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Abstract
This paper describes the development of a new chromefree, high-temperature, high-pressure (HTHP) stable waterbased fluid system. The new fluid uses a combination of clay
and unique chrome-free additives that provide exceptional
fluid-loss control and rheological stability to temperatures
exceeding 400F (204C), and at densities exceeding 18
lb/gal. The paper presents the results of extensive development
testing demonstrating the flexibility of the new fluid and its
tolerance to drill solids contamination. Results from some
initial field testing of the fluid system are also presented.
Industry economics, coupled with stricter environmental
regulations, have provided the impetus for the increased use of
water-based drilling fluids with the capacity to operate
similarly to invert emulsion drilling fluids in HTHP
conditions. Chrome-containing materials were, and in many
places still are, commonly part of these high-temperature
water-based fluids, acting as efficient, stable dispersants and
fluid-loss control agents. The tightening of environmental
discharge regulations has placed restrictions on the use of
chrome-based products in water-based fluids and as such,
alternative, chrome-free, HTHP drilling fluids are required
that will demonstrate an equivalent or improved performance
to the current chrome-containing high-temperature, highdensity water-based fluid systems. Under high temperature
conditions, the thermal degradation of polymers that control
fluid loss and rheological properties create major challenges
for fluid performance and stability. Additionally, the gelation
of water-based fluids containing clays and/or drill solids can
become difficult to control under high temperature conditions.
Both of these issues are compounded when the high
temperature is coupled with a requirement for high fluid
density.
Introduction
Environmental and economical considerations have led to
increasing use of water-based drilling fluids (WBM) in
applications where oil-based drilling fluids (OBM) have
previously been preferred, including high-temperature, highpressure (HTHP) wells. In an increasing number of areas in
the world environmental regulations prohibit the discharge of
oil-based mud and cuttings containing OBM. These HTHP
wells, can be defined as those with a bottomhole temperature
between 300 and 500F and an expected shut-in pressure
from 10,000 to 25,000 psi. Conn et al. (2004). Dispersed
AADE-10-DF-HO-37
AADE-10-DF-HO-37
AADE-10-DF-HO-37
Base
Fluid 1
Fluid 2
Fluid 3
Fluid 4
Fluid 5
Fluid 6
238
8
2
1
3
15
238
8
2
1
3
5
238
8
2
1
3
5
238
8
2
1
3
5
238
8
2
1
3
5
238
8
2
1
3
5
238
8
2
1
3
5
15
15
15
15
15
6
18.4
296
2
6
18.4
296
2
6
18.4
296
2
6
18.4
296
2
6
18.4
296
2
6
18.4
296
2
15
6
18.4
296
2
AADE-10-DF-HO-37
Base
600-rpm reading
300-rpm reading
200-rpm reading
100-rpm reading
6-rpm reading
3-rpm reading
PV (cP)
2
YP (lb/100 ft )
2
10-sec Gel(lb/100 ft )
2
10-min Gel (lb/100 ft )
API Fluid Loss (mL/30 min.)
51
30
23
15
7
6
21
9
10
28
4.5
Fluid 1
54
39
33
27
20
18
15
24
26
45
21
Fluid 2
Fluid 3
Fluid 4
90
69
60
48
35
34
21
48
45
97
7.5
55
38
32
24
14
13
17
21
20
36
10.5
66
44
37
28
16
15
22
22
27
59
14.5
Fluid 5
43
24
19
12
4
3
19
5
5
25
8
Fluid 6
69
57
54
48
56
53
12
45
61
72
8.5
*Fluid properties after aging at 482F(250C) for 16 hours. Rheological properties recorded at 150F(66C).
Base
Water
Sepiolite
Caustic Soda
AMPS copolymer
Acrylate copolymer
Low-molecular-weight anionic polymer
Chrome-lignite dispersant
Mixed metal lignosulfonate
Divalent metal lignosulfonate
Resinated lignite complex
Polyglycol/gilsonite blend
Barite
Synthetic seawater
Oxygen Scavenger
238
8
2
1
3
15
6
18.4
296
2
Base a
238
8
2
1
3
15
6
18.4
456
2
Base b
238
8
2
1
3
15
6
18.4
296
41
2
Fluid 3
Fluid 3a
Fluid 3b
238
8
2
1
3
5
238
8
2
1
3
5
238
8
2
1
3
5
15
15
15
6
18.4
296
2
6
18.4
456
2
6
18.4
296
41
2
Fluid 5
Fluid 5a
Fluid 5b
238
8
2
1
3
5
238
8
2
1
3
5
238
8
2
1
3
5
15
6
18.4
296
2
15
6
18.4
456
2
15
6
18.4
296
41
2
Base
76
46
36
24
9
8
30
16
15
43
4.9
19.8
Base a
107
71
61
43
18
16
36
1635
35
80
5.6
27.2
Base b
Fluid 3
55
35
27
19
9
8
20
15
15
29
7.9
32.4
108
75
65
51
31
29
33
42
35
48
9.5
-
Fluid 3a
182
138
112
90
65
64
44
94
67
107
12
-
*Fluid properties after aging at 482F (250C) for 16 hours. Rheological properties recorded at 150F (66C).
Fluid 3b
Fluid 5
Fluid 5a
Fluid 5b
80
58
49
40
25
24
22
36
30
47
13.5
-
51
30
20
15
8
6
21
9
13
42
5
20
67
49
38
32
21
20
18
31
37
65
4
25.2
40
24
18
12
7
5
16
8
5
12
7.5
31
AADE-10-DF-HO-37
16.7 lb/gal
19.2 lb/gal
222
0.25
2
3
2
10
2
15
3
2
443
189
0.25
2
3
2
10
2
15
3
2
581
Units
T (F)
2
lb/100 ft
""
""
""
""
""
cP
2
lb/100 ft
""
""
mL/30 min
120
300
16.7 lb/gal
60
33
24
15
4
3
27
6
4
14
17.8
19.2 lb/gal
94
58
46
33
18
18
36
22
18
32
12.0
AADE-10-DF-HO-37
Figure 2 Rheological profile from field data for formulation used in Hungary.
Figure 3 - MBT and Fluid Loss data from field data for formulation used in Hungary.