Professional Documents
Culture Documents
Available at www.sciencedirect.com
http://www.elsevier.com/locate/biombioe
Review
ab st rac t
Article history:
Emissions of greenhouse gases such as CO2, CO, CH4 and NOX from fossil fuel use are
implicated in climate change. The use of bioethanol is one means to reduce fossil fuel
use and emissions of greenhouse gases. This study investigated research to produce
ethanol from sugar beet and use as fuel in Turkey. The calculated demand for bioethanol
Keywords:
Sugar beet
Ethanol
amounted to some 220,000 m3 where a 5% ethanol mix in petrol was used. Turkey has the
potential to produce 30 million ton of sugar beet, which is sufficient to meet the bioethanol
demand.
& 2008 Elsevier Ltd. All rights reserved.
Bioenergy
Contents
1.
2.
3.
4.
1.
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Material and method. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.1. Material . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.2. Method . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Introduction
1
2
2
3
4
6
7
Please cite this article as: Ic- oz E, Mehmet Tugrul K, Saral A, Ic- oz E. Research on ethanol production and use from sugar beet in Turkey.
Biomass and Bioenergy (2008), doi:10.1016/j.biombioe.2008.05.005
ARTICLE IN PRESS
2
] (]]]]) ] ]] ]]]
Rate (%)
2000
Rate (%)
2001
Rate (%)
Petroleum
Lignite
Hard coal
Natural gas
Hydro
No commerce
Other
23.901
9.765
6.15
3.11
1.991
7.208
0.862
45.11
18.43
11.61
5.87
3.76
13.60
1.63
32.297
13.219
9.983
13.729
2.656
6.457
2.91
39.75
16.27
12.29
16.90
3.27
7.95
3.58
30.936
11.929
7.06
14.868
2.065
6.211
2.883
40.73
15.71
9.30
19.58
2.72
8.18
3.80
Total
52.987
100.00
81.251
100.00
75.952
100.00
Gasoline
Ethanol
Chemical formula
CnH2n+2 (n:
412)
100105
C2H5OH
8588
1215
0
0.720.78
0.7190.779
44.4242.5
8694
22.2
275
350
52.2
13.1
34.7
0.796
0.792
95.5
100
96.1
440
920
45,60043,000
14.7
29,80026,800
9.0
Molecular weight
Composition, weight (%)
Carbon
Hydrogen
Oxygen
Specific gravity (33 1C)
Density (kg l1) (33 1C)
Boiling temperature (1C)
Octane number ((R+M) 21)
Freezing point (1C)
Autoignition temperature (1C)
Latent heat of vaporization
(kJ kg133 1C)
Heating value (kJ kg1)
Stoichiometric air fuel1,
weight
46.07
2.
2.1.
Material
Please cite this article as: Ic- oz E, Mehmet Tugrul K, Saral A, Ic- oz E. Research on ethanol production and use from sugar beet in Turkey.
Biomass and Bioenergy (2008), doi:10.1016/j.biombioe.2008.05.005
ARTICLE IN PRESS
BIOMASS AND BIOENERGY
Spain
Sweden
USA
Brazil
Production
amount in
2001 (m3)
0.115 106
0.100 106
0.050 106
8 106
12 106
Application
type
Mixed up in gasoline as
15% ETBE form
Mixed up in
gasoline as
15% ETBE
form
Mixed up in
gasoline as
5%
Barley and
wheat at 100%
Wheat at
100%
400450 h m3
400-450 h m3
550650 h m3
200250 h m3
Tax
exemption for
five years
Tax
exemption
for 50,000 m3
per year
Many supports of
government (price,
quantity and
subvention)
Planning 125,000 m3
additional capacity
increase
Planning
doubled
capacity
increase
No planning
Using raw
material
Ethanol
price
Incentive
pay
Future
expectation
Sugar beet
Wheat
Triticale
Rye
Corn
Potatoes
27.8
61.7
47 A, 29 B, 17 Ca
6.62
0.11
19,806
155,570
21.4
7.2
118
2.76
0.38
25,142
64,860
4.1
5.6
100
2.23
0.40
15,554
52,405
4.1
4.9
95
2.03
0.41
15,554
47,705
3.3
9.2
123
3.52
0.38
21,184
82,720
13.1
43
63
3.55
0.08
34,403
83,425
2000 for Germany are given in Table 4 [5]. Ethanol yield and
total energy yield is highest with sugar beet.
Sugar beet is grown under contract, one of the first examples
of contracted growing in Turkey. Sugar beet integrates agriculture with industry and has an important indirect added value
role on many sectors, by providing employment.
Sugar beet is generally grown in the high-altitude region and
irrigated grain sowing area on 4 years rotation. There are
450,000 growers in 65 cities in Turkey except for Aegean,
Mediterranean coast zone, Eastern Black Sea and Southern East
Anatolia Region. Per capita average sowing area is 0.7 ha, and
81% of growers have less than 1 ha according to 2003 data [12].
There are 30 sugar factories; 26 of which belong to the
government and 4 are privately owned. Daily beet-processing
capacity 131,000 ton; the amount produced between 1997 and
2003 is given in Table 5. Turkey has the potential to produce 30
million ton of sugar beet annually. However, because of the
quota and cornstarch-based sugar production, only half of the
potential is actually produced.
Sowing area
(1000 ha)
Production
amount (1000 ton)
Yield
(ton ha1)
1997
1998
1999
2000
2001
2002
2003
473
504
424
410
359
372
315
18,770
22,503
17,207
19,189
12,839
16,940
13,726
42.3
48.1
45.4
50.9
35.5
49.5
44.1
2.2.
Method
2CO2
2C2 H5 OH
Carbon dioxide
Ethanol
Please cite this article as: Ic- oz E, Mehmet Tugrul K, Saral A, Ic- oz E. Research on ethanol production and use from sugar beet in Turkey.
Biomass and Bioenergy (2008), doi:10.1016/j.biombioe.2008.05.005
ARTICLE IN PRESS
4
2C6 H12 O6
Monosaccharide-fructoseglucose
] (]]]]) ] ]] ]]]
Bioethanol will be used in mixtures of 25%. Petrol consumption in Turkey for the last 5 years is given in Table 6 [14];
approximately 4.1 million ton were used in 2002. The amount
of sugar beet to produce the ethanol required to match that
demand was calculated according to Fig. 2.
3.
Results
ARTICLE IN PRESS
5
669 kg soil,
49 kg stones
Weeds and waste water
25.996 kg
Pulp
1.251 kg
Animal feed
(85 % dry matter)
Waste water
Euro /l
SC
MC
LC
VLC
1.80
1.60
1.40
1.20
1.00
0.80
0.60
0.40
0.20
0.00
Rye
Triticale
Corn
1998
1999
2000
2001
2002
Normal petrol
Super petrol
Unleaded petrol
2.9
2.0
1.1
2.3
2.0
1.5
1.6
1.4
1.9
1.2
1.0
2.1
0.6
1.2
2.3
Total
6.0
5.8
4.9
4.3
4.1
Potato
Mixture
rate
2%
5%
Ethanol
requirement
(m3)
Unit
investment
cost (Euro
l1)
Investment
amount
(million Euro)
88,000
220,000
0.77
0.77
67.8
169.4
Please cite this article as: Ic- oz E, Mehmet Tugrul K, Saral A, Ic- oz E. Research on ethanol production and use from sugar beet in Turkey.
Biomass and Bioenergy (2008), doi:10.1016/j.biombioe.2008.05.005
ARTICLE IN PRESS
6
] (]]]]) ] ]] ]]]
Mixture rate
2%
5%
Large capacity
(360 m3 day1)
4
11
1
4
1
2
88,000
220,000
1.56
8.55
1.41
Ethanol Cost ($ l-1)
Small capacity
(60 m3 day1)
1.26
6.84
1.09
5.98
0.94
5.13
0.79
4.
3.42
0.47
2.56
1.00
2.00
7.00
8.00
9.00
100%
Discussion
4.27
0.62
0.00
7.69
Frachise Profit
Frachise Profit
Transportation
80%
SCT + VAD
60%
SCT + VAD
40%
Product Cost
20%
Product Cost
0%
Petrol
Ethanol
Fig. 5
Please cite this article as: Ic- oz E, Mehmet Tugrul K, Saral A, Ic- oz E. Research on ethanol production and use from sugar beet in Turkey.
Biomass and Bioenergy (2008), doi:10.1016/j.biombioe.2008.05.005
ARTICLE IN PRESS
BIOMASS AND BIOENERGY
Please cite this article as: Ic- oz E, Mehmet Tugrul K, Saral A, Ic- oz E. Research on ethanol production and use from sugar beet in Turkey.
Biomass and Bioenergy (2008), doi:10.1016/j.biombioe.2008.05.005