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q=mc T
where q is the quantity of heat, m is the
mass of substance, c is the specific heat and
qsystem =
~*~*~*~*~*~*~
I.
Thermochemistry
Calorimetry
ENDOTHERMIC
Heat is ABSORBED
EXOTHERMIC
Heat is RELEASED
H
-
w = -P
Types of systems:
Closed System
Open System
Isolated
System
U = q
1 atm L = 101.325 J
**Ideal gas equation can be helpful in getting
the volume
PV=nRT
1 cal = 4.184 J
U=q+w
+q
- q
+w
-w
II.
H of the
individual steps.
MAKE SURE THE EQUATIONS ARE
BALANCED!!!!!!
Spontaneous Changes: Entropy
and Gibbs Free Energy
that
magulo,
mas
mataas
ang
S=
H
T
87
H vap
kJ
=
mol T boiling pt .
G= HT S
<0
>0
=0
H
-
S
+
G
-
Result
Spontaneous at all
temperatures
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Spontaneous at low
temperature
Nonspontaneus at high
temp
Spontaneous at high temp
Nonspontaneous at low
temp
nonspontaneous at all temp
+
+
Rate = k[A]m[B]n
(coeffecients
exponents)
k is the rate constant, and the larger its
value, the faster a reaction goes.
If exponent is 1, reaction is first order. If 2,
second order... and so on
-Zero order: there is no effect on the initial
rate of the reaction
G= G RT ln Q
G =RT ln K
ln
K 2 H 1 1
=
K 1 8.314 ( R ) T 2 T 1
G and one
negative
G,
to
obtain
Zero-order Reactions
A
products
Rate of reaction
Given the reaction: aA + bB
[A]t = -kt +
[A]o
First-Order Reactions
gG + hH
ln [A]t = -kt + ln
[A]o
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Second-Order Reactions
HALF 1/[A]
LIFE!!!t
= kt + 1/[A]o
Zero-order
t1/2 =
[ A ]o
2k
t1/2 =
0.693
k
First Order
Second-order
t1/2 =
1
k [ A ]o
ln k =
Ea
RT
ln
K2
K1
Ea 1
1
R T1 T2
1)
2)
3)
4)
Elementary Process
Steady State approximation
Pseudo-order reactions
Application: smog and kinetics of
environments
Catalysis
1) Homogenous Catalysis all species
in the reaction are in solution
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IV.
cC + dD
k 1 [C ]c [ D]d
=
=K eq
k 2 [ A ]a [B] b
G =RT ln K
V.
Autoionization of Water
H 2O
(l)
+ H 2O
(l)
RT
K p=K c
K w =K a K b
pH of salt solutions:
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m+ n
VII.
K sp
mm n n
theory outermost
nagpaparticipate sa
Werners
Theory
of
coordination
compounds- metal ions have two types of
valency-primary and secondary, where the
primary valency is said to be satisfied by
negative ions only, and the secondary
valency can be satisfied by positive ligand,
negative or neutral molecule.
VI.
Isomerism
yung
Structural Isomers
(atoms are
connected
differently)
Ionization
Isomers (give
different ions
in solutions)
Coordination
(different
ligand sets in
anions and
cations)
Linkage
(same ligand
connected by
different
atoms)
Stereoisomers
(same number
and types of
ligands; differ in
the postion in
space)
geometric
(diastereomers)
(different
arrangement
around a metal
ion cis/trans)
optical
(enantiomers)
(nonsuperimpo
sable mirror
images)
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strong field.
VIII.
To classify the ligands, the spectrochemical
series is used:
Terms:
Anode- electrode where oxidation occurs
Cathode- electrode where reduction occurs
Cell diagram:
G =nF E cell
F= 96 485 C/mol eNernst Equation:
Ecell =E cell
0.0592
logQ
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n
of
LEORA Loss
Reducing Agent
of
Electrons
Electrons
Or RED CAT , AN OX
Reduction
Oxidation
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