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pH Control
in Sour Water Stripping
In petroleum refining, so called sour water (process water that contains dissolved hydrogen sulfide H2S) is produced in various processes. Due
to environmental legislation and the fact that H2S
is extremely toxic, refineries nowadays adhere to
strict sulfur management which involves removing
the H2S from the sour water through steam stripping.
Background
Sulfur compounds such as mercaptans and hydrogen sulfide
occur naturally in crude oil or are formed in certain process
steps. Water and steam are extensively used in petroleum refining, and sour water is formed in the presence of hydrogen
sulfide. The increased use of sour crudes obviously leads to an
increase in sour water formation. Apart from H2S, sour water
contains ammonia, phenols, HCN, CO2, acids, salts and many
other water soluble waste compounds. After stripping, the water may be used as process water, for example in the desalter,
or be treated as waste water.
Process
After the removal of solids and hydrocarbons, the sour water
is fed to the top of the stripper column. A reboiler provides heat
or steam to the bottom of the stripper, or steam is injected
directly. In a counter current flow the steam liberates the dissolved gases from the sour water. Subsequently, the overhead
gas flow is directed to the Sulfur Recovery Unit where elemental sulfur is produced through catalytic oxidation of H2S.
Unfortunately things are slightly more complicated than this
and the use of steam alone is not enough to remove all the
dissolved (sour) gases. Gas concentrations vary and both hydrogen sulfide and ammonia occur in different forms. Fur-
Stripper
Caustic
Process
ss water
w
reuse or
to treatment
atment
Reboiler
Application Note
Mettler-Toledo AG
Process Analytics
Im Hackacker 15
CH-8902 Urdorf
Switzerland
Transmitter M420
www.mt.com/pro
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