Professional Documents
Culture Documents
OF
LAKE
SUPERIOR
CHARLES KENNETH
IRON
ORES2
LEITH.
: The iron-oresof the Lake Superior region occur as concentrations in "iron-formations," ranging from a few hundred to
I,OOO feet or more in thickness.
the more important. In the Crystal Falls district the ironformation is in both Upper Huronian and Lower Huronian
series,the former being the principalproducer. In the Menomineedistrictthe formationis of Upper Huronian age.
The iron-formations of the different districts and ages are
8, 36, 43, 45, 46 and 47 and the Twenty-First Annual Report'by R. D. Irving
and C. R. Van Hise, or under Dr. Van Hise's direction by W. S. Bayley,
J. Morgan Clements, H. L. Smyth, C. K. Leith and others. It covers also
work done sincethe publicationof these reports. The general geologyof the
ores and ore-bearing series is summarized by the writer in Vol. XXXVI. of
the Transactionsof the 4raercanInstitute of Mining Engineers. Parts of
that summary are quoted in the present paper.]
47
48
CHARLES KENNETH
LEITH
It may be emphasized
that almostthe entirebulk of the ironformation now consistsof iron oxide and silica, with carbonates
chemically,
or both,givesall of the rocktypesabovelisted.
THE
ORIGINAL
ROCKS.
subordinate
amounts
of iron carbonate.
In the Felch
GENESIS
OF LAKE
SUPERIOR
IRON
ORES
49
vast
scale on which
the alteration
of
ferrous
silicate
of iron carbonate as
originaland secondary
iron carbonateand pseudomorphs
after
greenaliteare foundsowell exposed
and socloselyassociated
in
distributionthat it is hopedthat the studyof this districtnow
in progress
mayfurnishdecisive
evidence
of the realrelations
of
these two substances.
clearthattheyarenotwater-deposited
sediments
of an ordinary
nature. They are not fragmental;their nearestanalogues
are
chemical sediments, such as limestones.
CH/IRLES
50
KENNETH
LEITH
It is...
my belief that the iron for the iron-bearing formations was
largely derived from the more ancient basicvolcanic rocks of the Lake Superior
region. When the individual districts are taken up it will be seenthai a greenstone, often ellipsoidal, in many places porous and amygdaloidal, in many
places schistose, and rich in iron, is the most characteristic rock of the
Archcan, and that similar rocks occur abundantly in the Huronian. Where
these igneous rocks were adjacent to the seas they would be leached'by the
underground-water and the iron transported to the adjacent seas. It is probable that to some extent this leaching processalso went on below the waters
of the sea. The iron was probably transported to the water mainly as carbonate, but to some extent as sulphate. The carbonate would there be
thrown down by oxidation and hydration as limonite, and the sulphate in
part as basic ferric sulphate. Much of the sulphate was probably directly
precipitated as sulphide by the organic material. The limonite would be
mingled with the organic matter which was undoubfedlypresent, as shown
by the associatedcarbonaceousand graphitic shalesand slates. When deeply
buried the organic matter would reduce the iron sesquioxideto iron protoxide.
By the simultaneous decompositionof the organic matter carbon dioxide
be reduced
to thesulphide
by theorganicmaterial,thusproducing
thepyric
carbonates. Where the iron was brought to the water mainly as sulphatethe
direct reduction of this salt by organic matter would form iron sulphide with
little or no carbonate. Simultaneously with the production of these substanceschert was formed, probably through the influence of organisms.
Some of this silica would unit'e with a part of the protoxide, producing
ferrous
silicate.
More
or less mechanical
sediment would
Thus the original rocks--the cherty iron carbonates,the ferrous silicate rocks,
and the pyritic cherts--would be produced.
It has chanced that at three different periods in the history of the Lake
Superior region, these processesof the developmentof the original rocks of the
iron-bearing formations have occurred extensively. While this might at first
be thought' remarkable, there is no good reason for thus regarding it. At
sometime during each of the Archcan, Lower Huronian and Upper HuronJan
periods the quiescentconditionsof chemical and organic sedimentationhave
occurred, and since the iron-bearing volcanic rocks were each time available
ganicagencies
havingtakenpart in the'development
of the
greenalitegranules.
Spurr had previouslyconcluded
them to
be entirelyof organicorigin.a (See p. 64.)
"The Penokee Iron-Bearing Series of Michigan and Wisconsin," by R. D.
Irving and C. R. Van Hise. Mon. U.S. Geol. Survey No. x9, x892,pp. 246-253.
-" The Mesabi Iron-Bearing District of Minnesota,"by C. K. Leith. Mon.
U.S. Geol. Survey No. 43, x9o3.
a ,, The Mesabi Iron-Bearing Rocks," by J. E. Spurr, Bull. Geol: and Nat.
Hist. Survey o[ Minn., No. X., x894.
GENESIS
ALTERATION
OF LAKE
SUPERIOR
IRON
ORES
OF ORIGINAL
ROCKS TO IRON-ORES,
JASPERS AND OTHER ROCKS.
51
CHERTS,
This has consistedbroadly, first, in the oxidation of the ferrous iron and recrystallizationof the chert of the original rocks
under surfaceconditionsthrough the agencyof meteoricwaters
and, second,in the partial oxidation, sillcationand recrystallization of both original and weatheredproductsunder the anamorphic conditionsof deep burial or igneousassociations. The
chemistryof the changesis summarizedin Table I. They have
beenbegunor completedin one district or horizonbeforethey
have been begun in another.
The alteration of the iron-formation, resulting in the concentration of the iron-ore or in the developmentof ferruginous
partsof thesame
district,
showconsiderable
lithological
variety.
The sameingredients--ironoxide and silica--appearhere me-
chanically
combined
as highlycrystalline
jasper,thereas a soft
ferruginouschert, or both mechanically
and chemicallycombinedas an amphibole-magnetite
schist. The iron-oxidemay
appearhereas a brilliantspecular
hematiteor magnetite,
and
thereas a softgranularhematiteor limonite. The oresof the
Mesabidistrictare soft and granularand associated
with ferruginous
cherts.At theeastendtheybecome
amphibolific,
magneffticandnon-productive.
The oresof the Gogebic
districtare
of a similarnatureandbecome
amphibolitic,
magnetiticandnon-
productive
at boththeeastandwestendsof thedistrict.The
ores of the Vermilion district are hard, blue and red ores,--at
Ely, brecciated,
associated
with jaspers.The oresof the Marquettedistrictcomprise
hardblueoresandbrilliantspecular
ores
associated
with jaspers,called"hard-orejaspers"; soft oresassociatedwith ferruginouscherts,or "soft-ore jaspers"; and with
underlyinglates,and at the west end of the district magnetite
and specularhematite ores associatedwith jaspers and with
amphibole-magnetite
rocks.
52
CHARLES
KENNETH
LEITH
Without going into the variableconditionsin the severaldistricts and the varying geologicalhistory of the different ores
and rocks,it may be said that, so far as the alterationof the
iron-formationhas proceededcontinuouslyunder the influence
of surface-waterswithout interruption by igneousactivity or
orogenicmovements,
the soft oresand ferrugnouschertshave
resulted. So far as these have been subsequentlyunder deepseatedconditionsof alteration,they havebecomedehydratedinto
burialandorogenic
movement,
the iron oxideandsilicaof the
formationcombined,with smallamountsof other substances,
to
form ferrous silicates,and the ferrous iron was oxidized to
nagnetite,
makingoneof thevarietyof rocksusuallydescribed
as amphibole-magnetite
schists.
An accountof the development
of the iron oresof the Mar-
quette
district
will illustrate
thecomplexity
of thefactors
which
havedetermined
thepresent
varietyof ironformation
material.
TheMarquette
ironoresbelong
to fivegeological
horizons.In
thelowerandmiddlepartsof theNegaunee
formation(Middle
Huronian)theoreis principally
a softhydrated
hematite
associatedwith ferruginous
chertsor "soft orejaspers."In the
upper
partoftheNegaunee
formation
theoreislargely
a crystallinehematite,
sometimes
specular
andmagnetic,
associated
with
hardcrystalline
jasper
or "hardorejasper,"
differing
fromthe
ferruginous
chertsimply
in beingrecrystallized
anddehydrated.
At the contactof the Negauneeformationwith the overlying
Goodrichquartzite(Upper Huronian)is againhard hematite
associated
with jasper. This includes
the alteredconglomeratic
baseof the Upper Huronianseries. The ore bodiesat this
horizonare so intimatelyrelated to both Upper HuronJanand
Lower Huronian seriesas to weld them together. In the Bessie
iron formation at or near the base of the Michigamme slate
GENESIS
OF L.4KE
SUPERIOR
IRON
ORES
53
fromtheNegaunee
formation
below. Later,whenthedeposition
of themudof theMichigammeformationhadbegun,iron carbonate of the Bessieformationwas deposited,which was in turn
accompanied
with and overlaidby mud.
Up_lift.
folding,
andintrusion
ofbasic
igneous
rocks
which
acI
companied
andIollowect
sectmen{allon,
furnished
conditions
of
54
CH.4RLES
KENNETH
LEITH
constituents
with
and jasperpebbles
havebeenpartly or wholly removed,leaving
pits, while an inch or so from the surfacethesesubstances
remain.
GENESIS
OF LAKE
SUPERIOR
IRON
ORES
THE
AGENT
OF
BEARING
ALTERATION
OF
THE
IRON-
ROCKS.
Themedium
of thealteration
is water,coming
moreor less
directly from the surface,carrying oxygen and carbondioxide.
The
concentration
to occur where
such waters have been converged. Various factors have determined this convergence--fracturingand brecciationof the
iron-formation, existenceof imperviouslayers in such attitudes
as either to convergewaters coming from aboveor to impound
the waters and deflect their course between two layers. The
presenceof an impervious layer forming a pitching-trough is
perhaps
the'mostconspicuous
structural
featuredetermining
the
convergenceof waters concentratingthe ores. The impervious
troughs consist, in the Mesabi district, of slate or paint-rock
layers within the formation itself; in the Vermilion district,
of greenstone with which the iron-formation is infolded or
interbedded;in the Penokee-Gogebicdistrict, of diorite dikes
intersectinga foot-wall quartzite; in the Marquette district, of
a greenstone.intrusive into the iron-formation, or of a slate
underlying the iron-formation; in the Menomineedistrict, of
dolomiteunderlying the iron-formation, or of slate layers within
the formation itself. In all these districts, except the Mesabi,
the presenceof this imperviousbasementseemsto be clearly the
controllingfactor in the convergence
of waterswhich have concentrated
the ores.
In the Mesabi district, also, impervioustroughsmay be immore important than, other factors. The iron-formation and
its associated
rockslie in bedson the souths!opeof the Giant's
range, and dip off gently to the southat anglesaveragingfrom
8 to 'xo. In additionto the generalsouthwardtilting of the.
beds, they are gently flexed into folds with axes transverseto
the trend of the range. Waters falling on the south slope of
56
the Giant's range, and flowing to the south, enter the eroded
edgesof the iron-formationand continuetheir way down along
its layers, some of which are pervious and some of which are
slaty and comparativelyimpervious to water. The flow thus
tends to becomeconcentratedalong the axes of the synclines
which pitch gently to the southward. Such synclinesare not
necessarily
Surface-troughs.
Theyareevidenced
by theattitude
of the layers of the iron-formation,and may not be apparentin
the unequally-erodedrock-surfaceor at the surfaceof the irregular covering of glacial draft. The concentration of the flow
along the synclinesin the layers of the iron-formationseemsso
simple and evident that there is a temptation to generalizeand
say that the undergroundcirculationhas probablyconcentrated
the ores along these broad synclines. When the district was
first examinedby the U.S. GeologicalSurvey this simple explanation was applied. But further study shows that other
factorsmodify the circulationof water and the localizationof the
ore, and that thesesecondaryfactorsmay be locallydominant.
The most importantof thesemodifying factorsis the fracturing of the iron-formation which has furnished numeroustrunkchannelsfor the circulation of underground-waters. The water
hasbeenconfined
to narrow,
irregular
andmostdevious
t,p-unkchannelsformed by the fracturing of the iron-formatiofi, and,
while it has probably followed the fracture-openingsalong
synclinesto a greater extent than along anticlines, it has not
filled the entire syncline formed by the folding of the ironformation. The result is that the ores have developedalong
irregular areas within the synclines. They may occupya considerablepart of the syncline,in which casethe synclinalstructure of the iron-formation may be observedin the layers of
wall-rock adjacent to the ores. In other cases,they occupyso
small a proportion of the synclinethat the layers of the ironformation in the adjacent wall-rock give no indicationof synclinal dips. Not infrequently several more or less independent
depositsmay have developedin the samegeneralsyncline,as, for
instance,in the area adjacentto the town of Virginia. To put
it briefly,the oresshowsuchposition,irregularity,extent,and
GENESIS
OF L.4KE
SUPERIOR
IRON
ORES
57
relationsto wall-rocksas to make applicablethe expressionsometimes heard in the district that the oreshave developedthrough
certain depositson the range which have their longer dimensionsparallelto the strikeof the layersof the iron-formation.
The pondingof the water and consequent
overflow has still
anothereffect. Where pondedthe flow is governedby the point
of lowestescaperather than by the shapeof the imperviousbasement. When water is drawn off at the edgeof a basin,the flow
is greatestnear the point of escapeand diminishesin all directions away from that point. This statement is true, whether
the bottom of the basin is flat or fluted; hence, in the Mesabi
iron-formation, where the water is ponded,the flow is concen-
58
CH.4RLES KENNETH
LEITH
havedeveloped
along
arches
aswell
asinsynclines
oftheironformation.
The abovefactsare intimatelyrelatedto theproblemof finding
ore under the solid black Virginia slate. The questionis frequently asked, is there any reasonwhy ore shall not be found
under the black slate? The absence of ore under the slate has
vigorous
circuiation
is lacking
undertheVirginiaslatebecause
of the ponding,we may haveherean adequatecausefor tle nonexistence of ore-deposits under the black slate. Yet, further
workmayhow
thatother
'actorsavnd,
consider-
GENESIS
OF LAKE
SUPERIOR
IRON
ORES
59
RELATIONS
OF THE
ORES.
With veryfewexceptions,
theore-deposits'
of theLakeSuperior regionlie eitheron the slopesor at the foot of conspicuous
rangesor hills. This has been explainedby Van Hise as due
to the concentration
of oresthrough the circulationof groundwaters. Topographicelevationshave given the waters sufficient
headto searchthe groundon their slopesand perhapsat the base
of the slopes. On the slopesthe movement of the water is
largelydo;nwardand more or lessdirectfrom the surface,thus
carrying an abundanceof altering agents,particularlyoxygen
and carbon diox!de, while in interveninglow-lying areas the
watersescapewith a lateraland upwardmovementafter a longer
underground-journey,
during which they have lost considerable
proportionsof the agents altering the iron-formation to ores.
Van I-tisehasheldthat, in the latter positions,theoreshavenotdelveloped
soabundantlyas on the slopes. The presenttopography
60
CHARLES
KENNETH
LEITH
FOR
WHICH
MORE
EVIDENCE
IS NEEDED.
iron carbonate'
andgreenalite
sutcientto preclude
ttlepossibility
that a part of the ores may have been originally depositedas
hydrated hematitein chemicalor organic sediment? The evidencethat the Lake Superior ores developedfrom the alteration
of ferrous compoundsof iron carbonate,or iron silicate (greenalite), or iron sulphide,is in briefestoutline as follows:
I. Completegradation may be observedbetween iron carbonateor greenaliteor iron sulphideon the one hand and iron
ore and associated
The
former
are un-
going reasonsthat the connectinggradationsrepresentalterations from the former toward the latter.
from them. The granular texturesof the greenaliterockspersistthroughthe ore and ferruginouschert. The bandingof the
iron carbonatesoften persistslikewise. These textures appear
mostconspicuously
and abundantlyin the lessalteredportionsof
the formation and may be entirely lacking in the more altered
portions,in which casesit is concluded
that the absenceof distinguishingtexturesis due simplyto the metamorphism.If due
GENESIS
OF LAKE
SUPERIOR
IRON
ORES
6I
are foundto die out at no very great depth. They are essentially
surface phenomena. If depositedoriginally as iron oxide in
sedimentarysuccession,
the depositsshouldbe found not only at
the 'erosionsurface,but uniformly throughoutits stratigraphic
horizon along anticlinesand synclinesto whatever depth this
may take them.
62
CHARLES
KENNETH
LEITH
or iron silicate.
stratification.
3. The physicalconditionsof the districtat the time the formation was depositedwere favorable for the formation of such
shallow water depositsas iron ore, as evidencedby the presence
of sun cracks and carbonaceousmaterial and rapid alternation
of the strata of the iron-formation.
lithologically,
asare the Lake SuperiorandBaraboodistricts,the
63
What is therelativeimportance
o[ transportation
anddeposition
oleiron compounds
and the leachingo[ silicain concentration
of
ore? The concentrationof iron ore involvesthe transportation
and depositionof iron saltsand the removal of silica. That iron is
actuallytransportedin solutionand depositedis shownby its replacementof other substances,the former presenceof which is
recognizedby its textures, by the occurrenceof iron oxide in
veins, by the structural relationsof the iron ore to the surrounding rocks, and by laboratory experiment. That silica has been
compounds
have largely disappeared
and solutionsare acting
uponthe oxidizedcompounds,
as is the casetoday in most
64
65
elements in
of the Lake
Su-
theirdevelopment
arestillnotquantitatively
knownandqualitatively only partly, and until they are known it will be difficultto
determineto what extent, if any, they have enteredinto the developmentof the homogeneous
granulesof the Mesabi and Clinton formations.
Issociationo[ iron-[orrna.
tion with slate. The usualconformable association
of iron-formation
with
thick
slate formations
66
CHARLES
KENNETH
LEITH
General.
It seems
probable
thatmost
oftheprincipal
factors