IIT-JAM Chemistry Mock Test Guide

C SIR NET, GA TE, IIT-JA M, UGC NET , TIFR , IISc , JEST , JNU, BHU , ISM , IBPS , C SAT, SLET,
NIMCET, C TET
IIT-JAM - CHEMISTRY
MOCK TEST PAPER(Acco rding to new patter n)
PART-A:- Attempt ALL the objective questions

(Questions 1-10). Each of these questions carries
two marks. 0.25 negative mark for each wrong answer.
PART-B:- Attempt ALL questions
three marks
PART-C:- Attempt ALL questions
five marks
Pattern of questions : MCQs + Fill i n the blanks + Subj ective
Total marks
: 100
Durati on of test
: 3 Hours
For IIT-JAM, JNU, GATE, NET, NIMCET and Other Entrance Exams
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Page 1
C SIR NET, GA TE, IIT-JA M, UGC NET , TIFR , IISc , JEST , JNU, BHU , ISM , IBPS , C SAT, SLET, NIMCET, C TET
GUIDELINES FOR J AM ASPIRANTS:

1.
CHANGE OF SYLLABUS :
(i) After 8 years , IIT-JAM s yllabus of Chem is try has been changed.
(ii) The following new topics have been added from JAM 13 onwards .
Allenes , Biphenyls , cyclohexanes Acid-Base , Redox reactions
, Organometallic
Reagents ,Solid state,Bioinorganic Chemis try, N MR, IR s pectros copy, Adsorption

etc.
(iii) The JAM as pirants s hould s pecially s tress upon these above m entioned topics &
s hould practice the problems related to these topics.
2.
CHANGED EXAM PAPER P ATTERN:

(i) IITs have changed the exam paper pattern als o & have Introduced Fill in the blank
type of ques tions for the firs t time .
(ii) The given mock tes t paper reflects the paper pattern and the toughness level of JAM
papers . The questions of new syllabus have als o been incorporated in this pattern.
(iii) Students can s tart preparing for IIT-JAM from B.Sc. First year its elf, s o that in the
cours e of three years duration, their preparation level reaches to the level of JAM
paper. This helps in raising the percentage in univers ity e xams als o.
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PART-A (1-10)
1.
The relationship betw een the dissociation energy of N2 and N2+ is

(A) N2 = N2+
(B) Unpredictable
(C) N2 > N2+
(D) N2 + > N2
2.
The correct absolute configuration assigned for compound (I) and (II) respectiv ely is
(A) R, R
(B) R, S
(C) S, S
(D) S, R
3.
The correct order of acidic strength is

(A) SiO2 < CO2 < N2O 5 < SO3
(B) SiO2 < N2O5 < CO 2 < SO3
(C) CO2 < SiO2 < N2O5 < SO3
(D) SO3 < CO2 < N2 O5 < SiO2
4.
Which of the follow ing has maximum number of lone pairs on central atom?
(A) ClO3
(B) XeF4
(C) SF 4
(D) I3
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5.
Which of the follow ing is an arachno borane

(A) [B6H6]2
(B) [B5H9]
(C) [B2 H6]
(D) [B6 H12]
6.
1. B2 H6 / T.H.F.
2. H2 O2 / OH
Which of the follow ing is incorrect for above reaction?
(A) Product is optically activ e
(B) It is an oxidation reaction
(C) Overall reaction is stereospecific syn addition
(D) B2 H6 adds on alkene by forming a cyclic transition state.
7.
The Miller indices of crystal plane w hich cuts through the crystal axis at 2a, 3b, 3c is ,
(A) 2 3 3
(B) 3 2 6
(C) 6 2 3
(D) 3 2 2
8.
IR spectra of benzaldehyde and acetophenone w ill show distinguishing peaks in the region
(A) 3000 - 3600 cm1
(B) 1200- 1300 cm1
(C) 2700-2800 and 2860-2975 c m1
(D) 1600 and 1740 cm1
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9.
Which is not correctly matched?

(A) XeO3: trigonal bipyramidal
(B) CIF 3 : T shaped
(C) XeOF4 : square pyramidal
(D) XeF2 : linear shape
10.
If standard reduction potentials of Ni2+/Ni and Au3+/Au couples are 0.25 V and 1.50 V
respectively, then the EMF of the cell
Ni/Ni2+ (0.01 M) || Au3+ (0.1 M) Au w ill be
(A) unpredictable
(B) = EMF
(C) < EMF
(D) > EMF
PART- B (11-20)
11.
Compound (X) __________ on reduction w ith LiA lH4 giv es a hybride (Y) containing 21.72%
hydrogen along w ith other products. The compound (Y) reacts w ith air explosively resulting
in boron trioxide. The structure of Y is ___________.
12.
______ and _____ metalloenzymes are responsible for the removal of hydrogen peroxide.
.
13.
D-Glucose and D- Galactose are _______ w hile -D and -D Glucose are ______.
14.
The structure of an alcohol C5 H11 OH is _________. It gives a ketone on oxidation. When

the alcohol is dehydrated and the resulting alkene is oxidised, a mixture of a ketone and an
acid results.
15.
At certain temperature the r.m.s. speed of molecules of Nitrogen gas is U.When the
temperature is doubled, the molecules dissociate into individual atoms. The new r.m.s.
speed of atoms is _________.
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16.
Difference betw een H and U for the combustion of benzene at 300 K is ________.
17.
The molar conductance at infinite dilution of HCl, NaCl and NaZ (Sodium Crotonate) are 425
104, 125 104 and 80 104 Sm2 mol1, respectively. The specific conductance of
0.001 M aqueous solution of crotonic acid ( HZ) is 3.8 103 Sm1. The degree of
dissociation is _____.
18.
------------- are responsible for electron transfer in plants and bacteria.
19.
In Plastocyanin Cu(I) and Cu(II) are respectively arranged as------------ respectively
20.
10 moles of an ideal gas expand isothermally and reversibly from a pressure of 10 atm to 2
atm at 300 K. _______ is the largest mass w hich can be lifted through a height of 1 metre in
this expansion
PART-C (21-30)
21.
When 16.8 g of w hite solid, X w ere heated, 4.4 g of acid gas A, that turned lime-w ater milky
w as driven off together w ith 1.8 g of a gas B w hich condensed to a colourless liquid. The
solid that remained, Y, dissolved in w ater to give an alkaline solution, w hich w ith excess of
barium chloride solution gave a w hite precipitate Z. The precipitate effervesced w ith acid
giving of carbon dioxide. Identify A, B and Y and w rite dow n the equation for the thermal
decomposition of X.
22.
Acetylene + CH3 MgBr X + CH4

H+
X + CO2 Y
Z(C H O )
3 2 2
H O, H SO , HgSO
2
2
4
4
Z
W(C3 H4 O3)
W + KMnO4
CH2( COOH) 2
Identify X, Y, Z , W and w rite complete reaction equation.
23.
ether
Bromobenzene + Mg E(C6 H5 MgBr)
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H+
E + ethylene oxide
F(C H O)
8 10
F + PBr 3 G(C8 H9 Br)
G + NaCN
H( C9 H9N)
H + H2SO 4
I(C H O )
9 10 2
H2O
I + SOCl 2
J(C9 H9 OCl)
catal yst
J + anhydrous HF
K(C H O)
9 8
catalyst
K + H2
L(C9 H10 O)
W ar m
L + H2SO4, M( C9 H8)
Identify E, F, G, H, I, J, K, L, M and w rite complete reaction equation.
24.
The degree of dissociation of Ca(NO3) 2 in a dilute aqueous solution, containing 7.0 g of the
salt per 100 g of w ater at 100 C is 70%. If the vapour-pressure of w ater at 100 C is 760 mm,
calculate the vapour-pressure of the solution.
25.
Heat of combustion of ethylene (C2 H4) is 337 kcal mol1 under standard state at 298 K.
Assuming 70.0% efficiency, how many kg of w ater at 20 C can be converted into steam at
100C burning 1.00 m3 of C2 H4 gas measured at STP? Specific heat of w ater is 1 kcal kg1
K1 and its latent heat of vaporization is 540kcal kg1.
26.
Identify the intermediate products X, Y, Z and W in the follow ing sequence of reactions.
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EtO Na
Zn /H+
, (H O)

(X)
(Y) 2
(Z)
OH, H O
2
hydrolysis
(W)
27.
co2
The vapour-pressure of ethanol and methanol are 44.5 and 88.7 mm Hg respectively. An
ideal solution is formed at the same temperature by the mixing 60 g of ethanol w ith 40 g of
methanol. Calculate the total vapour-pressure of the solution and the mole-fraction of
methanol in the vapour.
28.
The rate law for the reaction 2NO(g) + O2(g) 2NO2(g) is
[O ]
2
t
= k[NO]2[O 2]
The proposed mechanism is

NO(g) + O2(g) NO3(g)
NO(g) + NO3(g) 2NO2(g)
(a) The reaction mechanism does not include a collision among three molecules. Since the
reaction order is three, shouldnt the mechanis m include such a collision ?

(b) Which step in the proposed mechanism is the slow est step ?
(c) What is the molecularity of each step ?
29.
(a) Cv for uranium metal is 3.04 JK1 mol1 at 20K. Calculate the absolute entropy of the
metal in JK 1 mol 1 at 20K.
(b) Calculate the uncertainty in the velocity of an electron if uncertainty in its position is 1A .
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30.
If is the volume of a gas adsorbed on the surface of a solid, the plot of p/ versus p w here
p is the gas pressure in the Langmuir adsorption isotherm, gives a straight line. What w ill be
the slope of this line?
ANSWER KEY
Question
Solution
1
C
2
B
3
A
4
D
5
D
6
A
7
D
8
C
9
A
10
D
HINT & SOLUTION

1.(C)
According to MOT the bond order of N2 is 3 w hereas that of N2 + is 2.5. So the bond
dissociation energy of N2 w ill be greater than that of N2+. Bond dissociation energy is
directly proportional to bond order.
(B.O BDE)
2. (B)
3
NH2
NH2
1
CH3
2 CH2 SH
(R)
(S)
Priority Sequence
Priority Sequence
NH2 > COOH > CH3 > H NH2 > CH2 SH > COOH
3
3. (A) These are the anhydrides of follow ing acids:
H2SO4, HNO3, H2 CO3 , H2 SiO3.
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The acid strength order of these acid is H2SO4,
>
HNO3> H2CO 3
>H2 SiO3. The oxides
also follow the same order.

4. (D) I 3 sp3d Hybridiz ation w ith 3 lone pairs
: ::
5. (D) Arachno boranes have the general formula - Bn H n+6

w ith (n+ 3) electron pairs B6H12 is arachno borane.
1. B2H6
2. H2O 2 / OH
6. (A)
7.(D)
1
2
1
3
1
3
Miller indic es are ( 3 2 2 ).

O
8.(C) C6 H5CHO and
C CH3 w ill differ in the absorption peaks due to aldehydic C H
(2700-2800 cm1) and sp3 C H stretch (2860-2975 cm1).
9. (A) XeO3 has trigonal pyradimal shape .
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10.(D)
EMF = EMF +
0.059
6
= EMF +
11.
BCl3,
Sol.
Y is
log
[Au3+ ] 2
[Ni2+] 3
0.059
6
= EMF +
(0.1)2
0.059
3
6 log (0.01)
= EMF +
0.059
6 log 104
4. Hence EMF > EMF .
2B H (Y) + 3AlCl + 3LiCl

4BCl3 (X) + 3LiAlH4
2 6
3
% of hydrogen in B2 H6 =
6
100 = 21.72
27.62
explosion
B2H6 + 3O2 (air)
B2O3 + 3H2O
Structure of B2H6
12.
Catalase and peroxidase.
Sol.
Catalase and peroxidase are tw o heme enzymes that catalyse reactions of hydrogen
peroxide.
Catalases prevent the accumulation of poisonous H2O2 and other peroxy compounds
resulting from the various oxidase reactions in the bio logical system. Catalase catalyses
disproportionation of H2O2 according to overall reaction :
2H2 O2
Catalase
2H O + O
2
2
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The process occurs in tw o steps :

PFe III + H2O 2 Compound I + H2 O
Compound I + H2O2 PFe III + H2 O2 + O2
Peroxidase reacts by mechanism similar to catalase, but the reaction catalysed is the
oxidation of a w ide variety of organic and inorganic substrate by H2O2
Peroxidase
H2O2 + AH2
2H2 O + A
or
Peroxidase
H2O2 + Substrate H2 ( Reduced form )
2H2O + Substrate
(Oxidised form)
13.
C-4 epimers, Anomers
Sol.
14.
Sol.
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Dehydration
15.
2u
Sol.
u1 =
u2 =
3RT
M
, T2 = 2T; M2 =
M
2
3R(2T)
3RT
=2
= 2u
M2
M
16.
3.74 kJ
Sol.
Combustion of Benzene is represented by

15
C6 H6(l) +
O2(g)
6CO2(g) + H2 O(l)
2
n = 6
15
3
=
2
2
H = U nRT
or
3
H U = nRT = (8.314)(300) 103 = 3.74 kJ
2
17.
0.10
Sol.
Crotonic acid is formed as follow s :

HCl + NaZ NaCl + HZ (crotonic acid)
w here Z stands for crotonate ion.
Crotonic acid is a w eak organic acid and HCl, NaZ and NaCl are strong electrolytes.
Hence, usin g Kohlraushs law of indep endent migration of ions,
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o
om HZ = mHCl
+ mo NaZ mo NaCl = (425 + 80 125) 10 4 S m2 mol1 = 380 104 S m2
mol1
Also, at the given concentration of crotonic acid,
m =
=
3.8 103 S m1
=
= 38.0 104 S m2 mol1
c 0.001 103 mol m3
m 38.0 10 4 S m2 mol1
=
= 0.10
om 380 104 S m2 mol 1
18..
Ferredoxins;
Sol.
Ferredoxins are group of non-haem iron-sulphur proteins w hich are responsible for electron
transfer in plants and bacteria.
19.
Flattened tetrahedron and octahedrally;
Sol.
n plastocyanin Cu(I) and Cu( II) are respectively arranged as flattened tetrahedron and as
octahedron respectively .Cu(I) forms distorted tetrahedron, w hile Cu(II)adopts octrahedral
arrangement
20.
Sol.
409.28 kg
Work done in this case is given by
w = nRT ln( P1 /P2) = 10 mol(8.314 J K1 mol 1)(300 K) ln (10atm/2atm) = 40.15 10 3 J
Let M be the mass w hich can be lifted through a height of 1 m.
Work done in lifting the mass = Mgh = M 9.81 m s 2 1 m
M 9.81 1 m2 s 2 = 40.15 103 J
21.
M = 409.28 kg
(X) is NaHCO3
(molecular w t. = 84)
Reactions involved are given below :
2NaHCO 3 Na2 CO3 (s) + CO 2 (g) + H2O(g)

( X)
2 84 = 168 g
(Y)
106 g
( A)
44 g
(B)
18 g
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16.8 g
10.6 g
4.4 g
1.8 g
CO2 + Ca(OH)2
CaCO 3 + H2 O
lim e water
white p pt.
H2 O(g) is condensed to liquid w ater

Na2 CO3 + BaCl2 BaCO 3 + NaCl
(Y )
(Z )
BaCO 3 + 2HCl BaCl2 + H2O + CO 2

(Z )
22.
H C C H + CH3 MgBr HC CMgBr + CH4

HO C C CH
H C CMgBr + O = C = O
(X)
O = C OMgBr
C CH
(Y)
O
(Z)
H2O, H2SO 4 , HgSO 4
COO H
CH 2
H C CH 2 C OH
O
COO H
KMnO 4
Malonic acid
(W)
MgBr
Br
CH2 CH +
2
Ether
+ Mg
23.
C6 H5 CH2 CH2 OH
(F)
H O+
O
-
(E)
3
C6H5 CH2 CH2 OMgBr
PBr3
C H CH2 CH 2 Br NaCN C 6H5 CH2 CH2 CN
6 5
(G)
(H)
C H CH 2 CH2 COOH
H SO 4
2
6 5
H2O,
(I)
24.
Ca(NO3 )2 Ca
2+
+ 2NO 3
Before dissociation
After dissociation
Total moles at equilibr ium = (1 + 2) = 1 + 2 0.7
( = 0.7)
= 2.4
m
For Ca(NO3) 2 : n or = 1 + 2
m exp
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164
nor
mexp =
=
= 68.33
1 + 2 0.7 2.4
Also at 100C, P0 = 760 mm, w = 7g

W = 100 g
Raoults Law
Now ,
25.
P0 Ps
wM
=
Ps
Wm
Po Ps
7 18
=
Ps
68.33 100
ps =
= 0.0184
or
P
1 = 0.0184
Ps
760
= 746.26 m
1.0184
1000
1.00 m3 at STP = 1000 L =
mol
22.4
1000
Enthalpy change due to burning of 1.00 m3 ethylene = 337
kcal
22.4
Due to 70% efficiency, useful heat is = 337
1000
70
kcal
22.4
100
H2 O(l) is converted into H2O(g) in tw o stages

H2 O(l, 20 C)
H2 O(l, 100 C), H1 = 80 kcal kg1
(rise in temperature = 80C)
H2 = 540 kcal kg1
H2 O(l, 100C) H2O(g, 100C),

H(Total) = 620 kcal kg1
thus, w ater converted into steam =
26.
(X) =
heat evolved 337 1000

70
1
=
= 16.98 kg
heat required
22.4
100 620
(Y) =
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(Z) =
27.
(W) =
Total vapour-pressure of solution:
Pm = Peth
M.F.eth + Pme th M.F.meth = Pe th xe th + Pme th xmeth
Peth
Pmeth
Given that:
Peth
= 44.5 mm Hg, p0meth = 88.7 mm Hg
w t. of ethanol = 60 g, w t. of methanol = 40 g
neth =
60
= 1.304
40
nmet h =
x eth =
n eth
n eth + nmeth
nmeth
( mol. w t. of ethanol = 40)
40
= 1.25
32
( mol. w t. of methanol = 32)
1.304
1.304
=
= 0.51
1.304 + 1.25 2.554
=
1.25
= 0.49
2.554
x meth =
nmeth + n eth
Pm = 44.5 0.51 + 88.7 0.49 = 22.67 + 43.46 = 66.13 mm Hg
mo le-f raction of methanol in vapour =
28.
Pmeth 43.46
=
= 0.66 m m Hg
Pm
66.13
(a) No, A collisio n a mong three mo lecules is not likely. The [ NO]2 term results because the
slow est step in the mechanis m dep ends on [ NO] and so me other concentration ter m t hat is
directly related to [ NO][ O2].
(b) The slow est step is the second step in the proposed reactio n mechanis m. A ssuming
that
the
f irst
step
is
f ast
and
has
reached
state
of
equilibriu m,
K
NO( g ) + O 2( g ) 1 NO 3( g )
NO( g ) + NO 3 ( g)
2NO 2( g )
K
2
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then the concentration of NO3(g) is related to the concentrations of NO(g) and O2(g) by
the equilibrium relation K1 = [NO3]/[NO] [O2] or [NO3] = K1[NO][O2]. The rate law for the
reaction, as deriv ed from the slow est step, is [O2]/t = k2[NO][NO3] = K2 [NO]
K1[NO][O 2] = k1k2[NO]2[O2] = k[NO2] 2[O2].
(c) Both steps are biomolecular.
29.
At temperatures (0< T < 20 K) , Cp = Cv = aT3
[Debyes T3 law ]
a = C / T 3 = 3.04JK 1mol1 / ( 20K ) = 38.03 10 5 JK 4 mol1

3
30.
Cp = aT 3 = 38.3 10 5 Jmol 1K 4 T 3
Hence ,
From Eq.14,
dS = (Cp/T)dT = 38.0310 J mol K
Or
S20 S0 = 38.03 10 JK mol
Or
S20 = 1.01JK 1mol1
[ S 0 = 0]
( 20K )
T dT
/3
A/C to langmuir isother m
Kp
1 + KP
1
1
= 1+
KP
Let =
mono
Where mono is the volume corresponding to complete
coverage
mono
1
=1+
Kp
Multip lying throughout by
p
mono
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p
p
1
=
+
mono K mono
y = mx + C
Slope =
1
mono
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C SIR NET, GA TE, IIT-JA M, UGC NET , TIFR , IISc , JEST , JNU, BHU , ISM , IBPS , C SAT, SLET,

PART-A:- Attempt ALL the objective questions

Web Site www.vpmclasses.com E-mail-vpmclasses@yahoo.com

GUIDELINES FOR J AM ASPIRANTS:

Reagents ,Solid state,Bioinorganic Chemis try, N MR, IR s pectros copy, Adsorption

CHANGED EXAM PAPER P ATTERN:

The relationship betw een the dissociation energy of N2 and N2+ is

The correct order of acidic strength is

Which of the follow ing is an arachno borane

Which is not correctly matched?

The structure of an alcohol C5 H11 OH is _________. It gives a ketone on oxidation. When

------------- are responsible for electron transfer in plants and bacteria.

In Plastocyanin Cu(I) and Cu(II) are respectively arranged as------------ respectively

Acetylene + CH3 MgBr X + CH4

Bromobenzene + Mg E(C6 H5 MgBr)

The rate law for the reaction 2NO(g) + O2(g) 2NO2(g) is

The proposed mechanism is

reaction order is three, shouldnt the mechanis m include such a collision ?

HINT & SOLUTION

3. (A) These are the anhydrides of follow ing acids:

H2SO4, HNO3, H2 CO3 , H2 SiO3.

The acid strength order of these acid is H2SO4,

>H2 SiO3. The oxides

also follow the same order.

5. (D) Arachno boranes have the general formula - Bn H n+6

Miller indic es are ( 3 2 2 ).

8.(C) C6 H5CHO and

C CH3 w ill differ in the absorption peaks due to aldehydic C H

(2700-2800 cm1) and sp3 C H stretch (2860-2975 cm1).

9. (A) XeO3 has trigonal pyradimal shape .

4. Hence EMF > EMF .

2B H (Y) + 3AlCl + 3LiCl

Catalase and peroxidase.

The process occurs in tw o steps :

C-4 epimers, Anomers

Combustion of Benzene is represented by

Crotonic acid is formed as follow s :

Hence, usin g Kohlraushs law of indep endent migration of ions,

Flattened tetrahedron and octahedrally;

M 9.81 1 m2 s 2 = 40.15 103 J

Reactions involved are given below :

2NaHCO 3 Na2 CO3 (s) + CO 2 (g) + H2O(g)

H2 O(g) is condensed to liquid w ater

BaCO 3 + 2HCl BaCl2 + H2O + CO 2

H C C H + CH3 MgBr HC CMgBr + CH4

H2O, H2SO 4 , HgSO 4

Total moles at equilibr ium = (1 + 2) = 1 + 2 0.7

Also at 100C, P0 = 760 mm, w = 7g

Due to 70% efficiency, useful heat is = 337

H2 O(l) is converted into H2O(g) in tw o stages

(rise in temperature = 80C)

H2 = 540 kcal kg1

H2 O(l, 100C) H2O(g, 100C),

heat evolved 337 1000

Total vapour-pressure of solution:

( mol. w t. of ethanol = 40)

( mol. w t. of methanol = 32)

Pm = 44.5 0.51 + 88.7 0.49 = 22.67 + 43.46 = 66.13 mm Hg

mo le-f raction of methanol in vapour =

At temperatures (0< T < 20 K) , Cp = Cv = aT3

a = C / T 3 = 3.04JK 1mol1 / ( 20K ) = 38.03 10 5 JK 4 mol1

dS = (Cp/T)dT = 38.0310 J mol K