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M. R. FENSKE ETAL
3,086,852
3 Sheets-Sheet 1
IO
35
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PRODUCT
FIGURE 1
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33
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OXYGEN 0R
HYDROGEN GAS
I
"
20
<
46
47
MERRELL. R _ FENsKE
LF t
VAPOR
BY
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M
ATTORNEY
M. R. FENSKE ETAL
3,086,852
3 Sheets-Sheet 2
FIGURE 2
MERRELL. R. FENSKE
JENNlNGs H. JONES
BY
INVENTOR.
ATTORNEY
M. R. FENSKE ETAL
3,086,852
2'0
3 Sheets-Sheet 3
20l
2l4
2n
209
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2l9
T
ZONE
D
FIGURE 3
MERRELL R. F'ENSKE
JENNINGS H. JONES INVENTORS
BY
35?
ATTORNEY
1 ,.
ICC
3,086,852
2
above the other in alternate fashionso'that'in an inter
3,086,852
catalyst zone.
provided to prevent the reaction from slowing down, 35 one group of heatlcarrier solids remains in'one area of
stances.
in vhorizontal rows.
3,086,852
TABLE 1
Material
Particle
Density
Settled
Fraction
Bed
Density
Free Space
(Settle
Free Fall
Velocity 1
Fluidization
Velocity 1*
Heat of
Pattl'clep"
Bed)
(Ft/Sec.)
(Ft/Sec.)
11131.21]?
Speci?c
.,
lg?mrogmieresxn
ass p eres.__
35
63
34
o. 47
0. 12
0. 18
104
62
170
so
1394
0.38
0. 46
0.2.05
8.. 3g
Alumina (A1203)
Glass Spheres _________ __
30s
125
230
176
114
110
0. 51
0.38
8.0
3. 0
Altflm?eiif?
V81 it" a
0.20
Carbon Granules-.-
550
as
32
0. 49
7. 5
e Y
0.18
____
600
176
110
0. 38
15
0. 20
1, 200 to
63
33
0. 48
21
0. 18
0. 18
2, 400
1 At 70 F. and 750 mm. Hg in air.
2 These velocgieg are near the minimum values required for incipient ?uidization with air at 70 F. and 750 mm. Hg.
3 20 C. to 10
freely falling, the reaction space between the ?xed clusters 30 This level is kept substantially ?xed by introducing a
small amount of inert gas continuously into these pipes.
may still be 90% or more voids.
The difference in gas pressure between pipes 34 and 35
A cross-sectional elevation view of a preferred ap
is proportional to the depth of solids in bed 6. If the
paratus for carrying out these catalytic conversions is
bed'exceeds the desired depth, the increased gas pressure
shown in FIGURE 1. FIGURE 2 is an enlargement of
a portion of the interior of the reaction vessel depicted 35 in pipe 34 operates a pilot valve which in turn operates
conventional pneumatic or hydraulic cylinder, not shown,
in FIGURE 1 with added detail to show how the down
attached to the upper end of valves 8 to move them up
?owing solids are contacted with the up?owing gaseous
and down.
.
reactants in the spaces between ?xed catalyst surfaces.
Oxygen in the case of oxidation, or hydrogen in the
The reactor in FIGURE 1 is a vertical cylindrical shell
1 with an expanded top 2 fabricated to withstand tem 40 case of dehydrogenation, enters pipes 33 which are placed
from 1 to 5 feet apart along the vertical length of the
peratures up to about 1000" and pressures up to about
5
tion into reaction chamber 1 via lines 18, 19 and 20.
The feed ?owing through lines 19 and 20 is introduced
into the reactor essentially as a liquid at or near its boil
E5
pump 17 is used to heat or cool and transport the lift
vapors which are inert gases such as nitrogen or vsteam.
Heat exchanger 29 heats the vapors in the case of
endothermic reactions so that their temperature in line
50 is about 100 to 400 F. above that in line 48. In
pass out line 32. Valve 49 is open, and [after the vapors
desirably ?ared at the bottom to facilitate the in?ow of
have been heated, cooled, or condensed, they pass through
?uidized solids at its base. The feedstock emerging from 10 line50, pump 17, and into lift pipe 23 via lines 18, 19
nozzle 22, partly in liquid and partly in vapor form, lifts
and coil 21. Any liquid entering via lines 19 and 22 is
the hot solids from bed 7 up through pipe 23 while the
vaporized by contact with the hot ?uidized solids. Some
hydrocarbon vaporization cools bed 7 and transports more 55 The catalyst in bed 206 may be in the form of regular
shapes such as cylinders, rods, or spheres, or it may be
solids into .bed 6. This serves to increase the amount of
in irregular shapes such as those formed by crushing.
solids per unit time and per unit of feed that rains down
through catalyst zone 13. In operation, the rising vapors
The size and arrangement of the ?xed bed is such that
at least in part ,pass through the catalyst clusters 41,
there is good gas-solids contacting with a minimum of
diverted by shield 40 the vapors then pass into the tem 60 pressure drop through bed 206.
perature control zone at 42. The amount of vapors pass
duced via pipe 44 into line 27. Valve 26 closes off line
3,086,852
8
zone E for chemical transformations.
In the case of an
This process
before.
If desired, additional quantities of one or more of the
tains a combustible component, then air or oxygen may 25 tions set forth since numerous modi?cations and alterna
14 and then proceeds through tank 15, line 16, valve 51,
reactor 200.
and 20.
into the desired products, if a dense bed of particulate 65 The Vapor Phase Dehydrogenation of Hydrocarbons
solids is con?ned above grid 202.
This example along with the following three illustrate
If a dense bed of solids is not maintained above grid
the second embodiment of the invention. Naphthenes
202, the vapors pass up through space 203, through grid
for dehydrogenation such as cyclohexane and methylcy
202, into space 201 and out via opening 210. In this
clohexane enter at line 44, FIG. 1. Part of the hydrogen
case the vapors mix with the lift gases used in pipe 214. 70 gas enters with the hydrocarbon at 44, the remainder being
Openings 211 and '219 are closed.
piped in through line 47. The products which are aro
In the co-current operation, a dense bed of solids is
matics such as benzene and toluene pass out through line
maintained above grid 202 of such a depth that the
4- to a recovery system. Since this reaction is endo
thermic, heat exchanger 29 is used to heat inert gases
vapors to undergo reaction, and which are introduced
via opening 211, are forced to pass downward through 75 such as steam or nitrogen so that their temperature in
3,086,852
10
inert gases ?ow through line 50, valve 49, pump 17, valve
43, line 19, and up through nozzle 22 and lift pipe 23
wherein they heat and lift the solids {from bed 7 to bed 6.
The solids can be fused alumina, quartz, sand or dense
carbon from about 100~500 microns in size. They may
also have catalytic properties such as magnesium or
EXAMPLE 5
25
EXAMPLE 6
EXAMPLE 3
27.
EXAMPLE 7
3,086,852
11
12
reaction zone, and ba?les which cover and Support the cata
molybdate.
These ?owing solids must have reasonably good me
chanical strength and resistance to attrition. The amounts
circulated range from about 3 to 30 pounds per pound of
naphtha feed.
'In the lowest zone H, the naphtha and hydrogen are
203, up through open grids 202, through space 201 and 25 ba?les while falling through said channels, said catalyst
exit via opening 210 to flow to a suitable recovery unit
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937,103