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INTRODUCTION
1.1 GENERAL
Concrete is probably the most widely used man-made construction material in the
world. Concrete is second highest consumptive material after water, which is used world
wide for most of the constructions. The properties of concrete, which makes it suitable
material for construction purpose, are high compressive strength, wear and tear
resistance, durability, excellent bonding, economy etc.
Concrete and steel were always considered the most important, and the most
commonly used structural materials. The development of new highperformance
compositematerialsthatarestrongerandmoredurablethanconventionalmaterials(e.g.,
Portlandcement concrete, steel,wood,andmasonry)isimportanttotheconstruction
industry.
In spite of this, it has some serious deficiencies; it is inherently weak in tensile
strength compared to other construction materials, a low specific modulus, limited
ductility, and little resistance to cracking.
Conventional concrete is very weak in tension; its tensile strength is only 10% of
its compressive strength so here is an attempt made to improve tensile strength by the
incorporation of Carbon Fibers, which is a nano material. Carbon fiber is an important
development in the field of concrete technology. Available literature is an indicator to the
tremendous interest and enthusiasm shown in adoption of carbon fiber for construction.
CHAPTER 2
REVIEW OF LITERATURE
2.1 HISTORY OF CARBON FIBERS
In 1958, Dr. Roger Bacon created the first high-performance carbon fibers at the
Union Carbide Parma Technical Center, located outside of Cleveland, Ohio.[The first
fibers were manufactured by heating strands of rayon until they carbonized. This process
proved to be inefficient, as the resulting fibers contained only about 20% carbon and had
low strength and stiffness properties. In the early 1960s, a process was developed using
polyacrylonitrile (PAN) as a raw material. This had produced a carbon fiber that
contained about 55% carbon and had much better properties. The polyacrylonitrile (PAN)
conversion process quickly became the primary method for producing carbon fibers. The
high potential strength of carbon fiber was first realized in 1963 in a process developed at
the Royal Aircraft Establishment at Farnborough in the UK.
CHAPTER 3
CARBON FIBER
4.1 Concept of Carbon Fiber
Carbon fiber is a polymer, which is a form of graphite. Graphite is a form of pure
carbon. In graphite the carbon atoms are arranged into big sheets of hexagonal aromatic
rings. The sheets look like chicken wire.( Fig 4) Carbon fiber is a form of graphite in
which these sheets are long and thin.
Fig 4
Carbon fibers are used in concrete for increasing the tensile and flexural
strengths,increasing the tensile ductility and flexural toughness,decreasing the drying
shrinkage and rendering the concrete the ability to sense its own strain.
Carbon fiber has a remarkably high strength and light weight compared to other
traditional materials.
It can be produced with very high modulus for applications such as spacecraft,
arms etc.
Lightweight
Non-corrosive
Alkali resistant
Acid resistant
4.4 ADVANTAGES
Polymerization
The process begins with a polymeric feedstock known as a precursor (that which
comes before), which provides the fibers molecular backbone. Today about 10 percent
of produced carbon fiber is made from a rayon- or pitch-based precursor, but the majority
is derived from polyacrylonitrile (PAN), made from acrylonitrile, which is derived from
the commodity chemicals propylene and ammonia.
Production of PAN-based carbon fiber
Most of a carbon fiber producers investment is spent on precursor, and the quality of the
finished fiber is directly dependent on that of the precursor.
Spinning
PAN fibers are formed by a process called wet spinning. The dope is immersed in
a liquid coagulation bath and extruded through holes in a spinneret made from precious
metals. The spinneret holes match the desired filament count of the PAN fiber (e.g.,
12,000 holes for 12K carbon fiber). This wet-spun fiber, relatively gelatinous and fragile,
is drawn by rollers through a wash to remove excess coagulant, then dried and stretched
to continue the orienting of the PAN polymer. Here, the filaments external shape and
internal cross-section are determined by the degree to which the selected solvent and
coagulant have penetrated the precursor fiber, the amount of applied tension and the
percentage of filament elongation. The last step in PAN precursor fiber formation is the
application of a finishing oil to prevent the tacky filaments from clumping. The white
PAN fiber then is dried again and wound onto bobbins.
Oxidation
These bobbins are loaded into a creel that feeds the PAN fiber through a series of
specialized ovens during the most time-consuming stage of production, oxidation. Before
they enter the first oven, the PAN fibers are spread flat into a tow band or sheet referred
to as warp. The oxidation oven temperature ranges from 392F to 572F (200C to
300C). The process combines oxygen molecules from the air with the PAN fibers in the
warp and causes the polymer chains to start crosslinking. This increases the fiber density
from ~1.18 g/cc to as high as 1.38 g/cc.
To avoid runaway exotherm (the total exothermic energy released during
oxidation) oven manufacturers use a variety of airflow designs to help dissipate heat and
control temperature. Oxidation time varies, driven by specific precursor chemistry. An
elapsed time of 60 to 120 minutes is typical, as are four to six ovens per production line,
with ovens stacked to provide two heating zones that offer 11 to 12 passes of the fiber per
oven. In the end, the oxidized (stabilized) PAN fiber contains about 50 to 65 percent
carbon molecules, with the balance a mixture of hydrogen, nitrogen and oxygen.
Carbonization
Carbonization occurs in an inert (oxygen-free) atmosphere inside a series of specially
designed furnaces that progressively increase the processing temperatures. At the
entrance and exit of each furnace, purge chambers prevent oxygen intrusion because
every oxygen molecule that is carried through the oven removes a portion of the fiber. In
the absence of oxygen, only noncarbon molecules, including hydrogen cyanide elements
and other VOCs (generated during stabilization ) and particulate (such as local buildup of
fiber debris), are removed and exhausted from the oven for post-treatment in an environmentally controlled incinerator. carbonization begins in a low-temperature furnace
that subjects the fiber to 1292F to 1472F (700C to 800C) and ends in a hightemperature furnace at 2192F to 2732F (1200C to 1500C). Fiber tensioning must be
continued throughout the production process. Ultimately, crystallization of carbon
molecules can be optimized to produce a finished fiber that is more than 90 percent
carbon. Although the terms carbon and graphite are often used interchangeably, the
former denotes fibers carbonized at about 1315C/2400F and that contain 93 to 95
percent carbon. The latter are graphitized at 1900C to 2480C (3450F to 4500F) and
contain more than 99 percent elemental carbon. As the fiber is carbonized, it loses weight
and volume, contracts by 5 to 10 percent in length and shrinks in diameter.
CHAPTER 4
CONCEPT OF INVESTIGATION
5.1 COMPOSITE MATERIALS
Composite materials (or composites for short) are engineered materials made
from two or more constituent materials with significantly different physical or chemical
properties which remain separate and distinct on a macroscopic level within the finished
structure.
The most primitive composite materials were straw and mud combined to form
bricks for building construction. Composites are made up of individual materials referred
to as constituent materials. There are two categories of constituent materials: matrix and
reinforcement. At least one portion of each type is required. The matrix material
surrounds and supports the reinforcement materials by maintaining their relative
positions. The reinforcements impart their special mechanical and physical properties to
enhance the matrix properties. The matrix material can be introduced to the reinforcement
before or after the reinforcement material is placed into the mold cavity or onto the mold
surface. Most commercially produced composites use a polymer matrix material often
called a resin solution. There are many different polymers available depending upon the
starting raw ingredients . The most common are known as polyester , vinyl ester, epoxy,
phenolic, polyimide, polyamide, polypropylene, PEEK, and others. The reinforcement
materials are often fibers but also commonly ground minerals.
Products :
Composite materials have gained popularity (despite their generally high cost) in highperformance products that need to be lightweight, yet strong enough to take harsh loading
conditions such as aerospace components (tails, wings, fuselages, propellers), boat,
bicycle frames and racing car bodies.
5.1.1 FIBERS
Fibers are special case of reinforcements. They are generally continuous and have
diameter from 3 to 200 m. Fibers are linear elastic or perfectly plastic. Fibers are
generally stiffer and stronger than same material in bulk form.
5.1.2 MATRIX
Matrix is binder material that supports, separates and protects the fibers. It
provides a path by which load is transferred to the fibers and redistributed among the
fibers in the event of fiber breakage. Matrix has lower density, stiffness and strength than
the fibers. Matrix material must be capable of being poured around the reinforcement
during some stage in manufacture of composites.
CHAPTER 5
EXPERIMENTAL INVESTIGATIONS
6.1 EXPERIMENTAL PROGRAMME
The investigation aims at comparing the flexural strength of plain concrete with
carbon fiber based concrete in which carbon fibers have different orientations.
Specific gravity, water absorption and sieve analysis of coarse and fine aggregates
is found out. Specific gravity of cement is found out.
Concrete mix is designed with the physical properties of available materials for
M20 concrete by using IS 10262:1982.
Experiments have been carried out for the following types of concrete
Plain Concrete
Concrete with carbon fibers in different orientations
In case of layered distribution, fibers are cut to the dimensions of the mould and
distributed in the form of layers.
6.2 MATERIALS
6.2.1 Materials used in the experimentation
Fine aggregates
Carbon Fibers
Casting of beams
Dry mix
Unidirectional
200 g/m2
1.80 g/cc
3 mm
1.5
3500 N/mm2
285 x 103 N/mm2
for mild exposure (refer Table 9.18). Adopt water cement ratio of 0.5.
w = Water content
C = Cement content
Sc = Specific gravity of cement
P = Ratio of FA to total aggregate by absolute volume
Fa = fine aggregate content
Sfa = Specific gravity of fine aggregate
fa = 634 Kg / m3
Ca = 1033 Kg / m3
200 liters/ m3
Cement
400 Kg/ m3
Fine aggregates
634 Kg/ m3
Coarse aggregates
1033 Kg/ m3
R = PL
BD2
Where, R= Modulus of rupture
P = Maximum load
L = Span length
B = Width
D = Depth of the section
The above formula is valid only if the fracture in the tension surface is within the
middle third of the span length (i.e. a > 13.3cm).
When the fracture is outside by more than 5% of the span length (i.e. a < 11cm),
then the test results are rejected.
If the fracture is outside by not more than 5% of the span length, a modified
formula is used:
R= 3Pa
BD2
Where, a = The average distance between the line of fracture and the nearest support
measured on the tension surface of the beam.
= (2.32*1.585) = 3.677 Kg
= (2.32*1.585) = 3.677 Kg
= (2.32*1.585) = 3.677 Kg
Weight of cement
Weight of sand
= (1.390*1.585) = 2.203 Kg
Weight of aggregates
= (1.390*2.580) = 3.586 Kg
Weight of sand
= (0.930*1.585) = 1.474Kg
Weight of aggregates
= (0.930*2.580) = 2.399 Kg
Weight of cement
Weight of sand
= (1.390*1.585) = 2.203 Kg
Weight of aggregates
= (1.390*2.580) = 3.586 Kg
Weight of sand
= (0.930*1.585) = 1.474Kg
Weight of aggregates
= (0.930*2.580) = 2.399 Kg
CHAPTER 6
RESULTS
7.1.1 Plain concrete
Specimen 1
Ultimate load =27KN
Distance of crack from nearest support = a = 16.5 cm
Maximum displacement =2.6 mm
Modulus of rupture =R= (P*L)/ (B*D2)
= (27*103*400)/ (100*1002)
=10.8 N/mm2
Specimen 2
Ultimate load =28KN
Distance of crack from nearest support = a = 18.5cm
Specimen 1
Ultimate load =23 KN
Distance of crack from nearest support = a = 17.5 cm
Maximum displacement =0.9 mm
Modulus of rupture =R= (P*L)/ (B*D2)
= (23*103*400)/ (100*1002)
= 9.2 N/mm2
Specimen 2
Ultimate load =24 KN
Distance of crack from nearest support = a = 19.5 cm
Maximum displacement =1.2 mm
Modulus of rupture =R= (P*L)/ (B*D2)
= (24*103*400)/ (100*1002)
= 9.6 N/mm2
Mean R = 9.4 N/mm2
Specimen 1
Ultimate load =28 KN
Distance of crack from nearest support = a = 15 cm
Maximum displacement =2 mm
Modulus of rupture =R= (P*L)/ (B*D2)
= (28*103*400)/ (100*1002)
= 11.2 N/mm2
Specimen 1
Ultimate load =29 KN
Distance of crack from nearest support = a = 18.5 cm
Maximum displacement =2 mm
Modulus of rupture =R = (P*L)/ (B*D2)
= (29*103*400)/ (100*1002)
= 11.6 N/mm2
Specimen 2
Ultimate load =30 KN
Distance of crack from nearest support = a = 18 cm
Maximum displacement =3.6 mm
Modulus of rupture =R= (P*L)/ (B*D2)
= (30*103*400)/ (100*1002)
= 12 N/mm2
Mean R= 11.6 N/mm2
Specimen 1
Ultimate load =30 KN
Distance of crack from nearest support = a = 21 cm
Maximum displacement =0.5 mm