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Belousov [8] , Zhabotinsky , 1964
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Oregon R. M. Noyes, Monyana R. J. Field, E. Koros BZ
FKN [18] Oregonator[19],
:
A+YX+P
X+Y2P
A+X2X+Z
2XA+P
ZfY
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Bray-Liebhafsky , Briggs-Rauscher [22], I. R. Epstein
, , [23-24], pH
[25]
1977 Texas Schmitz CSTR (Continuous Stirred Tank
Reactor) BZ [26], [27-32], 1986 H.
Swinney [33], BZ
, CSTR , ,
, , , [34]
1.1 1.2

1.1 CSTR BZ ()[35]

1964
1973
1974
1975
1976
1976-81
1978
1980
1980-2
1981-3
1985
1985-7
1986

Zhabotinsky, Vavilin Zaikin

Zhabotinsky, Vavilin Zaikin
Srensen
Marek and Svobodova, Marek and Stuechl
De Kepper et al
Graziani, Hudson, Schmitz et al
Rossler and Wegmann
Mzselko
Bordeaux-1
Texas/Roux
Hourai et al
Bordeaux-2
Maselko and Swinney
1.2 BZ

1972
1974

FKN
Field and NoyesOregonator

10

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1975-9
1978
1980
1983
1985
1987
1988
1988-9

Fieldreversible Oregonator
Edelson et al
SNBE Computation
Rossler and Wegmannmapping
Janz et alP feed back
Dekepper and BarEli
Richetti and Arneodo
Barkley et al
BarEli and Noyes
Field and Gyogyi

1987 Luis. F. Razon [36],

1990 R. M. Noyes BZ
[22,37], BZ ,

, ,
Brusselator[38-39], Oregonator, Lokta-Votterrs[40], Gray-Scott[41-43]

: (Multiple Steady State), (Relaxation Oscillation),

(Near-Sinasoidal Oscillations), , , ,
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()
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11

, (), ,
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,

(multiple stationary state), 1913 J. Taffanel C.

leFloch, 1918 Liljenroth 1928 N. N. Semenov (
) [86], 1938 , D. A. Frank-Kamenetskii
[87]
1941 , Zeldovich (CSTR)[88]Zeldovich
CSTR

CSTR: 1941 , Zeldovich ,

[88]40 K. G. Denbigh CSTR [89]60 ,
CSTR 1976 , B. F. Gray
[90] 70 , Schlogl 70 , K. F. Lin CSTR
nA+mB(m+n)B [91]80 , P.Gray S. K. Scott ,

CSTR: 1941 , Zeldovich[88],

, Y. A. Zysin ,
1954 , L. A. Vulis [92], 1967
12

 , T. Furusama [93] 70 , V.
Hlavace , [94]1974 1976 , W.
H. Ray [95,96]80 , [97]
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Vant Hoff [1] , C.
Taffanel J. le. Floch 1913
N. N. Semenov 1928 Semenov
, ,
, [2]
Semenov , ,
, Todes, Rice,
Frank-Kamenetskii , D.A. Frank-Kamenetskii
[3], 1958 ,
P. H. Thomas [4], Semenov Frank-Kamenetskii
, ,
, , P.
Gray P. R. lee [5] A. G. Mershanov F. I. Dubovitskii [6]
,
R. N. Rogers [7-9],
,
, P. H. Thomas, P. C. Bowes [10,11], P. Gray[12], A. G.
Mershanov[13], ,

, [14-16]
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15

, [21],

[22,23]

, [24],

204 , [2527]

, ()[26],
[30][31],

[29]

213 [32][33]
[34] , 1983
1988 [35],

Ya. B. Zelodvich[36],
,
, R. J. Seager[37]
, ,
, G. B. Cook[38] B. L. Hicks[39]
,
,
[40-46],
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1986 , ,
1990 , [50],
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1881 1882 Berthelot Vieille[20,21], Mallard Le
Chatelier[22],
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1949 , Eyring[27]
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Kirwood[3] ZND , ,
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CJ ,
W-K , W-K W-K ,
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; 1993 , [42],
, ,

20


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1948 , Jones[7]
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,
1981 , Cox[72] TATB ,
,
Bonthux[73] RDX PETN
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, Bartlma
Schroder[77],
, ,
1990 , [64],
1994 , [78]
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1977
1983 ,
1989,
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1975 1937 30
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1987,(1997)

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2002 5
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[ 5] IEF
1.1 IEF
IEF
IEF

, , , 1987
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, , , 1987,1989
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IEF

IEF

IEF

IEF

, , , 1992a, b
, , 1992, 1993
Lu Yun, Zhang Zhu and Zeng Hanmin, 1994
, , , 1999
, , , 1983
, , , 1998

23

 IEF

, 2003
, , , 2000
, , , 2001
, , , 1991
Lin Weipin, Yun Lu and Zeng Hanmin, 1993a, b
, , , 1995, 1996a, b
, , , 1991
, ,, 1996
Li Huanqiu and Zhou Shaoji, 1996, 1997
, , , 1995a, b, 1998

(: , , , , 2004)

[ 6] IEF
1.2 IEF
IEF

, , , 1987
, , , 1986
, , , 1987, 1988, 1993
, , 1987a, b, c
, , , 1997, 1999

, , 1987, 1988, 1993

, , , 1998, 1999
, , , 1990

24

, , 1990

, 1994
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, , , 1999a, b
, 1995
, , , 1996
, , , 1997
, , 2001a, b, c

(: , , , , 2004)

[ 7]
1.1
1 ()1)
Murota(1993)
Ozawa(1993)
Yashima(1994)
Fornasiero(1995)
Ranga(1996)
Vlaic(1997)

CexZr1-xO2
CexZr1-xO2 TWC
CexZr1-xO2 (X=0.2~0.8) tt, t,,

OSC
Hori(1998)
Jen(1999)

Putna(1999)
Gonzalez-Velasco(2000)
Rh/Ce0.5Zr0.5O2
Martinez-Arias(2000)
Bedrane(2002)
Martinez-Arias(2002)

1000, CexZr1-xO2 Pt OSC

25

Liotta(2003)

Pd CexZr1-xO2

(2003)

CexZr1-xO2
-Al2O3 (2D)CeZrO4

, Ce0.63Zr0.37O2 OSC ,

TWC CexZr1-xO2 Pd

, CexZr1-xO2 OSC
CexZr1-xO2 PdTWC

: 1) 1 ,
(: , , ,
, 2003)

[ 8]
1.1

/
(mmol-g-1)

OPO3Na2
OC2H4N(C2H5)2

0.7
1.0
3.70
<2
5.94

OPOOH2
SO3HCOOH
COOH

COOH
SO3H

N(CH3)2

7.4
3.0~4.6
3.1~4.4

/(mmol-g-1)

La,Ca:2.8

La:80~114mg-g-1

,1984
,1984
,1985
,1984
,1987
,1987
Soldatov V S,
1988
Soldatov V S,
1988

26

Toshio Yoshioka,
2.6
/
SO3H
1983, 1984

+
Toshio Yoshioka,
1.3~2.4
/ CH2N (CH3)3Cl
Pb:86~670,
1983,1984

/
:3.64
:760

1995,1997

(: , , , , 2004)

[ 9]
1.1

1997
1990
1991
1997
2000

(: , , ,
, 2004)

[ 10]
1.1

Harborne(1988a)
Harborne

1980 1988
1992 1 1994 12

1995
Harborne

1995 1 1997 12

27

1998
Merken 2000

Pietta(2000)
Harborne

1992 2000

2000
Harborne

1998 1 2000 12

2001
Moore 2002

(: , , , 200 )

[ 11]
1.2

1962
1963
1967
1970
1975
1982
1982
1986
1986
1986
1988
1988b
1989
1989
1989
1992
1994
1996

Geissman
Dean
Harbrne
Mabry
Harborne
Farkas
Harborne
Cody
Farkas
Gabor
Cody
Harborne
Agrawal
Harborne
Haslam
Hemingway
Harborne
Antus

The Chemistry of Flavonoid Compounds

Naturally Occurring Oxygen Ring Compounds
Comparative Biochemistry of the Flavonoids
The Systematic Identification of Flavonoids
The Flavonoids
Flavonoids and Bioflavonoids1981
The Flavonoids: Advance in Research
Plant Flavonoids in Biology and Medicine I
Flavonoids and Bioflavonoids 1985
The Pharmacology of Benzopyrone Derivatives
Plant Flavonoids in Biology and Medicine II
The Flavonoids
Carbon-13 NMR of Flavonoids
Methods in Plant Biochemistry, Vol 1, Plant Phenolics
Plant Polyphenols: Vegetable Tannins Revisited
Plant Polyphenols
The Flavonoids: Advance in Research since 1986
Flavonoids and Bioflavonoids 1995

28

1999

Harborne

The Handbook of Natural Flavonoids

Harborne (1991)
(: , , , , 2003)

(:,)

(1999-2004)

1. , ,
,,2004
2. , ,,
, 2004
3. , ,,
, 2003
4. , , , ,
2002
5. , , ,
, 2001
6. , , ,
, 2001
7. , , , ,
2000
8. , , ,
, 1999
9. , , ,
, 1998

1. , , . [J]. ,
2004, 24(11): 10~14
2. , , . CO [J].
, 2004, 4(4): 70~73
3. , , .
()[J]. , 2004, 4(4): 56~59
4. , , . NO [J]. , 2004, 9:
656~660
5. , , . Ce1-xZrxO2 [J]. ,
2004, 32(4): 502~506
6. , , .
() [J]. , 2004, 4(3): 81~84
7. , . .[J]. , 2004, 23(5):
476~479
8. , , , . [J].
29

, 2004, 4(2): 3~6

9. , , . [J].
, 2004, 24(3): 57~61
10. ,,,,.
,,2004,22(12):35-40
11. , , . Ce0.6Tb0.1Zr0.3O2
[J]. , 2003, 23(S1): 173~175
12. , , . [J]. , 2003,
3(5): 21~26
13. , , . NO x .
[J]. , 2003, 3(5): 27~33
14. , , , , . -Al2O3
[J]. , 2003, 3(4): 18~21
15. , , . [J].
, 2003, 20(2): 159~162
16. , , , , .
[J]. , 2003, 21(S2): 105~107
17. , , , , . CexZr1-xO2
[J]. , 2003, 20(2): 72~73,104
18. . Ce0.6Tb0.1Zr0.3O2 .
2003,4http://www.sesmag.sh.cn
19. , , , . [J].
, 2003, 15(5): 712~714
20. , , , . (PP)[J].
, 2003, 23(2): 255~259
21. , . . , 2003,
03048, http://hxtb.icas.ac.cn
22. , , , . Pd/Na2O/K2O/-Al2O3
[J]. , 2002, 10(6): 35~38
23. , , , . -Al2O3 [J].
, 2002, 10(3): 52~55
24. , , , , . Pd/CeZrO4/-Al2O3
[J]. , 2002, 25(5): 8~9
25. , , , , , .
CexZr1-xO2 [J]. , 2002, 25(4): 42~44,47
26. , , , .
[J]. , 2002, 2(5): 3~5
27. , . CO [J]. ,
2002, 2(4): 7~10
28. ..
2002, 4http://www.sesmag.sh.cn
29. , , . Pd/CexZr1-xO2/-Al2O3
[J]. , 2002, 22(S1): 95~97
30. . Pd/ CexZr1-xO2/-Al2O3
..
, 2002, 785~786
31. Chang-Gen Feng, Yu-Cai Hu , Li-Qiong Wang. Effects of CexZr1-xO2 Solid Solutions
on the Thermostability of the Pd-based Three-way catalysts. Proceedings of International
Symposium on Frontiers in Molecules Science, 79. Qingdao, China, 2002
30

32. , , , . [J].
, 2002, 22(6): 56~58
33. , , . -Al2O3 [J].
, 2002, 17(4): 891~894
34. , , . [J]. ,
2002, 20(5): 23~26
35. , . [J].
, 2002, 3(12): 89~91
36. , , , . .
, 2002, 02024, http://hxtb.icas.ac.cn
37. , , , . [J].
, 2001, S1: 27~29
38. , , , , , . Pd/CeO2 Pd CeO2
SMSI [J]. , 2001, 9(3): 20~23
39. , , , . [J]. ,
2001, 19(2): 110~115
40. , , , , , . (TWC)
[J]. , 2001, 9(5): 46~49
41. , , , , , , , . Pd/Al 2O 3 [J]. , 2001, 9(4): 21~24
42. , , , . [J].
, 2001, 9(3): 42~46
43. , , , , .
[J]. , 2001, 1: 5~7
44. , , , , . -Al2O3 [J].
, 2001, 3: 135~140
45. , , , , , . Pd/-Al2O3 Pd
[J], 2001, 21 (5): 653~657
46. , , , , , . Pd
[J]. , 2000, 8(6): 23~27
47. , , , , . [J].
, 2000, 8(5): 3~8
48. , , , , . [J].
, 2000, 8(4): 3~8
49. , , . ()[J]. ,
2000, 8(3): 7~16
50. , , . [J]. , 2000, 8(2):
3~10
51. , , , , .[J]. ,
2000, 29(2): 37~40
52. , , , , .
[J]. , 2000, 20(9): 38~41
53. , , . [J].
, 2000, 6(3): 257~262
54. , , , .
[J]. , 2000, 5: 32~35
55. , , . [J]. , 1999, 7(6): 3~7
56. , , , , . [J].
, 1999, 11: 21~23
31

57. , , , , .
[J]. , 1999, 19(5): 627~630

32