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PhysicochemicalPropertiesEvonikisoneoftheworld'slargestproducersofhydrogenperoxideH2O2
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Physicochemical Properties
Hydrogen peroxide (H2O2) is a colorless watersoluble liquid. The molecule of hydrogen peroxide is asymmetrical and
strongly polarized. A high tendency to form hydrogenbond networks causes higher viscosity than water. Because of
free electron pairs on both oxygen atoms, the H2O2molecule tends to form donoracceptor compounds. Pure hydrogen
peroxide is primarily of scientific interest only. Its aqueous solutions, however, are widely used in many industrial
branches for various applications. Important physical properties of hydrogen peroxide and its aqueous solutions as
summarized in the table on the left side.
The molecular structure as well as oxygen's oxidation state define the chemical properties of hydrogen peroxide. The oxygen
atom, being in the oxidation state I, allows hydrogen peroxide to participate in both oxidation as well as reduction reactions.
Although hydrogen peroxide is well known as a strong oxidizing agent, its reduction properties play an important role in
some applications. Typical chemical reactions, in which hydrogen peroxide is involved, are oxidation and reduction
reactions, formations of other peroxygen or adduct compounds. In contrast to many other redox agents, hydrogen peroxide
introduces no additional substances other than water into the reaction system and an excess can be easily decomposed into
water and oxygen, not interfering thereby with subsequent reaction steps. Hydrogen peroxide is often regarded as a true
"green chemical".
Despite its high reactivity, pure hydrogen peroxide is a stable substance and, if kept under optimal conditions, can be stored
for years. The most important factors increasing the rate of decomposition are high pH value, high temperatures, UV
irradiation, presence of transition metal salts and all kinds of impurities.
The decomposition of hydrogen peroxide into oxygen and water is a quite complex process, which involves formation of
various free radicals. In some applications (soil remediation) the induced instability is intentionally caused and used.
%(wt.)
30
35
50
60
70
100
g(H2O2) /
kg
300
350
500
600
700
g(H2O2) /
l
332
395
596
742
899
mol/ l
l 9,8
11,6
17,5
21,8
26,4
mol%
18,5
22,2
34,6
44,3
55,3
%(wt.)
14,1
16,5
23,5
28,2
32,9
47,1
g/mol
18,015
34,015
g/ml
0,998
1,111
1,131
1,195
1,241
1,289
1,450
26
33
52
56
40
0,4
100
106
108
114
119
125
150
132
135
145
152
158
147
150
161
168
176
mbar
42
33
32
24
19
15
mm. Hg.
31,6
25
24
18
14
11
HO partial vapor
mbar
0,3
0,4
0,8
1,2
1,7
pressure at 30 C
mm. Hg.
0,25
0,3
0,6
0,9
1,3
J*g/K
4,2
3,6
3,5
3,3
3,2
3,1
2,6
Active oxygen
content
Molecular weight
Density at 20 C
Freezing point
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PhysicochemicalPropertiesEvonikisoneoftheworld'slargestproducersofhydrogenperoxideH2O2
Refractive index,
n25D at 25C
1,3325
1,3519
1,3554
1,3661
1,3734
1,3814
1,4067
mPa*s
1,00
1,11
1,12
1,18
1,21
1,23
1,25
mN/m
72,8
74,2
74,5
75,7
76,4
77,3
80,4
Viscosity at 20C
Surface tension at
20C
1) The tabulated values, which are given above, describe physicochemical properties of salt free
pure aqueous solutions of hydrogen peroxide in water.
2) Hydrogen peroxide concentration can be expressed in weight percent, gram of 100%age hydrogen
peroxide in 1 kg solution, gram of 100%age hydrogen peroxide in 1L solution and as molar
concentration or molar fraction of hydrogen peroxide in solution. The tabulated values for g(H2O2)/l
and mol/l are given for the temperature of 25C.
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