P1 QP

NARAYANA IIT ACADEMY
INDIA
Sec: Sr.IIT-IZ3-CO-SPARK
PTA-3
JEE-ADVANCE-2013-P1-Model
IMPORTANT INSTRUCTIONS
Time: 3:00
Dt: 02-11-14
Max Marks: 180
PHYSICS:
Section
Question Type
Sec I(Q.N : 1 10)
Questions with Single Correct Choice

Questions with Multiple Correct
Choice
Questions with Integer Answer Type
Sec II(Q.N : 11 15)

Sec III(Q.N : 16 20)
+Ve
Marks
- Ve
Marks
No.of
Qs
Total
marks
10
20
-1
20
-1
20
20
60
Total
CHEMISTRY:
Section
Question Type
Sec I(Q.N : 21 30)

Choice
Sec II(Q.N : 31 35)

+Ve
Marks
2
- Ve
Marks
0
No.of
Qs
10
Total
marks
20
-1
20
-1
20
20
60
Total
MATHEMATICS:
Section
Question Type
Sec I(Q.N : 41 50)

Choice
Sec II(Q.N : 51 55)

+Ve
Marks
2
- Ve
Marks
0
No.of
Qs
10
Total
marks
20
-1
20
-1
20
20
60
Total
PAPER SETTERS : HYD-DNM VEDAVYAS

MATHEMATICS: SANTHOSH G
(9396714888)
PHYSICS
:ADITYA SACHAN ((9885774968)
CHEMISTRY
: D SRINIVAS RAJU(9490231058)
02-11-14_Sr.IIT-IZ3-CO-SPARK_JEE-ADV_(2013_P1)_ PTA-3
Narayana IIT Academy
PHYSICS
Max Marks : 60
Section-1
(Only one Option correct Type)
This section contains 10 Multiple Choice questions. Each Question has Four choices (A),
(B), (C) and (D). Out of Which Only One is correct
1.
Three blocks are initially placed as shown in the figure. Block A has mass m and initial
velocity v to the right. Block B with mass m and block C with mass 4m are both initially at
rest. Neglect friction. All collision are elastic. The final velocity of block A is
A) 0.6v to the left

2
B) 1.4v to the left C) v to the left
D) 0.4v to the right
In the arrangements shown in figure masses of each ball 1 kg and mass of trolley is 4 kg. In
the figures shell of mass 1 kg moving horizontally with velocity v=6 m/sec collides with
the ball and get stuck to it then its maximum deflection of the thread (length 1.5 m) with
vertical is
A) 530
B) 370
C) 300
D) 600
A body of mass 1 kg starts moving from rest at t = 0, in a circular path of radius 8 m. Its
kinetic energy varies as a function of time as : KE = 2t 2 joules, where t is in seconds. Then:
A) tangential acceleration 4 m / s 2
B) power of all forces at t 2 sec is 8 watt
C) first round is completed in 2 sec
D) tangential force at t = 2 sec is 4 newton
Sr.IIT (IZ3)_P1_Advanced
space for rough work
Page 2
A ball is held at rest in position A by two light cords. The horizontal cords is now cut and
the ball swings to the position B. What is the ratio of the tension in the cord in position B to
that in position A ?
A)3/4
5
C)3
D)1
Figure shows the overhead view of a disk rotating counter clockwise. The angular speed
of the disk is decreasing. Which of the vector correctly represents total acceleration of a
point on the rim of the disk
A)1
6
B)1/2
B)2
C)3
D) 4
A sphere of mass M and radius R is rolling on a horizontal surface with a velocity v and
then climbs up on a smooth inclined plane up to a height h. The height up to which its
rises will be
A) directly proportional to the square of the velocity and inversely proportional to the
angle of the inclination
B)directly proportional to the velocity and inversely proportional to its mass
C) directly proportional to the square of the velocity and independent of mass and the
angle of the inclination
D) directly proportional to its velocity and inversely proportional to the angle of the
inclination
Page 3
A hemispherical shell of mass m and radius R is hinged at point O and placed on a

horizontal surface. A ball of mass m moving with a velocity u inclined at an angle
tan 1 1/ 2 strikes the shell at point A (as shown in the figure) and stops . What is the
minimum speed u given to the ball so that the hemispherical shell can reach the horizontal
surface OP?
A) Zero
C)
8
B)
gR
2 gR
3
D) It cannot come on the surface for any value of u
A straight uniform metal rod of length 3l is bent through angle as shown. The bent rod is
then placed on a rough horizontal table. A light string is attached to the vertex of the right
angle . The string is then pulled horizontally so that the rod translates at constant
velocity. Then the angle which the side 2l makes with string is
A) tan 1
1
2
B) tan 1
1
4
C) sin 1
1
2
D) sin 1
1
4
Page 4
A particle of mass is attached to a disc of equal mass m by means of a slack string as

shown. The disc is hinged about its centre C. on a horizontal smooth table. The particle is
projected with initial velocity v. The velocity of particle when the string becomes taut is
A) v
10
B) v / 3
C) 2v / 3
D)
3v
4
Two thin rods: each of mass m and length l are joined to form L shape as shown . The
moment of inertia of rods about an axis passing through free end (O) of a rod end and
perpendicular to both the end is
A)
2 2
ml
7
B)
ml 2
6
C)
5 2
ml
3
D) ml 2
Page 5
Section-2
(One or More options Correct Type)
This section contains 5 multiple choice questions. Each question has four choices (A) (B)(C) and (D)
out of which ONE or MORE are correct.
.
11. Which of the following graphs cannot represent one dimensional motion a particle ?
A)
B)
C)
12
D)
Two bodies are moving with constant speed v clockwise and are initially diagonally
opposite . The particle B now achieves a tangential acceleration of a m / s 2 . Then :
A)they collide after time
R
a
B) they collide after time
2 R
a
C) relative velocity just before collision is aR

D) relative velocity just before collision is
2 aR
Page 6
13
A disc is given an initial angular velocity 0 and placed on rough horizontal surface as
shown. The quantities which will not depend on the coefficient of friction is/are
A)The time until rolling begins

B)The displacement of the disc until rolling begins
C) The velocity when rolling begins
D) The work done by the force of friction
14
The angular acceleration of the toppling pole shown in figure is given by

k sin , where is the angle between the axis of the pole and the vertical , and k is a
constant. The pole starts from rest at 0 . Choose the correct options
A) The tangential acceleration of the upper end of the pole is lk sin

B)The centripetal acceleration of the upper end of the pole is 2kl 1 cos
C)The tangential acceleration of the upper end of the pole is 2kl 1 cos
D)The centripetal acceleration of the upper end of the pole is lk sin
Page 7
15
In the figure shown, the plank is being pulled to the right with a constant velocity v. If the
cylinder does not slip, then
A)the speed of the centre of mass of the cylinder is 2v

B)the speed of the centre of mass of the cylinder is zero
C)the angular velocity of the cylinder is v/R
D)The angular velocity of the cylinder is zero
Section-3
(Integer Value Correct Type)
This section contains 5 questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive).
16. A block of mass 2kg starts from rest with spring unstretched on a rough inclined plane.
1
8
Force constant of spring is K 8 N/m, coefficient of kinetic friction k . What is the

speed of the block (in m/s) when it slides a distance x 0.5 m down the incline plane ?
17
A small ball is projected from point p on floor towards a wall as shown in fig. It hits the
wall when its velocity is horizontal. Ball reaches point p after one bounce on the floor. If
the coefficient of restitution is the same for the two collisions, and its value is 1/x, then the
value of x is
Page 8
18
A thin uniform rod AB of mass m=1.0kg moves translationally with acceleration

a 2.0 m / s 2 due to two antiparallel forces F1 and F2 as shown in figure. The distance
between the points at which these forces are applied is equal to y=20cm. Besides, it is
known that F2 5.0 N . Find the length of the rod (in m)
19
A uniform rod of mass m=5.0 kg length L=90cm rests on a smooth horizontal surface.
One of the ends of the rod is struck with the impulse J=3.0N.s in a horizontal direction
perpendicular to the rod. Find the force (in Newton) with which one half of the rod will act
on the other half during the process of motion
20
A roller of diameter 6cm rides between two horizontal bars moving in opposite direction
as shown in figure. Find the distance y (in cm) of the instantaneous centre of rotation of
the roller (Assuming,there is no slipping at any contact )
Page 9
CHEMISTRY
Max Marks : 60
Section-1
This section contains 10 Multiple Choice questions. Each Question has Four choices (A), (B), (C) and
(D). Out of Which Only One is correct
21. The major product formed in the following reaction is

dil.NaOH
CH3 CO CH 2 3 CHO
Major product
O
O
CHO
(A)
(B)
(C)
CHO
(D)
CHO
OH
22.
X ; X is
CH2
(A)
(B)
(C)
(D)
23.
Which of the following is correct comparison of rate of haloform reaction with various
halogens?
(A) rCl rBr rI
2
(B) rI rBr rCl

2
(C) rBr rCl rI

2
(D) rCl rBr rI

2
Page 10
24. Which of the following compound(s) can undergo predominantly Cannizaro reaction?
H3C N CH3
CH3 O
CH3 O
I.
II. CH3
O
CH C H
IV. H3C
III.
C H
CH3
CHO
CHO
A) only I, IV
25.
B) only I, II, IV
C) I, II, III and IV
D) only I, III, IV
The amines shown are isomers. Choose the one with the lowest boiling point
A)
B)
C)
D)
26. Which of the following Carboxylic acid donot undergo decarboxylation on heating?
O
A)
B)
COOH
COOH
27.
C)
O
COOH
D)
HOOC
CH 2-COOH
Which one of the following compounds is less acidic than benzoic acid?
COOH
COOH
O
A)
HO
28.
B)
C)
HO
OH
D)
OH
OMe
NO 2
Which is correct about the three C-N bond lengths marked as a, b and c in the
following molecules.
H 3C
NH2
CH3
NH2
b
NO2
CH3
A) a = b > c
c
C N
NO2
NO2
B) a > b > c
NO2
NO2
NO2
C) b > a > c
D) a = b = c
Page 11
29.
Increasing order of the reactivity of the following compounds towards the nitration will
be
O
O
O
O
(I)
30.
(II)
(IV)
(III)
A) I > IV > III > II B) IV > I > III > II C) III > IV > I > II D) IV > I > II > III
Reason for retention of configuration in the following reaction is
OTs
O
- +
NK
Ph
+
O
HN
Ph
O
HN
(A) OTs is an excellent leaving group.

(B) Neighboring group participation by NH group.
(C) Neighboring group participation by Ph group.
(D) The reaction involves SNi mechanism.
Page 12
Section-2
31.
Which of the following statement is correct regarding above reaction
A)The reaction mechanism involves initial formation of alkyl chlorosulfite
from C6 H 5 N HCl
B)
can bring SNi displacement of very good leaving group ClSO2
C) overall 100% retention takes place during the reaction

D) overall 50% retention and 50% Inversion takes place during the reaction.
32.
Which among the following compounds is/are not formed as the main product in the
given reaction?
H
A)
B)
Ph
C)
D)
Ph
33.
Which of the following will produce aromatic compound as product?

Al O
Re d hot Fe tube
(A) CH3 C CH
2 3
(B) nC6 H14
...
o
Cr2O3 /600 C
+ CHCl
...
3
(C)
N
CHO
NH2
tBuO
(D)
NH2
......
CHO
Page 13
34.
CH3
KMnO4
Phenol
A
CH3
B (Product)
H+
Which of the following is correct regarding product B

A) B is colourless in acidic medium
B) B is pink colour in basic medium
C) B has Benzenoid form in Basic medium
D) B exists in Ionic form in Basic medium
35 .
CH2
H3CO
CH2
NO2
One mole
of HI
Product
Products are
A)
H3CO
CH2I
O2N
CH2I
O2N
CH2OH
B)
C)
H3CO
CH2OH
D)
Page 14
Section-3
36.
An alkyne gives ethanoic acid as the only product on ozonolysis. The total number of
cyclic isomers of that alkyne is
37.
The number of esters formed in the following reaction is

O
HO
OH
+
Con.H2SO4
H3 C
H
38.
The number of compounds which give white precipitate of AgCl with aqueous AgNO3 is
Cl
Cl
Cl
Cl
CH3
Cl
Cl
Cl
H3C
39.
Cl
CH 3 CH CH O CH 2 CH 3
X Y (positive haloform test)
dil acid
The number of possible isomers for X excluding stereo isomers and including X.
40.
During the conversion of Glycerol into Allyliodide number of moles of HI molecules

consumed is.
Page 15
MATHEMATICS
Max Marks : 60
Section-1
This section contains 10 Multiple Choice questions. Each Question has Four choices (A), (B), (C) and
(D). Out of Which Only One is correct
41. Consider the point A(0,1) and B(2,0) and P be a point on the line 4 x 3 y 9 0.
Coordinates of P such that PA PB is maximum, are
12 17
A) ,
84 13
B) ,
6 17
C) ,
5 5
D)(0,-3)
42
Let ax by c 0 be a variable straight line, where a, b and c are 1st, 3rd and 7th terms of an
increasing A.P. Then the variable straight line always passes through a fixed point which
lies on_______([ ] and { } are step and fractional functions respectively)
A) | x | | y | 5
B)[x]+[y]=1
C){x}+{y}=1
D) | xy | 5
43
If (sin , cos ), 0, 2 and (1,4) lie on the same side or on the line 3 x y 1 0, then the
maximum value of sin will be
A)1
44
B)0
C)
1
2
D) 1
3
2
The value of for which the points , 2 is an interior point of the smaller segment of
the circle x 2 y 2 4 0 made by the chord whose equation is 3x 4 y 8 0 is
20
A) ,
45
B) 2, 0
20
C) ,
2, 0
D) No value of
Let P be any moving points on the circle x 2 y 2 2 x 1 . AB be the chord of contact of this
point with respect to the circle x 2 y 2 2 x 0 . The locus of the circumcentre of the triangle
CAB,(C centre of the circles ) is
A) 2 x 2 2 y 2 4 x 1 0
B) x 2 y 2 4 x 1 0
C) x 2 y 2 4 x 2 0
D) 2 x 2 2 y 2 4 x 3 0
Page 16
46
Let f x, y 0 be the equation of a circle. If f 0, y 0 has equal roots y 3,3 and f(x,0)
1
has roots x 1, , then centre of the circle is:
2
3
4
A) , 3
3
B) , 3
2
3
C) ,3
4
D)Circle is not possible
inconsistent
47
If positive number a 1 , b1 , c 1 are in A.P., then product of roots of equation

x 2 kx 2b101 a101 c101 0 k R
A) has +ve sign

48
49
50
If
B)has ve sign
C)equal to zero
D)no definite sign
a a
a2 a3 a2 a3
3 2 3 then a1 , a2 , a3 , a4 are in
a1a4 a1 a4
a1 a4
A) A.P
B) G.P
C)H.P
D) A.G.P`
Locus of points in the argand plane, which have constant real part is of the form ( and
are real numbers) 0 )
A) ( z z )i 0 B) ( z z ) 0 C) ( z z )i 0 D) ( z z ) 0
x
and y sin cos , where [.] denotes

2
10
10
the greatest integer function, is given by n I
The point of intersection of the curves y sin
A) (4n 1,1)
B) (4n 1, 1)
C) (4 n 1,1)
D) (2n, 0)
Page 17
Section-2
51.
If
2iz1 z1 z2
cos i sin
and z1 , z2 , z3 are non zero complex numbers, then

2iz1 z1 z2
cos i sin
A)
52
z1 z2
z
z z
is purely real B) 1 is purely real C) 1 2 is purely real
z1
z2
z1 z2
The points k , 2 2k k 1, 2 k and 4 k , 6 2k are collinear for

A) All values of k B) k=-1
C)k=1/2
D) none of these
D) no value of k
53
If the lines x 2a m, y 1 and y mx 2 are concurrent, then the value of a can lie any
where interval
A) a 1
B) a 1
C) 1 a 1
D) a 0
54
The equation of straight line(s) passing through ordered pairs (a, b) satisfying equation
sec2 ( a 2)b a 2 1 0, b
1
And having slope is
2
A) x 2 y 0
B) x 2 y 1
55
C) x 2 y
D) x 2 y 0
The value of in [0, 2 ] so that x 2 y 2 2 sin x (cos 1) 0 having intercept on xaxis always greater than 2 is/are

A) ,
4 2
B) ,
4
5
C) ,
4
D) 0,
Page 18
Section-3
56. If the circle passing through the distinct points (1,t),(t,1) and (t,t) for all values of t R also
passes through fixed point (a, b) then a 2 b 2 is equal to
57
If the ratio of the area of equilateral triangles made of the common chord of the circle
x 2 y 2 4 and x 2 y 2 8 x 4 0 and their respective pairs of tangents drawn from points
on the positive x-axis is 57 24 3 : k then k is________
58
The number of integral value of a for which the point (a 1, a 1) lies in the larger
segment of the circle x 2 y 2 x y 6 0 cut by the chord whose equation is x y 2 0
is equal to
59
If n N , the (n 3) (1)r
n
r 0
60
cr
is equal to
cr
r 3
The number of pairs ( x, y ) satisfying the equation sin x sin y sin( x y) and x y 1 is
equal to
Page 19

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NARAYANA IIT ACADEMY

Sec I(Q.N : 1 10)

Questions with Single Correct Choice

Sec II(Q.N : 11 15)

Sec I(Q.N : 21 30)

Questions with Single Correct Choice

Sec II(Q.N : 31 35)

Sec I(Q.N : 41 50)

Questions with Single Correct Choice

Sec II(Q.N : 51 55)

PAPER SETTERS : HYD-DNM VEDAVYAS

Narayana IIT Academy

A) 0.6v to the left

B) 1.4v to the left C) v to the left

D) 0.4v to the right

B) power of all forces at t 2 sec is 8 watt

C) first round is completed in 2 sec

D) tangential force at t = 2 sec is 4 newton

space for rough work

Narayana IIT Academy

space for rough work

Narayana IIT Academy

A hemispherical shell of mass m and radius R is hinged at point O and placed on a

D) It cannot come on the surface for any value of u

space for rough work

Narayana IIT Academy

A particle of mass is attached to a disc of equal mass m by means of a slack string as

space for rough work

Narayana IIT Academy

A)they collide after time

B) they collide after time

C) relative velocity just before collision is aR

space for rough work

Narayana IIT Academy

A)The time until rolling begins

The angular acceleration of the toppling pole shown in figure is given by

A) The tangential acceleration of the upper end of the pole is lk sin

space for rough work

Narayana IIT Academy

A)the speed of the centre of mass of the cylinder is 2v

Force constant of spring is K 8 N/m, coefficient of kinetic friction k . What is the

space for rough work

Narayana IIT Academy

A thin uniform rod AB of mass m=1.0kg moves translationally with acceleration

space for rough work

Narayana IIT Academy

21. The major product formed in the following reaction is

(B) rI rBr rCl

(C) rBr rCl rI

space for rough work

(D) rCl rBr rI

Narayana IIT Academy

C) I, II, III and IV

Narayana IIT Academy

(A) OTs is an excellent leaving group.

space for rough work

Narayana IIT Academy

can bring SNi displacement of very good leaving group ClSO2

C) overall 100% retention takes place during the reaction

Which of the following will produce aromatic compound as product?

space for rough work

Narayana IIT Academy