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Phosphorylation
Chapter 15
Chapter 3 (81-85)
15.1
Oxidative phosphorylation =
process by which energy released
from electron transport
(oxidations) is conserved in form
of phosphate-bond energy of ATP
electron acceptor + e- !
proton donor
electron donor
EA
Bo + e- ! Br
EB
Ao + Br ! Ar + Bo
E = EA - EB = reduction potential difference
pp. 81-83
(acceptor)
(donor)
Electrochemical cell
0.77 V
Fe3+ + e- ! Fe2+
H+ + e- ! 1/2H2
p. 82
The more
negative the
potential for a
redox pair, the
reductant has
greater tendency
to lose electrons.
The more
positive, the
reductant has less
tendency to lose
electrons.
G'= nFE'
= nF(E'acceptor E'donor )
(eqn. 15.1)
G' RT
E'=
=
ln keq
nF
nF
Ao + Br " Ar + Bo
RT [A r ][Bo ]
E = E'
ln
nF [A o ][Br ]
Variable
G
pH
E
[A r ][Bo ]
G = G' + RT ln
[A o ][Br ]
(eqn. 15.2)
Standard
=
+
term
=
=
=
G
pKa
E
Logarithmic
concentration term
RT ln
[Products]
[reactants]
[A ]
log
[HA]
RT [Ar ][Bo ]
ln
nF [Ao ][Br ]