UNIVERSIDAD NACIONAL DEL CENTRO DEL PER

Universidad
Innovadora, Cientfica
y Humanista.

Un Ingeniero
Qumico Ambiental,
Una Empresa.

FACULTAD DE INGENIERA QUMICA

ESCUELA ACADEMICA PROFESIONAL DE INGENIERIA

QUIMICA AMBIENTAL
PROGRAMAS PARA SISTEMAS LIQUIDO-VAPOR
ISOTRMICO E ISOBRICO APLICANDO LOS
MODELOS DE MARGULES, VAN LAAR Y WILSON
(Matlab)

CTEDRA

: TERMODINMICA DE LOS PROCESOS QUMICOS II

CATEDRTICO
SALVADOR ORE VIDALON

: Ing.

REALIZADO POR: ORE PAYANO EVELYN

SEMESTRE

: VI

FECHA: 23-09-2015

HUANCAYO-PER

GRAFICAS EQUILIBRIO LIQUIDO-VAPOR EN

SISTEMAS BINARIOS
[SISTEMA BINARIO ACETATO DE ETILO- ETANOL]
1.PROCESO ISOTERMICO (T=CTE)
a. ECUACION MARGULES
clc,clear all
disp('ALUMNA: Ore Payano Evelyn')
disp('ESCUELA: INGENIERIA QUIMICA AMBIENTAL')
disp('FECHA: 22-09-15')
T=40.3;%Temperatura constante en C
disp('Equilibrio Liquido - Vapor: Etil Acetato(1)-Etanol(2) MODELO DE
MARGULES')
disp('-----------------------------------------------------')
%Constantes de Antoine para Hallar el Pvp;(TABLA I)
%Ethyl Acetate
antA_1=7.09808;
antB_1=1238.71;
antC_1=217.0;
%Ethanol
antA_2=8.04494;
antB_2=1554.3;
antC_2=222.65;
%Parametros de Margules para hallar el coeficiente de Actividad;(TABLA
IV)
a12=0.4130;
a21=0.4816;
x1=[0 0.02 0.04 0.06 0.08 0.1 0.15 0.2 0.25 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.95 1];
x2=1-x1;n=length(x1);
%Determinacion de las presiones de vapor
Pvp1=10^((antA_1)-antB_1/(T+antC_1));
Pvp2=10^((antA_2)-antB_2/(T+antC_2));
%Modelo termodinamico de Margules
for c=1:n
gama1(c)=10^(x2(c)^2*(a12+2*x1(c)*(a21-a12)));
gama2(c)=10^(x1(c)^2*(a21+2*x2(c)*(a12-a21)));
P(c)=x1(c)*Pvp1*gama1(c)+x2(c)*Pvp2*gama2(c);
y1(c)=(x1(c)*Pvp1*gama1(c))/P(c);
y2(c)=(x2(c)*Pvp2*gama2(c))/P(c);
end
disp('
x1
x2
Pvp1
Pvp2
gama1
gama2
P
y1
y2')
for c=1:length(x1)
fprintf('%10.6f %10.6f %10.6f %10.6f %10.6f %10.6f %10.6f %10.6f
%10.6f\n',x1(c),x2(c),Pvp1,Pvp2,gama1(c),gama2(c),P(c),y1(c),y2(c))
end
%Datos experimentales:

xexp=[0.02240;0.03640;0.06880;0.09910;0.13620;0.17400;0.22850;0.24240;0.2
8340;0.36410;0.45900;0.56110;0.64460;0.65590;0.76840;0.77440;0.87150;0.92
430];
yexp=[0.08080;0.11320;0.18360;0.24560;0.30790;0.35580;0.41700;0.42400;0.4
6850;0.50900;0.56830;0.59780;0.66930;0.65860;0.73860;.72550;0.81260;0.877
40];
pexp=[145.999;151.497;158.000;164.998;176.002;183.997;191.498;191.498;200
.499;204.496;210.999;216.002;215.500;216.002;216.002;213.497;211.997;205.
996];%Presion experimental en mmHg=KPa*7.5006
disp('')
disp('Datos experimentales: ');
disp('====================================================');
disp(' x(1)
y(1)
P (mmHg) ');
disp('====================================================');
disp([xexp yexp pexp])
%Grafica1: Diagrama x1 vs y1
subplot(1,2,1),plot(x1,y1,'-m',xexp,yexp,'m*',x1,x1,'-r');legend('Puntos
teoricos','Puntos experimentales',4)
grid on
title('Equilibrio Ethyl Acetate(1)-Ethanol(2)a 40C; Modelo Margules')
xlabel('X')
ylabel('Y')
%Grafica2: Diagrama x1,y1 vs P
subplot(1,2,2),plot(x1,P,'g',xexp,pexp,'gv',yexp,pexp,'ro',y1,P,'r');legend('Puntos teoricos PX1','Puntos experimentales P-X1','Puntos experimentales P-Y1','Puntos
teoricos P-Y1',4)
grid on
title('Equilibrio Ethyl Acetate(1)-Ethanol(2)a 40C; Modelo Margules')
xlabel(' X,Y')
ylabel(' P mmHg ')
grid on

b. ECUACION VAN LAAR

clc,clear all
disp('ALUMNA: Ore Payano Evelyn')
disp('ESCUELA: INGENIERIA QUIMICA AMBIENTAL')
disp('FECHA: 22-09-15')
T=40.35;%Temperatura constante en C
disp('Equilibrio Liquido - Vapor: Ethyl Acetate(1)-Ethanol(2) MODELO DE
MARGULES')
disp('-----------------------------------------------------')
%Constantes de Antoine para Hallar el Pvp;(TABLA I)
%Ethyl Acetate
antA_1=7.09808;
antB_1=1238.71;
antC_1=217.0;
%Ethanol
antA_2=8.04494;
antB_2=1554.3;
antC_2=222.65;
%Parametros de Van Laar para hallar la constante de actividad
a12=0.4151;
a21=0.4833;

x1=[0 0.02 0.04 0.06 0.08 0.1 0.15 0.2 0.25 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.95 1];
x2=1-x1;n=length(x1);
%determinacion de las presiones de vapor
Pvp1=10^((antA_1)-antB_1/(T+antC_1));
Pvp2=10^((antA_2)-antB_2/(T+antC_2));
%Modelo termodinamico de Van Laar
for c=1:n
gama1(c)=10^(a12/((1+(x1(c)/x2(c))*(a12/a21))^2));
gama2(c)=10^(a21/((1+(x2(c)/x1(c))*(a21/a12))^2));
P(c)=x1(c)*Pvp1*gama1(c)+x2(c)*Pvp2*gama2(c);
y1(c)=(x1(c)*Pvp1*gama1(c))/P(c);
y2(c)=(x2(c)*Pvp2*gama2(c))/P(c);
end
disp('
x1
x2
Pvp1
Pvp2
gama1
gama2
P
y1
y2')
for c=1:length(x1)
fprintf('%10.2f %10.2f %10.2f %10.2f %10.2f %10.2f %10.2f %10.2f
%10.2f\n',x1(c),x2(c),Pvp1,Pvp2,gama1(c),gama2(c),P(c),y1(c),y2(c))
end
%datos experimentales:
xexp=[0.02240;0.03640;0.06880;0.09910;0.13620;0.17400;0.22850;0.24240;0.2
8340;0.36410;0.45900;0.56110;0.64460;0.65590;0.76840;0.77440;0.87150;0.92
430];
yexp=[0.08080;0.11320;0.18360;0.24560;0.30790;0.35580;0.41700;0.42400;0.4
6850;0.50900;0.56830;0.59780;0.66930;0.65860;0.73860;.72550;0.81260;0.877
40];
pexp=[145.999;151.497;158.000;164.998;176.002;183.997;191.498;191.498;200
.499;204.496;210.999;216.002;215.500;216.002;216.002;213.497;211.997;205.
996];%Presion experimental en mmHg=KPa*7.5006
disp('')
disp('Datos experimentales: ');
disp('====================================================');
disp(' x(1)
y(1)
P kPa ');
disp('====================================================');
disp([xexp yexp pexp])
%Grafica1: diagrama x1 vs y1
subplot(1,2,1),plot(x1,y1,'-m',xexp,yexp,'m*',x1,x1,'r');legend('Puntos
teoricos','Puntos experimentales',4)
grid on
title('Equilibrio Ethyl Acetate(1)-Ethanol(2)a 40C; Modelo Vaan Laar')
xlabel('X')
ylabel('Y')
%Grafica2: Diagrama x1,y1 vs P
subplot(1,2,2),plot(x1,P,'-gs',xexp,pexp,'gv',yexp,pexp,'ro',y1,P,'r');legend('Puntos teoricos P-X1','Puntos experimentales P-X1','Puntos
experimentales P-Y1','Puntos teoricos P-Y1',4)
grid on
title('Equilibrio Ethyl Acetate(1)-Ethanol(2)a 40C; Modelo Van Laar')
xlabel(' X,Y')
ylabel(' P mmHg ')
grid on

c. ECUACION WILSON
clc,clear all
disp('ALUMNA: Ore Payano Evelyn')
disp('ESCUELA: INGENIERIA QUIMICA AMBIENTAL')
disp('FECHA: 22-09-15')
T=40.35;
disp('Equilibrio Liquido - Vapor: Ethyl Acetate(1)-Ethanol(2)MODELO DE
WILSON')
disp('-----------------------------------------------------')
%Constantes de Antoine para Hallar el Pvp;(TABLA I)
%Ethyl Acetate
antA_1=7.09808;
antB_1=1238.71;
antC_1=217.0;
v1=95.3;
%Ethanol
antA_2=8.04494;
antB_2=1554.3;
antC_2=222.65;
v2=57.141;
%Fraccion molar del compuesto 1(Ethyl Acetate)
x1=[0 0.02 0.04 0.06 0.08 0.1 0.15 0.2 0.25 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.95 1];
x2=1-x1;n=length(x1);
%Determinacion de las presiones de vapor
Pvp1=10^((antA_1)-antB_1/(T+antC_1));
Pvp2=10^((antA_2)-antB_2/(T+antC_2));
%Modelo termodinamico de Wilson
%Parametros de Wilson para el equilibrio Ethyl Acetate-Ethanol(TABLA III)
I11=-62.43;%(a12-a11)
I21=822.03;%(a21-a22)
R=1.987;%cal/kmol
%Coeficientes de Actividad: lambda12 y lambda21
lambda12=(v2/v1)*exp(-(I11)/(R*(T+273.15)));
lambda21=(v1/v2)*exp(-(I21)/(R*(T+273.15)));
for c= 1:n
gama1(c)=exp(-log(x1(c)+lambda12*x2(c))+x2(c)*((lambda12/(x1(c)
+lambda12*x2(c))-(lambda21/(lambda21*x1(c)+x2(c))))));
gama2(c)=exp(-log(x2(c)+lambda21*x1(c))-x1(c)*((lambda12/(x1(c)
+lambda12*x2(c))-(lambda21/(lambda21*x1(c)+x2(c))))));
P(c)=x1(c)*Pvp1*gama1(c)+x2(c)*Pvp2*gama2(c);
y1(c)=x1(c)*gama1(c)*Pvp1/P(c);
y2(c)=x2(c)*gama2(c)*Pvp2/P(c);
end
disp('
x1
x2
Pvp1
Pvp2
Gama 1
Gama 2
P
y1
y2 ')
for c=1:length(x1)
fprintf('%10.6f %10.6f %10.6f %10.6f %10.6f %10.6f %10.6f %10.6f
%10.6f\n',x1(c),x2(c),Pvp1,Pvp2,gama1(c),gama2(c),P(c),y1(c),y2(c))
end

%Datos experimentales:
xexp=[0.02240;0.03640;0.06880;0.09910;0.13620;0.17400;0.22850;0.24240;0.2
8340;0.36410;0.45900;0.56110;0.64460;0.65590;0.76840;0.77440;0.87150;0.92
430];
yexp=[0.08080;0.11320;0.18360;0.24560;0.30790;0.35580;0.41700;0.42400;0.4
6850;0.50900;0.56830;0.59780;0.66930;0.65860;0.73860;.72550;0.81260;0.877
40];
pexp=[145.999;151.497;158.000;164.998;176.002;183.997;191.498;191.498;200
.499;204.496;210.999;216.002;215.500;216.002;216.002;213.497;211.997;205.
996];%Presion experimental en mmHg=KPa*7.5006
disp('')
disp('Datos experimentales: ');
disp('====================================================');
disp(' x(1)
y(1)
P (mmHg)');
disp('====================================================');
disp([xexp yexp pexp])
%Grafica1: diagrama x1 vs y1
subplot(1,2,1),plot(x1,y1,'-m',xexp,yexp,'m*',x1,x1,'r');legend('Puntos
teoricos','Puntos experimentales',4)
grid on
title('Equilibrio Ethyl Acetate(1)-Ethanol(2)a 40C; Modelo Wilson')
xlabel('X')
ylabel('Y')
%Grafica2: diagrama x1,y1 vs P
subplot(1,2,2),plot(x1,P,'gs',xexp,pexp,'bv',yexp,pexp,'ro',y1,P,'k');legend('Puntos teoricos PX1','Puntos experimentales P-X1','Puntos experimentales P-Y1','Puntos
teoricos P-Y1',4)
grid on
title('Equilibrio Ethyl Acetate(1)-Ethanol(2)a 40C; Modelo Wilson')
xlabel(' X,Y')
ylabel(' P mmHg ')
grid on

2.PROCESO ISOBARICO (P=CTE)

[SISTEMA BINARIO TETRACLORURO DE

CARBONO- BENCENO]
a. ECUACION MARGULES
clc
clear memory
%Presentado por: Ore Payano Evelyn
%Escuela: Ingenieria Quimica Ambiental
%Fecha: 22-09-15
%Programa para determinar el equilibrio entre el Carbon Terachoride(1)Acetone(2)
disp('===================================================================
==================')
disp('
Sistema de equilibrio Carbon Terachoride(1)Benzene(2)
')
disp('
Presin constante usando la Ecuacin de Margules
')
disp('===================================================================
==================')
%la presion a la que el sistema es isobarica (en mmHg)
P=760; %presion en mmHg
%Constantes de Antoine(TABLA I)
%Para el Carbon Terachoride:
A1=6.9339;
B1=1242.43;
C1=230;
%Para el Benzene:
A2=6.90565;
B2=1211.033;
C2=220.790;
%Parametros de Margules para el equilibrio Carbon Terachoride Y Benzene
A12=0.0488;
A21=0.0359;
%Valores de las fracciones molares
x1=[0 0.001 0.101 0.201 0.301 0.401 0.501 0.601 0.701 0.801 0.901];
x2=[1 0.999 0.899 0.799 0.699 0.599 0.499 0.399 0.299 0.199 0.099];
%Declarar a la temperatura una variable
syms T
%Calculo de las presiones de vapor
pvp1=10^(A1-B1/(C1+T));
pvp2=10^(A2-B2/(C2+T));
%Calculo de las temperaturas iniciales
Tv1=B1/(A1-log10(P))-C1;
Tv2=B2/(A2-log10(P))-C2;
for i= 1:11
gamma1(i)=10^((x2(i)^2)*(A12+2*x1(i)*(A21-A12)));
gamma2(i)=10^((x1(i)^2)*(A21+2*x2(i)*(A12-A21)));
y1(i)=x1(i)*gamma1(i)*pvp1/P;
y2(i)=x2(i)*gamma2(i)*pvp2/P;
end
%Determinacin de las temperaturas de equilibrio
disp('
T C
x1
y1
Gamma 1
Gamma 2');
disp('====================================================')
f=y1+y2-1;
for i = 1:11

xo=(Tv1+Tv2)/2;%valor inicial para la temperatura

e=10^-4;%criterio de convergencia
distancia=1;
while distancia > e
fxi=subs(f(i),sym('T'),xo);
derivada=diff(f(i),sym('T'));
Dxfxi=subs(derivada,sym('T'),xo);
x_1=single(xo-(fxi/Dxfxi));
distancia=single(abs(subs(f(i),sym('T'),x_1)));
xo=x_1;
end
Tm(i)=x_1;
t(i)=Tm(i);
Y1(i)=single(subs(y1(i),sym('T'),Tm(i)));
G1(i)=single(subs(gamma1(i),sym('T'),Tm(i)));
G2(i)=single(subs(gamma2(i),sym('T'),Tm(i)));
disp([t(i) x1(i) Y1(i) G1(i) G2(i)])
end
%grafica1: diagrama x1 vs y1
subplot(1,2,1),plot(x1,Y1,'-m',x1,x1,'r');legend('Puntos teoricos',1)
grid on
title('Equilibrio Carbon Terachoride(1) Benzene(2)a 760 mmHg; Modelo
Margules')
xlabel('X(Carbon Terachoride)[mol/mol]')
ylabel('Y(Carbon Terachoride)[mol/mol]')
subplot(1,2,2),plot(x1,t,'-b*',Y1,t,'m');legend('Puntos teoricos PX1','Puntos teoricos P-Y1',1)
grid on
title('Equilibrio Carbon Terachoride(1) Benzene(2)a 760 mmHg; Modelo
Margules')
xlabel(' X,Y(Carbon Terachoride)[mol/mol]
')
ylabel(' T C ')
grid on

b. ECUACION VAN LAAR

clc
clear memory
%Presentado por: Ore Payano Evelyn
%Escuela: Ingenieria Quimica Ambiental
%Fecha: 22-09-15
%Programa para determinar el equilibrio entre el Carbon Terachoride(1)%Acetone(2)
disp('===================================================================
==================')
disp('
Sistema de equilibrio Carbon Terachoride-Acetone
')
disp('
PROCESO ISOBARICO (P=CTE)- MODELO VAN LAAR
')
disp('===================================================================
==================')
%la presion a la que el sistema es isobarica (en mmHg)
P=760; %presion en mmHg
%Constantes de Antoine(TABLA I)
%Para el Carbon Terachoride:

A1=6.9339;
B1=1242.43;
C1=230;
%Para el Benzene:
A2=6.90565;
B2=1211.033;
C2=220.790;
%Parametros de Van Laar para el equilibrio Carbon Terachoride Y Benzene
(TABLA V)
A12=0.0509;
A21=0.0360;
%valores de las fracciones molares
x1=[0 0.001 0.101 0.201 0.301 0.401 0.501 0.601 0.701 0.801 0.901];
x2=[1 0.999 0.899 0.799 0.699 0.599 0.499 0.399 0.299 0.199 0.099];
%Declarar a la temperatura una variable
syms T
%Calculo de las presiones de vapor
pvp1=10^(A1-B1/(C1+T));
pvp2=10^(A2-B2/(C2+T));
%Calculo de las temperaturas iniciales
Tv1=B1/(A1-log10(P))-C1;
Tv2=B2/(A2-log10(P))-C2;
for i= 1:11
gamma1(i)=10^(A12/((1+(x1(i)*A12/(x2(i)*A21)))^2));
gamma2(i)=10^(A21/((1+(x2(i)*A21/(x1(i)*A12)))^2));
y1(i)=x1(i)*gamma1(i)*pvp1/P;
y2(i)=x2(i)*gamma2(i)*pvp2/P;
end
%Determinacin de las temperaturas de equilibrio
disp('
T ,C
x1
y1
Gamma 1
Gamma 2');
disp(' --------------------------------------------------')
f=y1+y2-1;
for i = 1:11
xo=(Tv1+Tv2)/2;%valor inicial para la temperatura
e=10^-4;%criterio de convergencia
distancia=1;
while distancia > e
fxi=subs(f(i),sym('T'),xo);
derivada=diff(f(i),sym('T'));
Dxfxi=subs(derivada,sym('T'),xo);
x_1=single(xo-(fxi/Dxfxi));
distancia=single(abs(subs(f(i),sym('T'),x_1)));
xo=x_1;
end
Tm(i)=x_1;
t(i)=Tm(i);
Y1(i)=single(subs(y1(i),sym('T'),Tm(i)));
G1(i)=single(subs(gamma1(i),sym('T'),Tm(i)));
G2(i)=single(subs(gamma2(i),sym('T'),Tm(i)));
disp([t(i) x1(i) Y1(i) G1(i) G2(i)])
end
%Grafica1: diagrama x1 vs y1
subplot(1,2,1),plot(x1,Y1,'-g',x1,x1,'k');legend('Puntos teoricos' ,1)
grid on
title('Equilibrio Carbon Terachoride(1)- Benzene(2)a 760 mmHg; Modelo Van
Laar')
xlabel('X(Carbon Terachoride)[mol/mol]')

ylabel('Y(Carbon Terachoride)[mol/mol]')
%Grafica1: diagrama x1,y1 vs T
subplot(1,2,2),plot(x1,t,'-k+',Y1,t,'r');legend('Puntos teoricos Px1','Puntos teoricos P-Y1',1)
grid on
title('Equilibrio Carbon Terachoride(1)- Benzene(2)a 760 mmHg; Modelo Van
Laar')
xlabel(' X,Y(Carbon Terachoride)[mol/mol]
')
ylabel(' T C ')
grid on

c. ECUACION WILSON
clc; clear memory
%Presentado por: Ore Payano Evelyn
%Escuela: Ingenieria Quimica Ambiental
%Fecha: 22-09-15
%Programa para determinar el equilibrio entre el Carbon Terachoride(1)Acetone(2)
disp('===================================================================
==================')
disp('
Sistema de equilibrio Carbon Terachoride(1)Benzene(2)
')
disp('
Presion constante usando la ecuacion de WILSON ')
disp('===================================================================
==================')
%la presion a la que el sistema es isobarica (en mmHg)
P=760; %presion en mmHg
%Constantes de Antoine y presiones de vapor
%Para el Carbon Tetrachoride:
A1=6.9339;
B1=1242.43;
C1=230;
v1=96.518;
%para el Acetone:
A2=7.02447;
B2=1161;
C2=224;
v2=86.783;
%parametros de Wilson para el equilibrio BENCENO Y 1-BUTANOL
l11=204.82;
l21=-103.41;
R=1.987;%cal/kmol
%Valores de las fracciones molares
x1=[0 0.001 0.101 0.201 0.301 0.401 0.501 0.601 0.701 0.801 0.901 0.999];
x2=[1 0.999 0.899 0.799 0.699 0.599 0.499 0.399 0.299 0.199 0.099 0.001];
%Declarar a la temperatura una variable
syms T
%Calculo de las presiones de vapor
pvp1=10^(A1-B1/(C1+T));
pvp2=10^(A2-B2/(C2+T));
%Calculo de las temperaturas iniciales
Tv1=B1/(A1-log10(P))-C1;

Tv2=B2/(A2-log10(P))-C2;
%Determinacion de las constantes para determinar los coeficientes de
actividad: lambda12 y lambda21
lambda12=(v2/v1)*exp(-(l11)/(R*(T+273.15)));
lambda21=(v1/v2)*exp(-(l21)/(R*(T+273.15)));
for i= 1:12
gamma1(i)=exp(-log(x1(i)+lambda12*x2(i))+x2(i)*(lambda12/(x1(i)
+lambda12*x2(i))-lambda21/(lambda21*x1(i)+x2(i))));
gamma2(i)=exp(-log(x2(i)+lambda21*x1(i))-x1(i)*(lambda12/(x1(i)
+lambda12*x2(i))-lambda21/(lambda21*x1(i)+x2(i))));
y1(i)=x1(i)*gamma1(i)*pvp1/P;
y2(i)=x2(i)*gamma2(i)*pvp2/P;
end
%Determinacin de las temperaturas de equilibrio
disp('
T ,C
x1
y1
Gamma 1
Gamma 2');
disp('====================================================')
f=y1+y2-1;
for i = 1:12
xo=(Tv1+Tv2)/2;%valor inicial para la temperatura
e=10^-4;%criterio de convergencia
distancia=1;
while distancia > e
fxi=subs(f(i),sym('T'),xo);
derivada=diff(f(i),sym('T'));
Dxfxi=subs(derivada,sym('T'),xo);
x_1=single(xo-(fxi/Dxfxi));
distancia=single(abs(subs(f(i),sym('T'),x_1)));
xo=x_1;
end
Tm(i)=x_1;
t(i)=Tm(i);
Y1(i)=single(subs(y1(i),sym('T'),Tm(i)));
G1(i)=single(subs(gamma1(i),sym('T'),Tm(i)));
G2(i)=single(subs(gamma2(i),sym('T'),Tm(i)));
disp([t(i) x1(i) Y1(i) G1(i) G2(i)])
end
%Grafica1: diagrama x1 vs y1
subplot(1,2,1),plot(x1,Y1,'-r',x1,x1,'m');legend('Puntos
teoricos','Puntos Teoricos',4)
grid on
title('Equilibrio Carbon Tetrachoride (1) Benzene(2) a 760 mmHg; Modelo
Wilson')
xlabel('X(Carbon Tetrachoride)[mol/mol]')
ylabel('Y(Carbon Tetrachoride)[mol/mol]')
%Grafica2: diagrama x1,y1 vs T
subplot(1,2,2),plot(x1,t,'-gs',Y1,t,'k');legend('Puntos teoricos PX1','Puntos teoricos P-Y1',4)
grid on
title('Equilibrio Carbon Tetrachoride (1) Benzene(2)a 760 mmHg; Modelo
Wilson')
xlabel(' X,Y(Carbon Tetrachoride)[mol/mol]
')
ylabel(' T C ')
grid on