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ABSTRACT
The most important environmental Impediments at the present time is the accumulation of glass waste (transparent glass
bottles) many experiments and researches have been made on waste and recycling to get use of it as much as possible. this
research study recycling of colorless glass waste and turn them into raw materials alternative for cement to save the
environment from glass waste and reduce some of the disadvantages of cement and its interactions with conserving the
mechanical and physical properties of concrete.This research include recycling of colorless glass bottle which is locally used
and turn them into a fine powder to be replaced by a certain percentages of cement. A set of required samples were prepared for
mechanical tests at a rate of ten samples for different weight percentage which is (2% ,4% ,5% ,6% ,8% ,10% ,15% ,20% ,25%) .
Three point bending was measured to American standard for calibration (ASTM C133-97) to measure the results showed that
the highest Maximum applied of rupture is at the low ratios 2% ,4% ,5% which is (280.52, 233.49, 277.20) KN respectively for
indigenous mix recorded bending resistance (272.60) KN.
1.INTRODUCTION
Cement (cement Portland )is ceramic materials [1] The importance of ceramic materials in the possession of a high
melting points and good mechanical properties and chemical and the provide first-hand in most parts of the world
[2,3].The most important hydraulic cement used extensively in various types of construction , as mortars , plasters
grouting and concrete . The Portland cement mainly as calcium silicates and aluminates and even smaller quantities of
potassium and sodium oxide may also be present [4]. Cement is one of the most cost and energy intensive components
of concrete. Across the world, significant environmental problems result from the manufacture of Portland cement. [5].
The heat produced by the hydration of cement may prevent freezing of the water in the capillaries of freshly placed
concrete in cold weather, and a high evolution of heat is therefore advantageous[6]. Many of the world suffer from the
problem of the accumulation of industrial waste and special waste resulting from the concentration of defective material
Or because of consumer use, such as broken glass and causing other environmental and health problems that require
the development of practical solutions to get rid of them through the re-use or by taking advantage of them partial
substitute for some construction materials (cement, sand,) involved in asphalt or concrete admixtures[7,8,9,10]. The
reuse of waste glass is one of the most important issues around the world due to the increase of solid wastes in the
landfill and non-degradable nature of its disposal. The use of recycled waste glass in concrete has attracted much
interest worldwide and numerous researches have been carried out, showing the possibility of use of waste glass as
building materials by partially replacing concrete mixtures (Shi and Zheng 2007)[11]. The glass powder pozzolanic of
materials that can be added to concrete or mortar (pozzolanic material) or cement paste. pozzolanic and materials are
natural materials or industrial contain the active silica (amorphous) and which are the Association of properties when
they interact with calcium presence of water and varying unusual heat hydroxide, (Ca (OH)2) and calcium hydroxide is
one of the outputs of the process of cement interaction with water Shown in the Figure (1).
Figure 1Schematic representation of the formation and hydration of Portland cement [6].
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2.THREE-POINT BENDING
The stress at fracture using this flexure test is known as the flexural strength, modulus of rupture, fracture strength or
bend strength are an important mechanical parameter for brittle ceramics. For a rectangular cross section, the flexural
strength fs is equal to [12].
fs = 3PL/2bd2(1)
where
P: is the load (force) at the fracture point
L: is the length of the support (outer) span
b: is width
d: is thickness
3.Experimental work
3.1Raw materials
3.1.1Cement
Iraq ordinary Portland cement, commercially known as (TASLUJA) It was stored in dry place to minimize the effect of
humidity on cement properties.
Examination particle size the Mastersizer 2000 laser diffraction particle size analyzer delivers rapid. The diameter
from (5.344 m- 57.822 m)as shown in figure (2)
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Table (2) Potential composition result for Portland cement (Bogues equations)[13]
C3S
39.99
C2S
39.33
C3A
2.286
C4AF
7.945
% Passing by
Weight
100
Specification Limit[15]
4.75
93.2
90-100
2.36
84.2
75-100
1.18
68.0
55-90
0.60
37.8
35-59
0.30
19.6
8-30
0.15
8.8
0-10
100
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Chemical analysis
The used Glass was analyzed according to ASTM C618, and The result showed a good agreement with standard values
of element as shown in table (5).
Table (5): - Chemical composition of glass powder
Element
Content %
stander %[16]
SO3
0.7%
---
Na2O
13.626%
12-15%
Fe2O3
1.321%
---
SiO2
72.52%
73%
CaO
7.21%
10%
K2O
0.227%
---
MgO
2.208%
---
AL2O3
1.75%
---
L.O.I
0.347%
---
3.1.4 Water
Ordinary Tap water ofthe drinking net was used for all concrete admixtures according to (IQS 1992/1703 ).
4.SAMPLE
PREPARATION
The molds were made out of wood according to ASTM C133-97 standar, the volume of the samples are as shown in
table (6)
Table (6) for used molds
The weight percentages Mixing of the components of concrete cement, sand and water (1:2.75:0.485) respectively
according to ASTM C109/C109M . The details and proportions of mixes are shown in Table (7).
In order to achieve what it takes to search the mixes were divided into two sets as follows:
At first the Controled mix where prepared is composed of cement ,water and natural sand.
9 mixes that are and them composed of cement , natural sand and fine waste glass as a partial substitute of cement in
weight percentages of 2, 4, 5, 6, 8, 10, 15, 20, 25 %. The weight percentage of replacement glass was add to cement
and then mixed with cement , sand and water.
Mixing process was carried out by using 0.1 m3 rotary type mixer for all mixes. To prepare the first set of the controlled
mix, the sand and cement were initially mixed for 2-5 minutes, then the required amount of water was added with
mixing for additional 2 minutes until achieving a homogenous mixture. For preparing fine aggregate substitution
mixes, the fine glass aggregate with differentweightpercentage was mixed with cement before adding it to the mixer.
Finally, the mixed cement and glass were added and mixed for 10 minutes until achieving a homogeneous mixture.
To prepare samples with dimension as shown in table (2-7)all the molds were cleaned and thoroughly oiled before
casting. A vibrating table was used for a sufficient period to extract the air voids. The top surfaces of the molds were
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leveled and covered with nylon sheets to prevent evaporation. All samples surfaces were cleaned and polish as show in
figure (5)and Scheme 2 show Stages of sample .
Table (7): - Descriptions of Investigated Mixes
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Table (8) three point bending results for cement mortar samples
7. CONCLUSION
Depending on the results obtained from the production of glass concrete and study some properties Compared with the
results of the control concrete (C) can be concluded the following:
1.Possible to produce concrete replacement of part of the cement waste glass powder after grinding to the asymptotic
size of the cement.
2.The results showed that the replacement of part of the cement powder glass gives strength to bending greater or the
nearest strength to the control mixture (C) compared with other weight percentage .
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3.In economic terms it would prefer to take advantage of waste glass to return of use in concrete with good production
properties.
REFERENCES
[1]
[2]
[3]
[4]
[5]
[6]
[7]
AUTHOR
Mustafa A. Mahmoud((born in Baghdad in December,1990). Received a B.Sc (2013) in physics department\
collage of science\university of Baghdad and now she is student, she is publishing this paper as a required part
to get MSc in material physics from Baghdad university
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