Professional Documents
Culture Documents
2
User's Manual
Revised November 2006
ERGUN 6.............................................................................................................................. 1
User's Manual ........................................................................................................................ 1
Chapter 1 - Presentation......................................................................................................... 3
1.1. Introduction .................................................................................................................... 3
1.2. Installation of the program.............................................................................................. 3
Chapter 2 - Environment ....................................................................................................... 5
2.1. Program Structure........................................................................................................... 5
2.2. Using Menus.................................................................................................................. 6
2.3. Data File Management................................................................................................... 6
2.3.1. Manual and automatic data transfer during Item by Item Design .............................. 9
2.3.2. Importing data from Database ................................................................................... 10
2.4. Running the program ................................................................................................... 10
2.4.1. Typical application .................................................................................................... 11
2.4.2. Building a Global Model .......................................................................................... 12
2.5. Results Files................................................................................................................. 12
2.6. Operator's privilege...................................................................................................... 13
2.7. Gas/Solid Database...................................................................................................... 14
2.7.1. Preparing data with pure gases ................................................................................. 14
2.7.2. Preparing data with gases mixtures............................................................................ 15
2.8. Cut & Paste possibility, printing diagrams .................................................................. 15
2.9. Tutorials........................................................................................................................ 16
2.10. About ERGUN 6......................................................................................................... 16
Chapter 3- Hydrodynamics of Fluidized Systems ............................................................... 17
3.1. Introduction .................................................................................................................. 17
3.2 Geldart's classification ................................................................................................... 17
3.3 Terminal Velocity.......................................................................................................... 18
3.4. Fluidization Grids ......................................................................................................... 19
3.4.1 Perforated plate distributors:....................................................................................... 20
3.4.2 Tuyere type distributors:............................................................................................. 21
3.5. Expansion properties in fluidized beds ......................................................................... 22
3.5.1 Calculation of Umf ..................................................................................................... 23
3.5.2. Calculation of .......................................................................................................... 23
3.5.3 Calculation of b ......................................................................................................... 24
3.5.4 Calculation of Db........................................................................................................ 24
3.5.5. Fluidized bed design .................................................................................................. 25
3.6. Werthers Bubbling and Bed Expansion Model ........................................................... 26
3.7. TDH and Entrainment................................................................................................... 27
3.7. Cyclones ....................................................................................................................... 29
Chapter 1 - Presentation
1.1. Introduction
The program ERGUN is the result of a collaboration among researchers in the field of
fluidization on one hand and computer scientists on the other. This resulted in the creation
of a user friendly software, particularly well adapted to the needs of engineers.
The ERGUN computer program is fully on-line documented; dialogue messages are present
at all levels, without slowing down the calculations.
This extensive self-documentation makes it possible to learn in a couple of hours the
different possibilities offered by the program environment and to start performing
calculations without any waste of time.
It is for this reason that the user's manual is highly condensed for the program
environment and ismainly focused on the scientific presentation of the program.
We recommend that you read carefully this set of instructions before starting your
calculations. In order to obtain additional information please contact us.
ERGUN 6 package is distributed by:
Divergent S.A.
R.P. Guy Denielou - 66, av. de Landshut
60200 - Compigne FRANCE
phone (33) 3. 44 23 46 28
Fax: (33) - 3.44.23.45.60
e-mail : ergun@utc.fr
In some cases, the set-up may inform you about some files in use. This means that some
files already exist on your computer. Please choose Ignore option to complete
installation.
Ergun6 needs Acrobat Reader to display the tutorials and the users manual. If you
dont have this freeware please download and install this program from
http://www.adobe.com .
Note that ERGUN 6 is usually installed in an ERGUN6.2 directory. However this is
only optional ; you can change the name of this directory to any other you want.
If you have an ancient version of ERGUN program, please be careful when installing the
new version. You would better to install the new version in a new directory to avoid files
confusion. Note that some Data files created by older versions of Ergun Software are not
compatible with the new version. In the case of problem please contact us.
Chapter 2 - Environment
Database is a twined program that lets the user to study and prepare physical data for
some 60 different gases and solids. Please refer to the Database section of this manual
to learn more about the use of the Database .
..
Data for Bubbling Module
Solid density ..
Gas density
Gas Viscosity
..
..
The reason why the user needs to enter the data for each module independently is to make
possible each module to be executed independently. This also help the user to avoid some
common confusions. For example, the gas properties are always not the same in the windbox, in the bubbling suspension or in the cyclone. This is why the data manager conserves
separately the data for each module. To avoid to retype the data, one can use the
Automatic Data Transfer procedure (see the corresponding section 2.3.1 below).
Once the name of a data file is loaded in any module, the program will automatically open
this data file for any new module to avoid retyping the same name. Meanwhile, the user can
operate to open any other data file if desired.
To make a new personal data file, use the <File / Preparing data file> menu. This sub-menu
lets to make a new copy of original ERGUN 6 data file to the user's given name. A new
copy of data file can also be prepared with the <Save As> option of file modification submenu. This option can only be used when the user if modifying an existing data file. In this
case, the program saves the current state of the file to the given name, while the original file
is not modified.
Note to OPERATORS ONLY:
You can modify the source data file ERWIN.$$$ using the text editor available in the
main menu. However, be sure that you keep a copy of original file if any thing goes wrong
with the new one. The interest of modifying this file may be to add some extra lines into the
dp( ), g( )... and any other array parameters (or simply cut some of them.
Choose the TextEditor from the main menu and load ERWIN.$$$ (type the ERWIN.$$$
to load this file). Note that this file contains a number of segments corresponding to each
module of the program. Each segment begins with the name of the corresponding module
and ends with an END statement. Its very important not to change these lines.
What can be changed in the data source Erwin.$$$ file?
Read this paragraph carefully if you want modify any line in this file. First, note that each
column of this file has a maximum number of characters. A data line is composed of for
columns:
Value
unit
name
comment
10 ch
7 ch
7ch
up to 40 characters
______________ Example of file portion: ___________
CYCLONE
0.1132
2600.
0.444
4.45E-5
0.25
m3/s
kg/m3
kg/m3
Ns/m2
m
38E-6
63E-6
88E-6
113E-6
150E-6
200E-6
250E-6
300E-6
400E-6
500E-6
m
m
m
m
m
m
m
m
m
m
0.02
0.03
0.10
0.15
0.45
0.15
0.10
0.
0.
0.
g(1)
g(2)
g(3)
g(4)
g(5)
g(6)
g(7)
g(8)
g(9)
g(10)
Qg
Rop
Rof
Dcy
mass
mass
mass
mass
mass
mass
mass
mass
mass
mass
fraction
fraction
fraction
fraction
fraction
fraction
fraction
fraction
fraction
fraction
cut
cut
cut
cut
cut
cut
cut
cut
cut
cut
1
2
3
4
5
6
7
8
9
10
For example, lines can be copied an added to the dp( ) and g ( ) arrays. To add two new cuts
to the size distribution of particles copy and paste two new lines at the end of each dp( ) and
g() sections, as below:
.
.
.
400E-6
500E-6
600E-6
700E-6
m
m
m
m
dp(9)
dp(10)
dp(11)
dp(12)
mean
mean
mean
mean
size
size
size
size
cut
cut
cut
cut
9
10
11
12
g(11)
g(12)
and
.
.
0.
0.
Note that if the dp( ) array changes, all corresponding arrays should be changed as well, if
not this will generate an error.
The limitation of the array length depends upon the memory capacity.
Units, Names and Comments have no effect on the program execution and can be
changed if necessary. However, we advise not to change any species unless it is necessary.
Note that no tabulation character can be used in this file. Lines contain as much as
necessary, blank characters and are ended by <RETURN>. After any modification of data
source file, all new files from the Main menu / File item, will have the modified form.
2.3.1. Manual and automatic data transfer during Item by Item Design
An automatic Data Transfer Manager is available in the new version 6.1. Click on the
Auto.Data Transfer check box in the Item Design frame of the main menu before
beginning a series of calculations if you desire to transfer data from each step to another.
This option is also available (can be turn on or off) from Data sheet menu.
Note that all possible data is automatically transferred from one module to another. For
the exceptional case of particle size distribution, the latest size distribution in memory is
transferred. However, if the TDH & Entrainment module is executed just before going to
Cyclone design module, the program transfers the size distribution calculated from
carryover result (fine particles) into cyclone design data file section.
If the automatic data transfer option is not activated, the user can always import data at any
time by clicking on the menu Import Data / Bed Conditions or Import Data / Size
Distribution.
The Data Transfer System is based on the allocation of memory to resident data. In some
cases the user may need to clear the data in memory, i.e. when beginning a new case study.
Instead of closing the application and running again, you can just click File/ Clear
memory menu option of the main window.
We always need to initialise the conversion rate, in the cases where the fluid bed is a
reactor. At the end of the calculation procedure, exposed above, we need to verify if the
initial conversion rate is estimated correctly. If not, some items have to be changed until the
conversion rate is satisfied.
Like conversion rate, heat exchangers are studied at the end of the design (or study)
procedure. We always search for the heat exchange surface (number of tubes to put inside
the bed) to remove or to give the necessary heat, in order to maintain the bed temperature.
If the volume of these tubes is important compared to the volume of the fluid bed, one
needs to revise the problem because, initially this volume is not taken into account...etc.
Once different items composing the fluidized system are studied individually, a GLOBAL
MODEL can be developed using the module Fluid Bed Modeling and Expert Analysis.
This step is especially useful because it helps to verify the compatibility of different items.
The user can also save the result file into a personal name. We advise you to use a <.TXT>
extension recognised by WINDOWS NOTEPAD.
Note that if the data file is saved before Run (the user can always load data without
saving) the portion of the data file used for the calculation is automatically inserted into the
results file.
Also, the Virtual Experts comment are automatically inserted into the results file.
server). For example, the file path, source code modifications and any other set-up
operations are generally under operator's privilege.
However, personal data file copy and window-type managing can be done by any user and
are not protected.
2.9. Tutorials
ERGUN 6 is especially useful for engineer training purposes. The program has been used
since many years in a number of universities. Some <Case Studies> are provided for this
purpose.
These examples are explained in the <Tutorial> menu. Note that the operator can add any
other examples. The solution of some of these examples is given within the same text. This
will help some users to learn the "Design Procedure" of a process including fluid beds.
3.1. Introduction
This chapter serves to review a certain number of definitions and concepts in order to
emphasise the problems a process engineer may face during the design of an installation. At
the same time it presents the important role played by fluidization, even if the installation is
primarily designed as a reactor or a heat exchanger.
Even though fluidization phenomena have been the object of numerous scientific
investigations, the design of such installations is still highly dependent upon experiments
and industrial experience.
We highly recommend all users of the ERGUN program to be aware of the limits of
applicability of all correlations available in the chemical engineering literature. Actually,
many of these correlations have been obtained in laboratories, without the necessary
validation through industrial applications.
On the other hand, certain types of solids, in particular those belonging to the C group in
the Geldart diagram (see module H.1.1), are hard to fluidize, and do not follow the methods
usually applied to other types of solids.
s-g
kg/m3
group B
sand-like
group
coarse
group A
aerable
1.0
group C
cohesive
0.1
10
100
1000
(1)
The constants a, b et c are defined as function of Rep according to the following table:
Rep <= .1
.1 < Rep <= 1
1 < Rep <= 10
10 < Rep <= 100
100< Rep <= 1E3
1000 < Rep <=5E3
5000 < Rep <=1E4
10000 < Rep
a
a
a
a
a
a
a
a
=
=
=
=
=
=
=
=
0
:
3.69 :
1.222:
.6167:
.3644:
.3571:
.4599:
.5191:
b
b
b
b
b
b
b
b
= 24
:
= 22.73:
= 29.17:
= 46.5 :
= 98.33:
=148.62:
=-490.5:
=-1663 :
c
c
c
c
c
c
c
c
= 0
=.0903
= -3.9
=-116.7
= -2278
=-47500
=-57.87
=5.42E6
(3)
and the terminal velocity combining the variables from the equations above is given by:
CD
laminar
transient
10-2
1.0
turbulent
102
104
Rep
Figure 2 - Variation of the drag coefficient as a function of particle Reynolds number.
Ut =
4 ( p f ). g . d p
3. Cd . f
(4)
The calculation of the terminal velocity using equations (1) to (4) is interactive, since the
Reynolds number is a function of the velocity Ut and vice versa.
cost, difficult grid design, formation of long jets (this is disadvantageous because the grid
region is normally less active than bubbling region).
Many types of grids are used in industry, but most of them can be designed or studied as a
simple "Perforated Plate Distributor" or a "Tuyere Type Distributor". Note that the physical
properties of the fluidization gas, used for grid design proposes, is that of the "Wind Box"
(a common mistake is to use properties corresponding to fluidized bed conditions).
(1)
where Uor is the velocity at the orifice and Ubv is the velocity in the wind box.
For a plate with a thickness "e" CD is given by the relation:
CD = 0.82 (e/)0.13
(2)
(3)
Knowing the diameter of the orifices (chosen by the designer), we can calculate the spacing
between the orifices (L) :
L = .[3.14/(4f)]0.5 = .8862/(f 0.5)
(4)
Zenz's criterion:
Zenz observed that bubbles formed from grid jets have a mean diameter about two
times the jet penetration length. On the other hand, we know that the equivalent diameter of
a bubble with its cloud if about 1.5 time Db (equivalent spherical diameter). In this case, the
necessary condition to avoid the coalescence of bubbles is:
2 L > 1.5 Lj
(5)
where L is the distance between orifices and Lj the jet penetration length than can be
estimated from the following equations :
a. Zenz's correlation:
0.0144 Lj/ + 1.3 = log10 ( 1.93 g)
(6)
(7)
c. Merry's correlation:
Lj = 5.2 dor(f.dor/p.dp).3 [1.3 (Uor2/g.dor).2 -1]
(8)
(1)
(2)
where Uj is the speed of the jet ( outside of the tuyere). Finally, the continuity equation
written between the wind box and the jet exit gives:
2. Um = j . Uj
(3)
where is he diameter of the inlet orifices and j is the diameter of the orifices at the jet
level.
On the other hand: P grille = P jet + P orifice
(4)
Knowing the pressure P grille, the solution equations 1 to 4 gives the unknowns Uj, Um,
P jet and Por.
Perforated plate
Tuyere
dor
e
Figure 3 - Examples of perforated plate and vertical tuyere
presented in the literature. This method is limited by the range of applicability of the
proposed correlations (study modules).
In the module dedicated to design fluidized beds a set of coherent equations is
chosen to calculate a fluid bed according to classical methods. These equations are chosen,
as much as possible, among those derived from the continuity equation, but also from well
confirmed empirical correlations.
(1)
(2)
(3)
(4)
(5)
3.5.2. Calculation of
Babu et al. :
H/Hmf=1+14.315(U-Umf)0.738 dp p0.376/(Umf0.937 f0.126)
(6)
(1-)=(1-mf) Hmf/H
(7)
(8)
(9)
(10)
Goroshko :
=(18 Rep +.36 Rep)0.21 / Ar0.21
(11)
Wen & Yu :
=((18 Rep+ 2.7 Rep1.657) / Ar)(1 / 4.7)
(12)
3.5.3 Calculation of b
The Ergun program uses the following continuity equations:
1-b = (1-)/(1-mf)= Hmf/h
or
= (U-U )/U
b
mf b
(13)
(14)
b= (1/H)
b.dh
(15)
3.5.4 Calculation of Db
This module is developed for perforated plates and tuyeres distributors. However, the
module can be used for grids made of porous plates using an arbitrary large number of
pores (i.e. n=10000).
(16)
(17)
(18)
(19)
Note that in Mori & Wen's equation Dbm is the maximum size of bubbles formed in a
vertical chain. Do not consider its value for maximum bubble size in industrial fluidized
beds. The calculation method for Dbmaxi in an industrial fluidized bed is controversial.
Geldart[ref. 1] thinks that Davidson's equation : Dbmaxi = 2Ut2/g is the safest way to
calculate it. Thus, he proposes the use of dp'=2.7dp for the calculation of Ut.
(20)
(21)
where Umf and UB are determined by the equations of Wen & Yu and Davidson &
Harrison.
The integration of b along the height of the bed gives its average value:
= 1- (1-b)(1-mf)
(22)
(23)
(24)
(25)
Where dv is the base bubble size and h the height where bubbles appear. Note that the
equation (25) is written in cgs old units. In his further publications, Werther used this
base equation to drive his bubbling model with three parameters dv, and are functions
of particle class :
d v = d ov [1 + 27( U U mf )] (1 + 6.84h )1.2
(26)
U b = (U - U mf) + 0.71 g d v
(27)
U U mf
Ub
, and d ov Solid of Class A
(28)
1/ 3
b =
Note that the particles of class D generally make big bubbles with irregular form (see one
of the videos provided with Ergun Software). These big bubbles may be broken into smaller
ones when a heat exchanger bundle with horizontal tubes occupies the bed section (see
Heat Exchange options). This surely depends on the size of bubbles and the distance
between tubes (horizontal pitch). Werther proposed another method especially developed
to take in consideration the behaviour of these irregular bubbles and the effect of heat
exchanger bundle. Ergun Software provides features for both common Werther model
(equations given above) and that for the Heat Exchanger Effect.
For more information, please refer to the Werthers publication (ref. 12 to 15).
(1)
the mass flux Ei (at the bed surface) is given later by Wen & Chen's equation. The Z*
coefficient must be such that at Z=TDH -> EiH=~Ei*
thus
Z*=~TDH/5
(2)
In practice, equations (1) and (2) are not useful. We only need to calculate the size
distribution of the solid phase above the TDH.
The Ei fluxes are proportional to the solid mass fraction of size "i" present in the bed:
Ei= Ki.xi ; Ki et Ei in kg/s.m2
(3)
The values of Ki are calculated by four methods:
1)- Geldart et al.
(4)
.( p /f -1)
0.725
Rep
1.15
[(U-Ut)/Ut]0.1
(5)
(6)
(7)
(8)
(9)
(10)
(11)
Note that if U< Ut the particles will not be ejected from the fluidized bed and that in this
case Kiis equal zero.
Among the different methods for the calculation of TDH we use the following:
1)- Wen & Chen's
TDH(i)= (1/ai).Ln[(E-Ki)/.01 Ki], where ai 1/m
and
E= 3.07E-9 A.Dbs.[f3.5 g.5 (U-Umf)2.5]/2.5
(12)
(13)
A is the diameter of the bed and Dbs is the size of the bubbles at the surface of the bed.
Note: do not use this correlation for fluid beds with a diameter larger than 1 m (if
you do consider Dt=1 m).
2)- Horio & al.
TDH = 4.47 Dbs0.5
(14)
(15)
(16)
Ut,m/s
0.20
0.25
0.5
1.2
gbed(i), %
10
20
50
20
gelut(i), %
33.3
66.6
-----------
In this example, only particles of size 50 microns or less can leave the bed. There is 10% of
fines and 20% of coarser particles. That mean 1/3 (33%) of size 1 and 2/3 (66%) of size 2.
Please note that this method is only a rough estimation of solid size distribution above
TDH. The real size distribution of particles is finer than what we get with this method.
3.7. Cyclones
3.7.1. Standard Cyclones
Cyclones are always an essential part of fluid beds. Among the diverse types of cyclones
used in the industry, standard cyclones are those used currently for common fluid beds. A
standard cyclone is designed from a given well known proportions as shown in the figure
below:
Dc/2
Dc/2
2 Dc
Dc
Dc/4
Dc/2
2 Dc
Side View
Top View
Figure 5 Users defined cyclones may have any desired proportions. They are mostly
used for highly loaded flows.
(1)
Considering that the gas circulation velocity in the cyclone is the same as the inlet velocity,
we can define the residence time of the gas (approximately equal to particle residence time)
and write that:
Tp= L/Up
(2)
Tg= .Dc.Ns/Up
(3)
where L represents the width of the inlet window (Dc/4 for Zenz's cyclone) and Ns
represents the number of turns performed by the particles before exiting the cyclone.
5
1.7
10
3
15
4.5
20
5.7
In this case the size of particles just touching the wall (at the bottom of the cyclone) can
be calculated from the next equations:
9..L
Ns .U.(p f )
dp50 =
(5)
Zenz considered that only half of the particles of size dp min are actually recovered. Thus
the efficiency of the cyclone for particles of size dp50 would be equal to 50%. For the other
cut sizes efficiencies are calculated from an efficiency diagram. This diagram gives the
efficiency as a function of the ratio dp/dp50. Note that the calculations performed here are
only valid for low charged flows only (generally less than 1%). The efficiencies calculated
must be corrected for cyclones loaded with particles.
Figure 6 In the Time of Flight theory, particles of size dp50 arriving at the left hand
side would have 50% chance of capture (efficiency for these particles would be 0.5)
Cyclone Efficiency
Std. Cyclones
1.00
Efficency, -
0.80
0.60
0.40
0.20
0.00
0
0.5
1.5
2.5
dp/dp50, -
RX
VCS
V 2
mP CS
RX
Wall
region
Central
region
Control
Surface
(CS)
Equilibrium
Orbit
drag
3d P .VrCS
Equilibrium
Orbit
This model has been initially proposed by Barth (ref. 3) and then modified and improved
by Muschelknautz & al. (ref.4). The base idea of the model is that a imaginary cylinder
exists under the vortex finder (Rx) region where particles are in equilibrium between
centrifugal forces and the gas/solid drag forces. The centrifugal forces are expressed in
terms of a angular velocity (applying Stocks law). To define the drag forces, Barth
considers that the gas flow-rate is distributed uniformly over the lateral surface of the above
cylinder. This equality lets calculate the particle cut size dp50 in a quite similar equation
compared to the time of flight model :
(6)
Where the radial and angular velocities VrCS and VCS are obtained from a series of
equations, mainly the momentum balances of the entering and internal currents. Note that
Barths model is a kind of scientific approach to the cyclone understanding behaviour. It
has been tested over some laboratory smooth steel wall cyclones (with no back mixing)
and is probably an optimist model.
2
Plost VLocal
(7)
(8)
The difference between Pin and Pout is the cyclone pressure drop. Among a number of
diverse methods for the estimation of the pressure drop, the equations of Barth (Core
Friction), Stairmand (Dissipative) and Shephered and Lappel (Empirical) are the most
reliable.
The pressure drop is always expressed in a simple equation based on the entrance Euler
number :
P =
1
f U in2 E in
2
(9)
(10)
Where a and b are the width and the height of the entrance window and Dcy the vortex
finder diameter. Barth proposed a much more complicated expression using the internal
velocities calculated from his model. Stairmand & al. proposed an equation similar to that
of Shephered and Lappel. They advantageously included the wall friction and exit effect
dissipations into their correlation.
For detailed information about these models we invite the user to consult the corresponding
references given at the end of this chapter.
Ws0
Ws1
WS2
Pag
Pas
Pgw
Psw
Pg
Ps
P/L
pressure drop per unit height of the bed Pa
P/L)mf pressure drop at min. fluidization velocity Pa
i
mf
p
f
p
3.9. References
3.9.1. ref. Bed Expansion
1)- Davidson J.F., Harrison D., "Fluidized particles", Cambridge Univ. Press, 1969
2)- Wen C.Y., Yu Y.H., Chem. Eng. Prog. Sym. Ser., vol.62, p100, 1966
3) - Werther J., 2nd Eng. Foundation Conferance on Fluidization, p7-12, 1978
4) - Hilligardt K., Werther J., Chem. Eng. Technol. 10, p272-280, 1987
5) - Werther J., Bellgardt D., Groenewald H. and Hilligardt K., Int. Conf. Fluid Bed
Combustion, Boston, p515-522, 1987
6) - Hilligardt K., Werther J., Ger. Chem. Eng., 9, p215-221, 19861)- Babu S.P., Shah B.,
Talwalker A., AIChE Sym. Ser. vol.74, p176,1978
7)- Goroshko V.D.,Rozenbaum R.B., Todes O.M., in: " Hydrodynamics and heat transfer in
fluidized beds",
M.I.T. Press. Cambridge,MA/ p71, 1966
8)- Thonglimp V., Hiquily N., Laguerie C., Powder Tech.,no38, p233, 1984
Bubble phase
Emulsion phase
Grid region
Figure 2 presents a scheme representative of most fluidized bed reactors. Several zones can
be observed:
1) - The jet region right on top of the distributor plate, with a complicated hydrodynamic
behaviour.
2)- The bed core zone has three phases: bubbles, clouds and emulsions, with a transfer of
reactive mass from bubbles -> clouds -> emulsions and a transfer of product mass in the
opposite sense.
3)- The disengagement zone on top of the bed surface where particles are thrown by the
eruption of the bubbles. Figure 3 presents the different models used for dimensioning
industrial reactors.
Due to the complexity of the hydrodynamic phenomena in the jet zone as well as
in the disengagement zone, models tend to be simple and few. On the other hand there is a
large number of models to calculate conversion rates in the bubbling zone of the bed.
Among the simpler models we can mention those by Orcutt & Davidson and Grace
et al. They consider only two phases constituted in part by bubbles and in part by the
suspension solid/gas. Another model was proposed by Kato & Wen, it assumes a chain of
bubbles to be similar to "n" reactors in series. So far this model has not been verified in
industrial applications.
Kunii & Levenspiel proposed a model relatively simple where they consider the
three phases: bubbles, clouds and emulsion and assume that all the fluid passes through the
"bubble phase". This model has been the object of controversy during certain time, but
investigations by Grace and other researchers demonstrated that, among existing models,
the one by Kunii & Levenspiel gives the best results, probably because it adapts better to
different situations.
Bubble
emulsion
U-Umf
Bubble
cloud
emulsio
n
Bubble
emulsion
U
Umf
- Very fast reactions (K'>>Nk: most of the chemical reaction occurs at the bubble-emulsion
interface (the cloud region). The Werther model is the best suited for this case, since it
takes into account the concentration profile around the bubbles. Nevertheless, the jet region
just above the distributor plate has an important role in this type of reaction, it is thus
desirable to combine the model for the bubbling portion with a model that takes into
account the effect of the jets ( such a model is presente further down in this text).
- Intermediary reactions ( K' and Nk are comparable): the chemical reaction and the transfer
of mass together constitute the limiting steps for the conversion. The Kunii & Levenspiel
model can be applied in this case.
G a s s o lid r e a c tio n
P r e p a r a ti o n o f k i n e t i c s
S h r in k i n g c o r e
e a c tio n w ith n o
c h a n g e in p a r ti c l e
siz e
R ea c tio n s w ith
c h a n g e in
p a r tic le s iz e
R T D based m od el
P o p u la ti o n b a la n c e
typ e m o d e l
Figure 4 presents a decision diagram for choosing the most suitable model as a first
approximation. It is evident that the simpler models (such as Orcutt's) produce large errors.
Nevertheless, they offer two essential advantages:
1)- their simplicity allows rough results to be obtained quickly and also to perform a simple
analysis.
2)- they do not require any specific development for reactions with order different from
one.
It is advised to use either Kunii and Levenspiel's or Werther's models. However,
these models require writing and solving a more complex set of equations (model and
kinetics are more complex).
emulsion
Cb
Bubble
film
Ce
Werther's model equations are based on the conservation of mass in the bubble,
cloud and emulsion phases. These equations are relatively complicated, but for a first order
reaction they can be simplified to give:
Mass balance on the gas phase:
-(U-Umf) A (dCAb/dz) +D(dCAn/dy y=0) a.A.dz=0
transfer by +
convection
(1)
transfer = consumption
by diffusion
=0
(2)
=0
(3)
(4)
(5)
(6)
The solution of above equations gives the concentration profile through the fluidized bed.
For a simple first order reaction the conversion rate can be obtained by the following
equation :
1 - XA = exp -
(1/ -1).Ha+tanh(Ha)
(1/ -1).Ha.tanh(Ha)+1
. Ha . Nk
(7)
The factor Ha is the Hatta number defined as for gas-liquid reactors by:
Ha=(Kr.D).5/K
(8)
(9)
The dimensionless number Nk represents the importance of the mass transfer in the whole
reactor:
Nk=K.a.H/(U-Umf).
(10)
(1)
(2)
Ub' is the rise velocity of an isolated bubble and Ub is the velocity of a bubble in a
bubbling bed. The mass transfer constants between the "bubble", "cloud" and "emulsion"
phases ( these media are called "phases" by convention), are determined from an estimate
of the average size of the bubbles in the bed using Werther's method (see the
Hydrodynamics module H.3.1.4 for the calculation of the average db and b).
Figure 6 Kunii and Levenspiel's three phases concept
The Davidson & Harrison relation is used to determine the bubble-cloud constant:
Kbn = 4.5 (Umf/db)+5.85 (D.5) (g 0.25)(db-1.25)
(3)
0.5
(4)
This is exactly the point for which frequently the Kunii & Levenspiel's model is criticised,
namely, the use in a more or less arbitrary fashion of correlations to define two of the most
important variables of the system.
Cloud
Kne
Bubble
Kbn
Emulsion
negligible
Figure 6 Kuniis model with Bubble, Cloud and Emulsion phases
(5)
KT = b .Kr +
1
1 / K bn +
(6)
1
n .Kr +
1
1 / K ne + 1 / e . K r
(7)
n = (1-mf)
3 Umf/mf
Ub - Umf/mf
b + n + e = (1-mf)/b
(8)
(9)
The value of depends of the type of catalyst and seems in general to vary between .1 and
.33.
(1)
(U-Umf).(CAo-CAe)+
Kg.(CAb-CAe).ab.b.dZ =
(1-)H.Kr.CAen
(2)
The simultaneous solution of equations (1) and (2) gives the concentration profiles of
reactant A, in both the bubble and emulsion phases, so the average concentration at the free
surface of the bed can be calculated from:
CAf = .CAb Z=H + (1-).CAe
(3)
with = (U-Umf)/U
For a first order reaction the concentration CAf is obtained from:
1 - .exp(-Nk) + .K'.exp(-Nk)
(4)
CAf/CA =
1 - .exp(-Nk) + K'
where the parameters Nk and K' represent respectively the numbers of 'mass transfer units'
and 'reaction number':
Nk = Kg.ab.b.H/(U)
K'= Kr.Hmf(1-mf).CA(n-1)/U
(5)
(7)
(6)
The interest of this extremely simple model is found in Modeling reactions of order
different from one.
(1)
and if the particle residence time distribution principle is applied, the conversion rate of dpi
size particles is calculated as:
1- Xi
(2)
where Ei(t) represents the particle residence time distribution function in a stirred system,
and is defined by:
Ei(t) = (1/ti).exp(-t/ti)
(3)
"ti" represents the average residence time of dpi size particles. For fluidized beds with a
certain elutriation, the average particle residence time for particles with initial diameter dpi
can be obtained from:
ti = M/{W1+Ki.A}
(4)
X =
(5)
Xi.Gi
i =1
with:
Wso-Ws1-Ws2= 3.M. +
[ F1(R).Keff/R ].dR
(2)b
Equation (2)b represents the solid global mass balance. The function F1(R), calculated by
solving equation (1)b, must satisfy the following integral :
F1(R).dR = 1.0
(3)b
(4)b
Note that the elutriation constant in equations (1)b and (4)b refers to the whole bed and is
expressed in s-1.
Finally, the global solid conversion rate can be calculated as the difference between the
inlet and outlet flow rates:
X = (Wso - Ws1 - Ws2) / Wso
(5)b
E(t), s-1
Time, s
F( R), m-1
R, m
According to Orcutt's (3) model the mass balance for the fluid phase is analogous
to those used in catalytic reaction models. For a first order reaction, according to Orcutt's
model we have :
1 - .exp(Nk)
CAe/CAo =
1 - .exp(-Nk) + K'
(6)
where
7)
Nk = Kg.a.b.H/(U)
Kg = 0.75 Umf + 0.975 g0.25 D0.5/(Db0.25) (8)
K': must be obtained by iteration from the stoechiometric equation for the
consumption of the solid and fluid phases (as we will see later).
The estimation of the concentration CAe (emulsion) is necessary for the calculation of the
solid conversion rate. On the other hand, for the fluid phase we have :
1 - .exp(-Nk) + .K'.exp(-Nk)
CA/CAo=
(9)
1 - .exp(-Nk) + K'
CA
XA = 1 -
CA
(10)
According to the catalytic reaction models, the application of the kinetics laws to
consumable solids, requires the use of a constant K, which takes into account both the
reaction kinetics and the diffusion resistances (see Orcutt model).
On the other hand the mass conservation equations for the fluid and solid phases
must satisfy the stochiometric relation between the two phases:
n.(CA.U.A).XA = (W/MB).X
(11)
During the solution of the system of equations (1) to (11) we notice that the
calculated conversion rate X depends on the concentration of reactive fluid in the
suspension (CAe). CAe depends on the mass transfer phenomenon on one hand and on the
fluid-solid stoechiometric conservation equation (11) on the other.
Thus the resolution of the system of equations (1) to (11) requires the use of an
interactive method to calculate K' (chemical reaction number).
Figure 9 - Size distribution of solid in the underflow and the entrainment from a fluidized
bed.
4.6. Notation
A
Ar
ab
CA
CAb
CAe
CAf
D
Db
Dbmax
dor
dp
dpi
H
Hj
Ha
h*
Kbn
Ki
Kne
KT
kg
K'
Lj
M
Nk
Nr
ti
U
Ub
Umf
Ut
W
W1
X
XA
Xpi
Z
f
mf
b
e
g
p
4.7. References
1- Wen C.Y., Yu Y.H., AIChE J., v.12, p.610, 1966
2- Darton R.C., La Nauze R.D., Davidson J.F., Harrison D., Trans. Inst. Chem. Engrs.,
v.55, p.274, 1977
3- Clift R./ed. by Geldart/ Gas Fluidization Tech./ pub. J. Wiley & Sons, 1986
4- May W.G., Chem. Eng. Prog., v.55, n.12, p.49, 1959
5- Van Deemter J.J., Chem. Eng. Sc., v.13, p.143, 1961
6- Orcutt J.C., Davidson J.F., Pigford R.L., Chem. Eng. Prog. Sym., v.58,n.38, p1, 1962
7- Grace J.R./ ed. by Geldart / Gas Fluidization Tech./ pub. J. Wiley & Sons, 1986
8- Kato K., Wen C.Y., Chem. Eng. SC., v.24, p.1351, 1969
9- Kunii D., Levenspiel O., /Fluidization Engineering/ pub. J.Wiley & Sons, 1969
10- Grace J.R., I & EC Fundamentals, v.14, parts I,II et III, p.75 91, 1975
11- Westerink E.J., Wersterterp K.R., Chem. Eng. Sc., v.45, n.1, p.333, 1990
12 - Werther J., 2nd Eng. Foundation Conferance on Fluidization, p7-12, 1978
13- Werther ., Chem. Eng. Sc., v35, p372, 1980
14 - Hilligardt K., Werther J., Chem. Eng. Technol. 10, p272-280, 1987
15 - Werther J., Bellgardt D., Groenewald H. and Hilligardt K., Int. Conf. Fluid Bed
Combustion, Boston, p515-522, 1987
16 - Hilligardt K., Werther J., Ger. Chem. Eng., 9, p215-221, 1986
17- Werther J., 7 th. International Chem. Reaction Eng. Conf., Boston ,p.1, 1982
18- Yates J. G., Fundamentals of Fluidized-bed Chemical Processes, ed. Butterworths, 1983
19- Grace J.R., NATO repport, june 1985
20- Yates J.G., Rowe P.N., Trans. Instn. Chem. Engrs., v.55, P.137, 1977
21-Grace J.R., deLasa H.I., AIChE, v.24, p.364, 1978
22- Baker H.A., Beer J.M., Gibbs B.M., Inst. Fuel Sym. ser., n1, pA1-1, 1975
Entrained solid
Furthermore, the bubbles coalesce and break assuring an additional motion of the solids.
All these phenomena generally assure sufficient mixing to consider the fluidized bed as
isothermal. The presence of obstacles in the bed, such as a bundle of heat exchanger tubes,
in certain cases reduces sufficiently the mixing so as to produce vertical and lateral
temperature gradients in the bed (for example compact bundles in pressurised fluidized
beds).
The transfer of heat between solids and a wall cannot be calculated without a good
idea of the hydrodynamics of a fluidized bed, mainly of the bubble distribution in the bed.
The motion of bubbles that induces the motion of solids is usually governed by the design
of the gas distributor and the elements immersed in the bed. When using correlations
available in the literature it is necessary to verify whether they have been obtained under
similar hydrodynamic conditions. Frequently, in small diameter fluidized beds (<1 m) the
bubbles have a tendency to gather in the centre, creating an ascendant motion of the solids
in the centre and a descendant one along the walls. The contact between the solids and a
wall will depend on whether the wall is the external envelope or a tube immersed in the
bed. The values of the transport coefficients, as well as the correlations used for their
determination, will as a consequence also be different. Thus, the heat transfer coefficient
will vary with the position of the exchanger wall in the section, as well as with its elevation.
The most important parameter is the time average porosity of the bed at the exchange
surfaces. Fortunately, for most calculations, an average value for the whole bed is sufficient
and the average hydrodynamic parameters for the whole volume of the bed can be used.
After having reviewed all parameters capable of influencing the heat transfer coefficient,
we present the different heat exchange mechanisms in a fluidized bed. The variation of the
heat transfer coefficient with the particle diameter indicates clearly that we cannot hope to
find a correlation for h valid in all cases. Those models that present a correlation that takes
into account the different mechanisms have a better chance of giving good results than
strictly empirical correlations. After having mentioned the different correlations applicable
to horizontal and vertical tube banks, we present Bock's (1983) and Martin's (1984) models.
Umf
Uopt
Ut
For the larger diameter particles, the dominant term for the heat transfer is the gas
convection coefficient ( hgc later to be introduced in the presentation of the heat transfer
mechanisms) and we do not see the same sudden increase in its value when the bed passes
form fixed to fluidized.
The influence of other parameters is much less direct, they essentially affect the
hydrodynamics of the bubbles.
We can already see that the complex variation of the heat transfer coefficient with
the different parameters cannot be easily represented by a single correlation of the power
law type, and that this type of correlations can only be valid for a given range of the
parameters. The modern tendency is to decompose the heat transfer coefficient into three
terms corresponding to three different mechanisms.
(1)
This representation is correct only when the terms have values very different from
each other. The conduction term (still called particle convection by some authors) uses the
mechanism of energy transfer caused by the motion of particles near the wall. The heat is
transferred to a particle during its contact with the heated surface by conduction through the
gas near the contact point. The motion of the particles allows the transfer of this heat to the
fluidized medium, where it is almost instantly transferred to the gas and the other particles.
It is the main term for small particles (<1 mm).
The convection term, hgc, represents the direct transfer between the gas that
percolates between the particles and along the surfaces. This contribution increases with the
gas velocity. This is the dominant term for the large particles (>800 m) requiring high
fluidization velocities and/or in the case of pressurised beds.
The radiation term is only important for temperatures higher than 800 C.
times, such that the heat does not penetrate beyond the first layer of particles. Furthermore,
in order to reconcile the theory with the experimental results, Botterill had to introduce a
film resistance between the first layer of particles and the wall.
2-Models that consider aggregates of solids in contact with the wall for a
determined time.
The first of these models is due to Mickley and Fairbanks (1955). In this model an
aggregate of particles, initially at the temperature of the interior of the bed, is placed in
contact with wall by a bubble. An unsteady heat transfer process occurs. According to
Mickley and Fairbanks the aggregate of solids constitutes an homogeneous medium whose
conductivity and specific heat are calculated as in a gas-solids mixture at minimum
fluidization. After each bubble the aggregate is replaced by another and the process is
restarted. The exchange of heat increases as the frequency of passage of bubbles increases.
This model produces an expression for the instantaneous heat transfer coefficient identical
to the one obtained for unsteady conduction in a semi infinite homogenous medium in
contact at t=0 with a wall at constant temperature:
hpci= {e.s.Cps.(1-mf)/(.t)}
(2)
The thermal characteristics of the aggregate are those of the bed at minimum fluidization.
The instantaneous heat transfer coefficient decreases with time. Before thermal
equilibrium is reached the aggregate is replaced by a new one due to the passage of a
bubble. When the bubble surrounds the transfer surface the local instantaneous heat transfer
coefficient decreases dramatically.
The mean heat transfer coefficient can be obtained by the integration of equation (2)
considering a time distribution of wall contact. For aggregates that spend a time t at the wall
we obtain:
hpc= 2
{ e . s .C ps .(1 - mf ) / ( . t)}
(3)
This physically plausible model gives good results for long contact times with the wall (fine
particles).
The deficiencies of this model are two:
on one hand the uniformity of thermal properties of aggregates is not a good
assumption near the wall.
on the other hand this model predicts transfer velocities much too large for the short
particle contact times.
The penetration of a thermal perturbation from a flat surface into a semi infinite
homogeneous medium can be approximated by:
X =~4
.t
(4)
(5)
where l is the mean free path derived from gas kinetic theory, in which an accommodation
coefficient is introduced to account for the incomplete transfer of energy when the
molecules of gas hit the wall. This model assumes that the contact particle/wall is punctual,
it does not consider the particle or wall rugosities. Decker and Glicksman (1981) the
rugosity of a surface of a typical surface is of the order of 10-2 to 10-4 m, while the mean
free path of gas molecules is of the order of 10-4 m. For them it is the inherent rugosity of
the particles and wall which prevents a close contact and creates the thermal resistance.
They experimental study lead them to introduce a contact resistance Rc given by:
1/Rc = 12 g/dp
(6)
(7)
with:
(1-b) = Ub/(U-Umf+Ub)
(8)
Ub=0.71 (gDb)
(9)
(10)
If this time is much shorter than the residence time of the particles at the wall, the particle
renewal frequency (fb) plays a very important role. This is the case for very fine particles.
The residence time of particles is given approximately by the inverse of the local frequency
of the bubbles and hpc is written as:
hpc=~ hpc = {e.s.Cps.(1-mf)/(1-b)}
(11)
The mean frequency of bubbles fb for the volumetric fraction occupied by the bubbles can
be obtained with a method described by Grace (1982).
For the larger particles whose temperatures varies during the residence time at the wall
(t>>1/fb) hpc is given by Glicksman:
hpc = 11.2(1-b)g/dp
(12)
Other models such as those by Martin (1984) and Block (1983) use Schlunder's approach to
calculate hpc. These models are described in more detail later on.
Certain authors such as Botterill and Denloye (1978) suggest that the heat transfer
at minimum fluidization is a good approximation of the term hgc?. They propose the
following empirical correlation:
hgc.dp1/2/g = 0.86 Ar0.39 for 103 <Ar< 106
Note that this equation has dimension m-1/2.
(14)
(15)
The effective emissivity of the bed is higher than that of a single isolated particle
due to the multiple reflections. The results by Botterill 1975 suggest that:
Esusp = 0.5 (1+Ep)
(16)
For smaller particles the problem is more complex since these particles change
temperature during their exposure to the wall. The rate at which are renewed at the wall
becomes important.
The relative importance of the transfer by radiation increases with the size of the
particles and the temperature. A literature review on the contribution of radiation to the
transfer of heat wall/fluidized bed was recently published by Flamant and Bergeron (1988).
Flamant and Arnaud (1984) published a literature review of the contribution of the
coefficient of heat transfer by radiation to the total heat transfer coefficient.
(17)
(18)
(h.dp/f)/[(1-)Cps.s/Cpg.g]
{1+7.5exp[-0.44(L/D) Cps/Cps]}
(19)
(20)
Grace (1982) recommends the use of correlations established for vertical tubes, but
also suggests that a value of 80% of the result obtained from the correlation be retained, to
account for the fact that the transfer of heat is not as good at the wall to the bed.
(21)
hw maxi = Num f / dp
(22)
(23)
(24)
(25)
(26)
Conditioned to Y/d =2, where Y is the horizontal spacing of tubes dp for ambient
temperature between 360 and 710 C.
5)- Grewal & Saxena :
hmax.dp/f = 0.9 (.0127 Ar/d).21 [(Cps/Cpf)^(45.5*Ar-.7)]
for 300 < Ar < 1E+5
(27)
6)- Vreedenberg :
Vreedenberg proposed several correlations that have been adopted by other authors
(Bansai). We use here only the correlation obtained with a cracking catalyst (fine and light
particles), which complements well the correlations by Catipovic and that by Zabrodsky
(dp>1000 m).
The inconvenient of this relation is that it strongly depends on , which is difficult to
estimate (correlation to be avoided).
for horizontal tubes :
(28)
(29)
(30)
subject to dp=2300 m
8)- Catipovic & al. :
h.dp/f = 6(1-)+(.0175.Ar.46 Pr.33)(1-) + (dp/d)(.88*
Repmf .5+.0042 Repmf) Pr.33
where = .55-.66/[(U-Umf)+.125]
9)- Glicksman & Decker :
h.dp/f = (1-b)[9.42+.042(dp.U.f.Cpf/f)]
(31)
(32)
(33)
(34)
(35)
(36)
(37)
where wp is an average velocity of the random displacement of the particles between the
interior of the bed and the surface. The term between brackets represents a degree of
thermal accommodation of the particle during its contact with the heated or cooled wall.
And N is a non-dimensional contact time:
N=(6.hwp.tc)/[(s.Cps. wp).(4dp)]
(38)
The heat transfer coefficient between a plane wall and a single particle, hwp, is composed
of two components:
1/hwp = 1/hwp.max +1/hi
(39)
The first term, usually the dominant resistance term, is due to the conduction through the air
contained between the wall and the particle, and can be calculated by the Schlunder's
formula:
hpw.max = (4f/dp)[1+2l/dp)ln(1+dp/2l)-1]
(40)
The equations in the model contain two quantities that up until now haven't been
calculated directly, namely the contact time, tc, of the particle with the wall and the average
speed of random displacement of particles, wp. To eliminate this two unknowns two
additional assumptions have been introduced in the model:
tc= (
( f )( 1 )
). Z 0 . 8 . s
U U mf
s
dp
Z = (1/6) s.Cps/f
0 .4
(41)
g . d 3p . ( mf )
(42)
5 ( 1 mf ) ( 1 )
The average displacement velocity of particles ,wp, is linked to the "mean free
path" through:
l = 2(2/ -1) [ f.(2RT/Mm).5/(2.P.Cpf -R./Mm)
(43)
where =~ 0.9 (ideal gas), R gas constant, P pressure, T temperature, Mm gas molar mass
and 'f' its conductivity.
For air at 1 bar and 25 C, l is equal to 274 nm, this produces hwp(max) of 24 + 20% for
particles having sizes between 200 m and 2 mm. This result is in accordance with the
experimental results of Gloski, Decker and Glicksman (1984).
In the equation above l is calculated in an manner analogous to the that used in the gas
kinetic theory using the diameter and the concentration of the particles. Thus, the
concentration of particles (in numbers per unit of free volume) allows to relate the unknown
wp to the size of the particles and to the voidage in the bed. The model is finally written as:
hpc=(f/dp)(1-).Z.[1-exp(-Nuwp/C.Z)]
1
1
(f/s)
= +
Nuwp Numax
4 [1+(1.5 C.Z.f/ .s).5]
(44)
(45)
(46)
These equations give the term hpc as function of the properties of the particles, of
the gas properties, of the degree of voids in the bed ( which itself depends on the
(47)
Db is the size of the bubbles (see hydrodynamic chapter) and Ub is the rising speed of the
bubbles in the bed.
b =
b .dh / H
(48)
Martin's model seems to follows closely the variations of the heat transfer
coefficient with different operating parameters as long as the mobility of the particles is not
reduced by obstacles located in the bed (Martin 1984).
According to Martin the model can be used for vertical or horizontal tubes as well
as under pressure.
For a given solid changing the value of C we can improve the determination of h
obtained, for example, in a cold bed.
(49)
1
1
c
=
+
h pc 1 h max (1 mf ) 2
t
(..c p ) bed
(50)
(51)
The constant C takes into account the rugosity of the particles and of the surface.
Bock found that C was equal to 3 for all particles he tested.
If there is experimental data available to determine t and ?, we can calculate them
from the following correlations:
t = 62.2(U-Umf)-x Dh0.67 Hy dp0.54
(52)
(53)
with
(54)
where Db is the diameter of the column, d is the diameter of the tubes and n is the number
of tubes.
b = Z (U-Umf)
(55)
(56)
with
This model was established for vertical tubes, the hydraulic diameter has no meaning for
horizontal tubes.
5.14. Conclusion
The discussion above, showed that the methods presented here give an idea about the
values of heat transfer coefficient (tendencies), but the hydrodynamics of the bed are too
complex and dependent on the design of the bed to obtain precise results
There are numerous correlations in the literature that can be used in similar conditions.
However, its very important to choose a proper method corresponding the exact operating
conditions under which these correlations are obtained. Many of these papers describe well
the conditions under which they were obtained. Before applying a correlation it is necessary
to make sure that it was obtained under similar conditions (same particle diameter, same
pressure, same temperature level).
We advise the user to compare results from correlations to those obtained from Martins (or
Bocks) models. These last methods have the great advantage not to be far from reality.
5.15. Notation
Cp
CR
Cpg
Cps
Db
Dt
Dh
dp
specific heat
correction for a non-axial position
gas heat capacity
solid heat capacity
bubble diameter
fluid bed diameter
hydraulic diameter
particle meau diameter
d
Esus
Ep
Mm
g
h
hgc
hmax
hpc
tube diameter
suspension emissivity
wall emissivity
gas molar mass
gravitation constant
heat transfer coefficient
gas contribution to the heat transfer coefficient
maximum heat transfer coefficient for optimal velocity
heat transfer coefficient for conduction in a semiinfinite medium
heat transfer coefficient portion due to conduction in
the particles
heat transfer coefficient radiation contribution
heat transfer coefficient between a single particle
and a plane wall
mean free path of the particles
height of the fluidized bed
height of the tube above the grid
pressure
ideal gas constant
hpc
hr
hwp
l
L
H
P
R
T
t
tc
U
Ub
Umf
Uopt
Vp
wp
X
temperature
time
contact time
fluidization velocity
bubble rising velocity
minimum fluidization velocity
optimum fluidization velocity
particle velocity
random displacement velocity (Martin's model)
heat penetration
g
g
s
Solid conductivity
Gas viscosity
Gas density
Solid density
Subscripts:
b
bubble
f
fluid
mf
minimum of fluidization
p
particle
s
solid
5.16. References
1)- Andeen B.R., Glicksman L.R., ASME/AIChE Heat Transfert Conf., St. Louis, Aug.
n76-HT-67, 1976
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