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4)
1. What is a solution?
A homogeneous system (may be solid, liquid, vapor or gas) that has more
than one component and the components are miscible.
2. Which two special "properties" will be explored in this chapter? What are they used
for in thermodynamics?
∂(nG)
µi ≡
∂ni P,T ,n j
T, P and µi
6. Specifically, what is a partial molar property? How is it defined? What does it tell
us?
∂ (nM )
Mi = A partial molar property tells us the
∂ n i P ,T , n j
dependence on composition of thermodynamic properties. We have seen
how properties depend on other properties, but how the properties
specifically depend on the number of moles of the species of interest in a
homogeneous mixture is described here by partial molar properties.
8. Explain the notational convention of the three kinds of properties used in solution
thermodynamics.
The solution property (the value that the solution has) has no special
notation such as H, U, S, G.
The pure species property Mi is the value of the species alone at the
pressure and temperature of the solution.
9. Draw and explain Figs. 11.1 (a) and (b). What do they tell us?
dM dM
M 1 = M + x2 and M 2 = M - x1
dx1 dx1
graphically, this is shown on Fig. 10.1. The heavy line is a plot of the
solution property, M, as a function of x1 on the x axis. Note that x2 = 1 - x1
and where x1 is 0 on the axis, the solution is pure component 2, and the
intercept of the plot is the value of M for the pure species at the
temperature and pressure of the solution. (T & P are obviously constant
on this plot). The left hand y-axis intercept is the pure species value for
species 2, M2, and the right hand
y-axis intercept is the
pure species value for species 1, or M1. M1
The tangent to the curve at x = x1, M1
dM M(x1)
is and the intercepts of the
dx1
tangent show the partial
properties of component 1, M 1
(right y-axis, where we have pure M2
component 1) and of component 2
M 2 (left y-axis, where we have pure M2
component 2).
0 x1 1
M1∞
Figure 10.2 shows how we can obtain
the infinite dilution values of the partial
properties from our plot of M vs. x1.
M1
This time two tangents are drawn at
∞
x1 = 0,showing us the value of M 1∞ M2
where it intersects the right y-axis,
and at x1 = 1, showing us the value
of M 2∞ where it intersects the left y-axis.
M2
These infinite dilution parameters
are particularly helpful in separation
problems, where we need to obtain
the removal of a particular component.
As the concentration gets lower and 0 x1 1
lower, we need to know how the component behaves in the solution where
it is "infinitely dilute."
The relationships are between the partial molar Gibbs energy change with
temperature at constant pressure and mole fractions of the other
components, which is the partial molar entropy, and the partial molar
Gibbs energy changy with pressure at constant temperature and other
mole fractions, which is the partial molar volume.