15-8-2015, Junior IIT Answers.

IIT-JEE Mains Model Paper (Juniors)
Answer & Solutions :

M, P, C Key Sheet
1.
11.
21.
31.
41.
51.
61.
71.
81.
c
c
d
c
b
d
d
d
c
2.
12.
22.
32.
42.
52.
62.
72.
82.
c
a
c
c
b
a
b
d
a
3.
13.
23.
33.
43.
53.
63.
73.
83.
c
b
c
c
d
b
c
d
a
4.
14.
24.
34.
44.
54.
64.
74.
84.
b
b
d
b
c
b
b
c
c
5.
15.
25.
35.
45.
55.
65.
75.
85.
b
c
d
d
c
c
a
d
d
6.
16.
26.
36.
46.
56.
66.
76.
86.
a
c
b
c
d
b
c
b
b
7.
17.
27.
37.
47.
57.
67.
77.
87.
d
c
a
c
c
d
d
b
b
Date : 15/08/2015
8.
18.
28.
38.
48.
58.
68.
78.
88.
d
b
b
a
d
a
c
a
c
9.
19.
29.
39.
49.
59.
69.
79.
89.
d
b
d
b
c
d
b
a
b
10.
20.
30.
40.
50.
60.
70.
80.
90.
d
b
d
b
c
b
d
c
c
Maths .
1.
2.
3.
Ans. (c).
Ans. (c).
Ans. (c).
If A x1 , y1 , B x2 , y2 , C x3 , y3 be the vertices of the triangle and if (0, 1), (1, 1) and (1, 0) are the
middle points of AB, BC and CA respectively, then
x1 x2 0, x2 x3 2, x3 x1 2
y1 y2 2, y2 y3 2, y3 y1 0 , So A 0, 0 , B 0, 2 and C 2, 0 are the vertices of the ABC .
Now a BC 2 2, b CA 2, c AB 2 .
The coordinates , of the in-centre are given by
ax1 bx2 cx3

2 2 ,
abc
ay by2 cy3
1
2 2
abc
i.e., the in-centre is 2 2, 2 2 .

4.
Ans. (b).
O 0, 0 is the orthocenter. B is found to be 1, 1 , OB ax by 1 0 .
a
1 1 a b
b
(1)
Equation of line through A is ax by 1 2 x 3 y 1 0

It is to BC .
# 2-1-520 to 526 Vijaya Sri Sai Celestia II
nd
Floor, Above Bajaj Electronics Nallakunta, Hyderabad 500 044 m : +91 98660 60123
2x
+3
y1=
0
0
1=
y+b
ax
x+2y-1 = 0
B(- 1, 1)
a 2 1
1
b 3 2
a 2 2b 6
Also OA passes through origin.
1 0 1 .
a 2 2b 6 a 2b 8
Solving (1) and (2), we get b 8, a 8
5.
6.
7.
(2)
Ans. (b).
Ans. (a).
Ans. (d).
From figure., it is clear that there are six natural points.
C
(0, 5)
4
2x+y=2
x+y=5
D 2
1
O
8.
(2, 0) (3, 0) (4, 0)
A (1, 0)
Ans. (d).
Slope of line x sec y cos ec a
is sec / cos ec sin / cos
Slope of line to this line cos / sin
Equation of required line is
y a sin 3 cos / sin x cos3

or
x cos y sin a cos 4 sin 4

a cos 2 sin 2 cos 2 sin 2
or
9.
x cos y sin a cos 2
Ans. (d).
Let A 2a , 0 and B 0, a be the ends of the base of isosceles ABC .
Y
C (2a, k)
If the equation of side say AC is x 2 a , then the coordinates of vertex C can be taken as 2a, k .
nd
2
2
CA CB k 2 a 0 k a
0 5a 2 2 ak k 5a / 2
Coordinates of C are 2a , 5a / 2 .
Equation of side BC is
ya
5a / 2 a
x 0
2a 0
3x 4 y 4a 0 .
or
10.
Ans. (d).
Equation of CD is y 8 3 x 3
3x y 17
Equation of EF is
i.e.,
D
. (1)
C
(3, 8)
E
(2, -1)
A (1, 2)
B(3, - 4)
y 1 1/ 3 x 2 x 3 y 5
. (2)
28 1
,
5 5
Solving (1) & (2), mid-point of CD i.e., F is

11.
Ans. (c).
Let L a 2 x aby 1 0 .
L 0, 0 1 0, L 1, 1 a 2 ab 1 .
(0, 0) and (1, 1) lie on the same side of the line L 0 .
12.
a 2 ab 1 0 a R ,
b2 4 0
i.e., 2 b 2
Since b 0 , we have 0 b 2 .
Ans. (a).
Let A x1 , y1 , B x2 , y2 , C x3 , y3 be the points of intersections of the line y 3 x with the curve.
x 3 3 3x 3 3 3x 2 5x 2 9 x 2 4 x 5 3x 1 0
1 3 3 x 14 3 3 x 4 5 3 x 1 0
3
(1)
OA.OB.OC
4 x 4 x 4 x
x12 y12
2
1
8 x1 x2 x3
x22 y22
2
2
x32 y32
2
3
8
4
3 3 1
1 3 3 13
nd
13.
Ans. (b).
x
y
r
cos sin
For A , let OA r1 , then A r1 cos , r1 sin lies on
x r cos , y r sin .
Let equation of the line OAB be
L0
P
B
A
O
L1 y x 10
OA
Similarly, OB
1 sin cos
r2
20
2
2 1 1

OP r r1 r2
2 sin cos sin cos
r
10
20
40 3r sin 3r cos 3 y 3x
Locus of P is 3x 3 y 40 0
14.
15.
1 sin cos
r1
10
P h, k r cos , r sin .
Let
Then
L2 y x 20
Ans. (b).
Ans. (c).
image
y = -x
(1, 0)
x>0
image : y =-(x-2)
image
(1, 0) (2, 0)
image : y =x-2
(2, 0)
equation of the image is y x 2 .
16.
y=x
Ans. (c).
Locus of P consist of lines x 1 3, y 2 3
y
A
Q(1, 2)
x
O
C
nd
x 4, x 2, y 5, y 1 .
i.e.,
17.
18.
Which form a square.

Ans. (c).
Ans. (b).
The equation of straight line through (0, 0) is
y mx
(1)
The given lines are 2x y 2
(2)
2y x 2
and
. (3
Solving (1) and (2), (1) and (3), we get A 2 / m 2 , 2 m / m 2

and B 2 / 2m 1 , 2m / 2m 1
If P h, k is the middle point of AB , then
3m 1
1 2
2
h
2 m 2 2m 1 m 2 2 m 1
and k
m 3m 1
1 2m
2m
2 m 2 2m 1 m 2 2m 1
. (4)
. (5)
Now to find the locus of P h, k we have to eliminate m between (4) and (5). We thus divide (5) by (4) to get
m k /h
Substituting m k / h in (4), we have
k
2k 3k
h 2
1
1
h
h
h
or
2h2 3hk 2k 2 h 3k 0
Hence the locus of midpoint P h, k is 2 x 2 3 xy 2 y 2 x 3 y 0

19.
20.
21.
Ans. (b).
Ans. (b).
Ans. (d).
x4
x y 5
E
C 4,
1, 2
D
B h, k
E 5 / 2,
E lies on x y 5 .
5 2
5 3
2
2
C is (4, 3).
h 1 k 2
,
2
2
Let B be h, k . Then D is
D lies on x 4 .
Also, B h, k lies on x y 5
7 k 5 k 2 .
nd
B is 7, 2 .
22.
23.
24.
Ans. (c).
Ans. (c).
Ans. (d).
3
(1, 1)
2
C
(2, 4)
8 14
C ,
5 5
8 14
5 5
Line 2x y k passes through C ,
2 8 14
k
5
5
k 6
25.
26.
Ans. (d).
Ans. (b).
B(5, 1)
A
(-1, -7)
D
2:1
C
(1, 4)
Bisector BD of ABC divides AC in 2:1
27.
28.
D 1/ 3, 1/ 3 .
Equation of BD is y 1
x 7y 2 0 .
2/3
x 5
14 / 3
Ans. (a).
Ans. (b).
Solving 3x 4 y 9 and y mx 1, we get x
5
, m is an integer. x will be integer for m 1 and
3 4m
2 .
29.
30.
Ans. (d).
Ans. (d).
Physics:
31.
Ans. (c).
d
d
1 2d
1
v / 2 ev / 2 e v
2v sin 45
Where T
g
T
2v / 2 1 2d
1
g
e v
gd
e 2
v gd
nd
32.
Ans. (c).
m v ' m v ' m v m v p
1
33.
1 1
p = |change in momentum of the two particles|
p = |External force on the system| time interval
p 2 m1 m2 g 2t0
p 2 m1 m2 gt0
Ans. (c).
d p
F
2 Bt
dt
When a and u are at 45 , F and will also be inclined at 45 . This will happen at t
34.
A
B
A
F 2B
B
Ans. (b).
1
Horizontal and vertical components of initial velocity are u x 20 2 cos 45 20 ms
and u y 20 2 sin 45 20 ms 1
After 1 s, horizontal component remains unchanged while the vertical component becomes
v y u y gt
v y 20 10 1 10 ms 1
Due to explosion one part comes to rest. Hence, from conservation of Linear Momentum, vertical component of
'
1
second part will become v y 20 ms . Therefore, maximum height attained by the second part will be
H h1 h2
Where, h1 be the height attained in 1 s.
h1 20 1
1
2
10 1 15 m
2
and h2 be the height attained after 1 s.
35.
h2
v'2y
2g
20
2 10
20 m
H 20 15 35m
Ans. (d).
At maximum extension, velocity of both the blocks will be same
Let v be the common velocity of the blocks (towards right). By Law of Conservation of Linear Momentum, we
get
6 2 3 1 3 6 v
v 1 ms 1
If x be the maximum extension in the spring, then by Law of Conservation of Mechanical Energy, we get
1
1
1
1
2
2
2
3 1 6 2 200 x 2 9 1
2
2
2
2
2
3 24 200 x 9
nd
18
200
x 0.3 m
x 30 cm
36.
Ans. (c).
Since, h << radius of earth, acceleration due to gravity g can be assumed to be constant. Let v be the velocity of
block at height
MV
h
. Then by Law of Conservation of Linear Momentum, velocity of earth will be
2
Mv
0
3
M h 1 M 2 1
v
By Law of Conservation of Mechanical Energy, we get
g v M
2
3 2 2 3
3
37.
3gh
2
Ans. (c).
v1 = 14 ms-1
v2 = 0
m1 = 10 kg
vcm
m2 = 4 kg
m1v1 m2 v2
m1 m2
38.
vcm
10 14 4 0 10 14
10 ms 1
10 4
14
Ans. (a).
Let speed of block be V. Then by Law of Conservation of Linier Momentum (applied along the horizontal
direction), velocity of cylinder will be v in opposite direction, then
mv MV 0
Mv
MV
2
v 2V
By Law of Conservation of Mechanical Energy, we have mgh
1
1
2
MV 2 m 2V
2
2
Where, h R r 1 m
Substituting the values, we get 110 1
39.
3v2 10
1
1
2 V 2 1 4V 2 .
2
2
10 1
ms
3
Ans. (b).
dM
dt
dM M 0 g
dt
v
M 0 g Thrust v
nd
dM 60000
60 kgs 1
dt
1000
40.
Ans. (b).
Let h be the height of each step. Then e
41.
2 gh
v
1
u
2
2 g 2h
Ans. (b).
Relative velocity Relative velocity
=
= v
of separation
of approach
2 r
Time of next collision

v
42.
{as e = 1}
Ans. (b).
dx
6t 2
dt
Impulse J p m vf vi
v
J 2 6 1 0 12 Ns
43.
Ans. (d).
4 ms 1
v
1ms
1ms 1
Before Collision
After Collision
Let v be the velocity of ball after an elastic collision with the wall, so
Relative velocity Relative velocity
of separation
of approach
44.
{away from the wall}
v 1 4 1
v 6 ms
Ans. (c).
vcos60 =
v
2
v
60
A
vB
hB
h
But path of B will be first straight line and then parabolic as shown in figure. For N and B, Loss in KE = Gain in
PE
1 2 1 2
mvB mv mgh
2
2
1 2 1
mv m 8 gh mgh
2
2
1 2
mv 3mgh
2
nd
v 6 gh
So,
hB h
2g
9h 13h
hB h
4
4
hA 4
hB 13
45.
v 2 sin 2 60
Ans. (c).
Retardation due to friction a g 0.25 10 2.5 ms 2
Since collision is elastic, i.e., after collision first block comes to rest and the second block acquires the velocity
of first block. Distance travelled by it will be
2
v2
5 5 m
s
2a 2 2.5
So, final separation x is
x 5 2 3m
46.
Ans. (d).
Impulse = Change in Linear Momentum
eu cos
u sin
u sin
u cos
After collision
Befre collision
47.
Ft m eu cos u cos
mu cos 1 e
t
Ans. (c).
Let Origin be placed at B x-axis along BC. By Law of Conservation of Momentum
y
A
mv
30 G
mv
mv
B
30
along x-axis
0 mv cos 30 mv cos 30 0 mv cos 30 mvx
vx v cos 30
.(1)
along y-axis
mv mv sin 30 mv sin 30 0 mv sin 30 mvy
v y v sin 30
. (2)
Squaring (1) and (2) and adding, we get
vnet vx2 v y2 v at
nd
mv net
vy
vx
30
48.
Hence, the particle C will have the same magnitude of velocity but directed along the original direction
(direction before collision) of particle B.
Ans. (d).
By Law of Conservation of Momentum
along x-axis
m 9 m 0 mv1 cos 30 mv2 cos 30
v1 v2
18
3
6 3
Along y-axis
0 mv1 sin 30 mv2 sin 30
49.
v1 v2
v1 v2 3 3 ms 1
Ans. (c).
By Law of Conservation of Momentum 2.9 0 0.1150 2.9 0.1 v
0.1150
3
v 5 ms
Loss in K.E.of Gain in P.E.of
combined system combined system
By Law of Conservation of Energy
1
M m v 2 M m gh
2
v 2 2 gh
But
h l 1 cos
v 2 2 gl 1 cos
25 2 10 2.5 1 cos
cos
60
50.
1
2
Ans. (c).
Let u be the velocity of ball before collision. Speed of ball after collision will become.
2
5
u u
v

8u
2 2 2
1
1
mu 2 mv 2
2
2
Fraction of KE lost in collision
1
mu 2
2
nd
v
u
51.
Fraction Lost 1 1
5 3
8 8
Ans. (d).
2
av
F av
a
3
Where, 10 kgm 3 ,
2
av 20 10 6 m 3 s 1
2
d2
10 2
4
4
and a
Substituting the values, we get

6 2
10 20 10
F
3
104
4
52.
5.1 103 N
Ans. (a).
Since both particles move under the influence of gravity, so relative acceleration of one as seen by other is zero.
Therefore, the relative motion between the two is uniform. Relative velocity of the two is
vr 10 5 ms 1 15 ms 1 in horizontal direction. Therefore, the collision will take place after a time
t
60
4s
15
Net linear momentum in horizontal direction of the two particles is zero. Therefore, after collision the combined
mass will fall vertically downwards. The desired distance from A would be x vr t 10 4 40 m
53.
Ans. (b).
Let mass of gun to be M and that of shell to be m . The two cases are shown in figure as below
v
m
vf
v2
m
M
v - v1
case (i)
30
v2
case (ii)
Here, v1 and v2 are the recoil speeds of the gun in two cases. Applying Law of Conservation of Linear
Momentum in horizontal direction in two cases, we get
Case (i): m v v1 Mv1
mv
M m
Case (ii): m v cos30 v2 Mv2
v1
v2
. (1)
3mv
2 M m
From equations (1) and (2), we get
v1
2
v2
3
54.
Ans. (b).
Let v1 and v2 be the velocities of the two masses after collision in the same direction. Then
m1
m2
m1
Before Collision
v2
After Collision
. (1)
m1v m1v1 m2 v2
m2
v1
nd
and
. (2)
v2 v1 ev
Solving equations (1) and (2) we get,
v1
v m1 em2
m1 m2
For v1 to be positive m1 em2
m1
e
m2
55.
Ans. (c).
sin
r 1
2r 2
30
v
By Law of Conservation of Linear Momentum
mu 2mv cos 30
u
3
. (1)
v2 n v1 n
u2 n u1 n
Now e
u
v
2
e
3
u cos 30 u 3 3
2
56.
Ans. (b).
m
3m
30 2
v
5
5
v 10 2 ms 1
m
30 2
5
m
30
5
45
45
135
135
m
30
5
3m
v
5
nd
57.
Ans. (d).
p
5p
1
tan 1
2
1 1
tan
2
5p
58.
2p
Ans. (a).
By Law of Conservation of Momentum 0 mu M v
mu
M
Is the velocity of the man in the upward direction.

Since, no gravity is existing hence ball will reach the floor in a time t
h
u
During this time the man will move up by a distance d vt
mu h mh
d

M u M
So, total distance of man from floor when ball reaches the floor is
s d h h 1
M
59.
Ans. (d).
Fraction Transferred
Fraction Lost
60.
4m1m2
m1 m2
Fraction
4n
n 1
Ans. (b).
At the highest point velocity before explosion is v cos 60 along + x-axis. By Law of Conservation of
Momentum mv cos 60 i
m
m
mv '
100 j
100 j
3
3
3
3v 3 200
i
i
2
2
v ' 300i ms 1
v'
Chemistry
61.
62.
Ans. (d).
Ans. (b).
For ideal gas
PV id
1
RT
RT
P
V id
For real gas,
PV RT
nd
PV
Z
RT
V
Z
V id
63.
Ans. (c).
rLPG
r SO3
80
1.25
M LPG
80
2
1.25
M
M LPG 51.2
M
51.2
M 1 butane X 1 M 2 propane X 2
X1 X 2
58 X 1 44 1 X 1
1
X 1 0.50
64.
Ans. (b).
N 2 3 H 2
2 NH 3
taken
Reacted(50% of N 2 )
left
2
1
5
3
0
2
Total mol of N 2 , H 2 and NH 3 5 mol

Initial mol = 7
Pressure at start = 7 atm
hence,
pressure at equilibrium = 5 atm
65.
partial pressure of NH 3
2
5 2 atm
5
Ans. (a).
When open end up, the weight of mercury represents an increase in the pressure on the gas of 400 cmHg = 40
mmHg
Final pressure = 760 + 40 = 800 mmHg
PV
1 1 P2V2
P1 A l1 P2 A l2
Where A is the area of cross-section (which is constant) and l1 , l2 length
P1 l1 P2 l2
760 10 800 l2
l2 9.50 cm
66.
Ans. (c).
By Avogadros law, equal volumes of gases contain equal number of moles.
nd
4 NH 3 g 5O2 g
4 NO g 6 H 2O g
4 mL NH 3 6 mL H 2 O
50 mL NH 3 75 mL H 2O
5 mL O2 6 mL H 2O
60 mL O2 72 mL H 2O
Stoichiometry, O2 is consumed completely.

Thus, 72 mL H 2O g
67.
Ans. (d).
N 2 3H 2
2 NH 3
1
4
0
1
3
Unreacted H 2 1 mol
taken
reacts
NH 3 formed = 2 mol
NH 3 dissolves in water and pressure is due to H 2 only. Also due to addition of water, volume occupied is = 10 L
68.
1 0.0821 300
10
Ans. (c).
If a gas is liquefied, volume decreases hence attractive forces exists.
a NH 3 a N 2
Thus,
b NH 3 b N 2
69.
Ans. (b).
PV RT
KE
70.
71.
72.
3
3
PV RT
2
2
2
RT E
3
2
P E per unit volume
3
Ans. (d).
Ans. (d).
Ans. (d).
PV
c c
3
RTc
8
PV
3
c c
RTc 8
73.
Ans. (d).
At point A near low pressure region, volume is very high thus V b V
P 2 V RT
V
a
PV RT
V
nd
74.
75.
76.
77.
78.
PV
a
1
RT RTV
Ans. (c).
Ans. (d).
Ans. (b).
Ans. (b).
Ans. (a).
H OC
HOCl
H OCl
Ka
HOCl
HOCl OH
OCl H 2O
K eq
HOCl OH
OCl
K a K eq H OH
Kw
11014
K w 1.0 10 14
K eq 3.6 107
Ka
2.8 108
79.
Ans. (a).
On doubling [A], rate is doubled. Hence, n 1
Kc
1 10 2
0.1 mol L1 s 1
0.1
kf
kb
kb
80.
d A / dt
kf
kf
kc
0.1
1102 L mol 1 s 1
10
Ans. (c).
Rate f
k f NO O2
2
Rate b kb NO2
at equilibrium
kf
kb
NO2 2.6 103 K

c
2
4.1
NO O2
for
1
NO2
NO O2
2
K c ' K c 25.18
81.
Ans. (c).
PCl3 Cl2 , n 1
PCl5
nd
K p K c RT K c RT
2 K c (given)
RT 2
2
2
T
24.36 K
R 0.0821
82.
Ans. (a).
Ag NH 3
Ag 2 NH 3
2
K1 1.8 10 7
Ag Cl
AgCl
K2 '
1
1
K 2 5.6 109
Ag NH 3 Cl
AgCl 2 NH 3
2
K K1K 2 '
83.
K1 1.8 107
3.21 10 3
K 2 5.6 109
Ans. (a).
PCl5
PCl3 Cl2
0.5
2 mol
2 2
PCl3 Cl2 2 2 4
Q (reaction quotient)
0.5
PCl5
2
Thus, Q K c , reaction mixture is in equilibrium.
PCl5
84.
0.5
0.25 mol L1
2
Ans. (c).
K decreases with increase in temperature. Thus, forward reaction is exothermic
Ea = activation energy of forward reaction

Ea ' ... backward.
Ea
Ea '
H
Ea H
Ea ' E a
Thus,
85.
Ans. (d).
C
A B
1
1 x 1 x
2 y 1 y
Kc
x2
1 x
D
0 set I
0
Set II
y
y2
1 since x 0.5
2 y 1 y
nd
2
3
Fraction of A converted into products
86.
2/3 1
0.33
2
3
Ans. (b).
log e K log e A
H
RT
H
2000
R
H 2000 R
G H T S
At equilibrium G 0
87.
H 2000 R
5R
T
400
Ans.(b).
log10 K log10 A
Slope =
H
2.303 RT
H
tan 45 1
2.303 R
H 2.303 R slope
4.606cal
88.
89.
90.
Ans. (c).
Ans. (b).
Ans. (c).
2 NH 3 g CO2 g
NH 2CO2 NH 4 s
2x
2p
p
, pCO2
3
3
Where p is the total pressure at equilibrium
PNH 3
2
K p p NH
. pCO2
3
4 p3
0.5
27
p 1.5 atm
p NH 3 1 atm,
nd
pCO2 0.5 atm

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IIT-JEE Mains Model Paper (Juniors)

Answer & Solutions :

The coordinates , of the in-centre are given by

ax1 bx2 cx3

i.e., the in-centre is 2 2, 2 2 .

O 0, 0 is the orthocenter. B is found to be 1, 1 , OB ax by 1 0 .

Equation of line through A is ax by 1 2 x 3 y 1 0

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

Also OA passes through origin.

(2, 0) (3, 0) (4, 0)

Slope of line to this line cos / sin

Equation of required line is

y a sin 3 cos / sin x cos3

x cos y sin a cos 4 sin 4

x cos y sin a cos 2

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

Solving (1) & (2), mid-point of CD i.e., F is

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

Let equation of the line OAB be

equation of the image is y x 2 .

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

Which form a square.

The given lines are 2x y 2

Solving (1) and (2), (1) and (3), we get A 2 / m 2 , 2 m / m 2

Hence the locus of midpoint P h, k is 2 x 2 3 xy 2 y 2 x 3 y 0

Line 2x y k passes through C ,

Bisector BD of ABC divides AC in 2:1

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

p = |change in momentum of the two particles|

p = |External force on the system| time interval

and h2 be the height attained after 1 s.

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

By Law of Conservation of Mechanical Energy, we have mgh

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

Relative velocity Relative velocity

Time of next collision

Relative velocity Relative velocity

{away from the wall}

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

0 mv cos 30 mv cos 30 0 mv cos 30 mvx

mv mv sin 30 mv sin 30 0 mv sin 30 mvy

Squaring (1) and (2) and adding, we get

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

m 9 m 0 mv1 cos 30 mv2 cos 30

0 mv1 sin 30 mv2 sin 30

Loss in K.E.of Gain in P.E.of

combined system combined system

By Law of Conservation of Energy

Substituting the values, we get

From equations (1) and (2), we get

Solving equations (1) and (2) we get,

For v1 to be positive m1 em2

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

Is the velocity of the man in the upward direction.

During this time the man will move up by a distance d vt

For real gas,

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

Total mol of N 2 , H 2 and NH 3 5 mol

Final pressure = 760 + 40 = 800 mmHg

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

Stoichiometry, O2 is consumed completely.

# 2-1-520 to 526 Vijaya Sri Sai Celestia II

NO2 2.6 103 K

Ea = activation energy of forward reaction