Professional Documents
Culture Documents
INDIA
Sec:
Dt: 28-
Max
Marks: 240
CHEMISTRY
Section
Sec I (Q.N : 1 7)
Sec II(Q.N : 8 11)
Sec III(Q.N : 12 16)
Sec IV(Q.N : 17 23)
Question Type
Questions with Single Correct
Choice
Questions with Multiple Correct
Choice
Questions with Comprehension Type
(2 Comprehensions 2 + 3 = 5Q)
Questions with Integer Answer Type
Total
+Ve
Mark
s
- Ve
Mark
s
No.of
Qs
Total
marks
-1
21
16
-1
15
7
23
28
80
+Ve
Mark
s
- Ve
Mark
s
No.of
Qs
Total
marks
-1
21
16
-1
15
28
23
80
PHYSICS
Section
Sec I(Q.N : 24 30)
Sec II(Q.N : 31 34)
Sec III(Q.N : 35 39)
Sec IV(Q.N : 40 46)
Question Type
Questions with Single Correct
Choice
Questions with Multiple Correct
Choice
Questions with Comprehension Type
(2 Comprehensions 2 + 3 = 5Q)
Questions with Integer Answer Type
Total
MATHEMATICS
Section
Sec I(Q.N : 47 53)
Sec II(Q.N : 54 57)
Sec III(Q.N : 58 62)
Sec IV(Q.N : 63 69)
Question Type
Questions with Single Correct
Choice
Questions with Multiple Correct
Choice
Questions with Comprehension Type
(2 Comprehensions 2 + 3 = 5Q)
Questions with Integer Answer Type
Total
Sr.IIT-Z(IZ)_P1_Advanced
+Ve
Mark
s
- Ve
Mark
s
No.of
Qs
Total
marks
-1
21
16
-1
15
28
23
80
Page 2
CHEMISTRY
SECTION-1
Section-I (Single Correct Answer Type, Total Marks: 21) contains 7 multiple choice questions. Each question has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct. For each question you will be awarded 3 marks if you
darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases,
minus one (-1) mark will be awarded.
1.
C is
Ph
A)
B)
Ph
Ph
C)
Sr.IIT-Z(IZ)_P1_Advanced
D)
Page 3
Ph3P = CH2
A (major)
2.
Major product (A) is
CH2
CH
A)
B)
HC CH3
C)
Sr.IIT-Z(IZ)_P1_Advanced
D)
Page 4
3.
4.
B NaBD
4
D2 O
B) R2C=NNH2
2 butanone
NaBD4
H 2O
C) RCH = NH
D) RCH = NNH2
NaBH4
D2O
C
A, B and C are :
A)
CH3
CH
OH
OH
B)
CH3
OD
CH2CH3 , CH3
D
OH
C)
CH3
C
D
Sr.IIT-Z(IZ)_P1_Advanced
OD
CH2CH3 , CH3
D
OH
CH2CH3 , CH3
CH2CH3
H
OD
CH2CH3 , CH3
CH2CH3
Page 5
D)
5.
A) 6
6.
B) 8
C) 10
D)12
dil . NaOH
A) 1
B) 2
Cannizzaro reaction is not given by
C) 3
D) 4
NO2
CH3
B) OHC
A) OHC
CHO
OH
C) OHC
Sr.IIT-Z(IZ)_P1_Advanced
D) OHC
Page 6
SECTION-2
SectionII(MultipleCorrectAnswersType,TotalMarks:16)contains4multiplechoicequestions.
Eachquestionhasfourchoices(A),(B),(C)and(D)outofwhichONEorMOREmaybecorrect.Foreach
questionyouwillbeawarded4marksifyoudarkenALLthebubble(s)correspondingtothecorrect
answer(s)ONLYandzeromarksotherwise.Therearenonegativemarksinthissection.
oo
A
8.
O3
Me2 S
A)
B)
C)
D)
Sr.IIT-Z(IZ)_P1_Advanced
Page 7
9)
10)
B) Aliphatic aldehyde
C) Ketones
D) -hydroxy ketones
Sr.IIT-Z(IZ)_P1_Advanced
Page 8
A) C6 H 5CHO
1) CH
B) C6 H 5CHO
( CH 3CO )2 O / CH 3COONa
2 ( COOC2 H 5 ) 2 , pyridine
2) H 3O ,
CH CHO / OH
C) C6 H 5CHO
3
H / Zn /
1) BrCH2) HCOOC
D) C6 H 5CHO
O / H /
2
2 5
SECTION-3
In
SectionIII(ParagraphType,TotalMarks:15)contains2paragraphs.Basedupononeofthe
paragraphs2multiplechoicequestionsandbasedontheotherparagraph3multiplechoice
questionshavetobeanswered.Eachofthesequestionshasfourchoices(A),(B),(C)and(D)out
ofwhichONLYONEiscorrect.Foreachquestionyouwillbeawarded3marksifyoudarken
ONLYthebubblecorrespondingtothecorrectanswerandzeromarksifnobubbleisdarkened.
allothercases,minusone(1)markwillbeawarded.
Paragraph-I:
The conversion of aldehyde having no alpha hydrogen to a mixture of carboxylic acid
and primary alcohol is known as Cannizzaro reaction. The most important feature of
this reaction is the conjugate base of hydrate of aldehyde.
Sr.IIT-Z(IZ)_P1_Advanced
Page 9
12.
13.
B) Step-II
C) Step-III
Sr.IIT-Z(IZ)_P1_Advanced
Page 10
A)
B)
C)
D)
Paragraph-II: 14 to 16
Sr.IIT-Z(IZ)_P1_Advanced
Page 11
A)
15)
C)
D)
B)
C)
D)
Structure of F is
A)
16)
B)
Sr.IIT-Z(IZ)_P1_Advanced
Page 12
A) Structure of E is identical to B
B) Structure of A is
C) G is
D) Structure of D is
SECTION-4
SectionIV(IntegerAnswerType,TotalMarks:28)contains7questions.Theanswertoeachofthe
questionsisasingledigitinteger,rangingfrom0to9.Thebubblecorrespondingtothecorrect
answeristobedarkenedintheORS.Foreachquestionyouwillbeawarded4marksifyoudarken
ONLYthebubblecorrespondingtothecorrectanswerandzeromarksotherwise.Thereareno
negativemarksinthissection.
17.
g)
h) CH 3COOH
18)
g)
i) CH 3COCH 2COCH 3
Sr.IIT-Z(IZ)_P1_Advanced
Page 13
d ) HCOOH
e) CH 3COCOCH 3
19)
20)
21)
22)
How many of the following are more reactive than acetaldehyde towards nucleophilic
addition?
FCH2CHO, O2N CH2CHO , CH3CH2CHO, CH3COCH3, PhCHO, PhCOCH3
Sr.IIT-Z(IZ)_P1_Advanced
Page 14
23)
Number of moles of RMgX consumed per molecule with the following reactant is.
COOH
OH
OHC
CH3
PHYSICS
SECTION-1
SectionI(SingleCorrectAnswerType,TotalMarks:21)contains7multiplechoicequestions.Each
Sr.IIT-Z(IZ)_P1_Advanced
Page 15
questionhasfourchoices(A),(B),(C)and(D)outofwhichONLYONEiscorrect.Foreachquestion
youwillbeawarded3marksifyoudarkenONLYthebubblecorrespondingtothecorrectanswerand
zeromarksifnobubbleisdarkened.Inallothercases,minusone(1)markwillbeawarded.
24. A potential difference V is applied across an X-ray tube. If e / m is the charge to mass
ratio of an electron and c the speed of light in vacuum, the ratio of the de Broglie
wavelength of the incident electrons to the shortest wavelength of X-rays produced is
given by
A)
25.
1
c
eV
2m
B)
1 eV
c m
C)
1 2eV
c m
D)
2 eV
c m
The magnitude of the magnetic moment of the electron in the nth the energy state of a
hydrogen atom is proportional to
A)
26.
1
n
B)
1
n
C) n
D) n2
If elements with principal quantum number n 4 were not allowed in nature, the
number of possible elements would be
A) 60
Sr.IIT-Z(IZ)_P1_Advanced
B) 32
C) 4
D) 64
Page 16
27.
Photoelectric effect experiments are performed using three different metal plates p,q
and r having work functions p 2.0eV .q 2.5eV and r 3.0eV , respectively. A light
beam containg wavelength of 550nm, 450 mm and 350 nm with equal intensities
illuminates each of the plates. The correct I-V graph for the experiment is
A)
28.
B)
C)
D)
Binding energy per nucleon versus mass number curve for nucle is shown in figure W,
X , Y and Z are four nuclei indicated on the curve. The process that would release
energy is
A) Y 2Z
Sr.IIT-Z(IZ)_P1_Advanced
B) W X Z
C) W 2Y
space for rough work
D) X Y Z
Page 17
29.
A radioactive element of mass number 208 at rest disintegrates by emitting an particle. If E is the energy of the emitted -particle, the energy of disintegration is
A)
30.
52
E
51
B)
51
E
52
C) 52E
D) E
A positron with kinetic energy 1 MeV and an electron with kinetic energy 1MeV meet
each other moving in opposite directions. They annihilate each other by emitting two
photons. If the rest mass energy of an electron is 0.51 MeV, the wavelength of each
photon is
0
A) 5.110 3 A
B) 10.2 10 3 A
C) 8.2 103 A
D) 6.2 103 A
SECTION-2
SectionII(MultipleCorrectAnswersType,TotalMarks:16)contains4multiplechoicequestions.
Eachquestionhasfourchoices(A),(B),(C)and(D)outofwhichONEorMOREmaybecorrect.For
eachquestionyouwillbeawarded4marksifyoudarkenALLthebubble(s)correspondingtothe
correctanswer(s)ONLYandzeromarksotherwise.Therearenonegativemarksinthissection.
31.
C) The stopping potential needed to stop the most energetic emitted photoelectrons as
hc
e
Sr.IIT-Z(IZ)_P1_Advanced
Page 18
32.
The intensity of X-rays from a Coolidge tube is plotted against wavelength as shown
in figure. the minimum wavelength found is c and the wavelength of K line is k . If
the accelerating voltage is increased
A) C Decreases
B) K increases
C) K c increases
D) C and K both decrease but K C remains unchanged
33.
For a certain radioactive substance, it is observed that after 4 hours, only 6.25% of the
original sample is left undecayed. It follows that
A) The half life of the sample is 1 hour
B) The mean life of the sample 1/(ln 2) hour
C) The decay constant of the sample is ( ln 2) hour-1
Sr.IIT-Z(IZ)_P1_Advanced
Page 19
D) After a further 4 hours, the amount of the substance left over would be only 0.39%
of the original amount
34.
SECTION-3
SectionIII(ParagraphType,TotalMarks:15)contains2paragraphs.Basedupononeofthe
paragraphs2multiplechoicequestionsandbasedontheotherparagraph3multiplechoice
questionshavetobeanswered.Eachofthesequestionshasfourchoices(A),(B),(C)and(D)out
ofwhichONLYONEiscorrect.Foreachquestionyouwillbeawarded3marksifyoudarken
ONLYthebubblecorrespondingtothecorrectanswerandzeromarksifnobubbleisdarkened.In
allothercases,minusone(1)markwillbeawarded.
Paragraph-I:
Hydrogen is the simplest atom of nature. There is one proton in its nucleus and an
electron moves around the nucleus in a circular orbit. According to Niels Bohr, this
electron moves in a stationary orbit, it emits no electromagnetic radiation. The angular
momentum of the electron is quantized, i.e., mvr = (nh / 2), where m = mass of the
electron, v = velocity of the electron in the orbit, r = radius of the orbit, and n = 1, 2,
3 when transition takes place from Kth orbit to Jth orbit, energy photon is emitted. If
the wavelength of the emitted photon is , we find that
1
1
1
R 2 2
K
J
, where R is
Rydbergs constant.
Sr.IIT-Z(IZ)_P1_Advanced
Page 20
+
ze
+ m
rn
On a different planet, the hydrogen atoms structure was somewhat different from
ours. There the angular momentum of electron was P = 2n(h / 2), i.e. an even
multiple of (h / 2).
Answer the following questions regarding the other planet based on above passage :
35.
36.
2 0 h 2
me 2
B)
4 0 h 2
me 2
C)
0 h 2
me2
D)
0 h 2
2me 2
In our world, the velocity of electron is v0 when the hydrogen atom is in the ground
state. The velocity of electron in this state on the other planet should be
A) v0
37.
B) v0 / 2
C) v0 / 4
D) v0 / 8
In our world, the ionization potential energy of a hydrogen atom is 13.6 eV. On the
other planet, this ionization potential energy will be
A) 13.6 eV
Sr.IIT-Z(IZ)_P1_Advanced
B) 3.4 eV
C) 1.5 eV
D) 0.85 eV
Page 21
PASSAGE-II
A radioactive elements decays by beta emission. A detector records n beta particles in
the first 2 seconds and 0.75 n beta particles in the next 2 seconds
38.
39.
B) ln
2 4
1
2
C) ln 2
3
4
D) ln 2
B) 6 s
C) 7 s
D) 8 s
SECTION-4
SectionIV(IntegerAnswerType,TotalMarks:28)contains7questions.Theanswertoeachofthe
questionsisasingledigitinteger,rangingfrom0to9.Thebubblecorrespondingtothecorrect
answeristobedarkenedintheORS.Foreachquestionyouwillbeawarded4marksifyoudarken
ONLYthebubblecorrespondingtothecorrectanswerandzeromarksotherwise.Thereareno
negativemarksinthissection.
40.
wavelength 975 A . How many different lines are possible in the resulting spectrum?
The ionization energy of hydrogen atom is 13.6 eV.
41.
Sr.IIT-Z(IZ)_P1_Advanced
Page 22
42.
V0 and r0 are constants and r is the radius of the electron orbit around the proton.
44.
Sr.IIT-Z(IZ)_P1_Advanced
Page 23
45.
versus t. Here
dN t
dt
dN t
is the rate of radioactive decay at time t. If the number of
dt
radioactive nuclei of this element decreases by a factor of p after 4.16 years, find the
value of p.
46.
The activity of a freshly prepared radioactive sample is 1010 disintegrations per second,
whose mean life is 109 s. the mass of an atom of this radioisotope is 1025 kg . The mass
(in mg) of the radioactive sample is
Sr.IIT-Z(IZ)_P1_Advanced
Page 24
MATHEMATICS
SECTION-1
SectionI(SingleCorrectAnswerType,TotalMarks:21)contains7multiplechoicequestions.Each
questionhasfourchoices(A),(B),(C)and(D)outofwhichONLYONEiscorrect.Foreachquestion
youwillbeawarded3marksifyoudarkenONLYthebubblecorrespondingtothecorrectanswerand
zeromarksifnobubbleisdarkened.Inallothercases,minusone(1)markwillbeawarded.
47.
n positive integers taken at random are multiplied together then the probability that
the last digit of the product is zero is__
A)
48.
10n 4n
10n
B)
10n 8n 5n
10n
C)
10n 5n 4n
10n
D)
10n 8n 5n 4n
10n
C) 0.28 x 0.52
D) 0.27 x 0.56
An urn contains 2 white 2 black balls. A ball is drawn at random and if it is white it is
not replaced into urn, otherwise it is replaced along with other ball of same colour. The
process is repeated, then the probability that the third ball drawn is black is
A)
42
60
Sr.IIT-Z(IZ)_P1_Advanced
B)
46
60
C)
48
60
D)
34
60
Page 25
50.
3
2
Consider f x x ax bx c . Parameters a,b,c are chosen respectively by throwing a
die three times, then the probability that f x is increasing function is____
A)
51.
5
36
B)
8
36
C)
4
9
D)
1
3
2
n
If three numbers are chosen randomly from the set 1,3,3 ,.......,3 without replacement
52.
A)
3
if n is odd
2n
B)
C)
3n
if n is even
n 1
D) 2 n 2 1 if n is odd
3n
Numbers are selected at random one at a time, from the number 00,01,02 99 with
replacement. An event E occurs if and only if the product of two digits of a selected
number is 18. If the four numbers are selected, then the probability that E occurs at
least 3 times
A)
53.
3
if n is even
2n
97
390625
B)
86
390625
C)
93
390625
D)
96
390625
Two persons A and B agree to meet at a place between 10 am to 11 am. The first one
to arrive waits for 10 minutes and then leave. If the time of the arrival be independent
and random, then is the probability that A and B meet is
A)
5
9
Sr.IIT-Z(IZ)_P1_Advanced
B)
11
36
C)
4
9
D)
1
3
Page 26
SECTION-2
SectionII(MultipleCorrectAnswersType,TotalMarks:16)contains4multiplechoicequestions.Each
questionhasfourchoices(A),(B),(C)and(D)outofwhichONEorMOREmaybecorrect.Foreach
questionyouwillbeawarded4marksifyoudarkenALLthebubble(s)correspondingtothecorrect
answer(s)ONLYandzeromarksotherwise.Therearenonegativemarksinthissection.
54.
55.
B) P A B 1/ 4
C) 3 / 8 P A B 5 / 8
D) 1/ 8 P A B 3/ 8
2r 1
2r
A) r1
n
nr
B) r1
2r
n
C)
Cr
2n
r 0
n
D)
r 0
2n
r 0
56.
Cr
2n
Cr
One of 10 keys open the door. If we try the keys one after the other then
A) Probability that the door opened in the first attempt is
1
10
1
10
Page 27
57.
A rifleman is firing at a distant target and has only 10% chance of hitting it(
log10 3 0.4771 ), then which of the following are correct?
A) The number of rounds required in order to have more then 50% chance to hit the
target atleast once is 7.
B) When two attempts are made, the probability that both are failures is
81
100
C) When two attempts are made, the probability of hitting the target at least once is
21
100
D) When two attempts are made, the probability to hit the target exactly one time is
18
100
Sr.IIT-Z(IZ)_P1_Advanced
Page 28
SECTION-3
SectionIII(ParagraphType,TotalMarks:15)contains2paragraphs.Basedupononeoftheparagraphs
2multiplechoicequestionsandbasedontheotherparagraph3multiplechoicequestionshavetobe
answered.Eachofthesequestionshasfourchoices(A),(B),(C)and(D)outofwhichONLYONEis
correct.Foreachquestionyouwillbeawarded3marksifyoudarkenONLYthebubblecorrespondingto
thecorrectanswerandzeromarksifnobubbleisdarkened.Inallothercases,minusone(1)markwill
beawarded.
Paragraph-I:
A circle of radius r touches the lines x 2 4 xy y 2 0 at A,B whose centre is C in
first quadrant (O is origin).
58.
If a point is selected in quadrilateral OACB, then the probability that the point is
from the smaller sector CAB is
A)
2 3
Sr.IIT-Z(IZ)_P1_Advanced
B)
C)
3 3
D)
3
Page 29
59.
A point is selected from the quadrilateral OACB and it is known that the point is
selected from the le OAC , then the probability that the point lies in le ABC is
A)
1
3
B)
1
4
C)
3
8
D)
2
3
PASSAGE-II
Each face of cubical die is marked with different letters of the word SINDHU. The die
is rolled 12 times and letters on the upper face of the die are noted.
60.
What is the probability of getting the letters to form the word SINDHU one time (Not
necessarily in order)?
A)
61.
362
3094
B)
461
6188
C)
231
3094
D)
361
6188
What is the probability of getting the letters to form the word SINDHU two times
(Not necessarily in order)?
A)
62.
1
3094
B)
1
6188
C)
1
1547
D)
2
1547
What is the probability of getting the letters, not to form the word SINDHU (Not
necessarily in order)?
Sr.IIT-Z(IZ)_P1_Advanced
Page 30
A)
2863
3094
B)
462
3094
C)
4613
6188
D)
3612
6188
SECTION-4
SectionIV(IntegerAnswerType,TotalMarks:28)contains7questions.Theanswertoeachofthe
questionsisasingledigitinteger,rangingfrom0to9.Thebubblecorrespondingtothecorrectansweris
tobedarkenedintheORS.Foreachquestionyouwillbeawarded4marksifyoudarkenONLYthe
bubblecorrespondingtothecorrectanswerandzeromarksotherwise.Therearenonegativemarksin
thissection.
63.
A bag contains n white and n black balls, pairs of balls are drawn without
replacement until the bag is empty. The probability that each pair contains one white,
one black is
64.
2
then n
5
A bag contains a white and b black balls. Two players A and B alternately draw a
ball from the bag replacing the ball each time after the draw till one of them draws a
Sr.IIT-Z(IZ)_P1_Advanced
Page 31
white ball and wins the game. If A begins the game then probability of A winning is
three times that of B then
65.
a
is__
b
A natural number x is chosen at random from first 100 natural numbers, then the
probability for the inequality x
66.
100
b
50 to be true is
then a b ___(H.C.F of a,b
x
a
is1)
If a 0, 2 then find the probability that the graph of function
f x 16 x 2 8 a 5 x 13a 23 is strictly above the x-axis is
67.
p
then pq
q
68.
Two number x, y are chosen at random from the numbers 1,2,3,4,5,6,7,8,9. Then the
probability that x3 y 3 is divisible by 3 is
69.
a
b
then =______
(H.C.F
of
a,b
is1)
b
a
64 players play in a knockout tournament. Assuming that all the players are of equal
strength, the probability that P1 loses to P2 and P2 becomes the eventual winner is
1
,
abc
Sr.IIT-Z(IZ)_P1_Advanced
Page 32