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-ELECT!)\O CHE1\HSTl{Y
.
.
\ l
,
.
wing questions in
n the redox rca ti 2 3+ a \\ ord or fill rn the blank ----- .. -- .
21
2
c ion Fe + - 2F )+ +Ii. What is ox id1.
W hat is
d
oxi
f
---..
zc .' Jethe . no. o S .
.
t n S 0 2: . '> .r-i.
3 .The
s l
.no. of
on
.
Pho
. 4 6 t . vc:
oxi
4 I \ 11. .
P torus may vary from ---------------------------.
a)
. ~ w uc of the following is hydrogen acting as oxidizing agent
r
'wvt ~ 12
1
to
give Hl b) with 02
tthStogivcH1s.
5.
rr'm'
is
to
.- ...
6. \V~1ich one of the following w~uld displace all others from their salt
solutions -rvtg, Al , Fe ,Zn .
Cl2 + 2e-+ 2cr. E0 = l .40 V, Au +3 + Je =- Au E0 .; J .50 V.
7 For
What is E0 cell for 2Au ~3 + 6Cr = 2Au + 3CJ2.
8. On passing a given quahtityof charge through molten salt of
aluminium 18 g of aluminium is produced. What mass of copper is
produced by same charge?
reduction
.soln .
I I. During electrolysis
arc-------------------------------------------------.
t hrougl: an clcctrnlytt:
i.-.; -------------------14. 11 tci! storage battery at cathode---------------;-
.-
is reduced .
of the soln are same then its
C + D12
increase
\aq)
cq.constt.
in temp.
while
is
~1
\ JJ\,),
-' ll rc1u v .
i\
c
,
,
... is
111tllH.\1
e ,vnen
cone.
r
\\/\\at happens to Kand I\ q
- Cl-,~
-1
~ll
cuon . NaOl l , )CJ Ba\ance the fo . tea
. - 'bl 'l
given below feasi e
4
the reaction
.
+ Cb .
,
_, ,IJaCl(aq) + Br2 ~ Na81{a~) u.: ;_ N01 -has
~t\~~
slaw
ta~:d~;~t
between
d 1
NaCl+
NaClOJ
f!'
Ln crease
an exarnpl_e:
+H
the
value of
Al IAl+3(0.03M)
[ I x 6 :::: 6 ]
What is cathodic
i1Gand
/I Fe +2(0.02M)
Ecc11
pt ocess .
l
at 298K ror t ie
c.
.
c. 1I 0J
I Fe .
ce
II
EFe+3,.F/+1rt=
2Fe+3 + Sn+2 -) 2Fe+2 + Sn.,. 4 _Given
77V'
~ o Sn t-4 +2 .
= O i 50V From the obtained value ot Kc '
E
/Sn
, Pt
+ ~
+2
- ot
S
2
h h s
d u cc Fe -- to Fe or n
+
-I
rr: - =
n lOll can r~
and
pre
er d ict W et
12.The A m" NH4Cl is I49.7Scn1-rnol
, the >-..,n OH . 198
A,1111.c1- = 76.J resp. Calculate Arn;NI-LiOH.
_ :-.
13.An N/2 soln. ofa salt occ-upying a vol_t'!T!e bet,_,r:en2~ Pt electrodes
I. 72 cm apart and of area of cross secrron of 4.5 cm nas a
n':
?-
n:.:.-;1::-;Uu1ce
or ]5 ohm
~o
can _.
K
d E0
_
hip
}.- Justify that rusting is an electrochen11cal
protection?
_/ Describe Fuel cell or Mercury cell.
_ 7/ Derive relations
7.~alculate
, fY"r
i.
)/ Jtate Kohlrausch
recharging
:.
. Ca lculnt: A co .
i.s
14.F.ind the weight of chlorine gas produced when l amp. current
passed for l 51nin through molten NaCl .
. 5.Calculate Kc and maximum work that can be obtained from a cell
with n = 2 . E0 cc11 = 0.46V .
l 6.Discuss the dependence of A m of strong and weak electrolyte on
the
cone. of soln of electrolyte .
o-
from
? How does salt bridge m t
I t which metal to which metal
?
am
1
1-tty in
e c
the two ha ves . Which metal has hi h am
Eo red ?
roneutra
g er
,
[2x 12 = 24]
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