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INVESTIGATION ON WATER
WAYS SUBSTANCES DISSOLVE & CHANGES THAT OCCUR TO PARTICLE ARRANGEMENT
SODIUM CHLORIDE (SOLUBLE IONIC COMPOUND)
Sodium Chloride, more commonly referred to as salt or table salt, is used in various foods
and medical treatments. Sodium Chloride is a compound which is made of two elements;
a Sodium cation (Na+) and a Chlorine anion (Cl-). As Chlorine is more
electronegative on the period table than Sodium, it attracts more electrons thus is
more negatively charged than Sodium (Fig 1.1). Chlorines electronegativity and
higher charge attracts the bonding pair of electrons more
Figure 1.1
strongly, making the molecule of Sodium Chloride polar.
The composition of Sodium Chloride is connected by an
ionic bond, as sodium is a metal and chlorine is a non-metal.
The dissolving process of Salt is shown by the following balanced equation:
2Na(s) + 2H2O 2NaOH (aq) + H2 (g), or Sodium Chloride + Water Sodium
Hydroxide + Hydrogen
Sodium Chlorides polarity, due to its alternating sodium cations and chloride anions
and waters polarity, following the principle of like dissolves like, causes a reaction
between Sodium Chloride and Water. Water is polar as it has an uneven charge
distribution. As a result of oxygens electronegativity, the oxygen element in the water
molecule is slightly more negative as it attracts the electrons which exist in the
hydrogen part of water, making Hydrogen positive. Waters polarity or uneven charge
distribution allows it to react with Sodium Chloride as the oxygen anions attract the
sodium cations available in the sodium chloride. Similarly, the hydrogen cations attract
the chloride anions. These two negative and positive relationships between Sodium
Chloride and Water allow the sodium chloride to dissolve in water, as well
as
showing a relationship between substances with like characteristics
(polarity).
Figure 1.2
Hydrogen
ions
Oxygen ions
become attached to the negative oxygen of the water molecule, and Chloride ions which are charged
negatively become attached to the positive hydrogen ions of the water molecule. The water molecules
essentially serve as barriers between the sodium and chloride ions, preventing any bonds from being
formed and separating the sodium and chloride ions, therefore making the salt dissolved. After the
first ions separate, the rest of sodium chloride dissolve, and eventually all of the salt is dissolved inside
the water.
SUCROSE (A SOLUBLE MOLECUL AR COMPOUND)
Sucrose, more commonly referred to as sugar, is a naturally occurring carbohydrate found in many
plants and plant parts. Sucrose is a compound made of three elements; Carbon, Hydrogen, and
Oxygen. Sucrose has oxygen atoms bonded to hydrogen atoms, or in other words; O-H Bonds. Due to
oxygens electronegativity, its areas are slightly more negative, while hydrogen ions are slightly more
positive, thus, O-H bonds are polar themselves. O-H bonds possess strong attractions as they are a
hydrogen bond; they have dipole-dipole attractions among Oxygen atoms in one molecule and
Hydrogen atoms in a neighbouring molecule. As a result of their O-H groups, they are able to dissolve in
water. Due to the polarity of its bonds and overall the molecule, Sucrose is a polar substance.
The dissolving process of Sucrose cannot be shown through an equation, as sugar, unlike salt, does not
disassociate into ions, rather it splits up into individual molecules of sugar, becoming aqueous.
C12H22O11 (s) --------> C12H22O11 (aq)
Similarly to salt, Sucrose is a polar substance; it dissolves
with water. Using the principle of like dissolves like,
sucrose is soluble in water due to its O-H groups, which
make them polar. The characteristic of Sucrose being polar
is the main reason of why sucrose is able to be dissolved
into water. As a result of Sucroses uneven electron
distribution and its polar nature, it is made up of positive
and negative molecules, and possesses a charge. The water
molecules and their hydrogen cations & oxygen anions are
(2.1) Basic structure of a Sucrose
attracted to Sucrose when they come in contact. Sucroses
crystal, as shown, there are many
main composition its many O-H bonds (fig. 2.1), are
O-H Groups which make up the
attracted to the ions in water. Adding water to Sucrose will
molecule.
break the hydrogen bonds which hold sucrose molecules
together, but not the covalent bonds which make up the sucrose molecule itself. The breaking of
sucrose molecules will cause them to be on their own (away from the crystal), in turn, they will react
with water, forming new hydrogen bonds with the water molecules. In figure 2.2, it is shown that the
polar water molecules are attracted the hydrogen and oxygen groups present in the sugar molecule.
These polar water molecules surround these sugar molecules and are carried off into the rest of the
aqueous solution.
During the breaking down of Sucrose into individual molecules, the water surrounds the sucrose
molecules, replacing the sucrosesucrose Hydrogen bonds with sucrosewater Hydrogen bonds. The reason water is
able
to break down these bonds is due to the
relative weakness of sucrose-sucrose
intermolecular forces compared to
sucrose-water intermolecular forces.
The strength of sucrose-water forces,
which are stronger than the original
forces in a sucrose crystal, allows
sucrose molecules to be separated
and
become attached to water molecules.
These
sucrose molecules leave the surface of
the crystal and disperse themselves
as
hydrated sucrose molecules.
Essentially, Sucrose dissolves into water by breaking itself
down into single sucrose molecules as a result of its reaction
with water the breaking down of weaker intermolecular
forces between sucrose-sucrose, and creating new, stronger
hydrogen bonds between sucrose-water. After the dissolving
of the first sucrose molecule, this process is repeatedly done
until there are no more sucrose molecules to be dissolved.
Thus, we have sucrose dissolved in water.
atom (Fig 4.1). Silicon Dioxides tetrahedral & covalent network cause the covalent bonds between the
Si-O bonds to be very strong, but weak intermolecular forces which can be broken.
As Silicon Dioxide possesses a non-polar nature, is it unable to dissolve in water which is polar. This is
due to the lack of atttraction between the polar water molecules and the silicon or oxygen atoms,
which, if there was an attraction would allow water molecules to overcome the covalent bonds in Silicon
Dioxide. Like Iodide, Silicon Dioxide still has a reaction, but does not dissolve, making the mixture of
Silicon Dioxide and water to be in dynamic equilibrium. The following equation sums the reaction up,
where Silicon Dioxide and Water reacts to create silicic acid, and silicic acid is continuously dissolving:
SiO2(s) + 2 H2O(l) <-> H4SiO4(s) or Silicon Dioxide + Water <-> Silicic Acid
The above equation demonstrates that the Silicon Dioxide is continuously being dissolved and turned
back into a solid at the same rate; precipitation rate = dissolving rate. At an atomic level, Silicon
Dioxide molecules are being dissolved and attaching themselves back to the original covalent network
substance of Silicon Dioxide. Due to Silicas giant molecule and large amount of covalent bonds in a
crystalline lattice structure, Silica cannot fully dissolve into water. Solubility is generally measured in
relation to the bond strength in the solvent and the solute, which is, in this case, respectively water and
Silica. The extensive network of covalent bonds and their strengths are much stronger than the
hydrogen bonds in water, therefore Silicon Dioxide is unable to be broken down from its crystal lattice
by water and form aqueous ions, making it insoluble.
Thus, we say that Cellulose is insoluble. However, although it doesnt dissolve, the structure of the
large molecule can be broken down by the water.
REL ATIONSHIP BETWEEN THE SOLUBILITY OF SUBSTANCES IN WATER AND THE POL AR
NATURE OF THE WATER MOLECULE
The polarity of a molecule is defined by whether its ends form electrical poles. For example, Water, one
of the most polar substances, has a positive end, and a negative end; the positive hydrogen ions and
negative oxygen ion form an electrical pole. A non-polar molecule does not have charges at the ends,
as electrons are distributed symmetrically and equally.
In reference to solubility, the principle of like dissolves like is used. Non-polar substances, such as
Kerosene, are insoluble with polar substances such as water. As a reference to the
compounds/elements in this report, polar substances such as Sucrose, Sodium Chloride are soluble in
water, while non-polar substances such as Silicon Dioxide are insoluble in water.
In the process of dissolution, the particles of a solute e.g. salt, separate from their neighbours (the
other ions in the compound) and move in between the spaces of the solvent particles. In this case, as
water dissolves salt, the separated salt ions; the cation Na and anion Cl, become attracted to the ions
of the water, that is, they become surrounded as water creates a hydration shell around the ion,
separating them from the substance. Here is a following diagram for a clearer understanding:
At the start of the dissolving process, the solute
still exists as one solid; that is, the particles are
still all together as one crystal or compound.
After water comes in contact with the
substance, the solute then separates its ions,
becoming surrounded by the solvent, and thus
becoming dissolved into the solute. In water,
polar molecules dissolve by overcoming their
bonds with water molecules, then the water molecules create new hydrogen bonds.
The forces of attraction which once kept the solute together are broken by the water molecules, and
new bonds are formed between the solvent and a solute.
The polar nature of a water molecule is defined by having an oxygen anion and hydrogen cations, as
well as an unequal distribution of electrons; that is, the ends of the ions have charges. The ions within a
polar molecule are determined their charge by its electronegativity. In water, as oxygen is more
electronegative than hydrogen, oxygen is slightly more negative as it attracts the electrons which are
present on hydrogen, this then makes hydrogen slightly positive. As the water molecule has positive
and negative ends, the solute in which it reacts with is dissolved through these bonds. Substances such
as sodium chloride are polar as well due to having negative and positive ends.
During a preliminary chemistry class, an experiment was conducted to determine what types of
substances are soluble in water. The following are a few results from the practical which were soluble in
the substances.
Dissolved
By
Substance
Polar/Non-Polar
Soluble?
Water(P)
Sodium Chloride
Polar
Yes
Water(P)
Iodine
Non Polar
No, Partially
Water(P)
Sucrose
Polar
Yes
Kerosene(
NP)
Iodine
Non Polar
Yes
Kerosene(
NP)
Sodium Chloride
Polar
Not
Kerosene(
NP)
Sucrose
Polar (?)
Yes
Kerosene
Non Polar
No
Water(P)
As shown in the results, polar substances are more soluble with water, while Kerosene is more soluble
with non-polar substances.
Therefore, the solubility of substances in water and the polar nature of water is directly related. The
polar nature of water allows it to be soluble with other polar substances which have a charge. In the
case of Sodium Chloride, water is able to dissolve Sodium Chloride as it is able to separate the solutes
particles and create hydration shells around it, along with the electronegativity of Sodium and positivity
of Chloride which attract the Hydrogen and Oxygen ions in water.
which are recommended by the Chemistry teacher, served to be great sources of sites
which would allow an allocation of clear and reliable information.
If I were to repeat this collection of information, I would look for more reliable sources
such as government sites and textbooks which would ensure my information to be
correct.
Link
Typ
e
Auth
or
Date
Acces
sed
Title
Site/Book
N/A
Dat
e
Writ
ten
N/A
https://www.chem.wi
sc.edu/deptfiles/genc
hem/sstutorial/Text7/
Tx75/tx75.html
http://www.lenntech.
com/periodic/water/s
odium/sodium-andwater.htm
http://preparatoryche
mistry.com/NaCl_flas
h.htm
http://study.com/acad
emy/lesson/what-issodium-chloridedefinition-structureformula.html
https://en.wikipedia.o
rg/wiki/Sucrose
http://www.middlesch
oolchemistry.com/les
sonplans/chapter5/le
sson4
http://socratic.org/qu
estions/how-do-polarcovalent-bondsdissolve-in-water
http://chemed.chem.
purdue.edu/genchem
/topicreview/bp/ch18/
soluble.php
http://chemistry.elmh
urst.edu/vchembook/
150Anpcovalent.html
http://web.mst.edu/~
gbert/ANIMATED/Asol
y.HTML
Site
29/8
Chem Wisc
Interactions
of
Water
Molecules;
Electrolytes
Nonelectrolytes
Site
N/A
N/A
29/8
Lenntech
Site
Mark
Bisho
p
John
Willia
ms
N/A
29/8
An Introduction
to Chemistry
N/A
29/8
Study.com
Site
N/A
N/A
29/8
Wikipedia
Sucrose
Site
N/A
N/A
29/8
ACS
Chemistry
Life
Site
Ernes
t Z.
29/8
Socratic
Site
N/A
Jun
29,
201
4
N/A
30/8
Bodner
Research Web
Solubility
Site
N/A
N/A
30/8
Elmhurst
Site
N/A
N/A
30/8
Dissolution
Site
Danie
l
M.
Dobki
n
N/A
30/8
Educational
Technology
at
University
of
Missouri-Rolla
Enigmatic
Consulting
http://www.enigmatic
consulting.com/semic
onductor_processing/
CVD_Fundamentals/fil
ms/SiO2_properties.h
tml
http://chemistryform
e.wikispaces.com/Sili
con+Dioxide
http://antoine.frostbu
rg.edu/chem/senese/
101/consumer/faq/wh
at-is-cellulose.shtml
http://www.sciencecl
arified.com/CaCh/Cellulose.html
Site
N/A
30/8
ChemistryForM
e
Silicon Dioxide
Site
Preeti
&
Puja
N/A
N/A
31/8
General
Chemistry
Online!
What is cellulose?
Site
N/A
N/A
31/8
Science
Clarified
Cellulose
Site
of
For
Title of Article
(if applicable)
wi
a
Silicon Dioxide:
Applications
bon
Properties
http://www.encyclope
dia.com/topic/cellulos
e.aspx#1
http://www1.lsbu.ac.
uk/water/cellulose.ht
ml
Site
N/A
N/A
31/8
Encyclopedia
Cellulose
Site
N/A
31/8
Water Structure
and Science
Cellulose
http://www.chemguid
e.co.uk/analysis/chro
matography/paper.ht
ml
http://socratic.org/qu
estions/how-ismolecular-polarityrelated-to-solubility
Site
Marti
n
Chapli
n
N/A
N/A
31/8
ChemGuide
Paper Chromatography
Site
Ernes
t Z.
23/6
/15
31/8
Socratic
Boo
k
H.
Steph
en
Stoke
r
30/8
General,
Organic,
Biological
Chemistry
and