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NAME
STUDENT I.D
: 2013892774
EXPERIMENT
DATE
: 22 SEPTEMBER 2015
SEMESTER
:5
GROUP
:A
PROGRAM
: EH221
SUBMIT TO
: DR RAHIDA WATI
No.
Title
Procedure
20
20
Workbook
30
30
TOTAL MARKS
Marks
100
Remarks:
Checked by:
Rechecked by:
-------------------------------
-------------------------------
Date:
Date:
PROCEDURE
1. First, a new ICON project is started by selecting New Project button.
2. Then, a property packaged window will appear:
All Property Package from the Chemical System Categories is shown at the
window
Then, the
Advanced
Peng-Robinson
property
package
for
the
WORKBOOK
Streams Summary
Name
FEED
LIQUID-IN
S2
S3
SEPARATOR.Liq0
CONDENSER.Out
VALVE.Out
VALVE.In
SEPARATOR.In
Description
Upstream Op
Downstream Op
VapFrac
T [C]
P [kPa]
MoleFlow/Composition
CONDENSER.In
1.00
0.00
0.96916
0.97879
143.6
122.0
137.5
122.0
1724.00
1034.00
1724.00
1034.00
Fraction
kmol/h
Fraction
kmol/h
Fraction
kmol/h
Fraction
kmol/h
AMMONIA
0.80884
3668.91
0.1779
17.11
0.80884
3668.91
0.80884
3668.91
WATER
0.19116
867.09
0.8221
79.09
0.19116
867.09
0.19116
867.09
1.00
4536.00
1.00
96.20
1.00
4536.00
1.00
4536.00
Total
Mass Flow [kg/h]
78104.46
1716.30
78104.46
78104.46
8439.308
1.985
8040.314
13380.449
117.134
1.900
117.134
117.134
2.579E+6
5.4699E+4
2.579E+6
2.579E+6
Energy [W]
1.725E+7
-6.581E+5
1.555E+7
1.555E+7
H [kJ/kmol]
13691.4
-24627.5
12342.2
12342.2
S [kJ/kmol-K]
182.451
97.947
179.186
183.084
17.22
17.84
17.22
17.22
9.2548
864.6381
9.7141
5.8372
Cp [kJ/kmol-K]
41.584
87.876
43.115
40.913
0.0399
0.5581
0.0552
0.0479
1.4343E-5
1.6602E-4
1.5511E-5
1.4571E-5
1.861
0.021
1.773
2.950
0.9298
0.0077
0.8991
0.9310
MW
Viscosity [Pa-s]
Molar Volume [m3/kmol]
Z Factor
Surface Tension
Speed of Sound
Name
VAPOR-OUT
Description
Upstream Op
SEPARATOR.Vap
Downstream Op
VapFrac
T [C]
P [kPa]
MoleFlow/Composition
1.00
122.0
1034.00
Fraction
kmol/h
AMMONIA
0.82251
3651.79
WATER
0.17749
788.00
1.00
4439.80
Total
Mass Flow [kg/h]
Volume Flow [m3/h]
Std Liq Volume Flow [m3/h]
Std Gas Volume Flow [Sm3/d]
76388.16
13378.464
115.234
2.5243E+6
Energy [W]
1.621E+7
H [kJ/kmol]
13143.3
S [kJ/kmol-K]
184.929
MW
17.21
5.7098
Cp [kJ/kmol-K]
39.895
0.0364
Viscosity [Pa-s]
Molar Volume [m3/kmol]
Z Factor
Surface Tension
Speed of Sound
1.3542E-5
3.013
0.9510
Name
COOL-OUT
FEED
LIQUID-OUT
VALVE-OUT
SEPARATOR.Liq0
VALVE.Out
Description
Upstream Op
CONDENSER.Out
Downstream Op
VapFrac
T [C]
P [kPa]
MoleFlow/Composition
VALVE.In
CONDENSER.In
SEPARATOR.In
0.97552
1.00
0.00
0.98996
133.0
143.6
118.5
118.5
1724.00
1724.00
1034.00
1034.00
Fraction
kmol/h
Fraction
kmol/h
Fraction
kmol/h
Fraction
kmol/h
AMMONIA
0.80884
3668.91
0.80884
3668.91
0.0075
0.34
0.80884
3668.91
WATER
0.19116
867.09
0.19116
867.09
0.9925
45.22
0.19116
867.09
1.00
4536.00
1.00
4536.00
1.00
45.56
1.00
4536.00
Total
Mass Flow [kg/h]
78104.46
78104.46
820.39
78104.46
8670.349
9116.787
0.877
14143.544
117.134
117.134
0.825
117.134
2.579E+6
2.579E+6
2.5902E+4
2.579E+6
Energy [W]
1.650E+7
1.820E+7
-3.359E+5
1.650E+7
H [kJ/kmol]
13092.0
14441.2
-26543.5
13092.0
S [kJ/kmol-K]
180.609
183.679
98.969
184.616
17.22
17.22
18.01
17.22
9.0082
8.5671
935.3494
5.5223
Cp [kJ/kmol-K]
39.270
38.242
86.212
38.137
0.0555
0.0399
0.6780
0.0428
1.5309E-5
1.4343E-5
2.3227E-4
1.3979E-5
MW
Viscosity [Pa-s]
Molar Volume [m3/kmol]
Z Factor
Surface Tension
Speed of Sound
1.911
2.010
0.019
3.118
0.9758
1.0000
0.0061
0.9900
Name
VAPOR-OUT
Description
Upstream Op
SEPARATOR.Vap
Downstream Op
VapFrac
T [C]
P [kPa]
MoleFlow/Composition
1.00
118.5
1034.00
Fraction
kmol/h
AMMONIA
0.81697
3668.57
WATER
0.18303
821.88
1.00
4490.44
Total
Mass Flow [kg/h]
Volume Flow [m3/h]
Std Liq Volume Flow [m3/h]
Std Gas Volume Flow [Sm3/d]
77284.08
14142.667
116.309
2.5531E+6
Energy [W]
1.683E+7
H [kJ/kmol]
13494.1
S [kJ/kmol-K]
185.485
MW
17.21
5.4646
Cp [kJ/kmol-K]
37.649
0.0361
Viscosity [Pa-s]
Molar Volume [m3/kmol]
Z Factor
Surface Tension
Speed of Sound
1.3410E-5
3.150
1.0000
Name
COOL-OUT
FEED
LIQUID-OUT
VALVE-OUT
SEPARATOR.Liq0
VALVE.Out
Description
Upstream Op
CONDENSER.Out
Downstream Op
VapFrac
T [C]
P [kPa]
MoleFlow/Composition
VALVE.In
CONDENSER.In
SEPARATOR.In
0.97553
1.00
0.00
0.98996
133.0
143.6
118.5
118.5
1724.00
1724.00
1034.00
1034.00
Fraction
kmol/h
Fraction
kmol/h
Fraction
kmol/h
Fraction
kmol/h
AMMONIA
0.80884
3668.91
0.80884
3668.91
0.0075
0.34
0.80884
3668.91
WATER
0.19116
867.09
0.19116
867.09
0.9925
45.21
0.19116
867.09
1.00
4536.00
1.00
4536.00
1.00
45.55
1.00
4536.00
Total
Mass Flow [kg/h]
78104.46
78104.46
820.25
78104.46
8670.289
9116.787
0.877
14143.504
117.134
117.134
0.825
117.134
2.579E+6
2.579E+6
2.5898E+4
2.579E+6
Energy [W]
1.650E+7
1.820E+7
-3.358E+5
1.650E+7
H [kJ/kmol]
13092.0
14441.2
-26543.7
13092.0
S [kJ/kmol-K]
180.609
183.679
98.969
184.616
17.22
17.22
18.01
17.22
9.0083
8.5671
935.3511
5.5223
Cp [kJ/kmol-K]
39.269
38.242
86.211
38.137
0.0555
0.0399
0.6780
0.0428
1.5309E-5
1.4343E-5
2.3228E-4
1.3979E-5
MW
Viscosity [Pa-s]
Molar Volume [m3/kmol]
Z Factor
Surface Tension
Speed of Sound
1.911
2.010
0.019
3.118
0.9758
1.0000
0.0061
0.9900
Name
VAPOR-OUT
Description
Upstream Op
SEPARATOR.Vap
Downstream Op
VapFrac
T [C]
P [kPa]
MoleFlow/Composition
1.00
118.5
1034.00
Fraction
kmol/h
AMMONIA
0.81697
3668.57
WATER
0.18303
821.88
1.00
4490.45
Total
Mass Flow [kg/h]
Volume Flow [m3/h]
Std Liq Volume Flow [m3/h]
Std Gas Volume Flow [Sm3/d]
77284.22
14142.627
116.309
2.5531E+6
Energy [W]
1.683E+7
H [kJ/kmol]
13494.0
S [kJ/kmol-K]
185.485
MW
17.21
5.4646
Cp [kJ/kmol-K]
37.649
0.0361
Viscosity [Pa-s]
Molar Volume [m3/kmol]
Z Factor
Surface Tension
Speed of Sound
1.3410E-5
3.149
1.0000
: 137.5 oC
Wilson
: 133.0 oC
UNIQUAC
: 133.0 oC
2) What are the mole fractions for ammonia and water in the vapor and liquid stream of
the separator?
Advanced Peng-Robinson
Vapor
Liquid
Water
0.17749
0.8221
Ammonia
0.82251
0.1779
Vapor
Liquid
Water
0.18303
0.9925
Ammonia
0.81697
0.0075
Vapor
Liquid
Water
0.18303
0.9925
Ammonia
0.81697
0.0075
Wilson
UNIQUAC
3) Determine the mass flow rate for each outlet stream of the separator.
Vapor (kg/hr)
Liquid(kg/hr)
Advanced Peng-Robinson
76388.16
1716.30
Wilson
77284.08
820.39
UNIQUAC
77284.22
820.25
DISCUSSION
This experiment shows the simulation of separatin between ammonia and water by
using ICON simulation software. The Thermodynamci Model used for this simulation is
Advanced Peng-Robinson, Wilson and UNIQUAC. Different types of model give different
result thus help for understanding better the effect of models on the calculation and the
output result. This simulation also had been done to understand the usage of condenser and
valve for the process as well as the separation process itself.
The process was began by passing through the mixture of ammonia and water as
feed at 143.6 0C and 1724 kPa. The feed is passed through the condenser with the flow rate
of 4536 kgmole/hr and contains 80 wt% ammonia and 20 wt% water. Then, the heat of 1700
kW was removed by using cooler. The temperature of the system will decrease because the
heat is being relaesed. Then, the controlling valve help to reduce the pressure of the process
as the outlet pressure of the valve have decreased to 1034 kPa. Finally, the mixture is being
fed to flash vessel to enable the separation process to separate the mixture of vapor and
liquid.
The thermodynamics models is also known as equation of state. Itis an equation that
describe state of matter in a specific physical conditions. There are many type of
thermodynamics model and it is widely used in industry. The thermodynamic model is differ
based on its usage so the selection for suitable model is needed for every system. The
selection for the suitable thermodynamic model is fundamental to process modelling. The
suitable selection of models will give more accurate results.
Advenced Peng-Robinson is developed from Peng-Robinson equation of state and
this model introduce a flexible attractive temperature dependent term for accurate PVT and
saturation property related to polar compound. The resulting output temperature and
pressure from the Advanced Peng-Robinson model is 1220C and 1034 kPa. The
temperature has been dropped from 143.60Cdue to the usage of cooler and the pressure is
also decreased from 1724 kPa. The product is expected to contains more water than
ammonia in liquid stream and vice versa for vapor stream. The mole fraction of ammonia in
output liquid stream is 0.1779 and 0.82251 in outlet vapor stream.
Wilson model is widely used in industrial aplication for the prediction of phase
equilibrium. Wilson equation is not suitable for LLE and the system with limited miscibility.
Wilson equation is most suitable for binary and multicomponent VLE calculation. The outlet
temperature and pressure calculated using Wilson equation is 118.5 0C and 1034 kPa
respectively. The product composition for ammonia in output liquid stream is 0.0075 and
0.81697 for outlet vapor stream.
UNIQUAC model is an activity coefficient model used for the description of phase
equilibria. This model also known as lattice model and become the basis of the development
of the new method which is UNIFAC. In general, UNIQUAC model prediction is marginally
superior and the new model developed more simpler but this model does not require the
molecular parameter such as Van Der Waals arean and volume. The outlet temperature and
pressure calculated is 118.50C and 1034 kPa respectively. The value is same with the value
calculate by Wilson model. This is may due to UNIQUAC and Wilson model is best used for
aqueous miscible system. So, the result obtained is more accurate becauese diffewrent
model give the same value. The product composition for ammonia in output liquid stream is
0.0075 and 0.81697 for output vapor stream.
CONCLUSION
From the calculated value of different models, it can be cocluded that Advanced PengRobinson model give higher output temperature which is 1220C rather than 118.5 0C
obtained from UNIQUAC and Wilson models. Furthermore, it produce more composition of
ammonia in outlet vapor stream rather than other models. The composition for ammonia in
outlet vapor stream for Advanced Peng-Robinson is 0.88251. Finally, valve is used in this
simulation ti decrease the ppressure value and condenser is used to relaease heat and
decrease the temperature of the system. Th e objective of the simulation is completely
achieved.