Professional Documents
Culture Documents
Workshop
Virtual Sugarcane Biorefinery
Campinas August 13-14
Schematic process
Steam pretreatment Acid hydrolysis
Fermentation of all sugars (incl. Pentoses)
Simultaneous saccharification and fermentation (SSF)
Energy integration
Integration with other processes
Biomass
Pretreatment
Enzymatic
hydrolysis
Fermentation
Distillation
SSF
Lignin
Ethanol
Techno-Economic Evaluation
Aspen Plus
Experimental
data
Swedish
conditions
Production
cost (SEK/L)
Useful for
Sensitivity analysis
(solid content in SSF)
28
26
Salix
Corn stover
Spruce
24
22
20
18
16
14
12
10
7
10
11
12
13
14
15
6,50 kr
Salix
Corn stover
Spruce
6,00 kr
5,50 kr
5,00 kr
4,50 kr
4,00 kr
3,50 kr
7
10
11
12
13
14
15
Concentrations (g/L)
12 % Fibres
Fed-Batch SSF
50
45
40
35
30
25
20
15
10
5
0
Glucose
Ethanol
50
100
Time (h)
150
200
20% WIS
80
New reactor
70
60
15% WIS
50
40
Conventional
fermentor
10% WIS
30
20
10
0
0
24
48
72
Time (Hours)
96
120
144
2-step pretreatment
Experimental set-up
Raw material
Pretreatment
step 1
Pretreatment
step 2
solid
liquid
slurry
Fermentation
test
Enzymatic
hydrolysis
SSF
OS
TS+W
TS-W
Total
Mannose
Glucose
Total
Mannose
Glucose
Total
Mannose
Glucose
Comparison yields
100
Liquid
Solid
Total
80
60
40
20
Economic evaluation
Catalyst
HX2
Steam
HX6
Catalyst
77.0%
no flashing
No flashing
Cooling
noWIS
washing
50%
to 20C
50% WIS
HX1
Steam
HX5
HX3
HX7
HX4
Wood
To SSF
71.8%
First step
To SSF
HX8
74.6%
Optional second step
4.2
4.1
4.0
3.9
3.8
3.7
3.6
3.5
BC one-step
BC two-step
Worst case
The Process
Replacement of evaporation with Biogas production
Pellets
Steam
Raw material
SO2
Feedstock
handling
Pretreatment
Water &
base
Enzymes &
nutrients
Ethanol
Distillation
& dehydr.
Drying
Process
steam
Stillage
Wastewater
treatment
Excess
solids
Condensates
Evaporation
Liquid
fraction
Filtration
Concentrated liquid
Biogas (methane)
Pellet
production
Electricty
Steam &
electr. gen.
Steam
Raw material
SO2
Feedstock
handling
Water &
base
Pretreatment
Enzymes &
nutrients
Ethanol
Distillation
& dehydr.
Drying
Process
steam
Stillage
Wastewater
treatment
Excess
solids
Liquid
fraction
Pellet
production
Filtration
Electricty
Steam &
electr. gen.
The Process
Pellets
Raw material
Steam
SO2
Feedstock
handling
Water &
base
Pretreatment
Enzymes &
nutrients
Ethanol
Distillation
& dehydr.
Drying
Process
steam
Stillage
Excess
solids
Wastewater
treatment
Liquid
fraction
Filtration
Sludge
Biogas
Biogas
upgrading
Vehicle
fuel
Pellet
production
Electricty
Steam &
electr. gen.
4.50
4.27 kr
MESP (SEK/L)
4.00
3.42 kr
3.50
3.00
2.50
2.00
1.50
1.00
0.50
0.00
Base case
No Evap - Pellets
No Evap - Biogas
Biogas production
Two key issues:
-
Biogas conversion:
-
Sludge handling:
-
Recirculation of process
streams in SSF
4,80
4,60
Maximum
Experimental value
4,40
Before
After
4,20
4,00
3,80
0
20
40
60
% recycling of stream
80
Steam
Raw material
SO2
Feedstock
handling
Pretreatment
Water &
base
Enzymes &
nutrients
Ethanol
Distillation
& dehydr.
Drying
Process
steam
Stillage
Wastewater
treatment
Excess
solids
Condensates
Evaporation
Liquid
fraction
Filtration
Concentrated liquid
Biogas (methane)
Pellet
production
Steam
generation
No pellet production
Pellets
Steam
Raw material
SO2
Feedstock
handling
Pretreatment
Water &
base
Enzymes &
nutrients
Ethanol
Distillation
& dehydr.
Drying
Process
steam
Stillage
Wastewater
treatment
Excess
solids
Condensates
Evaporation
Liquid
fraction
Filtration
Concentrated liquid
Biogas (methane)
Pellet
production
Electricty
Steam &
electr. gen.
5 Scenarios
Ethanol
Pellets
Electricity
District heating
BC: base case
LO: lower yield
HI: higher yield
A
X
X
B
X
X
C
X
X
X
D
X
E
X
X
X
X
X
Energy efficiency
100%
92%
76%
80%
60%
70%
70%
70%
Heat
Electricity
Pellets
Ethanol
53%
50%
40%
30%
20%
10%
0%
LO
BC
HI
WIS
HI&WIS
LO
BC
HI
WIS
HI&WIS
LO
BC
HI
WIS
HI&WIS
LO
BC
HI
WIS
HI&WIS
LO
BC
HI
WIS
HI&WIS
Energy efficiencyLHV
90%
4.73
4.65
4.56
4.40
4.20
4.20
4.00
3.87
3.80
3.60
3.40
3.20
3.00
LO
BC
HI
WIS
HI&WIS
LO
BC
HI
WIS
HI&WIS
LO
BC
HI
WIS
HI&WIS
LO
BC
HI
WIS
HI&WIS
LO
BC
HI
WIS
HI&WIS
MESP (SEK/L)
4.60
MESP (kr/L)
5,25
5,00
4,75
4,50
4,25
4,00
3,75
3,50
3,25
3,00
100
120
140
160
180
200
MESP (kr/L)
4,50
A
B
4,25
4,00
3,75
3,50
3,25
3,00
200
250
300
350
400
450
500
MESP (kr/L)
4,50
A
B
4,25
4,00
3,75
3,50
3,25
3,00
100
150
200
250
300
Raw
material
Enzymes
Wat er
Liquefaction
Enzymes
Yeast
Saccharification
Fermentation
Ethanol
Distillation
Solid material
Centrifugation
SSF
Liquid
1
Steam
Raw
material
Pretreatment
Wat er
Enzymes
Yeast
Enzymatic
hydrolysis
Fermentation
Ethanol
Distillation
Solid material
Filtration
SSF
Solid material
Liquid
Yield
92%
50
40
30
5% straw
81%
20
10
0
0
20
40
60
Time [hour]
80
100
Powerful tool
Assessment of improvements
What if - studies
Sensitivity analysis
Give guidelines for experimental work
Give data for LCA
Basic data for process design