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Crude oil often contains water, inorganic salts, suspended solids and water-soluble trace metals. The first
step in the refining process is to remove these contaminants by desalting (dehydration) in order to reduce
corrosion, plugging and fouling of equipment, and to prevent poisoning the catalysts in processing units.
ATMOSPHERIC DISTILATION
Crude oil distillation is used to separate the hydrocarbons in crude oil into fractions based on their boiling
points. These fractions are later distributed to other units, for further processing for quality enhancement.
VACUUM DISTILATION
Vacuum distillation towers provide the reduced pressure required to prevent thermal cracking when
distilling the residuum from the atmospheric tower at higher temperatures.
CATALYTIC CRACKING
It cracks the heavier, higher-boiling-point petroleum fractions into more valuable products such as gaseous
hydrocarbons (unsaturated gases), gasoline, gas oil and fuel oil.
-increase the quality and quantity of lighter, more desirable products and decrease the amount of residuals
The purpose of the FCC is to increase the quantity of lighter more valuable products, by cracking the heavy
petroleum fractions intro more valuable products (in a fluidized catalytic).
It has the purpose to convert the vacuum gas oils into more valuable products (desirable)
COKER
It has the purpose to convert the residual oil from the vacuum distillation column into low molecular weight
hydrocarbon gases, naphtha, light and heavy gas oils, and petroleum coke. The process thermally cracks
the long chain hydrocarbon molecules in the residual oil feed into shorter chain molecules.
It has the purpose to convert the residual oil from the vacuum distillation column into more valuable
products.
SCOP
Parametrii
Materii Prime
Produse Obtinute
Catalizatori
Desalinare
T= 140
P= 14
Titei brut
Titei desalinat
DA
T= 360
P= 1
DV
T= 400
P= 0.05-0.1
Pacura de DA
HB
T= 300
P= 40
Ni-Mo/ alumina
Exoterma
RC
T= 480-520
P=10-14
Benzina hidrofinata
Pl / alumina
Endoterma
HPM
T= 330-380
P=40-50
Ni-Co-Mo/ alumina
Exoterma
HDV
T= 350-380
P=50-60
Ni-Co-Mo/ alumina
Exoterma
Izom
T= 160-220
P=30
Izomerizat, LPG
Pl / Zeolit
Usor endoterma
FCC
T=520-530
P=2-3
Zeoliti (alumino
silicati cristalini)
Endoterma
GasCon
T= 30-40
P=15
Merox
T= 40
P=24
Fr.C3C4 // B stab
cat p baza de Co
T=
P=30-10
Fr.C2C5(HB,RC,DAV)
(hb si dav la tratare)
CX
T= 480-510
P=3-4
Rezidiu de vid
DGRS
T= 1100-1300
P=1
TiO2/ alumina
Exoterme
Fabrica de
H2
T= 480-800 (i-e)
P= 15
CH4, H2O
1. Ni / alumina
2. Oxid de Fe si Cr
Endot: ch4+h2o=co+h2
Exot: co+h20=co2+h2
Mtbe tame
T=50
P=15
Ic4, metanol
MTBE, LPG
Rasini schimbat de
ioni
Exoterma, in faza
condensta.
FGR
Scindare= endoterma
Aditie,substit= exoterma
Endoterma
PURPOSE
Desalting
AD (CDU)
VD
Nph-HDS
Platforming
Parameters
Feedstocks
Products
Catalyst
Pl / alumina
Kero-GO
Hydrotreating
Ni-Co-Mo/ alumina
VD HDT
Ni-Co-Mo/ alumina
Isomerisation
FCC
GasCon
Merox
Pl / Zeolit
Desulfan
Saturate
Gas Plant
Coker
MTBE
SRU
(Amine
treating)
H2 Plant
Hydrocracking
1-reactie reformer
2-reactie converter
Reformeaza aburul
Conver CO la CO2