PHREEQC

Getting Started:
Download program at the following webpage:
HTTP://wwwbrr.cr.usgs.gov/projects/GWC_coupled/phreeqc

Read through information on web page. There is much useful information

including multiple version (PC, Mac, Linux) and help information

Download the most current version. As of this March 2015, the version is
o PhreeqcI version 3.1.7-9213

Note: Phreeqc is updated often. Be sure to use the most recent version. There
also may be an issue with a conflict with windows. If so, there is a simple
explanation for how to download a patch on the download page.

A few examples of things that PHREEQC can do.

These notes provide a few examples of what the program can do in terms of
calculations of water chemistry, water-rock interactions, and speciation of water.
The program has many more functions, but it is intuitive and easy to use and once
you are able to input data and extract results, you will be able to run many types
of simulations. There is also a very good manual with multiple examples that you
can work through to develop other simulations to try.
I. Speciation Modeling: Calculate saturation states, complexation, and species
present given some water composition:
Given water with the following composition:

Solution 1.
Ion
Ca
Mg
Na
K
HCO3
SO4

Conc. (mg/L)
48
3.6
2.1
1.2
152
3.2

Ion
Cl
NO3
Fe
pH
T

Conc. (mg/L)
8.0
0.3
0.05
7.5
20

Questions to be addressed about this water:

(1) What complexes and species are present in the water?
(2) What are saturation states of various minerals?
A. Procedure:
(1) Click on Solution button (a picture of a small flask)
(2) Fill in data where needed. For this example, you will first provide T and pH under
the first tab on the sheet. Then move to individual element input tab. Include all
the data.
Note: a) be sure to include correct units. You may use Default Units or provide units
individually. All of Phreeqc calculations and reports are molar concentrations. The
program will automatically convert to molar units for you.
b) You may calculate the charge balance, or may correct for charge balance with
some ion, for example bicarbonate if you are missing that analysis.
c) Not that the program automatically includes the mass of water as 1 kg. That
can be changed, but the default is to react all solutions as 1 kg of water.
(3) Place cursor in the window on the right window. This window should now show
the values of the data that you have input. This will highlight the blue Run
button. Click button. You may be prompted to save, or if you have previously
saved the file, it will warn you that you will overwrite the previous file.
(4) Click Start. The calculations will be made. Click dismiss. At this point the tabs at
the bottom of the left page will change from blue input tab to green output tab.
And data will be shown.
B. Results:
When you shift to the output tab, you will be able to open folders by clicking on the
+ symbol next to any folder or symbol. Opening the folder next to the

Beginning of initial solution calculation gives another folder that is the Initial
solution 1. This will open up and allow access to the four sections of the data
results including:
Solution composition
Description of Solution
Distribution of Species
Saturation indices
By clicking on any one of these buttons will take you to that point of the data results.
Solution composition
This button shows the composition of the input solution, but concentrations have now
been converted to molality and it shows the number of moles of each input solute.
The values for molality and number of moles are identical in this simulation since
the solutes are dissolved in 1 kg of water.
Description of Solution
This button shows the characteristics of the solution, including those values that were
input initially, including pH, pe, and temperature. Much of the data shown here are
derived values including: specific conductance, density, volume, activity of water,
ionic strength, mass of water, total carbon and total CO2 (in this example, identical
since the only C came from alkalinity), electrical charge balance, an the present
error.
Description of Species
For each element, the total concentration of that element is listed, and then below each
element information about that element is included in the list. This information
includes: molality, activity, log values of these two variables as well as the activity
coefficient and the molar volume of the species.
For example:
Species
Ca
Ca+2
CaHCO3+
CaCO3
CaSO4
CaOH+
CaHSO4+

Molality
1.198e-003
1.155e-003
3.322e-005
6.046e-006
3.813e-006
4.929e-009
7.592e-013

Activity
8.748e-004
3.099e-005
6.052e-006
3.817e-006
4.590e-009
7.071e-013

Log
Molality

Log
Activity

-2.937
-4.479
-5.219
-5.419
-8.307
-12.120

-3.058
-4.509
-5.218
-5.418
-8.338
-12.150

Log
Gamma
-0.121
-0.030
0.000
0.000
-0.031
-0.031

For example, the Ca concentrations is about 1.2 x10-3 molar and there are several
dissolved species present including CaHCO3 (3.322 x 10-5 molar), CaCO3 (6.046 x
10-6 molar), CaSO4 (3.813x 10-6 molar) etc.

Saturation indices
The last value includes the saturation indices relative to all of the mineral phases for
which thermodynamic data are available in the data base you are using (more later)
and for which elements are provided in the solute composition list. Four our
example:
------------------------------Saturation indices------------------------------Phase
Anhydrite
Aragonite
Calcite
CO2(g)
Dolomite
Gypsum
H2(g)
H2O(g)
Halite
Melanterite
O2(g)
Siderite

SI log IAP
-3.36
-0.11
0.04
-2.24
-0.70
-3.14
-23.00
-1.51
-9.33
-8.74
-37.19
-0.78

-7.72
-8.44
-8.44
-3.70
-17.79
-7.72
-26.15
-0.00
-7.75
-10.95
-40.08
-11.67

log KT
-4.36
-8.34
-8.48
-1.47
-17.09
-4.58
-3.15
1.51
1.58
-2.21
-2.89
-10.89

CaSO4
CaCO3
CaCO3
CO2
CaMg(CO3)2
CaSO4:2H2O
H2
H2O
NaCl
FeSO4:7H2O
O2
FeCO3

This file shows each possible mineral phase, its Saturation Index, the log of the ion
activity product (IAP), and the log of the equilibrium constant for the temperature
of the water (KT). The last column is the stoichiometry of the mineral phase that is
equilibrium.
For example: on this page, aragonite is slightly undersaturated (SI = -0.11), but Calcite
is slightly oversaturated (SI = 0.04).
II. Changing Data bases
When you ran the program in part I, one of the menu items that popped up was called
Run. That menu gave you the option of indicating which Input file, Output file
and the Database file to run. The database includes all the thermodynamic data
used to make the saturation calculations and parameters for estimating the activity
coefficients. To change the database used in the calculations, double click on the
radio button with the three dots located to the right of the scroll down menu. This
button will open the Phreeqc Interactive folder to the group of .dat files. The
default file is set to phreeqc.dat, but you should have a choice of several others.
You will also have the option of resetting the default file to any .dat file you
choose. The different files have been compiled for other speciation software,
other laboratories, or gathered from the literature.
You may look at the structure of the .dat files and change them directly in the files.
Go to My Computer, in the C drive and look for Phreeqc Interactive folder.
4

Note: this folder may be located in a folder labeled USGS. Open the Phreeqc
Interactive folder and there should be several .dat files along with the
phreeqci.exe file, a folder with examples, and doc folder with the help manual,
among others. Right click one of the .dat files and open it with the WordPad
program. In this file you will find all the solutions species, logK values,
coefficients for calculating activity coefficients using the Debye-Huckel formula.
Although you can change, add, or delete parameters in this file, it is safer to do
this through the program when adding data to simulate.
Do the following procedure to observe how much the data base changes.
(1) With the data that was input as simulation one, run the simulation again, but this
time change the .dat file to the llnl.dat (data from Lawrence Livermore National
Laboratory).
(2) Scroll down to the Saturation indices to observe calculations of saturation states
of the various minerals. You will see several things have changed, including an
increase in number of minerals for which saturation states have been estimated.
Saturation indices can be calculated for more minerals because of the larger
amount of elemental data in the llnl.dat files; saturation indices cannot be
calculated without the constituents available. Saturation states of the minerals
have also changed, for example, SI aragonite is now -0.16, down from -0.11. For
dolomite, there are now calculations of different types including stoichiometric
dolomite, ordered dolomite and disordered dolomite.

III. Batch Reaction Modeling: What happens if two waters with different
compositions mix?
Given another water with the following composition:
Table 2. Solution 2
Ion
Ca
Mg
Na
K
HCO3
SO4

Conc. (mg/L)
96
7.2
4.2
2.4
304
6.4

Ion
Cl
NO3
Fe
pH
T

Conc. (mg/L)
16.0
0.6
0.1
8.0
25

A. Some questions:
(1) What is the composition of water derived from mixing specified amounts of two
different kinds of water?
(2) What are some of the species present in the mixed water?
(3) How do the saturation states of various minerals change?
B. Procedure:
(1) Go back to the input tab on the lower left window.
(2) Highlight simulation from the first simulation. Place an end at the end of the
simulation by clicking on the black dot in the menu.
(3) Make sure that end is highlighted and click on the solution button once more to
include a second solution. Input the data into the spreadsheet for this solution
similar to the first solution.
(4) Highlight end again and click on the mix button a red volumetric flask with a
plus (+) connected to it. A menu will open and should show radio buttons to
highlight both solutions.
(5) Click on the first and second solution. It will give a value of 1 for the mixing
proportions for each water. This mixing solution essentially represents 1 L for each
solution (e.g. 50% of each). You can change the proportions to any proportion you
wish it does not have to add to 100%. For this example, mix the two solutions in
proportion of 4:1, e.g., 4 of solution 1 and 1 of solution 2. (e.g., 80% solution
1, 20% solution 2).

(6) Place cursor in the window on the right. This will highlight the blue Run
button. Click button. You may be prompted to save, or if you have previously
saved the file, it will warn you that you will overwrite the previous file.
(7) Click Run. The calculations will be made. At this point the tabs at the bottom of
the left page will change from blue input tab to green output tab and data will
be shown.

C. Results:
Open the folder called Reading Input Data from Solution 1. If you open all the files
it will allow you to look through all the calculations, which will show the speciations
of the two solutions, and saturation states of all possible minerals. Open the Batch
Reactions button, which is a large dark dot with Rx in white.
(1) In this file, it will show the composition of the mixing proportions of the mixed water
as well as the composition of the mixed water determined from the Batch reaction. Note,
your results may differ from these presented below, for example, the Specific
conductance and volume of water not shown, since that is a new feature in the model.
These were calculated using an older version of the model
Reaction step 1.
Using mix 1.
Mixture 1.
4.000e+000 Solution 1
1.000e+000 Solution 2
-----------------------------Solution composition-----------------------------Elements
C
Ca
Cl
Fe
K
Mg
N
Na
S

Molality

Moles

5.237e-003
1.678e-003
4.798e-004
1.577e-006
3.070e-005
5.714e-004
8.860e-005
3.256e-004
1.517e-004

2.618e-002
8.388e-003
2.399e-003
7.884e-006
1.535e-004
2.857e-003
4.430e-004
1.628e-003
7.585e-004

----------------------------Description of solution---------------------------pH
pe

=
=

7.458
11.620

Activity of water

1.000

Charge balance
Adjusted to redox

equilibrium

Ionic strength
Mass of water (kg)
Total alkalinity (eq/kg)
Total CO2 (mol/kg)
Temperature (deg C)
Electrical balance (eq)
Percent error, 100*(Cat-|An|)/(Cat+|An|)
Iterations
Total H
Total O

= 7.402e-003
= 5.000e+000
= 4.917e-003
= 5.237e-003
= 25.000
= -4.665e-003
= -9.06
= 20
= 5.550865e+002
= 2.776123e+002

Note that in the description of the water it shows the percentage error based on the charge
imbalance.
(2) It will have the distribution of species; shown here are just the H2O, C, and Ca
species. Again, the list has the concentrations listed in terms of their molality, activities,
log molality, log activity and the activity coefficients:
----------------------------Distribution of species---------------------------Species

Molality

Activity

Log
Molality

Log
Activity

Log
Gamma

OHH+
H2O
C(-4)
CH4
C(4)
HCO3CaHCO3+
CO2
MgHCO3+
CaCO3
CO3-2
MgCO3
NaHCO3
NaCO3FeHCO3+
FeCO3
Ca
Ca+2
CaHCO3+
CaSO4
CaCO3
CaOH+
CaHSO4+

4.553e-007
3.637e-008
5.551e+001
0.000e+000
0.000e+000
1.303e-001
1.108e-001
8.588e-003
5.537e-003
3.122e-003
1.341e-003
3.819e-004
2.998e-004
1.997e-004
1.409e-005
1.092e-012
3.083e-013
2.976e-002
1.682e-002
8.588e-003
3.013e-003
1.341e-003
4.431e-008
7.031e-010

3.370e-007
2.961e-008
9.969e-001

-6.342
-7.439
1.744

-6.472
-7.529
-0.001

-0.131
-0.089
0.000

0.000e+000

-130.715

-130.702

0.013

8.547e-002
6.627e-003
5.708e-003
2.393e-003
1.382e-003
1.354e-004
3.090e-004
2.059e-004
1.080e-005
8.365e-013
3.178e-013

-0.956
-2.066
-2.257
-2.506
-2.873
-3.418
-3.523
-3.700
-4.851
-11.962
-12.511

-1.068
-2.179
-2.244
-2.621
-2.860
-3.868
-3.510
-3.686
-4.967
-12.078
-12.498

-0.113
-0.113
0.013
-0.116
0.013
-0.450
0.013
0.013
-0.116
-0.116
0.013

6.077e-003
6.627e-003
3.106e-003
1.382e-003
3.395e-008
5.387e-010

-1.774
-2.066
-2.521
-2.873
-7.354
-9.153

-2.216
-2.179
-2.508
-2.860
-7.469
-9.269

-0.442
-0.113
0.013
0.013
-0.116
-0.116

(3) Finally at the bottom of the page, under the tab for Saturation indices it will show
the saturation state of the mixed water.
Phase

SI log IAP

log KT

Anhydrite
Aragonite
Calcite
CH4(g)
CO2(g)
Dolomite
Fe(OH)3(a)
FeS(ppt)
Goethite
Gypsum
H2(g)
H2O(g)
H2S(g)
Halite
Hematite
Jarosite-K
Mackinawite
Melanterite
N2(g)
NH3(g)
O2(g)
Pyrite
Siderite
Sulfur

-0.45
2.25
2.40
-127.84
-0.78
4.52
3.24
-130.88
9.13
-0.23
-38.21
-1.51
-128.91
-6.05
20.27
2.12
-130.15
-13.40
-2.04
-55.45
-6.76
-214.95
-5.99
-96.57

-4.81
-6.08
-6.08
-130.70
-2.24
-12.57
8.13
-134.80
8.13
-4.81
-41.36
-0.00
-129.90
-4.46
16.26
-7.09
-134.80
-15.61
-5.30
-53.68
-9.66
-233.43
-16.88
-91.69

-4.36
-8.34
-8.48
-2.86
-1.47
-17.09
4.89
-3.92
-1.00
-4.58
-3.15
1.51
-1.00
1.58
-4.01
-9.21
-4.65
-2.21
-3.26
1.77
-2.89
-18.48
-10.89
4.88

CaSO4
CaCO3
CaCO3
CH4
CO2
CaMg(CO3)2
Fe(OH)3
FeS
FeOOH
CaSO4:2H2O
H2
H2O
H2S
NaCl
Fe2O3
KFe3(SO4)2(OH)6
FeS
FeSO4:7H2O
N2
NH3
O2
FeS2
FeCO3
S

Notes:
(1) Notice that the mixed water is highly supersaturated with respect to both aragonite
and calcite. This is not too much of a surprise considering that the water has such high
alkalinities and Ca concentrations in the water.
(2) Also that there are many more mineral phases that have saturation indices that have
been calculated because of the higher concentrations in all of the water.

IV. Batch Reaction Modeling: How do these water react with solid phases?
What happens if the water comes into contact with a solid material (e.g. some mineral or
rock) and reaches equilibrium with that material.
A. Some questions are:
(1) How does the composition of the water change once it reaches equilibrium with the
mineral phase?
(2) How much of the mineral dissolves

B. Procedure:
(1) Go back to the input tab on the lower left window.
(2) Make sure that end is highlighted and click on the Equilibrium Phases button,
which looks like a double headed arrow. This button will open a window listing
various mineral phases at the top of the window.
(3) Chose the mineral phase or phases that you want to estimate how much equilibrates
with the water by clicking on the radio buttons. For this example, well react the
water with calcite. You can set the saturation index you want to achieve or leave it
at the default of 0 (e.g. equilibrium). Also, you can choose how much material you
want to have available for the reaction calculations. The default is 10 moles, which
for most minerals, except for highly soluble ones, is in excess of the amount that
can dissolve to reach equilibrium.
(4) Put the cursor in the right window and click Run.
C. Results
Because of the order of input solutions and the mixing between the two solutions, the
mineral phase is reacted with the mixed solution. If you want to react a solid with
one of the primary solutions, the reaction button would have to be put below the
composition of the water. Alternatively, it is possible to use the Save button, which
is a left pointing curved green arrow, to save the compositions of one of the water and
use it in a second simulation.
(1) Now the upper part of the output file will show the Reaction Step, the mixture used,
phase assemblages that are reacted with the solution, in this case it is calcite, the
solution composition, and a description of the solution:

Reaction step 1.
Using mix 1.
Using pure phase assemblage 1.
Mixture 1.
4.000e+000 Solution 1
1.000e+000 Solution 2
-------------------------------Phase assemblage-------------------------------Phase
Calcite

SI log IAP
0.00

-8.48

log KT

Initial

-8.48

1.000e+001

Moles in assemblage
Final
Delta
1.000e+001

9.685e-004

10

-----------------------------Solution composition-----------------------------Elements
C
Ca
Cl
Fe
K
Mg
N
Na
S

Molality

Moles

5.043e-003
1.484e-003
4.798e-004
1.577e-006
3.070e-005
5.714e-004
8.860e-005
3.256e-004
1.517e-004

2.522e-002
7.419e-003
2.399e-003
7.884e-006
1.535e-004
2.857e-003
4.430e-004
1.628e-003
7.585e-004

----------------------------Description of solution---------------------------pH
pe

=
=

7.240
11.882

Charge balance
Adjusted to redox

equilibrium
Activity of water
Ionic strength
Mass of water (kg)
Total alkalinity (eq/kg)
Total CO2 (mol/kg)
Temperature (deg C)
Electrical balance (eq)
Percent error, 100*(Cat-|An|)/(Cat+|An|)
Iterations
Total H
Total O

=
1.000
= 6.867e-003
= 5.000e+000
= 4.530e-003
= 5.043e-003
= 25.000
= -4.665e-003
= -9.74
= 28
= 5.550865e+002
= 2.776094e+002

(2) Again the program calculates the distribution of species. Here are the results are
shown for C and Ca concentration. As you will see, the concentration of Ca has
decreased from 1.682 x 10-3 molar to 1.484 x 10-3 molar. This decrease makes sense
because the original mixed water was supersaturated with respect to calcite and could
not dissolve calcite, and will only precipitate calcite, thereby reducing the Ca
concentration.
----------------------------Distribution of species---------------------------Species

Molality

Activity

Log
Molality

Log
Activity

Log
Gamma

OHH+
H2O
C(-4)
CH4
C(4)
HCO3CO2
CaHCO3+
MgHCO3+
CaCO3
CO3-2
MgCO3
NaHCO3
NaCO3-

1.899e-007
6.226e-008
5.551e+001
0.000e+000
0.000e+000
5.043e-003
4.428e-003
5.260e-004
5.649e-005
2.014e-005
5.556e-006
4.650e-006
1.224e-006
6.804e-007
2.006e-008

1.738e-007
5.759e-008
9.999e-001

-6.721
-7.206
1.744

-6.760
-7.240
-0.000

-0.039
-0.034
0.000

0.000e+000

-131.861

-131.861

0.001

4.069e-003
5.269e-004
5.190e-005
1.845e-005
5.565e-006
3.313e-006
1.226e-006
6.815e-007
1.838e-008

-2.354
-3.279
-4.248
-4.696
-5.255
-5.333
-5.912
-6.167
-7.698

-2.391
-3.278
-4.285
-4.734
-5.255
-5.480
-5.912
-6.167
-7.736

-0.037
0.001
-0.037
-0.038
0.001
-0.147
0.001
0.001
-0.038

11

FeHCO3+
FeCO3
Ca
Ca+2
CaHCO3+
CaSO4
CaCO3
CaOH+
CaHSO4+

4.438e-015
7.932e-016
1.484e-003
1.404e-003
5.649e-005
1.777e-005
5.556e-006
3.144e-009
6.551e-012

4.067e-015
7.945e-016

-14.353
-15.101

-14.391
-15.100

-0.038
0.001

9.998e-004
5.190e-005
1.779e-005
5.565e-006
2.881e-009
6.003e-012

-2.853
-4.248
-4.750
-5.255
-8.503
-11.184

-3.000
-4.285
-4.750
-5.255
-8.540
-11.222

-0.147
-0.037
0.001
0.001
-0.038
-0.038

(3) There is also a description of which mineral phases are in equilibrium with the
solution:
------------------------------Saturation indices------------------------------Phase
Anhydrite
Aragonite
Calcite
CH4(g)
CO2(g)
Dolomite
Fe(OH)3(a)
FeS(ppt)
Goethite
Gypsum
H2(g)
H2O(g)
H2S(g)
Halite
Hematite
Jarosite-K
Mackinawite
Melanterite
N2(g)
NH3(g)
O2(g)
Pyrite
Siderite
Sulfur

SI log IAP
-2.69
-0.14
0.00
-129.00
-1.81
-0.28
1.69
-133.46
7.58
-2.47
-38.24
-1.51
-129.91
-8.47
17.17
-5.42
-132.72
-15.84
-3.54
-56.24
-6.70
-218.50
-8.59
-97.55

-7.05
-8.48
-8.48
-131.86
-3.28
-17.37
6.58
-137.37
6.58
-7.05
-41.39
-0.00
-130.91
-6.88
13.16
-14.63
-137.37
-18.05
-6.80
-54.47
-9.59
-236.98
-19.48
-92.67

log KT
-4.36
-8.34
-8.48
-2.86
-1.47
-17.09
4.89
-3.92
-1.00
-4.58
-3.15
1.51
-1.00
1.58
-4.01
-9.21
-4.65
-2.21
-3.26
1.77
-2.89
-18.48
-10.89
4.88

CaSO4
CaCO3
CaCO3
CH4
CO2
CaMg(CO3)2
Fe(OH)3
FeS
FeOOH
CaSO4:2H2O
H2
H2O
H2S
NaCl
Fe2O3
KFe3(SO4)2(OH)6
FeS
FeSO4:7H2O
N2
NH3
O2
FeS2
FeCO3
S

As you can see, the calcite saturation is now at zero. This is because we told the program
to react with calcite until the water reached saturation. Of interest is the fact that the
decrease in the Ca concentration (as well as the alkalinity) causes the saturation state
with respect to aragonite to decrease as well from 2.25 to -0.14. Note that the water is
now undersaturated with respect to aragonite. If there is a mixture of aragonite and
calcite, then aragonite will dissolve, increasing the calcium concentration,
supersaturating the solution with respect to calcite and causing calcite to precipitate
the so called aragonite-calcite transformation.

12

V. Batch reaction modeling: Equilibrium with different atmospheric compositions

and its influence on geochemical reactions?
One of the most important controls on carbonate mineral dissolution is the concentration
of PCO2 in the water and its conversion to carbonic acid (H2CO3). The PCO2 of the
atmosphere is an important control on pH but other solutes can also change the pH which
in turn controls the relative proportions of H2CO3, HCO3- and CO32-. The species
influence the solubilities of various minerals.
A. Some questions are:
(1) How much will the saturation state of our water sample change if it is in equilibrium
with atmospheric PCO2 with a partial pressure of 10-3.5, similar to earths atmosphere, or in
a high PCO2 atmosphere of 10-1.5 for example that might occur in a cave.
(2) How much calcite can these two different waters dissolve?
B. Procedure:
(1) Go back to the input tab on the lower left window.
(2) Now we will start a new simulation. Highlight Simulation 2 after the end
button of Simulation 1. Add another end to Simulation 2. Open the file by
clicking on the + symbol.
(3) Highlight solution 1 in Simulation 1 and cut and paste to simulation 2 by using
control C and control V to move the data to directly above the end of simulation 2.
Be sure to highlight end before pasting the data into the simulation.
(4) Provide an amount of gas for the water to equilibrate with. Click on the small dark
green gas cylinder and a menu will open allowing you to choose which gas phase to
equilibrate with and the amount of gas to provide in the atmosphere.
Note: The description of the gas includes the total pressure of the atmosphere that is
equilibrating. The default is 1 atm, such as would be expected at the earth surface.
Other variables that can be changed include the initial volume of gas available for
equilibration. You can also change the reaction from fixed pressure, where the
pressure doesnt change regardless of the reaction, or a fixed volume, which can be
consumed by the extent of the reaction.
(5) Input the partial pressure of the CO2. Our first example will be a partial pressure of
10-3.5 atm. This needs to be input as a decimal fraction or in this case 0.000316
atm.

13

(6) Click Run, then open the output simulation tab and open the folder for the
Reaction button.
C. Results
Looking at the Description of the solution give the following table:
----------------------------Description of solution---------------------------pH
pe

=
=

7.471
11.506

Charge balance
Adjusted to redox

equilibrium
Activity of water
Ionic strength
Mass of water (kg)
Total alkalinity (eq/kg)
Total CO2 (mol/kg)
Temperature (deg C)
Electrical balance (eq)
Percent error, 100*(Cat-|An|)/(Cat+|An|)
Iterations
Total H
Total O

=
1.000
= 4.357e-003
= 1.000e+000
= 3.037e-003
= 3.236e-003
= 25.000
= -5.359e-004
= -8.86
= 20
= 1.110154e+002
= 5.551591e+001

And the saturation state provide the following table of data:

------------------------------Saturation indices------------------------------Phase
Anhydrite
Aragonite
Calcite
CH4(g)
CO2(g)
Dolomite
Fe(OH)3(a)
FeS(ppt)
Goethite
Gypsum
H2(g)
H2O(g)
H2S(g)
Halite
Hematite
Jarosite-K
Mackinawite
Melanterite
N2(g)
NH3(g)
O2(g)
Pyrite
Siderite
Sulfur

SI log IAP
-3.36
-0.14
0.01
-128.25
-2.21
-0.76
1.50
-133.42
7.39
-3.14
-37.96
-1.51
-129.83
-9.33
16.80
-7.88
-132.69
-16.96
-3.79
-55.93
-7.28
-218.68
-9.03
-97.76

-7.72
-8.47
-8.47
-131.11
-3.68
-17.85
6.39
-137.34
6.39
-7.72
-41.11
-0.00
-130.83
-7.75
12.79
-17.09
-137.34
-19.17
-7.05
-54.16
-10.17
-237.15
-19.92
-92.88

log KT
-4.36
-8.34
-8.48
-2.86
-1.47
-17.09
4.89
-3.92
-1.00
-4.58
-3.15
1.51
-1.00
1.58
-4.01
-9.21
-4.65
-2.21
-3.26
1.77
-2.89
-18.48
-10.89
4.88

CaSO4
CaCO3
CaCO3
CH4
CO2
CaMg(CO3)2
Fe(OH)3
FeS
FeOOH
CaSO4:2H2O
H2
H2O
H2S
NaCl
Fe2O3
KFe3(SO4)2(OH)6
FeS
FeSO4:7H2O
N2
NH3
O2
FeS2
FeCO3
S

14

If you compare these results with the previous calculation for solution 1, youll see some
subtle changes. In particular, the total CO2 concentrations have risen from 3.236 x 103
to 3.223 x 10-3 molar. This reflects the addition of CO2 from the atmosphere. This
change in the concentration of CO2 in the water has also reduced the pH from 7.5 to
7.471 and the change in the pH has decreased the saturation state of the carbonate
minerals; aragonite has decreased from -0.11 to -0.14 and calcite has decreased from
0.01 to -0.04. These are very small changes because the water presumably was
originally near saturation with atmospheric PCO2 and thus hasnt changed much in its
composition.
What happens if there is higher PCO2 in the atmosphere than the water is in equilibrium
with, for example, within a cave? Additional atmospheric gases could be H2S, which
can also be modeled.
Now lets run a revised model with water number 1 which reaches equilibrium with a
PCO2 of 10-3.5 atm (0.000316 atm) and PH2S of 10-5.4atm (about 4 ppm or 0.000004).
D. Procedure:
(1) Go back to the input tab on the lower left window.
(2) We will start a new simulation, which will be simulation number 3. Highlight
Simulation 3 after the end button of Simulation 2. Add another end to
Simulation 3. Open the file by clicking on the + symbol.
(3) Highlight solution 1 in Simulation 1 and cut and paste to simulation 3 by using
control C and control V to move the data to directly above the end of simulation 2.
Be sure to highlight end before pasting the data into the simulation.
(4) Provide an amount of gas for the water to equilibrate with. Click on the small dark
green gas cylinder and a menu will open allowing you to choose which gas phase to
equilibrate with and the amount of gas to provide in the atmosphere.
(5) Input the partial pressure of the H2S with a value of 0.000004 atm.
(6) Click Run, then open the output simulation tab and open the folder for the
Reaction button.

E. Results
We get the following table for the description of the solute.

15

----------------------------Description of solution---------------------------pH
pe

=
=

7.471
11.466

Charge balance
Adjusted to redox

equilibrium
Activity of water
Ionic strength
Mass of water (kg)
Total alkalinity (eq/kg)
Total CO2 (mol/kg)
Temperature (deg C)
Electrical balance (eq)
Percent error, 100*(Cat-|An|)/(Cat+|An|)
Iterations
Total H
Total O

=
1.000
= 4.357e-003
= 1.000e+000
= 3.037e-003
= 3.236e-003
= 25.000
= -5.359e-004
= -8.86
= 20
= 1.110154e+002
= 5.551591e+001

As you can see the major change in the water composition is that it now has a pe of
11.466, where the pe of the original water was 4. The reason the pe increases is that
the program calculates pe based on concentrations of species in the redox couple.
This change in the redox conditions changes the concentration of redox sensitive
species. For example, the NO3- concentration decreased from 2.142 x 10-5 to 2.098 x
10-5. This change came about because of reduction of NO3- to NO2- and N2 gas. All of
these species are now present in the water although they were absent before reaction
with H2S. Another common redox couple is the reduction of SO42- and H2S, but in
this case the added amount of sulfur in the system has now increased the SO42concentrations from 2.893 x 10-5 to 2.907 x 10-5.
The total solubility of various solutes is listed in the table below:
------------------------------Saturation indices------------------------------Phase
Anhydrite
Aragonite
Calcite
CH4(g)
CO2(g)
Dolomite
Fe(OH)3(a)
FeS(ppt)
Goethite
Gypsum
H2(g)
H2O(g)
H2S(g)
Halite
Hematite
Jarosite-K
Mackinawite
Melanterite
N2(g)
NH3(g)
O2(g)
Pyrite

SI log IAP
-3.36
-0.14
0.01
-127.93
-2.21
-0.76
1.50
-133.06
7.39
-3.14
-37.87
-1.51
-129.51
-9.33
16.80
-7.88
-132.32
-16.91
-3.40
-55.62
-7.44
-218.07

-7.72
-8.47
-8.47
-130.79
-3.68
-17.85
6.39
-136.97
6.39
-7.72
-41.02
-0.00
-130.51
-7.75
12.79
-17.09
-136.97
-19.12
-6.66
-53.85
-10.33
-236.55

log KT
-4.36
-8.34
-8.48
-2.86
-1.47
-17.09
4.89
-3.92
-1.00
-4.58
-3.15
1.51
-1.00
1.58
-4.01
-9.21
-4.65
-2.21
-3.26
1.77
-2.89
-18.48

CaSO4
CaCO3
CaCO3
CH4
CO2
CaMg(CO3)2
Fe(OH)3
FeS
FeOOH
CaSO4:2H2O
H2
H2O
H2S
NaCl
Fe2O3
KFe3(SO4)2(OH)6
FeS
FeSO4:7H2O
N2
NH3
O2
FeS2

16

Siderite
Sulfur

-8.99
-97.52

-19.88
-92.63

-10.89
4.88

FeCO3
S

For a final simulation, well run a revised model with water number 1 which reaches
equilibrium with a PCO2 of 10-1.5 atm (0.0316 atm) and compare the values with the
first time with a PCO2 of 10-3.5.
F. Procedure:
(1) Go back to the input tab on the lower left window.
(2) If we dont care about the results from the initial simulation with the H2S, we can
modify Simulation 3 by clicking off the concentration on the radio button for
H2S, and then modifying the PCO2 to a value of 0.0316.
(3) Run this simulation.
G. Results
We get the following table for the description of the solute. You can see that the solution
is now considerably different that just the natural water composition or the
composition of the water after it had equilibrated with atmospheric PCO2. For
example, now the pH of the water is much lower, 6.6 rather than 7.5 for the original
water.
----------------------------Description of solution---------------------------pH
pe

=
=

6.628
12.518

Charge balance
Adjusted to redox

equilibrium
Activity of water
Ionic strength
Mass of water (kg)
Total alkalinity (eq/kg)
Total CO2 (mol/kg)
Temperature (deg C)
Electrical balance (eq)
Percent error, 100*(Cat-|An|)/(Cat+|An|)
Iterations
Total H
Total O

=
1.000
= 4.368e-003
= 1.000e+000
= 3.037e-003
= 4.514e-003
= 25.000
= -5.359e-004
= -8.83
= 16
= 1.110154e+002
= 5.551847e+001

The total solubility of various solutes is listed in the table below:

17

------------------------------Saturation indices------------------------------Phase
Anhydrite
Aragonite
Calcite
CH4(g)
CO2(g)
Dolomite
Fe(OH)3(a)
FeS(ppt)
Goethite
Gypsum
H2(g)
H2O(g)
H2S(g)
Halite
Hematite
Jarosite-K
Mackinawite
Melanterite
N2(g)
NH3(g)
O2(g)
Pyrite
Siderite
Sulfur

SI log IAP
-3.36
-0.97
-0.83
-128.75
-1.36
-2.44
1.15
-133.61
7.04
-3.14
-38.29
-1.51
-129.50
-9.33
16.09
-6.42
-132.87
-15.79
-3.79
-56.44
-6.60
-218.19
-8.71
-97.08

-7.72
-9.31
-9.31
-131.61
-2.83
-19.53
6.04
-137.52
6.04
-7.72
-41.44
-0.00
-130.49
-7.75
12.08
-15.63
-137.52
-18.00
-7.05
-54.67
-9.50
-236.67
-19.60
-92.20

log KT
-4.36
-8.34
-8.48
-2.86
-1.47
-17.09
4.89
-3.92
-1.00
-4.58
-3.15
1.51
-1.00
1.58
-4.01
-9.21
-4.65
-2.21
-3.26
1.77
-2.89
-18.48
-10.89
4.88

CaSO4
CaCO3
CaCO3
CH4
CO2
CaMg(CO3)2
Fe(OH)3
FeS
FeOOH
CaSO4:2H2O
H2
H2O
H2S
NaCl
Fe2O3
KFe3(SO4)2(OH)6
FeS
FeSO4:7H2O
N2
NH3
O2
FeS2
FeCO3
S

As you can see the amount the water is undersaturated with respect to calcite and
aragonite have increased by quite a lot to -0.97 for aragonite and -0.83 for calcite.
VI. Downloading data
If you are only interested in a specific result of the modeling calculations, it is possible to
download those results into a file that can be opened in Excel or other similar
programs, for example notepad etc. Downloading is possible through the
selected_output button, which looks like a funnel with an equal sign, and is located on
the Printing and numerical methods ribbon at the top of the page. If it is not
displayed, right click on the ribbons at the top and you will be given the option of
turning on and off the ribbons.
Place your cursor at the end button and click the selected output button. This will provide
a window with a series of tabs at the top. The General tab will be open when the
window opens and will allow you to control options of several calculations such as
pH, pe, charge balance, percent error etc. Each option has a drop down menu in
which true, false or as is is selected. True indicates the option will be
downloaded, false indicates it will not be printed.
The other tabs in the selected output menu allow you to control which other results may
be downloaded. The tabs include:
Totals: Click on the radio button of elements for which you would like to download
the total concentration of that element
18

Molalities and Activities: Will download the concentrations (in molality) and
activities of various complexes and dissolved species
Equilibrium Phases and Gases: Will download the amount of a solid phase that
will dissolve or precipitate during a reaction, or the partial pressure of a gas which
is in equilibrium with the water
Saturation indices: Will download the saturation state of a water for which you have
provided concentrations or by reaction with equilibrium phases
VII. Running examples
The help file (Parkhurst, D.L, and Appelo, C.A.J., 1999, Users guide to PHREEQC
(Version 2) USGS Water-Resources Investigations Report 99-4259) in Phreeqc is
quite useful. You can access the file by clicking the help button in the menu.
Much of the manual describes the program, data input, running the program etc,
but at the end of the manual are 18 examples for each of the various simulations
the program will run.
The examples are easy to try and they give a good sense of what the program does and
how you can input your own data. If you open one of the examples, you will see
text describing the specific example, including the data (or simulation) that is to be
used in the example. Following the introduction is a text file of the input
parameters. The simplest method for trying one of the programs is to simply copy
the text from the manual and paste it into the window on the right (not the
workspace window). Once it is pasted into the window, you can open the
Simulation file in the workspace window and you will see the data and simulation
programming there. From there you can scroll through the output file and observe
what calculations have been completed.
In these examples, you will find two other applications that PHREEQ can do. These
include:
Transport modeling: This technique will calculate how migration of solutes will be
transported through advection, dispersion, diffusion and with chemical reactions.
Inverse modeling: Models the geochemical reactions and mixing between different
waters that account for changes in composition along a flow path.

19