1. Which of the following is chiral in nature?

(a) CH3CH(OH)CH3
(b) CH3CH(OH)C2H5 (c) CH3CH2OH
2. Relative stabilities of the following carbocation will be in order

(a)

I < II < III < IV

(b)

IV > III < II < I

(c)

IV < II < III < I

3. Which is dehydrated to a maximum extent using conc.

H 2 S O4 ?

(a)

(d)

(b)

(c)

(d) CH3CH(OCH3)CH3

(d)

II < IV < III < I

4. Most stable free radical is

(a)

(b)

(c)

(d)

S N 2 reaction rate

5. Arrange these compounds in order of increasing

(a)

III < I < II< IV

(b)

III < II < IIV

(c)

IV > II < III < I

(b)

I < II < III < IV

7. Most stable carbocation

(a)

8.

C H 2= CH

(d) none is correct

S N 1 reaction rate

6. Arrange these compounds in order of increasing

(a)

IV < III < I < II

(c)

IV < I < III < II

(d)

IV < I < II< III

is

(b)

(c)

C H 3 CH (C H 3) CH =C H 2+ HBr A , A

(d)

(predominant) is

(C H 3 ) C

(a)

(b)

(c)

(d) None is correct

9. Stability of following alkenes in the increasing order

is

(a)

I < III < IV < II

(b)

I < II < III < IV

(c)

IV < III < II < I

(d)

II < III < IV < I

I < III < IV < II

(d)

I < IV < II< III

10. Dehydration of the following in increasing order is

(a)

I < II < III < IV

(b)

11. Dehydrobromination

(a)

I < II < III

II < III < IV < I

(c)

(HBr) of the following in increasing order is

(b)

III < II < I

(c)

I =II < III

(d)

III < I =II

12. Increasing order of basic nature of

N H 3 ( I ) , C H 3 N H 2 ( II ) and (III ) is
(a)

III < II < I

(b)

I < II < III

(c)

III=II < I

(d)

III < I < II

13. Increasing order of the

(a)

I < II < III

(b)

III < II < I

I < III < II

14. Electrophile

N O2 attacks the following

following for

(c)

II < III < I

SE

reaction is

(d)

In which Cases

N O2 will be at meta-position?

(a) II and IV

(b) I, II and III

(c) II and III

C H 3 C H 2 C H 2 C H 2 Cl ,
15.
C H 3 C H 2 CHC H 3 ,

(d) I only

C H 3 CHC H 2 Cl

I
Increasing tendency for

S N 1 and S N 2 reaction is

( A ) S N 1 : I < III < II< IV

(a) A and B both are correct

( B ) S N 2: IV < II < III < I

(b) only A is correct

16. Increasing values of dissociation constant

(c) only B is correct

(d) Both are incorrect

K a of C H 3 COOH ( I ) , HCOOH (II ) and

C6 H 5 COOH (III ) are

(a)

I < II < III

(b)

III < II < I

(c)

I < III < II

(d)

II < III < I

17. Consider the following compounds:

I:
IV :

C H 2 C H 2 OH ,

II :

C H 3 C H 2 OH

III :

C H 3 CHOH

C H 2 C H 2 OH

|
|
|
F
F
Cl
Which one of the following is the correct order of acidic strength for the compounds given above?
(a)

IV > III > I > II

(b)

II > I > IV > III

(c)

II > IV > I > III

(d)

III > I > IV > II

18. Which one of the following compounds undergoes predominantly

NaOH

S N 2 reaction with aqueous

in polar aprotic solvents?

(a) (b) (c) (d)

19. Acid catalysed dehydration reaction of 2-methyl-1-butanol yields which one of the following?
(a) 2-methyl-1-butene

(b) 2-methyl-2-butene (c) A mixture of (a) and (b)

(d) None of these

20. Which of the following species does not exert a resonance effect?

C6 H 5 N H 2
(a)
C6 H 5 Cl

+ N H 3
(b) C6 H 5

(c)

C6 H 5 OH

(d)