
100
ml foy;u
1.5
M = 63
1.5
es a 63 gm HNO3 mifLFkr gS A
10
63
vr% M1V1 = M2V2

15 V1 = 3 1
V1 = 0.2 Litre
9.
284 g of mixture of CaCO3 and MgCO3 is heated to a constant weight. If total volume of CO2 produced is
67.2L at STP, then find the mass of residue left.
(Mole-1(P)) [M]
(A) 284 g
(B) 132 g
(C) 240 g
(D*) 152 g.
CaCO3 o MgCO3 ds 284 g feJ.k dks ,d fu;r Hkkj rd xeZ fd;k tkrk gSA ;fn STP ij mRikfnr CO2 dk dqy
vk;ru 67.2L gS] rks 'ks"k cps vof'k"V dk nzO;eku Kkr djksA
(A) 284 g
Sol.
gy
(B) 132 g
67.2
Moles of CO2 evolved =
= 3 moles
22.4
Mass of CO2 evolved = 3 44 = 132 g
mass of residue left = 284 132 = 152 g
Total mass = 152 g.
67.2
fu"dkflr CO2 ds eksy =
= 3 moles
22.4
fu"dkflr CO2 dk nzO;eku = 3 44 = 132 g
(C) 240 g
(D*) 152 g.
'ks"k cps vof'k"V dk nzO;eku = 284 132 = 152 g

dqy nzO;eku = 152 g.
10.
Similar to the % labelling of oleum, a mixture of H3PO4 and P4O10 is labelled as (100 + x) % where x is the
maximum mass of water which can react with P4O10 present in 100 g mixture of H3PO4 and P4O10. If such
a mixture is labelled as 127 %. Mass of P4O10 in 100 gm of mixture, is
(Mole-1(P))(M)
vkWfy;e ds % vadu ds leku H3PO4 o P4O10 ds ,d feJ.k dk vadu (100 + x) % ds :i essa fd;k tkrk gS tgk
ty dk vf/kdre nzO;eku x gS tks fd H3PO4 o P4O10 ds 100 g esa mifLFkr P4O10 ds lkFk f;k dj ldrk gSA ;fn
bl izdkj ds ,d feJ.k dk vadu 127 % gSA 100 g feJ.k esa P4O10 dk nzO;eku fuEu gS&
Sol.
(A*) 71 gm
P4O10 + 6H 2O
1
6
(B) 47 gm
4H 3PO4
(C) 83 gm
27 27
18 18
moles of P4O10 =
1
4
mass of P4O10 in 100 gm mixture =
1
284 = 71 gm
4
(D) 35 gm
Sol.
P4O10 + 6H 2O
1
6
27 27
18 18
P4O10 ds
100 g
11.
4H 3PO4
eksy =
1
4
feJ.k esa P4O10 dk nzO;eku =
1
284 = 71 gm
4
If the value of total spin for Xa+ ion is found to be 2, then the possible values of Z (atomic number) and 'a'
are respectively :
(ATS(P))(M)
;fn X vk;u ds fy, dqy p.k dk eku 2 ik;k tkrk gS] rc Z (ijek.kq ekad) rFkk 'a' ds lEHkkfor eku e'k% gSa %
a+
(A) 26 & 3
Sol.
gy.
(2*) 24 & 2
(3) 27 & 2
1
Total spin = n
= 2.
2
no. of unpaired electron = n = 4.
X 3+
1s2 2s22p6 3s2 3p6 3d5 (5 unpaired electron).
26
X 2+
24
X2
27
X+
24
dqy p.k = n
X 3+
26
24
12.
X 2+
2
27
24
X+
(4) 24 & 1
1
= 2.
2
v;qfXer bysDVkWu dh la[;k = n = 4.

1s2 2s22p6 3s2 3p6 3d5 (5 v;qfXer bysDVk Wu).
1s2 2s22p6 3s2 3p6 3d4 (4 v;qfXer
bysDVkWu).
1s 2s 2p 3s 3p 3d (3 v;qfXer bysDVkWu).
1s2 2s22p6 3s2 3p6 3d5 (5 v;qfXer bysDVkWu ).
2
Let the total number of orbitals in ath shell be 16 and value of azimuthal quantum number for the unpaired
electron in vanadium atom (Z = 23) be 'b', then find the sum (a + b).
(ATS(P))(M)
ekuk fd a dks'k esa d{kdksa dh dqy la[;k 16 gS rFkk osusfM;e ijek.kq (Z = 23) esa v;qfXer bysDVkWu ds fy, f}xa'kh
DokaVe la[;k dk eku 'b' gS rc (a + b) ds ;ksx dk eku Kkr dhft,A
th
Sol.
gy.
13.
(A) 4
(2) 5
(3*) 6
Total number of orbitals in ath shell = a2 = 16
a = 4.
value of for unpaired electron in V atom = 2.
b=2
(a + b) = 4 + 2 = 6.
ath dks'k esa d{kdksa dh dqy la[;k = a2 = 16
a = 4.
V ijek.kq esa] v;qfXer bysDVkWu ds fy, dk eku = 2.
b=2
(a + b) = 4 + 2 = 6
(4) 3
3d orbital)
3d d{kd)
Which of the following contain maximum number of radial nodes ?
(ATS(P))(E)
fuEu esa ls f=kT;h; uksM (radial nodes) dh vf/kdre la[;k dkSu j[krk gS\
(A*) 5s
(B) 5p
(C) 6d
(D) 4f
SCQ (12)
14.
Professor I.L. Finar instructed his student to convert the -Amino acid (X) into a new compound (Y) in
which the NH2 group is replaced by COOH group. The student was confused in writing the correct
IUPAC names of these two compounds. The correct IUPAC names of X and Y will be respectively.
(X) =
(IUPAC Nomenclature(O))
(A) 2-Ethyl-2-amino ethanoic acid, 2-Ethyl-2-carboxy ethanoic acid
(B*) 2-Aminobutanoic acid, Ethylpropanedioic acid
(C) 2-Aminobutanoic acid, 2-Carboxybutanoic acid
(D) 2-Carboxypropan-1-amine, Propane-1, 1-dicarboxylic acid.
izksQslj I.L. Finar us vius fo|kFkhZ dks ,d mnkgj.k fn;k ftlesa -vehuks vEy (X)
NH2 lewg dks COOH lewg }kjk izfrLFkkfir fd;k x;k Fkk] esa ifjofrZr djus ds
dks ,d u;s ;kSfxd (Y) ftlesa

fy, fn;kA bu nksuksa ;kSfxd ds
IUPAC uke fy[kus esa fo|kFkhZ dks my>u (confused) gqvkA e'k% X vkSj Y ds lgh IUPAC uke gSA
(X) =
(A) 2-,fFky-2-,ehuks ,FksukWbd vEy, 2-,fFky-2-dkcksZDlh

(B*) 2-,ehuksC;wVsuksbd vEy, ,fFkyizksisuMkbZvkWbd vEy
(C) 2-,ehuksC;wVsuksbd vEy, 2-dkcksZDlhC;wVsuksbd vEy
(D) 2-dkcksZDlhizksisu-1-,sehu, izksisu-1, 1-MkbZdkWcksZfDlfyd
Sol.
15.
,FksukWbd vEy
vEy
X=
Y=
2-Aminobutanoic acid
2-,ehuksC;wVsuksbd vEy
Ethylpropanedioic acid
In the following compound
,fFkyizksisuMkbZvkWbd vEy
R2
R1
CH
CH
O
O
which of the following R1 and R2 functional groups will change the word root. (Made by SSS SIR)
(A) CN and OH
(C*) CN and CH2 CH = CH2
R1
R2
fuEufyf[kr ;kSfxd esa]

CH
CH
O
fuEu esa ls
O
fdlesa R1 rFkk R2 f;kRed
(A) CN rFkk OH
Sol.
lewg ds dkj.k ewy 'kCn ifjofrZr gks tk;sxk\

(B) S2OH rFkk OCH3
(D) COOH rFkk CH3
(C*) CN rFkk CH2 CH = CH2

CN and CH2 CH = CH2 will give non as a word root.
CN
16.
(B) S2OH and OCH3

(D) COOH and CH3
rFkk CH2 CH = CH2 ewy 'kCn ds :i esa iz;qDr ugha gksxsaA
Select the structures with correct numbering for IUPAC name of the compound.
fuEu ;kSfxdksa ds IUPAC ukedj.k ds fy;s lgh ekadu okyh lajpukvksa dk p;u dhft;sA
(A)
(B*)
Sol.
&
Sol.
rFkk
17.
(D)
represent correct numbering
esa lgh ekadu fd;k x;k gSA
In which of the following side chain (acyclic chain) is the main chain ?
fuEu esa dkSulh ik'oZ J`
a[kyk vph; J`
a[kyk] eq[; J`
a[kyk gS ?
(A)
18.
(C)
(B)
(IUPAC(O))
(C*)
(D)
Which of the following substituent is absent on the parent chain of the given compound ?
(IUPAC(O))
(A) Ethyl
(B) Methyl
(C*) Tertiarybutyl
(D) None of these
uhps fn;s x;s ;kSfxd dh iSr`

d Ja`
[kyk eas fuEu esa ls dkSulk izfrLFkkih mifLFkr ugha gS \
Sol.
(A) ,fFky
(B) esfFky
Tertiarybutyl group is absent.
(C*) r`
rh;d
C;wfVy
(D)
buesa ls dksbZ ugha
r`
rh;d C;wfVy lewg mifLFkr ugha gSA
19.
COOH
COOH
The IUPAC name of this compound is :
(A) Decanoic anhydride

(C*) 2,9-Epoxydecanedioic acid
O
Sol.
COOH
COOH
(IUPAC(O))
(B) 2,8-Dicarboxyoxacyclononane
(D) 2,9-Epoxydecanedicarboxylic acid.
mijksDr ;kSfxd dk lgh IUPAC uke gS %
(A) Msdsuksbd ,sugkbMkbM

(C*) 2,9-bikWDlhMsdsuMkbvksbd vEy
2 1
4
3
5
COOH
O
COOH
6
8
9 10
7
2,9-Epoxydecanedioic acid
2,9- bikWDlhMsdsuMkbvksbd vEy
(B) 2,8-MkbdkcksZDlhvkWDlklkbDyksuksusu
(D) 2,9-bikWDlhMsdsuMkbdkcksZfDlfyd vEy
20.
1-(1-Chloropropyl)-4-(2-chloropropyl)cyclohexane and 1-(2-Chloropropyl)-4-(3-chloropropyl)cyclohexane

are
(Isomerism(O))
(A) Chain isomers
(B*) Position isomers (C) Metamer isomers (D) Identical compounds
1-(1-Dyksjksizksfiy)-4-(2-Dyksjksizksfiy)lkbDyksgsDlsu ,oa 1-(2-Dyksjksizksfiy)-4-(3-Dyksjksizksfiy)lkbDyksgsDlsu gSA
(A) J`
a[kyk leko;oh
(B*) fLFkfr leko;oh
(C) e/;ko;oh leko;oh
(D) le:i ;kSfxd
and (,oa)
Sol.
21.
are position isomers . (fLFkfr
W h ich am ongs the follo wing can b e th e str ucture of molecular form ula C 5 H 8 O 2 .
v.kqlw=k C 5 H 8 O 2 okys ;kSfxd dh nh xbZ lajpukvksa esa ls dkSulh lajpuk ;kSfxd dh gS\
(A )
Sol.
leko;oh gS)
(2)
C 5 H 8 O 2 h as two D.U.
D is c orrect.
C 5 H 8 O 2 ds fy, D.U. dk
D
(3)
(Isomerism(O))
(4*)
eku nks gSA
lgh fodYi gSA
22.
NH CHO ; H2N
CHO
I
II
Which type of isomerism is observed between I and II.
(Isomerism(O))
(A) Chain isomers
(B) Position isomers
(C*) Functional isomers
(D) Metamer
NH CHO ; H2N
I
I rFkk II ds
(A) J`
a[kyk
CHO
II
e/; dkSulh leko;ork ik;h tkrh gS\

leko;oh
(B) fLFkfr leko;oh
Sol.
(C*) f;kRed
leko;oh
(D) e/;ko;oh
Amide functional group
Aldehyde and 1 amine
,sekbZM f;kRed lewg

23.
How many position of the skeleton of 3-methylhexane at which double bond is placed and that gives
positional isomers only.
(Isomerism(O))
3-esfFkygsDlsu dh lajpuk esa fdruh fLFkfr ij f}ca/k mifLFkr gS tks dsoy fLFkfr leko;oh nsrk gS %
(A) 4
(B*) 5
(C) 6
(D) 7
5
Sol.
,fYMgkbM rFkk 1 ,ehu
4
2
4
2
6
5
4
3
,
5
4
3
6
5
24.
Sol.
The incorrect combination of names for isomeric alcohols with molecular formula C4H10O is:
(Isomerism(O))
(A) tert-butanol and 2-methylpropan-2-ol
(B*) tert-butanol and 1, 1-dimethylethan-1-ol
(C) n-butanol and butan-1-ol
(D) isobutyl alcohol and 2-methylpropan-1-ol
vk.kfod lw=k C4H10O okys leko;oh (isomeric) ,sYdksgkWyksa ds xyr ukeksa ds la;qDr gS gSa %
(A) r`
rh;d-C;wVsukWy (tert-butanol) ,oa 2-esfFkyizksi su-2-vkWy
(B*) r`
rh;d-C;wVsukWy ,ao 1, 1-MkbesfFky,sFksu-1-vkWy
(C) n-C;wVsukWy ,ao C;wVsu-1-vkWy
(D) vkblksC;wfVy ,YdksgkWy ,oa 2-esfFkyizksisu-1-vkWy
Alcohols with formula C4H10O are -
gy-
lw=k C4H10O ds ,YdkWgy fuEu gS %

OH
OH
OH
2-C;wVsukWy
1-C;wVsukWy
25.
r`
rh; C;wfVy ,Ydksgy ;k
2- esfFkyC;wVsu-2- vkW y
(1,1-MkbesfFky,sFksu -1-vkWy ugha )
Arrange the following molecules in increasing order of
fuEufyf[kr esa ls dkSulk e mijksDr v.kqvksa ds

N
to
bond ratio: (IUPAC(O))
o ca/k vuqikr dk c<+rk gqvk lgh e gS %

O
H
(I)
(II)
(A) I < II < III < IV
(III)
(B) I < II < IV < III
(IV)
(C*) II < I < IV < III
(D) IV < II < I < III
MCQ (3)
26.
Ammonia (NH3) gas combines with oxygen gas over Pt catalyst to produce Nitric oxide (NO) and water. If
13.6 g of NH3 gas is taken initially, then :
(Mole-1(P))(M)
(A*) Volume of oxygen gas required at NTP is 22.4 L
(B*) Volume of H2O( ) produced at 4C (assuming density of water as 1000 Kg/m3) is 21.6 mL.
(C*) Total mass of products obtained is 45.6 g.
(D*) Number of moles of NO produced is 0.8.
Pt mRiszjd dh mifLFkfr esa veksfu;k xSl (NH3), vkWDlhtu xSl (O2) ls f;k dj ukbfVd vkWDlkbM (NO) ,oa ty
mRikfnr djrh gSA ;fn izkjEHk esa 13.6 g NH3 xSl yh tk;s] rkss %
(A*) NTP ij vkWDlhtu xSl ds 22.4 L vk;ru dh vko';drk gksxhA
(B*) 4C rki ij mRikn H2O( ) dk vk;ru 21.6 mL gSA ty dk ?kuRo 1000 Kg/m3 ekudj
(C*) izkIr mRiknksa dk dqy Hkkj 45.6 g gSA
(D*) NO ds mRikfnr eksyksa dh la[;k 0.8 gSA
Sol.
4NH3 + 5O2
4NO + 6H2O
Volume of oxygen required at NTP =
13.6
17
5
4
22.4 = 22.4 L
13.6
6
18 = 21.6 g
17
4
volume of H2O ( ) = 21.6 mL ( dH2O = 1000 Kg/m3 = 1 g/mL)
13.6
4
moles of NO produced =
=
= 0.8
17
5
Mass of NO produced = 0.8 30 = 24 g
Total mass of products = m NO + mH2O = 24 + 21.6 = 45.6 g
Mass of water produced =
Sol.
4NH3 + 5O2
NTP ij O2 dk
4NO + 6H2O
vko';d vk;ru =
13.6
17
5
4
22.4 = 22.4 L
13.6
6
18 = 21.6 g
17
4
H2O ( ) dk vk;ru = 21.6 mL
( dH2O = 1000 Kg/m 3 = 1 g/mL)
13.6
4
NO ds mRikfnr eksy =
=
= 0.8
17
5
NO dk mRikfnr Hkkj = 0.8 30 = 24 g
mRiknksa dk dqy Hkkj = mNO + mH2O = 24 + 21.6 = 45.6 g
ty dk mRikfnr Hkkj =
27.
Which of the following statements is/are correct regarding 6.4g of
16 2
8O
ion :
24
(A*) Total number of proton present is about 1.924 10 .

(B*) Total number of electrons present is 4NA
(C) Magnitude of net charge on sample is 0.4 N AC (Coulomb.)
(D*) Total number of neutrons present is 3.2 N A
16 2
vk;u ds 6.4 xzke ds lEcU/k esa fuEu esa ls dkSulk@dkSuls dFku
8O
lR; gS@gSa?
24
(A*) mifLFkr izksVkWuksa dh dqy la[;k 1.924 10 gSA

(B*) mifLFkr bysDVkWuksa dh dqy la[;k 4NA gSA
(C) uewus ij dqy vkos'k dk ifjek.k 0.4 NAC (dqykEc)
(D*) mifLFkr U;wVkWuksa dh dqy la[;k 3.2 NA gSA
Sol.
Total number of proton present =
6 .4
NA
16
gSA
8 = 3.2 NA = 1.926 10
6. 4
24
N A 8 = 3.2 NA = 1.926 10
16
6. 4
Total number of electrons present =
NA 10 = 4NA
16
6. 4
mifLFkr bysDVkWuksa dh dqy la[;k=
NA 10 = 4NA
16
6 .4
Magnitude of net charge on sample =
N A 2e = 0.8 NAe
16
6 .4
uewus ij dqy vkos'k dk ifjek.k =
NA 2e = 0.8 N Ae
16
6 .4
Total number of neutrons present =
NA 8 = 3.2 NA
16
6 .4
mifLFkr U;wVkWuksa dh dqy la[;k =
NA 8 = 3.2 NA
16
mifLFkr izksVkWuksa dh dqy la[;k=
24
(Mole-1(P))(M)
28.
Which of the following statement is correct for 3dxy orbitals?
(ATS(P))(M)
(A*) The orbitals drawn has two nodal planes, xz and yz.
(B) The minimum probability point lie along = 45.
(C*) + ve and ve signs represent sign of amplitude of electron wave.
(D*) It is a non-axial orbital.
3dxy d{kdksa ds lUnHkZ esa dkSulk dFku lgh gS ?
Sol.
(A*) n'kkZ;k x;k d{kd nks uksMy ry xz o yz j[krk gSA

(B) = 45 ds vuqfn'k U;wure izkf;drk fcUnq gksrk gSA
(C*) + ve o ve fpUg bysDVkWu rjax ds vk;ke (amplitude)
(D*) ;g ,d fuj{kh; d{kd gSA
These are the fact.
ds fpUg dks iznf'kZr djrs gSA
;g rF; gSaA
MCQ (2)
29.
Which of the following relation is correct :
(Isomerism(O))
fuEu esa ls dkSulk laca/k lgh gS %
(A*)
and
(B)
and
(C*)
(D*)
30.
are chain iosmers
Ja`
[kyk leko;oh gSaA
are positional isomers
and
and
are functional group isomers f;kRed
Which of the following compounds is/are a pair of isomers ?
fuEu esa ls dkSulk@dkSuls leko;oh;ksa dk ;qXe gS \
fLFkfr leko;oh gSaA
are metamers e/;ko;oh
gSaA
lewg leko;oh gSaA
(Isomerism(O))
(A*)
and
(C*)
(B)
and
(D)
Sol.
(A)
and
Sol.
(B) These compounds are identicle

(C) These are chain isomers
(D) These are homologs.
(A)
rFkk
(B) ;s
(C) ;s
(D) ;s
and
and
are structural isomers.
lajpukRed leko;oh gSaA
;kSfxd le:ih gSA

J`
a[kyk leko;oh gSA
letkr gSA
Comp.(3 x 2Q) 2

iz'u 31 ls 32 ds fy, vuqPNsn
A gas X is introduced in a vessel of volume 60 Lt. at temperature 300K. When another gas Y along with
pervious gas X is added in the vessel of double capacity at 150 K temperature, the pressure becomes half.
On this basis answer the following.
(Mole-1(P))(M)
300 K rki ij 60 Lt. vk;ru okys ik=k esa ,d xSl X yh tkrh gSA tc 150K rki ij nksxquh {kerk ds ik=k esa mijksDr
xSl X dks vU; xSl Y ds lkFk feyk;k tkrk gS] rks nkc vk/kk gks tkrk gSA bl vk/kkj ij fuEu iz'uksa ds mRrj nhft;sA
31.
The relation between moles of gas X and gas Y present finally in the mixture is - (Mole-1(P))(M)
vUrr% feJ.k esa xSl X rFkk xSl Y ds eksyks ds e/; lEcU/k fuEu gS %
(A) 1 : 3
(B*) 2 : 2
(C) 3 : 4
(D) 4 : 3
32.
If mass of gas X added in 10 times the mass of Y added then the ratio molar mass of gas X and Y is
;fn feyk;h x;h xSl X dk nzO;eku] feyk;h x;h xSl Y ds nzO;eku ls 10 xquk gS] rc xSl X rFkk xSl Y ds eksyj
nzO;ekuksa dk vuqikr fuEu gS :
(Mole-1(P))(M)
(A) 1 : 5
(B) 0.2 : 0.25
(C*) 10 : 1
(D) 1 : 3
Sol.
X
60Lt. V
120Lt.
300K
150K
P1
P2
P/2
1
1
=
2X
X Y
X=Y
Mass of X = 10 gm
X dk nzO;eku = 10 gm
Mass of Y = X
Y dk nzO;eku = X
Moles of X =
X
ds eksy =
10a
;
MX
10a
;
MX
10a / MX
=1
a / MY
MY
MX
Moles of Y =
Y
ds eksy =
1
10
MX
MY
a
My
a
My
10
1

Following reaction sequence is given :
2A
+
B
A 2B
2A 2B +
B
A4B3
(A)
(2)
(2) reaction starts after (A) reaction is finished.
fuEu vfHkf;k vuqe fn;s x;s gS %

2A
2A 2B
+
+
B
B
A 2B
A4B3
(A)
(2)
vfHkf;k (A) ds iw.kZ gksus dss i'pkr~ vfHkf;k (2) izkjEHk gksrh gSA
(Mole-1(P))(M)
33.
If 10 moles of A and 7.5 moles of B are taken in a flask, then moles of A4B3 produced in reaction are :
(Mole-1(P))(M)
;fn ,d ykLd esa 10 eksy A o 7.5 eksy B fy;s tkrs gSa] rks vfHkf;k esa mRikfnr A4B3 ds eksy fuEu gSa %
(A) 1
(B) 1.5
(C) 2
(D*) 2.5
34.
Mass of A2B left in above reaction sequence (molar mass of A = 24 g/mol and molar mass of B = 16
g/mol.)
(Mole-1(P))(M)
mijksDr vfHkf;k vuqe esa 'ks"k cps A2B dk nzO;eku fuEu gS %
Sol.
(A dk eksyj nzO;eku = 24 g/mol rFkk B dk

(A*) 0
(B) 1
L.R.
2A
+
B
A 2B
10
7.5
5 mole
B left = 7.5 5
=2.5
2A 2B +
B
A4B3
5
2.5
2.5
moles of A4B3 produced = 2.5
moles of A2B left = 0
mRikfnr A4B3 ds eksy = 2.5

'ks"k cps A2B ds eksy = 0
eksyj nzO;eku = 16 g/mol.)

(C) 1.5
(D) 2
(No L.R.)
Comp.(3 x 2Q) 1

The analgesic drug ibuprofen (P) exist in two isomeric form. One isomer is Physiologically active, while the
other is inactive. The structure of ibuprofen is given below.
nnZfuokjd vkS"k/kh vkbczwQsu (P) ds nks leko;oh :i laHko gS ftuesa ls dsoy ,d leko;oh gh euksjksxfpfdRlk esa
lf; gS tcfd nwljk leko;oh vlf; gksrk gSA vkbczwQsu dh lajpuk uhps nh xbZ gS %
Me
COOH
(IUPAC Nomenclature (O))
35.
(P)
The IUPAC name of (P) is
(A) 3-[para-Isobutylphenyl] propanoic acid
(B*) 2-[para-Isobutylphenyl] propanoic acid
(C) 3-[para-sec-Butylphenyl] propanoic acid
(D) 2-[para-sec-Butylphenyl] propanoic acid
;kSfxd (P) dk lgh IUPAC uke gS %

(A) 3-[iSjk-vkblksC;wfVyQsfuy] izksisuksbd
vEy
(B*) 2-[iSjk-vkblksC;wfVyQsfuy] izksisuksbd
Sol.
vEy
(C) 3-[iSjk-f}rh;d-C;wfVyQsfuy] izksisuksbd
vEy
(D) 2-[iSjk-f}rh;d-C;wfVyQsfuy] izksisuksbd
vEy
3
Me
1
COOH
2
(P)
2-[para-Isobutylphenyl] propanoic acid
2-[ iSjk-vkblksC;wfVyQsfuy] izksisuksbd
36.
Sol.
vEy
The number of sp hybridised carbon atom in (P) is :

;kSfxd (P) esa fdrus ladfjr dkcZu ijek.kq mifLFkr gS\
(A) 3
(B) 4
(C*) 6
3
Number of sp hybridised carbon atom is 6.
mijksDr ;kSfxd esa 6 sp3 ladfjr dkcZu ijek.kq mifLFkr gS\
(D) 5
MTC (4 Vs. 5) 1
37.
Column-I
Column-II
(p) 6.02 10
(A) 64 g of SO2
(B) 6.02 10
23
molecules of CO2
23
(Mole-1(P))(M)
atoms of Sulphur
(q) 2 gm atoms of Oxygen

23
(C) 1 gm molecule of SO3
(r) 18.06 10
(D) 22.4 L of CO at 1 atm & 273 K
(s) 1 mole of given compound.
total atoms.
(t) 14 NA number of electrons.
LrEHk-I
LrEHk-II
ds 6.02 1023 ijek.kq
(A) SO2 ds 64 xzke
(p) lYQj
(B) CO2 ds 6.02 1023 v.kq
(q) vkWDlhtu
(C) SO3 ds 1 xzke
(r) dqy
ijek.kq 18.06 1023
(s) fn;s
x;s ;kSfxd ds 1 eksy
(D) 1 atm
v.kq
o 273 K ij CO ds 22.4 yhVj
(t)
Ans.
(A)
p, q, r, s ; (B)
Sol.
(A) 64 g of SO2
Moles of SO2 =
q, r, s ; (C)
p, s ; (D)
Number of molecules = 1 N A
Number of S atoms = 1 NA
Number of O atoms = 2 NA
Total number of atoms = 3 NA , No. of e = 32 NA.

(B) 6.02 10
23
molecules of CO2
moles of CO2 =
6.02 10 23
6.02 10 23
=1
Number of molecules = 1 NA.

Number of C atoms = 1 NA.
Number of O atoms = 2 NA.
Total number of atoms = 3 NA.
Number of e = 22 NA.
(C) 1 gm molecule of SO3
moles of SO3 = 1
Number of S atoms = 1 NA.
(D) moles of CO =
PV
1 22.4
=
=1
RT
0.0821 273

Number of C atoms = 1 NA.
bysDVkWu dh la[;k 14 NA
s, t
64
=1
64
ds 2 xzke ijek.kq
(A) SO2 ds 64 xzke
SO2 ds
64
=1
64
eksy =
v.kqvksa dh la[;k = 1 NA
S ijek.kqvksa
dh la[;k = 1 NA
O ijek.kqvksa
dh la[;k = 2 NA
ijek.kqvksa dh dqy la[;k = 3 NA , No. of e = 32 NA.

(B) CO 2 ds 6.02 10
CO2 ds
eksy =
23
v.kq
6.02 10 23
6.02 10 23
=1
v.kqvksa dh la[;k = 1 NA.

C ijek.kqvksa
dh la[;k = 1 NA.
O ijek.kqvksa
dh la[;k = 2 NA.
ijek.kqvksa dh dqy la[;k = 3 NA.

bySDVkWuksa dh la[;k = 22 NA.
(C) SO 3 ds 1 xzke
SO3 ds
v.kq
eksy = 1

S ijek.kqvksa
dh la[;k = 1 NA.
O ijek.kqvksa
dh la[;k = 3 NA.
ijek.kqvksa dh dqy la[;k = 4 NA.

(D) CO
ds eksy =
PV
1 22.4
=
=1
RT
0.0821 273

C ijek.kq dh la[;k = 1 NA.
O ijek.kq dh la[;k = 1 NA.
ijek.kq dh dqy la[;k = 2 NA.
Integer(Single digit) 4
38.
Consider the reaction

2As2O3 + 3UO2 (NO3)2
U3O8 + 6NO2 + 2As2O5
(U = 238, As = 75, N = 14, O = 16)

How many of the following conclusions are correct based on this equation ?
(Made by SM SIR On July2014) (Mole-1(P))(M)

(A) Mass ratio of As2O3 and UO2(NO3)2 present is 2 : 3
(B) Mole ratio of As2O3 and UO2(NO3)2 present is 2 : 3
(C) Mass ratio of As2O3 and UO2(NO3)2 reacted is 2 : 3
(D) Mole ratio of UO2(NO3)2 and U3O8 in reaction mixture is 3 : 1
(E) Mass ratio of UO2(NO3)2 and U3O8 in reaction mixture is 3 : 1
(F) Mole ratio of NO2 and U 3O8 formed is 6 : 1
(G) Mole ratio of As2O5 and As2O3 present in reaction mixture is 1 : 1
(H) Sum of number of moles of As2O3 and As2O5 in the reaction mixture is always constant. (POAC)
(I) Sum of number of moles UO2(NO3)2 and U 3O8 present in the reaction mixture is always constant.
(POAC)
fuEu vfHkf;k dk voyksdu dhft,

2As2O3 + 3UO2 (NO3)2
U3O8 + 6NO2 + 2As2O5
(U = 238, As = 75, N = 14, O = 16)
mijksDr lehdj.k ds vk/kkj ij fdrus fu"d"kZ fuEu esa ls lgh gS\

(A) As2O3 o UO2(NO3)2 dk
nzO;eku vuqikr 2 : 3 gSA
(B) As2O3 o UO2(NO3)2 dk
eksy vuqikr 2 : 3 eksy gSA
(C)
f;k'khy As2O3 o UO2(NO3)2 dk nzO;eku vuqikr 2 : 3 gSA
(D)
vfHkf;k feJ.k esas UO2(NO3)2 o U3O8 dk eksy vuqikr 3 : 1 gSA
(E)
vfHkf;k feJ.k esas UO2(NO3)2 o U3O8 dk nzO;eku vuqikr 3 : 1 gSA
(F)
cuk;s x;s NO2 o U3O8 dk eksy vuqikr 6 : 1 gSA
(G) vfHkf;k
(H)
(I)
feJ.k esa mifLFkr As2O5 o As2O3 dk eksy vuqikr 1 : 1 gSaA
vfHkf;k feJ.k esas mifLFkr As2O3 o As2O5 ds eksyksa dh la[;k dk ;ksx ges'kk fu;r jgrk gSA (POAC)
vfHkf;k feJ.k esas mifLFkr UO2(NO3)2 o U3O8 ds eksyksa dh la[;k dk ;ksx ges'kk fu;r jgrk gSA (POAC)
Ans.
Sol.
(C), (F) & (H) are correct statements. Rest are wrong.
(C), (F) o (H) lgh dFku gSaA 'ks"k xyr gSaA
39.
27 kg of SO2Cl2 is reacted with excess of NaOH completely. If the difference between masses of Na2SO4
and NaCl produced is x kg, then x is :
(Mole-1(P))(M)
(SO2Cl2 + NaOH
Na2SO4 + NaCl + H2O)
ds vkf/kD; ds lkFk iw.kZr% vfHkf;k djrk gSA ;fn mRIkkfnr Na2SO4 o NaCl ds nzO;ekuksa ds
e/; vUrj x kg gS, rc x dk eku Kkr dhft, :
27 kg SO2Cl2, NaOH
Ans.
Sol.
(SO2Cl2 + NaOH
5 Kg
SO2Cl2
+
moles =
Na2SO4 + NaCl + H2O)

4NaOH
27000
=200
135
Na2SO4
2NaCl
200 moles
400 moles
m = 200 142 g
= 28.400 kg
m = 400 58.5 g
= 23.4 kg
2H2O
x = 28.4 23.4 = 5 kg.

40.
Mole fraction of solute in solution is 0.25. What is the moles of solvent in solution having 1 mole of solute?
(Mole-1(P))(M)
,d foy;u esa foys; dh eksy fHkUu 0.25 gSA 1 eksy foys; j[kus okys foy;u esa foyk;d ds eksyksa dh la[;k fdruh
gksxh \
Ans.
Sol.
nsolvent =
0.75
1=3
0.25
41.
Find the weight of a sample(in g) which contains 0.5 mole of Ne gas and about 1.505 10
23
molecules of
an unknown gas X. If the sample has average molar mass 100 g/mole. Report your answer dividing the
weight of sample by 15.
(Mole-1(P))(M)
,d izkn'kZ dk Hkkj (xzke esa) Kkr dhft,] ftlesa Ne xSl ds 0.5 eksy rFkk ,d vKkr xSl X ds yxHkx 1.505 1023
v.kq gS ;fn izkn'kZ dk vkSlr eksyj nzO;eku 100 g/mol gS rks viuk mkj] izkn'kZ ds Hkkj dks 15 ls Hkkx nsus ds i'pkr~
nsaA
Ans.
Sol.
Average Molar mass =

total weight
100 =
0.5
100 =
total weight
total moles
1.505 10
23
total weight
0.5 0.25
6.023 1023
total weight
0.75
total weight = 100 0.75 = 75

75
=5
15
vkSlr eksyj nzO;eku =

dqy Hkkj
100 =
0. 5
100 =
dqy Hkkj
dqy eksy
1.505 10
23
6.023 10
23
dqy Hkkj
dqy Hkkj
0.5 0.25
dqy Hkkj = 100 0.75 = 75
0.75
75
=5
15
Integer(Single digit) 4
42.
How many positional isomers of dichloronaphthalene (C10H6Cl2) are possible in which each benzene ring
contains only one chlorine atom.
(Monochlorination(O))
MkbDyksjksuSFkSyhu (C10H6Cl2) ds fdrus fLFkfr leko;oh laHko gS ftlessa izR;sd csUthu oy; ij dsoy ,d Dyksjhu
ijek.kq ekStwn gS\

Ans.
6
Cl
Cl
Cl
Cl
Cl
Cl
Sol.
Cl
Cl
Cl
,
Cl
43.
,
Cl
Cl
Co nsid er all possible is omeric alcoh ols of MW = 102 . How man y of the m are sec ondar y
alc oho ls :
(Structure iso me r(O))
v.kqHkkj = 102 okys ;kSfxd ds lHkh lEHkkfor ,YdksgkWy ij fopkj dhft,s] buesa ls fdrus ,YdksgkWy] f}rh;d ,YdksgkWy
gSA
Ans.
Sol.
OH
C
OH
|
|
|
CCCCCC CCCCCC CCCCC CCCCC CCCCC CCCC
|
|
|
|
| |
|
|
,
,
,
OH ,
OH ,
OH
C
C
C
C OH
44.
Ho w m an y s ubs titu te d pheno l are poss ib le b y the molecu lar formula C 1 0 H 1 0 O.
v.kqlw=k C 1 0 H 1 0 O ds fdrus izfrLFkkih fQukWy lEHko gS\

Ans.
(H ydrogenation(O))
9
C2H5
CH3
CH3
CH 3
CH3
OH
Sol.
CH3
CH3
C2 H5
C2H5
,
OH
CH 3
,
OH
,
OH
OH
OH
,
OH
CH3
CH3
OH
OH
H3C
COOH
45.
O
COPh
HN
O
CH3
H 3C
NH
Ph
The number of functional group in the above compound is :
mijksDr ;kSfxd esa mifLFkr f;kRed lewgksa dh la[ ;k dk dqy ;ksx gS %

(IUPAC Nomenclature (O))
Ans.
Sol.
Sol.
5
Function group = 5
f;kRed lewg = 5

Analysis of Physics Test Paper 1

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Analysis of Physics Test Paper 1

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PT-01

No. of Questions Marks Negative

Integer Type Questions (Single Digit Answer)

SECTION-1 : (Only One option correct type)

buesa ls dksbZ ughaA

vdv (4x x 3 )dx

( A*) more than two times

oLrq dk fLFkfr lfn'k D;k gksxk :

(C*) ( 93i 124j )m

muds osx nzO;eku ij fuHkZj djrs gSa

(B*) 2.4 10 8 m/s

T his is a cas e of tota l interna l r eflectio n.

;g iw.kZ vkUrfjd ijkorZu dh fLFkfr gSa

dsoy (B) laHko ugha gSA

(D) cannot be decided

fu.kZ ; ugh dj ldrs

r1 < r2 (izFke rFkk

f}rh; fLFkfr esa r1 rFkk r2 e'k% viorZu dks.k gS )

A prism having refra ctive in dex

ikuh dh lrg ij ijkorZ u ds dkj.k vU; iz f rfcEc fp=kkuq l kj curk gS A

due to refraction at water d1 =

distance P P = 36 12 = 24 cm. Ans.

the requ ir e distanc e OB = 5

i = 37 ij o lrg ij vkifrr fdj.k ds ij fdj.kks a dk

( CBC ' ) will b e in de gree .......... nw

ork f=kT;k dk xksyh; i`

1.5 1.0 1.5 1.0

mi;q D r fpUg ds lkFk eku j[kus ij

2 has refracting angle 60. Angle of maximum deviation is :

A prism of refractive index

,d 60 viorZu dks.k okys fizT+e dk viorZukad

gSA egke fopyu dks.k gS %

i = sin ( 2 sin 15)

= 30 + sin1 ( 2 sin 15)

xqCckjs dh pkbZ gksxh

A ray of light travelling in the direction

travels along the direction

gSA ijkorZu ds ckn xkeh fn'kk

gks tkrh gSA fdj.k dk vkiru dks.k gS :

SECTION-2 : (One or more option correct type)

;k vf/kd lgh gSA

fuEu esa ls dkSulk dFku xksyh; niZ.k ds fy, xyr gS &

tc oLrq /kz q o rFkk Qks d l ds e/; gS ] iz f rfcEc vkof/kZ r gks x k

(A*) distance of first image formed in A is 50 cm from B.

(D*) total of infinite images are formed in the two mirrors

ijkorZuksa ds ckn fdj.k dk fopyu dks.k D;k gksxkA

(A*) 160 Clockwise

(B) 200 Clockwise

(A*) Average velocity of particle from t = 0 to t = 20 sec. is zero.

ckj leku gks tk,xkA

SECTION 3 : (Paragraph Type)

ftuesa ls dsoy ,d gh lgh gSA

,d d.k x-y ry es a fu;r Roj.k a 6i 8j (m/s2 es a ) ls xfreku gS A t = 0 le; ij d.k ds

The instant of time when speed of the particle is zero will be :

fdl le; ij d.k dh pky 'kw U ; gks x h &

The velocity vector at time t is

solving for v 0 we get t = 2 sec. Ans.

The velocity vector at time t is

solving for v 0 we get t = 2 sec. Ans.

solving for r.v 0 we get t =

putting t in equation (1) we get

fdlh le; t ij os x lfn'k